Abstract: A high-temperature stable solid-state bipolar battery is provided. The battery includes two or more electrodes, one or more solid-state electrolyte layers, and an ionogel disposed within void spaces within the battery. Each electrode includes a plurality of solid-state electroactive particles. Each solid-state electrolyte layer includes a plurality of solid-state electrolyte particles and a first solid-state electrolyte layer of the one or more solid-state electrolyte layers may be disposed between a first electrode and a second electrode of the two or more electrodes. The ionogel is disposed within void spaces between the two or more electrodes, the solid-state electroactive particles of the two or more electrodes, the solid-state electrolyte particles of the one or more solid-state electrolyte layers, and the one or more solid-state electrolyte layers, such that the battery has an reduced interparticle porosity. The ionogel may have an ionic conductivity between about 0.1 mS/Cm and about 10 mS/cm.

Abstract: A bipolar capacitor-assisted solid-state battery is disclosed that includes a plurality of electrochemical battery unit cells, each of which includes a negative electrode, a positive electrode, and a lithium ion-conductive electrolyte-containing separator disposed between the negative electrode and the positive electrode. The lithium ion-conductive electrolyte-containing separator of each electrochemical battery unit cell comprises a solid-state electrolyte material, and, additionally, at least one negative electrode of the electrochemical battery unit cells or at least one positive electrode of the electrochemical battery unit cells includes a capacitor material. The bipolar capacitor-assisted solid-state battery further includes a bipolar current collector disposed between a negative electrode of one electrochemical battery unit cell and a positive electrode of an adjacent electrochemical battery unit cell.

Abstract: A solid-state battery cell having a capacitor interlayer is disclosed. The solid-state battery includes an anode, a cathode spaced from the anode, a solid-state electrolyte layer disposed between the anode and the cathode, and a capacitor assisted interlayer sandwiched between at least one of (i) the anode and solid-state electrolyte layer, and (ii) the cathode and the solid-state electrolyte layer. The capacitor assisted interlayer comprise at least one of a polymer-based material, an inorganic material, and a polymer-inorganic hybrid material; and a capacitor anode active material or a capacitor cathode active material. The polymer-based material includes at least one of a poly(ethylene glycol) methylether acrylate with Al2O3 and LiTFSI, a polyethylene oxide (PEO) with LiTFSI, and a poly(vinylidene fluoride) copolymer with hexafluoropropylene (PVDF-HFP)-based gel electrolyte. The inorganic material includes a 70% Li2S-29% P2S5-1% P2O5.

Abstract: Individual electrodes for a solid-state lithium-ion battery cell may be formed, for example, by elevated temperature consolidation in air of a mixture of resin-bonded, electrode active material particles, oxide solid electrolyte particles, and particles of a non-carbon electronic conductive additive. Depending on the selected compositions of the electrode materials and the solid electrolyte, one or both of the cathode and anode layer members may be formed to include the non-carbon electronic conductive additive. The battery cell is assembled with the solid-state electrodes placed on opposite sides of a consolidated layer of oxide electrolyte particles. The electronic conductivity of at least one of the cathode and anode is increased by the incorporation of particles of a selected non-carbon electronic conducive additive with the respective electrode particles.

Abstract: A hybrid electrochemical device including at least two electrically connected solid-state electrochemical cells is provided. Each electrochemical cell includes a first outer electrode having a first current collector and a first electroactive layer, a second outer electrode having a second current collector and a second electroactive layer, and one or more intervening electrodes disposed between the electroactive layers. At least one of the intervening electrodes includes one or more capacitor additives. The first outer electrode is electrically connected to at least one of the intervening electrodes in a first electrical configuration. The second outer electrode is electrically connected to at least one of the intervening electrodes in a second electrical configuration. The at least two electrochemical cells are electrically connected in a third electrical configuration.

Abstract: Hybrid lithium-ion electrochemical cells include a first electrode having a first polarity and a first electroactive material that reversibly cycles lithium ions having a first maximum operational voltage and a second electrode having the first polarity with a second electroactive material having a second maximum operational voltage. A difference between the second and first maximum operational voltages defines a predetermined voltage difference. Also included are at least one third electrode including a third electroactive material that reversibly cycles lithium ions having a second polarity opposite to the first polarity, a separator, and electrolyte. A voltage modification component (e.g., diode) is in electrical communication with the first and the second electrodes.

Abstract: A bipolar capacitor-assisted solid-state battery is disclosed that includes a plurality of electrochemical battery unit cells, each of which includes a negative electrode, a positive electrode, and a lithium ion-conductive electrolyte-containing separator disposed between the negative electrode and the positive electrode. The lithium ion-conductive electrolyte-containing separator of each electrochemical battery unit cell comprises a solid-state electrolyte material, and, additionally, at least one negative electrode of the electrochemical battery unit cells or at least one positive electrode of the electrochemical battery unit cells includes a capacitor material. The bipolar capacitor-assisted solid-state battery further includes a bipolar current collector disposed between a negative electrode of one electrochemical battery unit cell and a positive electrode of an adjacent electrochemical battery unit cell.

Abstract: An electrode including micro-sized secondary particle (MSSP) with enhanced ionic conductivity for solid-state battery is provided. The MSSP comprises a cathode particle and a solid-state electrolyte. The cathode particle is at least partially coated by solid-state electrolyte. The lithium ion transport inside the micro-sized secondary particles is increased by the incorporation of solid-state electrolyte. The electrode can be prepared by casting the slurry comprising MSSP, another electrolyte, binders, and conductive additives on the current collector. The current collector is comprised of a conductive material. The current collector has a first side and a second side. The electrode active material layer is disposed on one of the first and second sides of the current collector.

Abstract: A bipolar battery may comprise first, second, and third bipolar electrodes that are physically and electrically isolated from one another by intervening non-liquid electrolyte layers. Each of the bipolar electrodes may comprise a bipolar current collector including a first electroactive material layer connected to a first side thereof and a second electroactive material layer connected to a second side thereof. Each electroactive material layer may comprise at least one of: (i) a lithium ion battery positive electrode material, (ii) a lithium ion battery negative electrode material, and/or (iii) a capacitor electrode material. At least one of the electroactive material layers comprises a capacitor electrode material.

Abstract: A solid-state battery cell having a capacitor interlayer is disclosed. The solid-state battery includes an anode, a cathode spaced from the anode, a solid-state electrolyte layer disposed between the anode and the cathode, and a capacitor assisted interlayer sandwiched between at least one of (i) the anode and solid-state electrolyte layer, and (ii) the cathode and the solid-state electrolyte layer. The capacitor assisted interlayer comprise at least one of a polymer-based material, an inorganic material, and a polymer-inorganic hybrid material; and a capacitor anode active material or a capacitor cathode active material. The polymer-based material includes at least one of a poly(ethylene glycol) methylether acrylate with Al2O3 and LiTFSI, a polyethylene oxide (PEO) with LiTFSI, and a poly(vinylidene fluoride) copolymer with hexafluoropropylene (PVDF-HFP)-based gel electrolyte. The inorganic material includes a 70% Li2S-29% P2S5-1% P2O5.

Abstract: A hybrid lithium ion capacitor battery and method of making the same is disclosed. The hybrid lithium ion capacitor battery includes a positive electrode separated from a negative electrode by a separator layer. A first activated carbon layer is disposed between the separator layer and one of the positive and negative electrodes. The first activated carbon layer is coated on a first surface of the separator layer. A second activated carbon layer is disposed between the separator layer and the other of the positive and negative electrodes. The second activated carbon layer is coated on a second surface of the separator layer. A first current collector coextensively contacts the first electrode and a second current collector coextensively contacts the second electrode. An electrolytic solution carries lithium cations between the positive and negative electrodes through the activated carbon coated separator layer.

Abstract: A battery having a plurality of electrodes immersed in a water-in-salt electrolytic solution is disclosed. The water-in-salt electrolytic solution includes a sufficient amount of a lithium salt disposed in an aqueous solvent, at least 14 moles of lithium salt per kg of aqueous solvent, such that a dissociated lithium ion is solvated by less than 4 water molecules. The plurality of electrodes includes a first type electrode, a second type electrode, and a third type electrode selectively assembled in a predetermined order of arrangement into an electrode stack assembly. The first type electrode includes an activated carbon, the second type electrodes include one of a lithium manganese oxide (LMO) and titanium dioxide (TiO2), and the third type electrodes include the other of the LMO and TiO2. The first type electrode may be that of a cathode and/or anode.

Abstract: Individual electrodes for a solid-state lithium-ion battery cell may be formed, for example, by elevated temperature consolidation in air of a mixture of resin-bonded, electrode active material particles, oxide solid electrolyte particles, and particles of a non-carbon electronic conductive additive. Depending on the selected compositions of the electrode materials and the solid electrolyte, one or both of the cathode and anode layer members may be formed to include the non-carbon electronic conductive additive. The battery cell is assembled with the solid-state electrodes placed on opposite sides of a consolidated layer of oxide electrolyte particles. The electronic conductivity of at least one of the cathode and anode is increased by the incorporation of particles of a selected non-carbon electronic conducive additive with the respective electrode particles.