Patents by Inventor Peter Herold

Peter Herold has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5627182
    Abstract: .delta.-Amino-.gamma.-hydroxy-.omega.-aryl-alkanoic acid amides of formula I ##STR1## and the salts thereof, have renin-inhibiting properties and can be used as antihypertensive medicinal active ingredients.
    Type: Grant
    Filed: July 25, 1996
    Date of Patent: May 6, 1997
    Assignee: Ciba Geigy Corporation
    Inventors: Richard G oschke, J urgen K. Maibaum, Walter Schilling, Stefan Stutz, Pascal Rigollier, Yasuchika Yamaguchi, Nissim C. Cohen, Peter Herold
  • Patent number: 5606078
    Abstract: Compounds of formula I ##STR1## wherein R.sub.1 is free or esterified carboxy, hydroxymethyl or formyl,R.sub.2 and R.sub.4 are each independently of the other aliphatic, cycloaliphatic-aliphatic, araliphatic or heteroarylaliphatic radicals andR.sub.3 is azido, or amino that is aliphatically or araliphatically substituted and/or protected by an amino-protecting group,and the salts thereof, are valuable intermediates in the preparation of medicinal active ingredients, for example of compounds of formula II ##STR2## wherein R.sub.A is an aromatic or heteroaromatic radical,R.sub.2 and R.sub.4 are each independently of the other aliphatic, cycloaliphatic, cycloaliphaticaliphatic or araliphatic radicals,R.sub.3 is unsubstituted or N-mono- or N,N-di-lower alkylated or N-lower alkanoylated amino, andR.sub.B is an aliphatically, cycloaliphatically or heteroaromatically-aliphatically substituted amino group,and the salts thereof, which can be used, for example, as antihypertensives.
    Type: Grant
    Filed: April 4, 1995
    Date of Patent: February 25, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Richard G oschke, Peter Herold, Pascal Rigollier, J urgen K. Maibaum
  • Patent number: 5559111
    Abstract: .delta.-Amino-.gamma.-hydroxy-.omega.-aryl-alkanoic acid amides of formula I ##STR1## and the salts thereof, have renin-inhibiting properties and can be used as antihypertensive medicinal active ingredients.
    Type: Grant
    Filed: April 4, 1995
    Date of Patent: September 24, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Richard G oschke, J urgen K. Maibaum, Walter Schilling, Stefan Stutz, Pascal Rigollier, Yasuchika Yamaguchi, Nissim C. Cohen, Peter Herold
  • Patent number: 5508258
    Abstract: Described is the use of surface-active alpha-sulfofatty acid di-salts as ecologically compatible emulsifiers of the W/O type and O/W type, respectively, in fluid and pumpable drilling fluids and other fluid drilling-hole treatment agents which comprise a continuous or a dispersed oil phase together with an aqueous phase and which are suitable for an environmentally acceptable exploitation of geological resources, for example oil or natural gas deposits. The invention further relates to inverted drilling fluids based on a continuous oil phase and, present therein, a dispersed aqueous phase which, in addition to the emulsifiers, contain further conventional auxiliary agents such as thickeners, fluid-loss additives, weighting agents, water-soluble salts and/or alkali reserves.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: April 16, 1996
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz Mueller, Claus-Peter Herold, Johann F. Fues
  • Patent number: 5461028
    Abstract: Described is the use of oleophilic monomeric and/or oligomeric diesters of carbonic acid with the same or different oil-soluble and ecologically compatible mono-functional and optionally polyfunctional alcohols as a component of oil-based or water-based drilling fluids and other fluid drill-hole treatment agents. The invention in one embodiment comprises oil-based fluids, and particularly inverted fluids of the W/O type, which in the continuous phase at least in part contain oleophilic carbonic acid diesters. In a further important embodiment the invention relates to water-based emulsion fluids which in the dispersed oil phase at least in part contain said oleophilic carbonic acid diesters.
    Type: Grant
    Filed: December 7, 1992
    Date of Patent: October 24, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz Mueller, Claus-Peter Herold, Alfred Westfechtel, Stephan von Tapavicza
  • Patent number: 5441927
    Abstract: Described is the use of oleophilic esters of ecologically compatible polycarboxylic acids with oil-soluble and ecologically compatible monofunctional alcohols and/or polyfunctional alcohols which may also be watersoluble as the oil phase or as a component of the oil phase of oil-based or water-based drilling fluids and other fluid drill-hole treatment agents. The oleophilic polycarboxylic acid esters are especially suitable as component of the continuous oil phase of inverted fluids of the W/O type. Here--if rheologically suitable compounds will be employed--they may comprise the at least predominant portion of the continuous oil phase; but also possible is the concomitant use of complex oleophilic polycarboxylic acid esters, which are not or just to a restricted degree fluid in a temperature range of from 0.degree. C. to 20.degree. C., as an additive in fluid oils of the class of the non-polluting oils.
    Type: Grant
    Filed: November 9, 1994
    Date of Patent: August 15, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz Mueller, Claus-Peter Herold, Stephan von Tapavicza, Johann F. Fues
  • Patent number: 5421907
    Abstract: 2-Ethylhexyl esters of fatty acids, optionally mixed with emulsifiers, solubilizers, corrosion inhibitors, and/or water, are useful as low viscosity agents for the cold cleaning of metal surfaces contaminated mainly with oil. Such agents are non-toxic when inhaled and completely biodegradable.
    Type: Grant
    Filed: November 19, 1993
    Date of Patent: June 6, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Claus Nieendick, Karl Schmid, Heinz Mueller, Claus-Peter Herold
  • Patent number: 5418278
    Abstract: The invention relates to aqueous emulsion copolymers of (meth)acrylates of long-chain alcohols in continuous aqueous phase, characterized in that they contain as storable disperse phase copolymers of the following monomer components:at least 50% by weight and preferably at least 60% by weight (meth)acrylates of C.sub.16-30 alcohols0 to 25% by weight and preferably 5 to 10% by weight (meth)acrylates of alcohols containing no more than 8 carbon atoms0.5 to 40% by weight and preferably 1 to 25% by weight olefinically unsaturated mono- and/or dicarboxylic acids or anhydrides containing more than 10 carbon atoms.The invention also relates to the use of these aqueous emulsion copolymers for depressing the pour or flow points of hydrocarbon mixtures, particularly crude oil or petroleum fractions, the described copolymers forming the disperse phase of aqueous emulsion copolymers in a highly concentrated, but readily mobile formulation for incorporation in hydrocarbon mixtures of the described type.
    Type: Grant
    Filed: May 10, 1991
    Date of Patent: May 23, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wolfgang Ritter, Claus-Peter Herold
  • Patent number: 5403822
    Abstract: The invention describes the use of selected esters, fluid at room temperature and with flash points above 80.degree. C., from monocarboxylic acids of synthetic and/or natural origin with 6 to 11 carbon atoms and mono- and/or polyfunctional alcohols as the oil phase or a component of the oil phase of invert drilling muds, which are suitable for environment-friendly development of petroleum and natural gas deposits and in a continuous oil phase contain a dispersed aqueous phase together with emulsifiers, weighting agents, fluid-loss additives and preferably further conventional additives. In a further embodiment the invention relates to invert-drilling fluids of the types mentioned, which are characterized in that the oil phase contains esters of monocarboxylic acids of synthetic and/or natural origin with 6 to 11 carbon atoms and with mono- and/or polyfunctional alcohols preferably in admixture with other components from the class of ecologically acceptable compounds.
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: April 4, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz Mueller, Claus-Peter Herold, Stephan von Tapavicza, Michael Neuss, Wolfgang Zoellner, Frank Burbach
  • Patent number: 5348938
    Abstract: The use is described ofa) mono- and/or polyfunctional alcohols of natural and/or synthetic origin which are at least largely water-insoluble and are fluid and pumpable in the temperature range of 0.degree. to 5.degree. C.,or ofb) solutions, fluid and pumpable in the given temperature range, in ecologically-acceptable water-insoluble oils, of at least largely water-insoluble mono- and/or polyfunctional alcohols of natural and/or synthetic origin,as the continuous oil phase of drilling fluids, which exist as W/O-emulsions, have a dispersed aqueous phase and preferably have further usual additives in the alcohol-containing oil phase, and which are suitable for the environment-friendly development of, e.g., petroleum and natural gas deposits.
    Type: Grant
    Filed: April 28, 1993
    Date of Patent: September 20, 1994
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz Mueller, Claus-Peter Herold, Stephan von Tapavicza
  • Patent number: 5322392
    Abstract: A process is described for rock consolidation, e.g. in tunnel construction and mining, by injection of aqueous preparations of melamine resin condensates and/or urea formaldehyde condensates together with an acid curing agent. The process is characterized by the use of aqueous solutions of hydrogen sulfate salts, especially solutions of alkali and/or ammonium bisulfates, as curing agents. The curing agent solutions can contain additional auxiliary agents and active substances such as corrosion inhibitors, structurizers and adhesion agents. Preferred resin solutions for consolidation with these aqueous curing agents contain added zeolite NaA and/or hydrosodalite for increasing their serviceability, and especially for prolonging their storage life.
    Type: Grant
    Filed: July 29, 1992
    Date of Patent: June 21, 1994
    Assignees: Henkel Kommanditgesellschaft auf Aktien, E. Epple & Co. GmbH
    Inventors: Heinz Mueller, Claus-Peter Herold, Stephan von Tapavicza, Helmut Edel
  • Patent number: 5318955
    Abstract: The invention describes the use of water-insoluble esters with flash points above 80.degree. C., from monohydric alcohols of natural and/or synthetic origin with at least 4 carbon atoms, preferably at least 6 carbon atoms in the alcohol radicals, as the oil phase, or a constituent of the oil phase of invert drilling fluids which exist as W/O-emulsions, have a dispersed aqueous phase and ideally also have further usual additives in the continuous oil phase, which is fluid and pumpable in the temperature range of 0.degree. to 5.degree. C., and which are suitable for the environment-friendly development of, e.g., petroleum and natural gas deposits. Drilling fluids of the above type are also described which are characterized in that they contain as the continuous oil phase, or dissolved in ecologically-acceptable water-insoluble oils, an additive of at least largely water-insoluble ethers from monohydric alcohols, the oil phase in each case being fluid and pumpable in the temperature range of 0.degree. to 5.
    Type: Grant
    Filed: March 24, 1993
    Date of Patent: June 7, 1994
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz Mueller, Gerhard Stoll, Claus-Peter Herold, Stephan von Tapavicza
  • Patent number: 5318956
    Abstract: The use is disclosed of water-dispersible esters, which are fluid or at least plastically deformable at working temperature and have flash points of at least 80.degree. C., from saturated and/or unsaturated carboxylic acids with up to 36 carbon atoms and mono- and/or polyhydric alcohols, as at least the main constituent of the dispersed oil phase of water-based O/W-emulsion drilling fluids which are suitable for the environmentally friendly development of geological formations and which contain, if desired, insoluble, finely particulate weighting agents for the formation of water-based O/W-emulsion drilling muds and/or further additives, such as emulsifiers, fluid-loss additives, wetting agents, alkali reserves and/or auxiliary substances for the inhibition of drilled rock of high water-sensitivity.
    Type: Grant
    Filed: April 29, 1993
    Date of Patent: June 7, 1994
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz Mueller, Claus-Peter Herold, Stephan von Tapavicza, Johann Friedrich Fues
  • Patent number: 5318954
    Abstract: The invention describes the use of selected esters, fluid at room temperature and with flash points above 80.degree. C., of C.sub.1-5 -monocarboxylic acids and mon- and/or polyfunctional alcohols as the oil phase, or a component of the oil phase of invert drilling muds which are suitable for environment-friendly development of petroleum or natural gas deposits and contain in a continuous oil phase a dispersed aqueous phase together with emulsifiers, weighting agents, fluid-loss additives and preferably further conventional additives. In a further embodiment the invention relates to invert drilling fluids of the type described, which are characterized in that the oil phase contains esters from C.sub.1-5 -monocarboxylic acids with mono- and/or polyfunctional alcohols preferably in admixture with other components from the class of ecologically acceptable compounds.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: June 7, 1994
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz Mueller, Claus-Peter Herold, Stephan von Tapavicza, Michael Neuss, Frank Burbach
  • Patent number: 5254531
    Abstract: In a first embodiment, the invention relates to the use of basic amine compounds of pronounced oleophilic character and at most limited solubility in water, which are capable of forming salts with carboxylic acids, as an additive for w/o invert drilling muds which contain in the continuous oil phase ester oils and, together with the disperse aqueous phase, emulsifiers, weighting agents, fluid loss additives and, if desired, other additives for protecting the drilling muds against unwanted thickening in use or for improving their flowability. In another embodiment, the invention relates to w/o invert drilling muds which are suitable for the improved offshore development of oil and gas sources and which are characterized by the presence of basic amine compounds of pronounced oleophilic character which are capable of forming salts with carboxylic acids.
    Type: Grant
    Filed: January 21, 1992
    Date of Patent: October 19, 1993
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz Mueller, Claus-Peter Herold, Stephan von Tapavicza
  • Patent number: 5252554
    Abstract: Invert emulsion muds for drilling of gas and oil, which are environmentally safe, and which contain:A. a continuous oil phase composed predominantly of at least one monocarboxylic acid ester of a C.sub.2 C.sub.12 monofunctional alkanol wherein the monocarboxylic acid contains from 12 to 16 carbon atoms and is aliphatically saturated,B. a disperse aqueous phase,C. at least one emulsifier,D. at least one weighting agent,E. at least one fluid loss additive, andF. a mild alkaline reserve.
    Type: Grant
    Filed: January 21, 1992
    Date of Patent: October 12, 1993
    Assignees: Henkel Kommanditgesellschaft auf Aktien, Baroid Limited
    Inventors: Heinz Mueller, Claus-Peter Herold, Stephan von Tapavicza, Douglas J. Grimes, Jean-Marc Braun, Stuart P. T. Smith
  • Patent number: 5232910
    Abstract: Invert emulsion muds for drilling of gas and oil, which are environmentally safe, and which contain:A. a continuous oil phase composed predominantly of at least one monocarboxylic acid ester of a C.sub.2 -C.sub.12 monofunctional alkanol wherein the monocarboxylic acid contains from 16 to 24 carbon atoms and is olefinically mono- or poly-unsaturated,B. a disperse aqeuous phase,C. at least one emulsifier,D. at least one weighting agent,E. at least one fluid loss additive, andF. a mild alkaline reserve.
    Type: Grant
    Filed: September 6, 1991
    Date of Patent: August 3, 1993
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz Mueller, Claus-Peter Herold, Stephan von Tapavicza, Douglas J. Grimes, Jean-Marc Braun, Stuart P. T. Smith
  • Patent number: 5199823
    Abstract: The invention relates to aqueous preparations of acid-catalyzed melamine resins and/or urea-formaldehyde condensates which contain an addition of zeolite NaA and/or hydroxysodalite to increase their usefulness. The preparations in question are particularly suitable for use in the stabilization of rock and/or plugging of cavities, for example in tunneling and mining. Accordingly, the invention also relates to a process for stabilizing rock, for example in tunneling and mining, by injection of corresponding preparations together with an acidic catalyst.
    Type: Grant
    Filed: November 6, 1991
    Date of Patent: April 6, 1993
    Assignees: Henkel Kommanditgesellschaft auf Aktien, E. Epple & Co. GmbH
    Inventors: Heinz Mueller, Claus-Peter Herold, Stephan von Tapavicza, Edmund Edel
  • Patent number: 5194422
    Abstract: Substantially water-insoluble, oleophilic mono- and/or polyfunctional alcohols of natural and/or synthetic origin which have flash points of at least 80.degree. C., or corresponding solutions of mono- and/or polyhydric alcohols in ecologically acceptable water-insoluble oils as the dispersed oil phase of water-based O/W-emulsion drilling fluids, which are suitable for an environmentally-acceptable development of geological formations and which, if desired, contain insoluble, finely particulate weighting agents for the formation of water-based O/W-emulsions drilling muds and/or further additives, such as emulsifiers, fluid-loss additives, wetting agents, alkali reserves and/or auxiliary substances for the inhibition of drilled rock of high water-sensitivity.
    Type: Grant
    Filed: November 15, 1991
    Date of Patent: March 16, 1993
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz Mueller, Klaus-Peter Herold, Stephan von Tapavicza, Johann F. Fues
  • Patent number: 5106516
    Abstract: The invention relates to the use of methylesters of C.sub.6-24 monocarboxylic acids as the oil phase or as part of the oil phase of invert drilling muds which are suitable for the environment-friendly development of oil and gas sources and which, in a continuous oil phase, contain a disperse aqueous phase together with emulsifirs, weighting agents, fluid loss additives and, if desired, other standard additives. In another embodiment, the invention relates to invert drilling muds which are particularly suitable for the environment-friendly development of oil and gas sources and which are characterized in that the oil phase contains methylesters of C.sub.6-24 monocarboxylic acids, if desired in admixture with other oil components from the class of non-polluting oils.
    Type: Grant
    Filed: February 9, 1990
    Date of Patent: April 21, 1992
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz Mueller, Claus-Peter Herold, Stephan von Tapavicza