Patents by Inventor Ralf Dotzel

Ralf Dotzel has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10226765
    Abstract: To be able to produce an SCR catalyst (2), in particular one having a zeolite fraction (Z) as catalytically active fraction, in a reliable process and at the same time achieve good catalytic activity of the catalyst (2), an inorganic binder fraction (B) which is catalytically inactive in the starting state and has been treated to develop catalytic activity is mixed into a catalyst composition (4). The inorganic binder component for the binder fraction (B) is, in the starting state, preferably porous particles (10), in particular diatomaceous earth, which display mesoporosity. To effect catalytic activation, the individual particles (10) are either coated with a catalytically active layer (12) or transformed into a catalytically active zeolite (14) with maintenance of the mesoporosity.
    Type: Grant
    Filed: March 27, 2015
    Date of Patent: March 12, 2019
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Juergen Bauer, Ralf Dotzel, Joerg Werner Muench
  • Publication number: 20180320970
    Abstract: A system (2) for extruding and drying an extruded honeycomb body (14) which has channels (18) that extend in a longitudinal direction (L) and which channels (18) are each bounded by first channel walls (20a) that extend in a first direction (A) which is transverse relative to the longitudinal direction (L), and by second channel walls (20b) that extend in a second direction (B) in which is also transverse relative to the longitudinal direction (L) comprises: (i) an extruder (16) having an extrusion head (17) for producing the honeycomb body (14) by extrusion; (ii) a microwave oven (4) comprising an arrangement of a plurality of microwave radiators (6), each microwave radiator being for irradiating the honeycomb body with a directional microwave beam in an irradiation direction (S); and (iii) a feed unit (12) adjoining the extruder (16) for transferring the honeycomb body from the extruder (16) into the microwave oven (4), wherein either: (a) the extrusion head (17) of the extruder is oriented in such a way th
    Type: Application
    Filed: August 31, 2016
    Publication date: November 8, 2018
    Inventors: Ralf DOTZEL, Walter FISCHER, Thomas HIRSCHMANN, Rainer LEPPELT, Joerg MUENCH, Thomas PROSKE, Thomas SCHOENE, Thomas ZAPF
  • Publication number: 20180298801
    Abstract: An extruded honeycomb catalyst for nitrogen oxide reduction according to the selective catalytic reduction (SCR) method in exhaust gases from motor vehicles includes an extruded active carrier in honeycomb form having a first SCR catalytically active component and with a plurality of channels through which the exhaust gas flows during operation, and a washcoat coating having a second SCR catalytically active component being applied to the extruded body, wherein the first SCR catalytically active component and the second SCR catalytically active component are each independently one of: (i) vanadium catalyst with vanadium as catalytically active component; (ii) mixed-oxide catalyst with one or more oxides, in particular those of transition metals or lanthanides as catalytically active component; and (iii) an Fe- or a Cu-zeolite catalyst.
    Type: Application
    Filed: October 20, 2017
    Publication date: October 18, 2018
    Inventors: Guy Richard CHANDLER, Neil Robert COLLINS, Ralf DOTZEL, Joerg MUENCH, Paul Richard PHILLIPS, Gudmund SMEDLER, Andrew Peter WALKER
  • Publication number: 20180280937
    Abstract: A SCR catalyst composition comprises a SCR catalyst; and a binder comprising a porous inorganic material, wherein the porous inorganic material comprises a disordered arrangement of delaminated layers, has a disordered porous structure, and has a multimodal pore size distribution comprising at least a first modal maximum having a macroporous or mesoporous pore size and a second modal maximum having a microporous pore size. The SCR catalyst composition can be manufactured using the method comprising the steps of: (i) providing an inorganic material having a layered structure; (ii) contacting the material with a cationic surfactant to form a swollen material; (iii) agitating the swollen material to form an agitated material; and (iv) calcining the agitated material to recover a delaminated inorganic material, wherein an SCR catalyst is mixed with the inorganic material prior to step (iv).
    Type: Application
    Filed: March 28, 2018
    Publication date: October 4, 2018
    Inventors: Juergen BAUER, Ralf DOTZEL, Joerg Werner MUENCH, Ralitsa PUROVA, Wilhelm SCHWIEGER, Thangaraj SELVAM, Ameen SHAHID
  • Publication number: 20180207627
    Abstract: An extruded, solid honeycomb body comprises a copper-promoted, small pore, crystalline molecular sieve catalyst for converting oxides of nitrogen in the presence of a reducing agent, wherein the crystalline molecular sieve contains a maximum ring size of eight tetrahedral atoms, which extruded, solid honeycomb body comprising: 20-50% by weight matrix component comprising diatomaceous earth, wherein 2-20 weight % of the extruded, solid honeycomb body is diatomaceous earth; 80-50% by weight of the small pore, crystalline molecular sieve ion-exchanged with copper; and 0-10% by weight of inorganic fibres.
    Type: Application
    Filed: March 22, 2018
    Publication date: July 26, 2018
    Inventors: Juergen Bauer, Ralf Dotzel, Joerg Walter Jodlauk, Rainer Leppelt, Joerg Werner Muench
  • Patent number: 9987619
    Abstract: A filter incorporates a catalyst for the Selective Catalytic Reduction (SCR) of NOx gases and removal of particulate matter from the exhaust gas of a lean burn combustion engine, wherein the catalyst includes a vanadate component having an alkaline earth metal, a transition metal, a rare earth metal, or combinations thereof. The vanadate component may be iron vanadate. The filter includes a supported vanadate component disposed on a wall-flow filter. The method of making the filter includes applying an aqueous mixture of the supported vanadate component as a washcoat on the wall-flow filter or extruding a composition containing the supported vanadate component. The method of treating exhaust gases from an engine includes contacting the exhaust gas with the catalyst including the vanadate component.
    Type: Grant
    Filed: May 31, 2013
    Date of Patent: June 5, 2018
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Kaneshalingam Arulraj, Ralf Dotzel, Rainer Leppelt, Jorg Werner Muench, Alexandra Tsami Goodwin, Gudmund Smedler
  • Patent number: 9937488
    Abstract: An extruded, solid honeycomb body comprises a copper-promoted, small pore, crystalline molecular sieve catalyst for converting oxides of nitrogen in the presence of a reducing agent, wherein the crystalline molecular sieve contains a maximum ring size of eight tetrahedral atoms, which extruded, solid honeycomb body comprising: 20-50% by weight matrix component comprising diatomaceous earth, wherein 2-20 weight % of the extruded, solid honeycomb body is diatomaceous earth; 80-50% by weight of the small pore, crystalline molecular sieve ion-exchanged with copper; and 0-10% by weight of inorganic fibers.
    Type: Grant
    Filed: January 23, 2015
    Date of Patent: April 10, 2018
    Assignee: Johnson Matthey Catalysts (Germany) GmbH
    Inventors: Juergen Bauer, Ralf Dotzel, Joerg Walter Jodlauk, Rainer Leppelt, Joerg Werner Muench
  • Patent number: 9782721
    Abstract: Systems and methods of continuous operation of a urea-SCR system at low temperatures (200-350° C.) in the presence of high SOx containing flue gas are described. The methods comprise introducing a solution of urea and an NO2 forming compound, preferably an alkaline earth metal nitrate, into an exhaust stream before the exhaust stream contacts an SCR catalyst.
    Type: Grant
    Filed: January 29, 2016
    Date of Patent: October 10, 2017
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Rodney Foo, Rainer Leppelt, Joerg Werner Muench, Ralf Dotzel, Maria Brandmair
  • Publication number: 20170144143
    Abstract: To be able to produce an SCR catalyst (2), in particular one having a zeolite fraction (Z) as catalytically active fraction, in a reliable process and at the same time achieve good catalytic activity of the catalyst (2), an inorganic binder fraction (B) which is catalytically inactive in the starting state and has been treated to develop catalytic activity is mixed into a catalyst composition (4). The inorganic binder component for the binder fraction (B) is, in the starting state, preferably porous particles (10), in particular diatomaceous earth, which display mesoporosity. To effect catalytic activation, the individual particles (10) are either coated with a catalytically active layer (12) or transformed into a catalytically active zeolite (14) with maintenance of the mesoporosity.
    Type: Application
    Filed: March 27, 2015
    Publication date: May 25, 2017
    Applicant: Johnson Matthey Public Limited Company
    Inventors: Juergen BAUER, Ralf DOTZEL, Joerg Werner MUENCH
  • Patent number: 9550182
    Abstract: An SCR-active zeolite catalyst and a method for producing same. To produce the catalyst, an Fe ion-exchanged zeolite is initially subjected to a first temperature treatment within a range of 300 to 600° C. in a reducing hydrocarbon atmosphere such that the oxidation state of the Fe ions decreases and/or the dispersity of the Fe ions on the zeolite increases, whereupon the reduced zeolite is subjected to a second temperature treatment within a range of 300 to 600° C. in an oxidizing atmosphere such that hydrocarbon residues or carbon residues are oxidatively removed, the zeolite being calcined to obtain a catalyst material during the two temperature treatments. Iron contained in the zeolite is stabilized in an oxidation state of less than +3 and/or the dispersity of the Fe ions on the zeolite is permanently increased such that a high SCR activity is achieved within a temperature range of less than 300° C.
    Type: Grant
    Filed: August 21, 2010
    Date of Patent: January 24, 2017
    Assignee: Johnson Matthey Catalysts (Germany) GMBH
    Inventors: Jorg Werner Munch, Ralf Dotzel
  • Publication number: 20170007985
    Abstract: In order to specify a catalytic converter, especially SCR catalytic converter, with maximum catalytic activity, this catalytic converter has at least one catalytically active component and additionally at least one porous inorganic filler component having meso- or macroporosity. The organic porous filler component has a proportion of about 5 to 50% by weight. More particularly, a diatomaceous earth or a pillared clay material is used as the porous inorganic filler component.
    Type: Application
    Filed: January 23, 2015
    Publication date: January 12, 2017
    Inventors: Juergen Bauer, Ralf Dotzel, Joerg Walter Jodlauk, Rainer Leppelt, Joerg Werner Muench
  • Publication number: 20170007991
    Abstract: An extruded, solid honeycomb body comprises a copper-promoted, small pore, crystalline molecular sieve catalyst for converting oxides of nitrogen in the presence of a reducing agent, wherein the crystalline molecular sieve contains a maximum ring size of eight tetrahedral atoms, which extruded, solid honeycomb body comprising: 20-50% by weight matrix component comprising diatomaceous earth, wherein 2-20 weight % of the extruded, solid honeycomb body is diatomaceous earth; 80-50% by weight of the small pore, crystalline molecular sieve ion-exchanged with copper; and 0-10% by weight of inorganic fibres.
    Type: Application
    Filed: January 23, 2015
    Publication date: January 12, 2017
    Inventors: Juergen BAUER, Ralf DOTZEL, Joerg Walter JODLAUK, Rainer LEPPELT, Joerg Werner MUENCH
  • Publication number: 20160288112
    Abstract: A honeycomb catalyst for exhaust gas purification comprising a honeycomb body, the honeycomb body comprising: a fraction acting as a pollutant trap and/or having a catalytically active fraction based on a catalytically active system comprising a base metal; and a catalytically inactive fraction, wherein the catalytically inactive fraction comprises at least one thermally stable sulphate or sulphide component for reducing thermally induced shrinkage of the honeycomb body.
    Type: Application
    Filed: March 31, 2016
    Publication date: October 6, 2016
    Inventors: Juergen BAUER, Diana BISKUPSKI, Ralf DOTZEL, Joerg Walter JODLAUK, Rainer LEPPELT, Joerg Werner MUENCH, Irene PIRAS, Johannes SCHU, Gudmund SMEDLER
  • Publication number: 20160220954
    Abstract: Systems and methods of continuous operation of a urea-SCR system at low temperatures (200-350° C.) in the presence of high SOx containing flue gas are described. The methods comprise introducing a solution of urea and an NO2 forming compound, preferably an alkaline earth metal nitrate, into an exhaust stream before the exhaust stream contacts an SCR catalyst.
    Type: Application
    Filed: January 29, 2016
    Publication date: August 4, 2016
    Inventors: Rodney Foo, Rainer Leppelt, Joerg Werner Muench, Ralf Dotzel, Maria Brandmair
  • Patent number: 9283519
    Abstract: A wall-flow filter for filtering particulate matter from a flowing exhaust gas comprises a catalyst for catalyzing both the conversion of solid carbon in the particulate matter by oxygen and the selective reduction of oxides of nitrogen in the exhaust gas with a nitrogenous reductant, which catalyst comprising optionally stabilized ceria and at least one metal selected from (i) tungsten and (ii) both tungsten and iron.
    Type: Grant
    Filed: February 1, 2011
    Date of Patent: March 15, 2016
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Jillian Elaine Collier, Ralf Dotzel, Sylvie Cécile Laroze, Rainer Leppelt, Paul James Millington, Jörg Werner Münch, Raj Rao Rajaram, Hubert Schedel
  • Publication number: 20160040576
    Abstract: An extruded honeycomb catalyst for nitrogen oxide reduction according to the selective catalytic reduction (SCR) method in exhaust gases from motor vehicles includes an extruded active carrier in honeycomb form having a first SCR catalytically active component and with a plurality of channels through which the exhaust gas flows during operation, and a washcoat coating having a second SCR catalytically active component being applied to the extruded body, wherein the first SCR catalytically active component and the second SCR catalytically active component are each independently one of: (i) vanadium catalyst with vanadium as catalytically active component; (ii) mixed-oxide catalyst with one or more oxides, in particular those of transition metals or lanthanides as catalytically active component; and (iii) an Fe- or a Cu-zeolite catalyst.
    Type: Application
    Filed: August 17, 2015
    Publication date: February 11, 2016
    Applicant: Johnson Matthey Public Limited Company
    Inventors: Guy Richard Chandler, Neil Robert Collins, Ralf Dotzel, Jörg Werner Münch, Paul Richard Phillips, Gudmund Smedler, Andrew Peter Walker
  • Patent number: 9138731
    Abstract: An extruded honeycomb catalyst for nitrogen oxide reduction according to the selective catalytic reduction (SCR) method in exhaust gases from motor vehicles includes an extruded active carrier in honeycomb form having a first SCR catalytically active component and with a plurality of channels through which the exhaust gas flows during operation, and a washcoat coating having a second SCR catalytically active component being applied to the extruded body, wherein the first SCR catalytically active component and the second SCR catalytically active component are each independently one of: (i) vanadium catalyst with vanadium as catalytically active component; (ii) mixed-oxide catalyst with one or more oxides, in particular those of transition metals or lanthanides as catalytically active component; and (iii) an Fe- or a Cu-zeolite catalyst.
    Type: Grant
    Filed: July 31, 2012
    Date of Patent: September 22, 2015
    Assignee: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
    Inventors: Guy Richard Chandler, Neil Robert Collins, Ralf Dotzel, Jörg Werner Münch, Paul Richard Phillips, Gudmund Smedler, Andrew Peter Walker
  • Publication number: 20150224486
    Abstract: Provided is a catalyst composition for treating exhaust gas comprising a blend of a first component and second component, wherein the first component is an aluminosilicate or ferrosilicate molecular sieve component wherein the molecular sieve is either in H+ form or is ion exchanged with one or more transition metals, and the second component is a vanadium oxide supported on a metal oxide support selected from alumina, titania, zirconia, cella, silica, and combinations thereof. Also provided are methods, systems, and catalytic articles incorporating or utilizing such catalyst blends.
    Type: Application
    Filed: August 16, 2013
    Publication date: August 13, 2015
    Inventors: Juergen Bauer, Ralf Dotzel, Joerg Jodlauk, Rainer Leppelt, Joerg Muench, Irene Piras, Gudmund Smedler
  • Publication number: 20150190787
    Abstract: A filter incorporates a catalyst for the Selective Catalytic Reduction (SCR) of NOx gases and removal of particulate matter from the exhaust gas of a lean burn combustion engine, wherein the catalyst includes a vanadate component having an alkaline earth metal, a transition metal, a rare earth metal, or combinations thereof. The vanadate component may be iron vanadate. The filter includes a supported vanadate component disposed on a wall-flow filter. The method of making the filter includes applying an aqueous mixture of the supported vanadate component as a washcoat on the wall-flow filter or extruding a composition containing the supported vanadate component. The method of treating exhaust gases from an engine includes contacting the exhaust gas with the catalyst including the vanadate component.
    Type: Application
    Filed: May 31, 2013
    Publication date: July 9, 2015
    Inventors: Kaneshalingam Arulraj, Ralf Dotzel, Rainer Leppelt, Jorg Werner Muench, Alexandra Tsami Goodwin, Gudmund Smedler
  • Patent number: 9040003
    Abstract: A three way catalyst includes an extruded solid body having by weight: 10-100% of at least one binder/matrix component; 5-90% of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 0-80% optionally stabilised ceria. The catalyst also includes at least one precious metal and optionally at least one non-precious metal, wherein: (i) the at least one precious metal is carried in one or more coating layer(s) on the body surface; (ii) at least one metal is present throughout the body and at least one precious metal is carried in one or more coating layer(s) on a body surface; or (iii) at least one metal is present throughout the body, is present in a higher concentration at a body surface, and at least one precious metal is carried in one or more coating layer(s) on the body surface.
    Type: Grant
    Filed: November 13, 2013
    Date of Patent: May 26, 2015
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Paul Joseph Andersen, Ralf Dotzel, Kwangmo Koo, Rainer Leppelt, Jörg Werner Münch, Jeffery Scott Rieck, Hubert Schedel, Duncan John William Winterborn, Todd Howard Ballinger, Julian Peter Cox