Abstract: In a process for the separation of a stream containing carbon dioxide, water and at least one light impurity including a separation step at subambient temperature, the feed stream is compressed in a compressor comprising at least two stages to form a compressed feed stream, the compressed feed stream is purified in an adsorption unit to remove water and form a dried compressed stream, the dried compressed stream or a stream derived therefrom is cooled to a subambient temperature and separated by partial condensation and/or distillation in a separation apparatus, liquid enriched in carbon dioxide is removed from the separation apparatus, the adsorption unit is regenerated using a regeneration gas and the regeneration gas is formed by separating, by permeation in a permeation unit, the dried compressed stream or a gas derived therefrom, the permeate of the permeation unit constituting the regeneration gas.

Abstract: The invention relates to a method for separating a feed gas containing at least 20 Mol % of CO2 and at least 20 Mol % of methane, by partial condensation and/or by distillation, the gas at a pressure of at least 40 bar abs, including expanding at least one portion of the feed gas in a turbine producing an expanded feed stream at a pressure of less than 90 bar abs, separating at least one portion of the expanded feed stream by partial condensation and/or by distillation thus obtaining a CO2-depleted gas and a CO2-enriched liquid, wherein the temperature of the expanded feed gas at the outlet of the turbine is below ?56.6° C., and wherein the process does not use an external refrigeration source; and wherein the CO2-depleted gas is introduced into a supplementary separation step, in order to obtain a stream that is more depleted in CO2 and a CO2-rich stream.

Abstract: The present invention is a process for removing carbon dioxide from a compressed gas stream including cooling the compressed gas in a first heat exchanger, introducing the cooled gas into a de-sublimating heat exchanger, thereby producing a first solid carbon dioxide stream and a first carbon dioxide poor gas stream, expanding the carbon dioxide poor gas stream, thereby producing a second solid carbon dioxide stream and a second carbon dioxide poor gas stream, combining the first solid carbon dioxide stream and the second solid carbon dioxide stream, thereby producing a combined solid carbon dioxide stream, and indirectly exchanging heat between the combined solid carbon dioxide stream and the compressed gas in the first heat exchanger.

Abstract: In a process for the separation of a gas rich in carbon dioxide and containing at least one component lighter than carbon dioxide, the feed gas rich in carbon dioxide is cooled in a first heat exchanger, partially condensed and separated to form a gaseous portion and a liquid, sending the liquid portion to the top of a distillation column, removing a liquid stream richer in carbon dioxide than the feed gas from the bottom of the distillation column, removing a gaseous stream less rich in carbon dioxide than the feed gas from the top of the distillation column and warming the gaseous stream in the first heat exchanger, sending the gaseous portion to a shell and tube heat exchanger having tubes in a bath of triple point carbon dioxide, in which it condenses at least partially to form a liquid fraction, sending the liquid fraction to the top of the distillation column, vaporizing a liquid stream from the bottom of the distillation column outside or within the distillation column to form a gas which is subsequent

Abstract: The present invention is a process for removing carbon dioxide from a compressed gas stream including cooling the compressed gas in a first heat exchanger, introducing the cooled gas into a de-sublimating heat exchanger, thereby producing a first solid carbon dioxide stream and a first carbon dioxide poor gas stream, expanding the carbon dioxide poor gas stream, thereby producing a second solid carbon dioxide stream and a second carbon dioxide poor gas stream, combining the first solid carbon dioxide stream and the second solid carbon dioxide stream, thereby producing a combined solid carbon dioxide stream, and indirectly exchanging heat between the combined solid carbon dioxide stream and the compressed gas in the first heat exchanger.

Abstract: A process to produce at least carbon dioxide and carbon monoxide from a feed gas containing carbon dioxide, hydrogen and carbon monoxide; comprises separating at least part of the carbon dioxide from the compressed feed gas by partial condensation and/or distillation producing a carbon dioxide product and a carbon dioxide depleted stream, treating the carbon dioxide depleted stream in a treatment unit to produce a feed stream containing carbon monoxide and hydrogen, less rich in carbon dioxide than the carbon dioxide depleted stream and feeding at least part of the feed stream containing carbon monoxide and hydrogen to a separation unit operating at cryogenic temperatures to produce a carbon monoxide product.

Abstract: Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.

Abstract: The apparatus for liquefying a gaseous stream received from a pipeline that is comprised predominantly of ethane and a relatively small amount of other components by using a mixed refrigerant refrigeration cycle loop incorporating heavy hydrocarbons, as well as a distillation column to remove constituents lighter than ethane. Prior to cooling in a main heat exchanger, the gaseous stream is split into two fractions. The main heat exchanger is configured to cool the first fraction before heading to the distillation column for separation therein. An expansion device expands the second fraction to produce a two phase fluid, which is separated in a gas/liquid separator, with the liquid fraction being introduced to the distillation column below the first fraction, and the gas fraction being cooled and then introduced to the distillation column at a point above the first fraction.

Abstract: The process for liquefying a gaseous stream received from a pipeline that is comprised predominantly of ethane and a relatively small amount of other components by using a mixed refrigerant loop incorporating heavy hydrocarbons (butane, and/or pentane), as well as a distillation column to remove constituents lighter than ethane. Prior to cooling in a main heat exchanger, the gaseous stream is split into two fractions. The first fraction is cooled in the main heat exchanger and introduced to the distillation column. The second fraction is expanded to produce a two phase fluid, with the liquid fraction being introduced to the distillation column below the first fraction, and the gas fraction being cooled and then introduced to the distillation column at a point above the first fraction.

Abstract: This present invention provides a method to more efficiently recover hydrogen and carbon dioxide, preferably at least 50%, even more preferably at least 80% and most preferably at least 90% of the carbon dioxide. The proposed use combines hydrogen selective membranes and carbon dioxide selective membranes together with carbon dioxide separation units such that hydrogen and carbon dioxide are produced with increased recoveries and improved process efficiency.

Abstract: In a process for the separation of a gas rich in carbon dioxide and containing at least one component lighter than carbon dioxide, the feed gas rich in carbon dioxide is cooled in a first heat exchanger, partially condensed and separated to form a gaseous portion and a liquid, sending the liquid portion to the top of a distillation column, removing a liquid stream richer in carbon dioxide than the feed gas from the bottom of the distillation column, removing a gaseous stream less rich in carbon dioxide than the feed gas from the top of the distillation column and warming the gaseous stream in the first heat exchanger, sending the gaseous portion to a shell and tube heat exchanger having tubes in a bath of triple point carbon dioxide, in which it condenses at least partially to form a liquid fraction, sending the liquid fraction to the top of the distillation column, vaporizing a liquid stream from the bottom of the distillation column outside or within the distillation column to form a gas which is subsequent

Abstract: In a process for the separation of a stream containing carbon dioxide, water and at least one light impurity including a separation step at subambient temperature, the feed stream is compressed in a compressor comprising at least two stages to form a compressed feed stream, the compressed feed stream is purified in an adsorption unit to remove water and form a dried compressed stream, the dried compressed stream or a stream derived therefrom is cooled to a subambient temperature and separated by partial condensation and/or distillation in a separation apparatus, liquid enriched in carbon dioxide is removed from the separation apparatus, the adsorption unit is regenerated using a regeneration gas and the regeneration gas is formed by separating, by permeation in a permeation unit, the dried compressed stream or a gas derived therefrom, the permeate of the permeation unit constituting the regeneration gas.

Abstract: In a process for storing liquid rich in carbon dioxide in solid form and subsequently releasing liquid containing mainly carbon dioxide, a solid containing mainly carbon dioxide is formed from at least part of the liquid with or without using indirect heat exchange means, storing the solid containing mainly carbon dioxide, the process steps including subsequently causing at least part of the solid containing mainly carbon dioxide to melt forming a liquid containing mainly carbon dioxide, by direct contact with an auxiliary gas rich in carbon dioxide, wherein the auxiliary gas is at least partially liquefied to form liquid containing mainly carbon dioxide by heat exchange with the melting solid and removing at least part of the liquid containing mainly carbon dioxide.

Abstract: The present invention relates to a method for producing hydrogen, with reduced carbon dioxide emissions, from a hydrocarbon mixture. In said method, the hydrocarbon mixture is reformed so as to produce a synthetic gas that is cooled, then treated in a shift reactor so as to be enriched with H2 and CO2. Optionally dried, said mixture is treated in a PSA hydrogen purification unit in order to produce hydrogen. The residue is treated by means of partial condensation with a view to capturing CO4 before said residue is sent as fuel to reforming.

Abstract: The present invention relates to a method for the combined production of hydrogen and carbon dioxide from a hydrocarbon mixture, in which the hydrocarbon mixture is reformed to produce a syngas which is cooled, then enriched with H2 and CO2, optionally dried, and treated in a PSA hydrogen purification unit to produce hydrogen, the PSA offgas being treated to capture the CO2 and to supply an offgas. This offgas is again treated to supply a stream enriched with H2 and CO2 which is returned to the PSA, where it constitutes a second feed distinct from the main feed.

Abstract: The present invention is a process for removing carbon dioxide from a compressed gas stream including cooling the compressed gas in a first heat exchanger, introducing the cooled gas into a de-sublimating heat exchanger, thereby producing a first solid carbon dioxide stream and a first carbon dioxide poor gas stream, expanding the carbon dioxide poor gas stream, thereby producing a second solid carbon dioxide stream and a second carbon dioxide poor gas stream, combining the first solid carbon dioxide stream and the second solid carbon dioxide stream, thereby producing a combined solid carbon dioxide stream, and indirectly exchanging heat between the combined solid carbon dioxide stream and the compressed gas in the first heat exchanger.

Abstract: Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.

Abstract: Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.

Abstract: Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.

Abstract: The present invention provides a process for recovering high purity gaseous hydrogen and high purity gaseous carbon dioxide from a syngas stream by utilizing a hydrogen selective membrane unit and a primary water gas shift reactor in combination with a cryogenic purification unit, a hydrogen recovery unit and a secondary water gas shift reactor or by utilizing a hydrogen membrane/water gas shift reactor in combination with a cryogenic purification unit, a hydrogen recovery unit and a secondary water gas shift reactor. Each of these embodiments may further include a sulfur recovery unit.