Patents by Inventor Ralf Dotzel
Ralf Dotzel has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20250135438Abstract: The specification describes a zirconia support comprising ?95 wt % ZrO2, wherein: the support has a crush strength of 20 to 140 N; the support has a total pore volume of 0.10 to 0.40 mL/g when measured by N2 physisorption; the support has an acid site density of 15 to 30 ?LNH3/m2; and the support has a basic site density of 0.006 to 0.015 wt %/m2 as measured by the MBOH test. Also described is a method for producing a zirconia supporting starting from zirconia or zirconium hydroxide as raw materials.Type: ApplicationFiled: October 24, 2024Publication date: May 1, 2025Inventors: Brian Blank, Ralf Dotzel, Dana Hatch, Philip John Hughes, Martin Max Langbein, Paul Andrew McGuire, Hubert Schedel, Stuart Michael Small, Edgar Steenwinkel, Charalambos Thoma
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Patent number: 12024438Abstract: The present invention further provides a method of making an metal-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms from pre-existing aluminosilicate zeolite crystallites, wherein the metal is present in a range of from 0.5 to 5.0 wt. % based on the total weight of the metal-loaded aluminosilicate zeolite.Type: GrantFiled: April 29, 2022Date of Patent: July 2, 2024Assignees: Johnson Matthey Public Limited Company, Johnson Matthey Catalysts (Germany) GmbHInventors: Juergen Bauer, John Leonello Casci, Ralf Dotzel, Joerg Muench, Ralitsa Purova, Wilhelm Schwieger, Ameen Shahid, Selvam Thangaraj, Tobias Weissenberger
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Patent number: 11634335Abstract: The present invention provides an iron-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms and having the framework type CHA, AEI, AFX, ERI or LTA, wherein the iron (Fe) is present in a range of from about 0.5 to about 5.0 wt. % based on the total weight of the iron-loaded aluminosilicate zeolite, wherein an ultraviolet-visible absorbance spectrum of the iron-loaded synthetic aluminosilicate zeolite comprises a band at approximately 280 nm, wherein a ratio of an integral, peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for the band at approximately 280 nm to an integral peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for a band at approximately 340 nm is >about 2.Type: GrantFiled: January 10, 2020Date of Patent: April 25, 2023Assignees: Johnson Matthey Public Limited Company, Johnson Matthey Catalysts (Germany) GmbhInventors: Juergen Bauer, John Leonello Casci, Ralf Dotzel, Joerg Muench, Ralitsa Purova, Wilhelm Schwieger, Ameen Shahid, Selvam Thangaraj, Tobias Weissenberger
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Patent number: 11571682Abstract: A SCR catalyst composition comprises a SCR catalyst; and a binder comprising a porous inorganic material, wherein the porous inorganic material comprises a disordered arrangement of delaminated layers, has a disordered porous structure, and has a multimodal pore size distribution comprising at least a first modal maximum having a macroporous or mesoporous pore size and a second modal maximum having a microporous pore size. The SCR catalyst composition can be manufactured using the method comprising the steps of: (i) providing an inorganic material having a layered structure; (ii) contacting the material with a cationic surfactant to form a swollen material; (iii) agitating the swollen material to form an agitated material; and (iv) calcining the agitated material to recover a delaminated inorganic material, wherein an SCR catalyst is mixed with the inorganic material prior to step (iv).Type: GrantFiled: August 10, 2020Date of Patent: February 7, 2023Inventors: Jürgen Bauer, Ralf Dotzel, Jörg Werner Muench, Ralitsa Purova, Wilhelm Schwieger, Thangaraj Selvam, Ameen Shahid
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Publication number: 20220250928Abstract: The present invention further provides a method of making an metal-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms from pre-existing aluminosilicate zeolite crystallites, wherein the metal is present in a range of from 0.5 to 5.0 wt. % based on the total weight of the metal-loaded aluminosilicate zeolite.Type: ApplicationFiled: April 29, 2022Publication date: August 11, 2022Inventors: Juergen BAUER, John Leonello CASCI, Ralf DOTZEL, Joerg MUENCH, Ralitsa PUROVA, Wilhelm SCHWIEGER, Ameen SHAHID, Selvam THANGARAJ, Tobias WEISSENBERGER,
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Patent number: 11291975Abstract: In order to specify a catalytic converter, especially SCR catalytic converter, with maximum catalytic activity, this catalytic converter has at least one catalytically active component and additionally at least one porous inorganic filler component having meso- or macroporosity. The organic porous filler component has a proportion of about 5 to 50% by weight. More particularly, a diatomaceous earth or a pillared clay material is used as the porous inorganic filler component.Type: GrantFiled: May 20, 2019Date of Patent: April 5, 2022Assignee: Johnson Matthey Public Limited CompanyInventors: Juergen Bauer, Ralf Dotzel, Joerg Walter Jodlauk, Rainer Leppelt, Joerg Werner Muench
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Patent number: 11198116Abstract: To be able to produce an SCR catalyst (2), in particular one having a zeolite fraction (Z) as catalytically active fraction, in a reliable process and at the same time achieve good catalytic activity of the catalyst (2), an inorganic binder fraction (B) which is catalytically inactive in the starting state and has been treated to develop catalytic activity is mixed into a catalyst composition (4). The inorganic binder component for the binder fraction (B) is, in the starting state, preferably porous particles (10), in particular diatomaceous earth, which display mesoporosity. To effect catalytic activation, the individual particles (10) are either coated with a catalytically active layer (12) or transformed into a catalytically active zeolite (14) with maintenance of the mesoporosity.Type: GrantFiled: March 11, 2019Date of Patent: December 14, 2021Assignee: Johnson Matthey Public Limited CompanyInventors: Juergen Bauer, Ralf Dotzel, Joerg Werner Muench
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Patent number: 11179707Abstract: A composite material comprises a macroporous silicate-based material at least partially substituted with at least one microporous zeolite, wherein the microporous zeolite is functionalised with either copper, iron or both copper and iron, and wherein the composite material is in the form of particles. The composite material can be obtained using a method comprising the steps of: (i) providing a mixture comprising a silicate-containing scaffold having a macroporous structure, an aluminium source and an organic template; (ii) hydrothermally treating the mixture to form a microporous zeolite-containing structure substantially retaining the macroporous structure of the silicate-containing scaffold; (iii) incorporating copper, iron or both copper and iron into the zeolite. The silicate-containing scaffold can be a diatomaceous earth.Type: GrantFiled: May 18, 2020Date of Patent: November 23, 2021Assignee: Johnson Matthey Catalysts (Germany) GmbHInventors: Juergen Bauer, Ralf Dotzel, Joerg Werner Muench, Ralitsa Purova, Wilhelm Schwieger, Thangaraj Selvam, Ameen Shahid
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Publication number: 20210094025Abstract: A composite material comprises a macroporous silicate-based material at least partially substituted with at least one microporous zeolite, wherein the microporous zeolite is functionalised with either copper, iron or both copper and iron, and wherein the composite material is in the form of particles. The composite material can be obtained using a method comprising the steps of: (i) providing a mixture comprising a silicate-containing scaffold having a macroporous structure, an aluminium source and an organic template; (ii) hydrothermally treating the mixture to form a microporous zeolite-containing structure substantially retaining the macroporous structure of the silicate-containing scaffold; (iii) incorporating copper, iron or both copper and iron into the zeolite. The silicate-containing scaffold can be a diatomaceous earth.Type: ApplicationFiled: May 18, 2020Publication date: April 1, 2021Inventors: Juergen Bauer, Ralf Dotzel, Joerg Werner Muench, Ralitsa Purova, Wilhelm Schwieger, Thangaraj Selvam, Ameen Shahid
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Publication number: 20210008524Abstract: A SCR catalyst composition comprises a SCR catalyst; and a binder comprising a porous inorganic material, wherein the porous inorganic material comprises a disordered arrangement of delaminated layers, has a disordered porous structure, and has a multimodal pore size distribution comprising at least a first modal maximum having a macroporous or mesoporous pore size and a second modal maximum having a microporous pore size. The SCR catalyst composition can be manufactured using the method comprising the steps of: (i) providing an inorganic material having a layered structure; (ii) contacting the material with a cationic surfactant to form a swollen material; (iii) agitating the swollen material to form an agitated material; and (iv) calcining the agitated material to recover a delaminated inorganic material, wherein an SCR catalyst is mixed with the inorganic material prior to step (iv).Type: ApplicationFiled: August 10, 2020Publication date: January 14, 2021Inventors: Jürgen BAUER, Ralf DOTZEL, Joerg Werner MUENCH, Ralitsa PUROVA, Wilhelm SCHWIEGER, Thangaraj SELVAM, Ameen SHAHID
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Patent number: 10828626Abstract: A composite material comprises a macroporous silicate-based material at least partially substituted with at least one microporous zeolite, wherein the microporous zeolite is functionalised with either copper, iron or both copper and iron, and wherein the composite material is in the form of particles. The composite material can be obtained using a method comprising the steps of: (i) providing a mixture comprising a silicate-containing scaffold having a macroporous structure, an aluminium source and an organic template; (ii) hydrothermally treating the mixture to form a microporous zeolite-containing structure substantially retaining the macroporous structure of the silicate-containing scaffold; (iii) incorporating copper, iron or both copper and iron into the zeolite. The silicate-containing scaffold can be a diatomaceous earth.Type: GrantFiled: March 29, 2018Date of Patent: November 10, 2020Assignee: Johnson Matthey Catalysts (Germany) GmbHInventors: Juergen Bauer, Ralf Dotzel, Joerg Werner Muench, Ralitsa Purova, Wilhelm Schwieger, Thangaraj Selvam, Ameen Shahid
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Publication number: 20200223708Abstract: The present invention provides an iron-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms and having the framework type CHA, AEI, AFX, ERI or LTA, wherein the iron (Fe) is present in a range of from about 0.5 to about 5.0 wt. % based on the total weight of the iron-loaded aluminosilicate zeolite, wherein an ultraviolet-visible absorbance spectrum of the iron-loaded synthetic aluminosilicate zeolite comprises a band at approximately 280 nm, wherein a ratio of an integral, peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for the band at approximately 280 nm to an integral peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for a band at approximately 340 nm is >about 2.Type: ApplicationFiled: January 10, 2020Publication date: July 16, 2020Inventors: Juergen BAUER, John Leonello CASCI, Ralf DOTZEL, Joerg MUENCH, Ralitsa PUROVA, Wilhelm SCHWIEGER, Ameen SHAHID, Selvam THANGARAJ, Tobias WEISSENBERGER
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Publication number: 20200038850Abstract: A composite material comprises a macroporous silicate-based material at least partially substituted with at least one microporous zeolite, wherein the microporous zeolite is functionalised with either copper, iron or both copper and iron, and wherein the composite material is in the form of particles. The composite material can be obtained using a method comprising the steps of: (i) providing a mixture comprising a silicate-containing scaffold having a macroporous structure, an aluminium source and an organic template; (ii) hydrothermally treating the mixture to form a microporous zeolite-containing structure substantially retaining the macroporous structure of the silicate-containing scaffold; (iii) incorporating copper, iron or both copper and iron into the zeolite. The cate-containing scaffold can be a diatomaceous earth.Type: ApplicationFiled: March 29, 2018Publication date: February 6, 2020Inventors: Juergen BAUER, Ralf DOTZEL, Joerg Werner MUENCH, Ralitsa PUROVA, Wilhelm SCHWIEGER, Thangaraj SELVAM, Ameen SHAHID
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Patent number: 10500572Abstract: An extruded, solid honeycomb body comprises a copper-promoted, small pore, crystalline molecular sieve catalyst for converting oxides of nitrogen in the presence of a reducing agent, wherein the crystalline molecular sieve contains a maximum ring size of eight tetrahedral atoms, which extruded, solid honeycomb body comprising: 20-50% by weight matrix component comprising diatomaceous earth, wherein 2-20 weight % of the extruded, solid honeycomb body is diatomaceous earth; 80-50% by weight of the small pore, crystalline molecular sieve ion-exchanged with copper; and 0-10% by weight of inorganic fibres.Type: GrantFiled: March 22, 2018Date of Patent: December 10, 2019Assignee: Johnson Matthey Catalysts (Germany) GmbHInventors: Juergen Bauer, Ralf Dotzel, Joerg Walter Jodlauk, Rainer Leppelt, Joerg Werner Muench
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Patent number: 10443472Abstract: An extruded honeycomb catalyst for nitrogen oxide reduction according to the selective catalytic reduction (SCR) method in exhaust gases from motor vehicles includes an extruded active carrier in honeycomb form having a first SCR catalytically active component and with a plurality of channels through which the exhaust gas flows during operation, and a washcoat coating having a second SCR catalytically active component being applied to the extruded body, wherein the first SCR catalytically active component and the second SCR catalytically active component are each independently one of: (i) vanadium catalyst with vanadium as catalytically active component; (ii) mixed-oxide catalyst with one or more oxides, in particular those of transition metals or lanthanides as catalytically active component; and (iii) an Fe- or a Cu-zeolite catalyst.Type: GrantFiled: October 20, 2017Date of Patent: October 15, 2019Assignee: Johnson Matthey Public Limited CompanyInventors: Guy Richard Chandler, Neil Robert Collins, Ralf Dotzel, Joerg Muench, Paul Richard Phillips, Gudmund Smedler, Andrew Peter Walker
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Publication number: 20190299198Abstract: Provided is a catalyst composition for treating exhaust gas comprising a blend of a first component and second component, wherein the first component is an aluminosilicate or ferrosilicate molecular sieve component wherein the molecular sieve is either in H+ form or is ion exchanged with one or more transition metals, and the second component is a vanadium oxide supported on a metal oxide support selected from alumina, titania, zirconia, ceria, silica, and combinations thereof. Also provided are methods, systems, and catalytic articles incorporating or utilizing such catalyst blends.Type: ApplicationFiled: April 5, 2019Publication date: October 3, 2019Inventors: Juergen BAUER, Ralf DOTZEL, Joerg JODLAUK, Rainer LEPPELT, Joerg MUENCH, Irene PIRAS, Gudmund SMEDLER
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Publication number: 20190270070Abstract: In order to specify a catalytic converter, especially SCR catalytic converter, with maximum catalytic activity, this catalytic converter has at least one catalytically active component and additionally at least one porous inorganic filler component having meso- or macroporosity. The organic porous filler component has a proportion of about 5 to 50% by weight. More particularly, a diatomaceous earth or a pillared clay material is used as the porous inorganic filler component.Type: ApplicationFiled: May 20, 2019Publication date: September 5, 2019Inventors: Juergen Bauer, Ralf Dotzel, Joerg Walter Jodlauk, Rainer Leppelt, Joerg Werner Muench
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Publication number: 20190201885Abstract: To be able to produce an SCR catalyst (2), in particular one having a zeolite fraction (Z) as catalytically active fraction, in a reliable process and at the same time achieve good catalytic activity of the catalyst (2), an inorganic binder fraction (B) which is catalytically inactive in the starting state and has been treated to develop catalytic activity is mixed into a catalyst composition (4). The inorganic binder component for the binder fraction (B) is, in the starting state, preferably porous particles (10), in particular diatomaceous earth, which display mesoporosity. To effect catalytic activation, the individual particles (10) are either coated with a catalytically active layer (12) or transformed into a catalytically active zeolite (14) with maintenance of the mesoporosity.Type: ApplicationFiled: March 11, 2019Publication date: July 4, 2019Inventors: Juergen BAUER, Ralf DOTZEL, Joerg Werner MUENCH
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Patent number: 10300461Abstract: In order to specify a catalytic converter, especially SCR catalytic converter, with maximum catalytic activity, this catalytic converter has at least one catalytically active component and additionally at least one porous inorganic filler component having meso- or macroporosity. The organic porous filler component has a proportion of about 5 to 50% by weight. More particularly, a diatomaceous earth or a pillared clay material is used as the porous inorganic filler component.Type: GrantFiled: January 23, 2015Date of Patent: May 28, 2019Assignee: Johnson Matthey Public Limited CompanyInventors: Juergen Bauer, Ralf Dotzel, Joerg Walter Jodlauk, Rainer Leppelt, Joerg Werner Muench
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Patent number: 10252252Abstract: Provided is a catalyst composition for treating exhaust gas comprising a blend of a first component and second component, wherein the first component is an aluminosilicate or ferrosilicate molecular sieve component wherein the molecular sieve is either in H+ form or is ion exchanged with one or more transition metals, and the second component is a vanadium oxide supported on a metal oxide support selected from alumina, titania, zirconia, cella, silica, and combinations thereof. Also provided are methods, systems, and catalytic articles incorporating or utilizing such catalyst blends.Type: GrantFiled: August 16, 2013Date of Patent: April 9, 2019Assignee: Johnson Matthey Public Limited CompanyInventors: Juergen Bauer, Ralf Dotzel, Joerg Jodlauk, Rainer Leppelt, Joerg Muench, Irene Piras, Gudmund Smedler