Patents by Inventor Ralf Dotzel
Ralf Dotzel has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10226765Abstract: To be able to produce an SCR catalyst (2), in particular one having a zeolite fraction (Z) as catalytically active fraction, in a reliable process and at the same time achieve good catalytic activity of the catalyst (2), an inorganic binder fraction (B) which is catalytically inactive in the starting state and has been treated to develop catalytic activity is mixed into a catalyst composition (4). The inorganic binder component for the binder fraction (B) is, in the starting state, preferably porous particles (10), in particular diatomaceous earth, which display mesoporosity. To effect catalytic activation, the individual particles (10) are either coated with a catalytically active layer (12) or transformed into a catalytically active zeolite (14) with maintenance of the mesoporosity.Type: GrantFiled: March 27, 2015Date of Patent: March 12, 2019Assignee: Johnson Matthey Public Limited CompanyInventors: Juergen Bauer, Ralf Dotzel, Joerg Werner Muench
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Publication number: 20180320970Abstract: A system (2) for extruding and drying an extruded honeycomb body (14) which has channels (18) that extend in a longitudinal direction (L) and which channels (18) are each bounded by first channel walls (20a) that extend in a first direction (A) which is transverse relative to the longitudinal direction (L), and by second channel walls (20b) that extend in a second direction (B) in which is also transverse relative to the longitudinal direction (L) comprises: (i) an extruder (16) having an extrusion head (17) for producing the honeycomb body (14) by extrusion; (ii) a microwave oven (4) comprising an arrangement of a plurality of microwave radiators (6), each microwave radiator being for irradiating the honeycomb body with a directional microwave beam in an irradiation direction (S); and (iii) a feed unit (12) adjoining the extruder (16) for transferring the honeycomb body from the extruder (16) into the microwave oven (4), wherein either: (a) the extrusion head (17) of the extruder is oriented in such a way thType: ApplicationFiled: August 31, 2016Publication date: November 8, 2018Inventors: Ralf DOTZEL, Walter FISCHER, Thomas HIRSCHMANN, Rainer LEPPELT, Joerg MUENCH, Thomas PROSKE, Thomas SCHOENE, Thomas ZAPF
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Publication number: 20180298801Abstract: An extruded honeycomb catalyst for nitrogen oxide reduction according to the selective catalytic reduction (SCR) method in exhaust gases from motor vehicles includes an extruded active carrier in honeycomb form having a first SCR catalytically active component and with a plurality of channels through which the exhaust gas flows during operation, and a washcoat coating having a second SCR catalytically active component being applied to the extruded body, wherein the first SCR catalytically active component and the second SCR catalytically active component are each independently one of: (i) vanadium catalyst with vanadium as catalytically active component; (ii) mixed-oxide catalyst with one or more oxides, in particular those of transition metals or lanthanides as catalytically active component; and (iii) an Fe- or a Cu-zeolite catalyst.Type: ApplicationFiled: October 20, 2017Publication date: October 18, 2018Inventors: Guy Richard CHANDLER, Neil Robert COLLINS, Ralf DOTZEL, Joerg MUENCH, Paul Richard PHILLIPS, Gudmund SMEDLER, Andrew Peter WALKER
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Publication number: 20180280937Abstract: A SCR catalyst composition comprises a SCR catalyst; and a binder comprising a porous inorganic material, wherein the porous inorganic material comprises a disordered arrangement of delaminated layers, has a disordered porous structure, and has a multimodal pore size distribution comprising at least a first modal maximum having a macroporous or mesoporous pore size and a second modal maximum having a microporous pore size. The SCR catalyst composition can be manufactured using the method comprising the steps of: (i) providing an inorganic material having a layered structure; (ii) contacting the material with a cationic surfactant to form a swollen material; (iii) agitating the swollen material to form an agitated material; and (iv) calcining the agitated material to recover a delaminated inorganic material, wherein an SCR catalyst is mixed with the inorganic material prior to step (iv).Type: ApplicationFiled: March 28, 2018Publication date: October 4, 2018Inventors: Juergen BAUER, Ralf DOTZEL, Joerg Werner MUENCH, Ralitsa PUROVA, Wilhelm SCHWIEGER, Thangaraj SELVAM, Ameen SHAHID
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Publication number: 20180207627Abstract: An extruded, solid honeycomb body comprises a copper-promoted, small pore, crystalline molecular sieve catalyst for converting oxides of nitrogen in the presence of a reducing agent, wherein the crystalline molecular sieve contains a maximum ring size of eight tetrahedral atoms, which extruded, solid honeycomb body comprising: 20-50% by weight matrix component comprising diatomaceous earth, wherein 2-20 weight % of the extruded, solid honeycomb body is diatomaceous earth; 80-50% by weight of the small pore, crystalline molecular sieve ion-exchanged with copper; and 0-10% by weight of inorganic fibres.Type: ApplicationFiled: March 22, 2018Publication date: July 26, 2018Inventors: Juergen Bauer, Ralf Dotzel, Joerg Walter Jodlauk, Rainer Leppelt, Joerg Werner Muench
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Patent number: 9987619Abstract: A filter incorporates a catalyst for the Selective Catalytic Reduction (SCR) of NOx gases and removal of particulate matter from the exhaust gas of a lean burn combustion engine, wherein the catalyst includes a vanadate component having an alkaline earth metal, a transition metal, a rare earth metal, or combinations thereof. The vanadate component may be iron vanadate. The filter includes a supported vanadate component disposed on a wall-flow filter. The method of making the filter includes applying an aqueous mixture of the supported vanadate component as a washcoat on the wall-flow filter or extruding a composition containing the supported vanadate component. The method of treating exhaust gases from an engine includes contacting the exhaust gas with the catalyst including the vanadate component.Type: GrantFiled: May 31, 2013Date of Patent: June 5, 2018Assignee: Johnson Matthey Public Limited CompanyInventors: Kaneshalingam Arulraj, Ralf Dotzel, Rainer Leppelt, Jorg Werner Muench, Alexandra Tsami Goodwin, Gudmund Smedler
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Patent number: 9937488Abstract: An extruded, solid honeycomb body comprises a copper-promoted, small pore, crystalline molecular sieve catalyst for converting oxides of nitrogen in the presence of a reducing agent, wherein the crystalline molecular sieve contains a maximum ring size of eight tetrahedral atoms, which extruded, solid honeycomb body comprising: 20-50% by weight matrix component comprising diatomaceous earth, wherein 2-20 weight % of the extruded, solid honeycomb body is diatomaceous earth; 80-50% by weight of the small pore, crystalline molecular sieve ion-exchanged with copper; and 0-10% by weight of inorganic fibers.Type: GrantFiled: January 23, 2015Date of Patent: April 10, 2018Assignee: Johnson Matthey Catalysts (Germany) GmbHInventors: Juergen Bauer, Ralf Dotzel, Joerg Walter Jodlauk, Rainer Leppelt, Joerg Werner Muench
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Patent number: 9782721Abstract: Systems and methods of continuous operation of a urea-SCR system at low temperatures (200-350° C.) in the presence of high SOx containing flue gas are described. The methods comprise introducing a solution of urea and an NO2 forming compound, preferably an alkaline earth metal nitrate, into an exhaust stream before the exhaust stream contacts an SCR catalyst.Type: GrantFiled: January 29, 2016Date of Patent: October 10, 2017Assignee: Johnson Matthey Public Limited CompanyInventors: Rodney Foo, Rainer Leppelt, Joerg Werner Muench, Ralf Dotzel, Maria Brandmair
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Publication number: 20170144143Abstract: To be able to produce an SCR catalyst (2), in particular one having a zeolite fraction (Z) as catalytically active fraction, in a reliable process and at the same time achieve good catalytic activity of the catalyst (2), an inorganic binder fraction (B) which is catalytically inactive in the starting state and has been treated to develop catalytic activity is mixed into a catalyst composition (4). The inorganic binder component for the binder fraction (B) is, in the starting state, preferably porous particles (10), in particular diatomaceous earth, which display mesoporosity. To effect catalytic activation, the individual particles (10) are either coated with a catalytically active layer (12) or transformed into a catalytically active zeolite (14) with maintenance of the mesoporosity.Type: ApplicationFiled: March 27, 2015Publication date: May 25, 2017Applicant: Johnson Matthey Public Limited CompanyInventors: Juergen BAUER, Ralf DOTZEL, Joerg Werner MUENCH
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Patent number: 9550182Abstract: An SCR-active zeolite catalyst and a method for producing same. To produce the catalyst, an Fe ion-exchanged zeolite is initially subjected to a first temperature treatment within a range of 300 to 600° C. in a reducing hydrocarbon atmosphere such that the oxidation state of the Fe ions decreases and/or the dispersity of the Fe ions on the zeolite increases, whereupon the reduced zeolite is subjected to a second temperature treatment within a range of 300 to 600° C. in an oxidizing atmosphere such that hydrocarbon residues or carbon residues are oxidatively removed, the zeolite being calcined to obtain a catalyst material during the two temperature treatments. Iron contained in the zeolite is stabilized in an oxidation state of less than +3 and/or the dispersity of the Fe ions on the zeolite is permanently increased such that a high SCR activity is achieved within a temperature range of less than 300° C.Type: GrantFiled: August 21, 2010Date of Patent: January 24, 2017Assignee: Johnson Matthey Catalysts (Germany) GMBHInventors: Jorg Werner Munch, Ralf Dotzel
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Publication number: 20170007985Abstract: In order to specify a catalytic converter, especially SCR catalytic converter, with maximum catalytic activity, this catalytic converter has at least one catalytically active component and additionally at least one porous inorganic filler component having meso- or macroporosity. The organic porous filler component has a proportion of about 5 to 50% by weight. More particularly, a diatomaceous earth or a pillared clay material is used as the porous inorganic filler component.Type: ApplicationFiled: January 23, 2015Publication date: January 12, 2017Inventors: Juergen Bauer, Ralf Dotzel, Joerg Walter Jodlauk, Rainer Leppelt, Joerg Werner Muench
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Publication number: 20170007991Abstract: An extruded, solid honeycomb body comprises a copper-promoted, small pore, crystalline molecular sieve catalyst for converting oxides of nitrogen in the presence of a reducing agent, wherein the crystalline molecular sieve contains a maximum ring size of eight tetrahedral atoms, which extruded, solid honeycomb body comprising: 20-50% by weight matrix component comprising diatomaceous earth, wherein 2-20 weight % of the extruded, solid honeycomb body is diatomaceous earth; 80-50% by weight of the small pore, crystalline molecular sieve ion-exchanged with copper; and 0-10% by weight of inorganic fibres.Type: ApplicationFiled: January 23, 2015Publication date: January 12, 2017Inventors: Juergen BAUER, Ralf DOTZEL, Joerg Walter JODLAUK, Rainer LEPPELT, Joerg Werner MUENCH
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Publication number: 20160288112Abstract: A honeycomb catalyst for exhaust gas purification comprising a honeycomb body, the honeycomb body comprising: a fraction acting as a pollutant trap and/or having a catalytically active fraction based on a catalytically active system comprising a base metal; and a catalytically inactive fraction, wherein the catalytically inactive fraction comprises at least one thermally stable sulphate or sulphide component for reducing thermally induced shrinkage of the honeycomb body.Type: ApplicationFiled: March 31, 2016Publication date: October 6, 2016Inventors: Juergen BAUER, Diana BISKUPSKI, Ralf DOTZEL, Joerg Walter JODLAUK, Rainer LEPPELT, Joerg Werner MUENCH, Irene PIRAS, Johannes SCHU, Gudmund SMEDLER
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Publication number: 20160220954Abstract: Systems and methods of continuous operation of a urea-SCR system at low temperatures (200-350° C.) in the presence of high SOx containing flue gas are described. The methods comprise introducing a solution of urea and an NO2 forming compound, preferably an alkaline earth metal nitrate, into an exhaust stream before the exhaust stream contacts an SCR catalyst.Type: ApplicationFiled: January 29, 2016Publication date: August 4, 2016Inventors: Rodney Foo, Rainer Leppelt, Joerg Werner Muench, Ralf Dotzel, Maria Brandmair
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Patent number: 9283519Abstract: A wall-flow filter for filtering particulate matter from a flowing exhaust gas comprises a catalyst for catalyzing both the conversion of solid carbon in the particulate matter by oxygen and the selective reduction of oxides of nitrogen in the exhaust gas with a nitrogenous reductant, which catalyst comprising optionally stabilized ceria and at least one metal selected from (i) tungsten and (ii) both tungsten and iron.Type: GrantFiled: February 1, 2011Date of Patent: March 15, 2016Assignee: Johnson Matthey Public Limited CompanyInventors: Jillian Elaine Collier, Ralf Dotzel, Sylvie Cécile Laroze, Rainer Leppelt, Paul James Millington, Jörg Werner Münch, Raj Rao Rajaram, Hubert Schedel
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Publication number: 20160040576Abstract: An extruded honeycomb catalyst for nitrogen oxide reduction according to the selective catalytic reduction (SCR) method in exhaust gases from motor vehicles includes an extruded active carrier in honeycomb form having a first SCR catalytically active component and with a plurality of channels through which the exhaust gas flows during operation, and a washcoat coating having a second SCR catalytically active component being applied to the extruded body, wherein the first SCR catalytically active component and the second SCR catalytically active component are each independently one of: (i) vanadium catalyst with vanadium as catalytically active component; (ii) mixed-oxide catalyst with one or more oxides, in particular those of transition metals or lanthanides as catalytically active component; and (iii) an Fe- or a Cu-zeolite catalyst.Type: ApplicationFiled: August 17, 2015Publication date: February 11, 2016Applicant: Johnson Matthey Public Limited CompanyInventors: Guy Richard Chandler, Neil Robert Collins, Ralf Dotzel, Jörg Werner Münch, Paul Richard Phillips, Gudmund Smedler, Andrew Peter Walker
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Patent number: 9138731Abstract: An extruded honeycomb catalyst for nitrogen oxide reduction according to the selective catalytic reduction (SCR) method in exhaust gases from motor vehicles includes an extruded active carrier in honeycomb form having a first SCR catalytically active component and with a plurality of channels through which the exhaust gas flows during operation, and a washcoat coating having a second SCR catalytically active component being applied to the extruded body, wherein the first SCR catalytically active component and the second SCR catalytically active component are each independently one of: (i) vanadium catalyst with vanadium as catalytically active component; (ii) mixed-oxide catalyst with one or more oxides, in particular those of transition metals or lanthanides as catalytically active component; and (iii) an Fe- or a Cu-zeolite catalyst.Type: GrantFiled: July 31, 2012Date of Patent: September 22, 2015Assignee: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: Guy Richard Chandler, Neil Robert Collins, Ralf Dotzel, Jörg Werner Münch, Paul Richard Phillips, Gudmund Smedler, Andrew Peter Walker
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Publication number: 20150224486Abstract: Provided is a catalyst composition for treating exhaust gas comprising a blend of a first component and second component, wherein the first component is an aluminosilicate or ferrosilicate molecular sieve component wherein the molecular sieve is either in H+ form or is ion exchanged with one or more transition metals, and the second component is a vanadium oxide supported on a metal oxide support selected from alumina, titania, zirconia, cella, silica, and combinations thereof. Also provided are methods, systems, and catalytic articles incorporating or utilizing such catalyst blends.Type: ApplicationFiled: August 16, 2013Publication date: August 13, 2015Inventors: Juergen Bauer, Ralf Dotzel, Joerg Jodlauk, Rainer Leppelt, Joerg Muench, Irene Piras, Gudmund Smedler
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Publication number: 20150190787Abstract: A filter incorporates a catalyst for the Selective Catalytic Reduction (SCR) of NOx gases and removal of particulate matter from the exhaust gas of a lean burn combustion engine, wherein the catalyst includes a vanadate component having an alkaline earth metal, a transition metal, a rare earth metal, or combinations thereof. The vanadate component may be iron vanadate. The filter includes a supported vanadate component disposed on a wall-flow filter. The method of making the filter includes applying an aqueous mixture of the supported vanadate component as a washcoat on the wall-flow filter or extruding a composition containing the supported vanadate component. The method of treating exhaust gases from an engine includes contacting the exhaust gas with the catalyst including the vanadate component.Type: ApplicationFiled: May 31, 2013Publication date: July 9, 2015Inventors: Kaneshalingam Arulraj, Ralf Dotzel, Rainer Leppelt, Jorg Werner Muench, Alexandra Tsami Goodwin, Gudmund Smedler
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Patent number: 9040003Abstract: A three way catalyst includes an extruded solid body having by weight: 10-100% of at least one binder/matrix component; 5-90% of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 0-80% optionally stabilised ceria. The catalyst also includes at least one precious metal and optionally at least one non-precious metal, wherein: (i) the at least one precious metal is carried in one or more coating layer(s) on the body surface; (ii) at least one metal is present throughout the body and at least one precious metal is carried in one or more coating layer(s) on a body surface; or (iii) at least one metal is present throughout the body, is present in a higher concentration at a body surface, and at least one precious metal is carried in one or more coating layer(s) on the body surface.Type: GrantFiled: November 13, 2013Date of Patent: May 26, 2015Assignee: Johnson Matthey Public Limited CompanyInventors: Paul Joseph Andersen, Ralf Dotzel, Kwangmo Koo, Rainer Leppelt, Jörg Werner Münch, Jeffery Scott Rieck, Hubert Schedel, Duncan John William Winterborn, Todd Howard Ballinger, Julian Peter Cox