Abstract: A capacitor is described with an NbO anode. The capacitor has an NbO anode and an NbO anode lead extending from the NbO anode. A dielectric is on the NbO anode and a conductor is on the dielectric.

Abstract: A capacitor is described with an NbO anode. The capacitor has an NbO anode and an NbO anode lead extending from the NbO anode. A dielectric is on the NbO anode and a conductor is on the dielectric.

Abstract: A pyrolysis oven provides uniform pyrolytic coatings on capacitor anodes. An oven chamber contains cross-flow blowers situated to provide uniform laminar flow of oven atmosphere over the objects to be treated. The top and side walls of the chamber meet in an inverted V such that when the blower operate, a vortex is created in the inverted V in the chamber.

Abstract: A solid electrical capacitor having lowered ESR and fewer short circuit from processing is obtained by adhering a number of islands of a material more basic than the dielectric coating on an anode before forming a conductive polymer on the dielectric coating by a chemical oxidation process.

Abstract: A pyrolysis oven provides uniform pyrolytic coatings on capacitor anodes. An oven chamber contains cross-flow blowers situated to provide uniform laminar flow of oven atmosphere over the objects to be treated. The top and side walls of the chamber meet in an inverted V such that when the blower operate, a vortex is created in the inverted V in the chamber.

Abstract: An electrolytic capacitor comprising a thermally treated anode prepared by heating a manganese dioxide coated porous anodized valve metal nitride anode to a temperature of about 325° C. to about 450° C. The anode may be heated to first temperature of about 200° C. to about 250° C. for a time sufficient for the valve metal nitride anode to reach thermal equilibrium, prior to increasing the temperature to about 325° C. to about 450° C.

Abstract: An intrinsically conductive polymer is prepared with a chemical oxidative process. The polymer is prepared by first dipping or coating a substrate with an Fe(III)-containing oxidizer solution and drying. The substrate is then dipped or coated with a monomer, such as 3,4-ethylenedioxythiophene solution, and reacted to form the conductive polymer. The monomer is dissolved in a solvent in which it has a high solubility but in which the Fe(III)-containing oxidizer has low solubility. This minimizes cross-contamination of the monomer and oxidizer dipping solutions thereby making this process suitable for high volume production. Dissolving the monomer in a solvent allows control over the stoichiometric ratio of monomer to oxidizer and prevents an excess of monomer thereby facilitating the removal of any unreacted monomer by water.

Abstract: The application of polypropylene carbonate in solution to valve metal powders having relatively high surface area, then evaporating the solvent under static (non-agitating) conditions. The static drying of the coated valve metal powder produces a semi-solid cake which may be converted into a free-flowing powder via screening. Valve metal powders so-coated with polypropylene carbonate are particularly well-suited for the fabrication of powder metallurgy anode bodies used for the manufacture of electrolytic capacitors.

Abstract: The invention relates to post pyrolysis thermal treatment for pyrolytic manganese dioxide coatings for use in conjunction with porous anodized valve metal nitride electrolytic capacitor anodes for the purpose of transforming the manganese dioxide to a higher conductivity form of manganese dioxide.

Abstract: The adhesion of a conductive polymer film to an oxidized porous pellet anode is improved by the incorporation of a silane coupling agent in the polymer impregnating solution. The incorporation of the silane coupling agent also decreases leakage current and dissipation factor. Suitable silanes are those of the general formula (R1—R3)—Si—(OR2)3. Each of R2 and R3 is a C1-C6 alkyl group such as methyl, ethyl, or propyl R1 can be chosen from a wide variety of organic functional groups such as epoxy, glycidoxy, amino, and pyrrole. The most preferred silane is 3-glycidoxypropyltrimethoxysilane.

Abstract: Conductive polymers are prepared from a stabilized solution containing a monomer, an Fe(III) oxidizing agent, and a mixed solvent. The solvents are selected to stabilize the Fe(III) oxidizing agent and monomer in solution while allowing highly conducting polymers to be produced upon evaporating the lower-boiling solvent. The higher-boiling solvent does not appreciably complex with Fe(III), while the lower-boiling solvent forms a weak complex with Fe(III). The mixed-solvent system of the present invention may be used for preparing a conductive polymer counter electrode in a solid tantalum capacitor by polymerizing the monomer inside a porous tantalum pellet.

Abstract: The adhesion of a conductive polymer film to an oxidized porous pellet anode is improved by the incorporation of a silane coupling agent in the polymer impregnating solution. The incorporation of the silane coupling agent also decreases leakage current and dissipation factor. Suitable silanes are those of the general formula (R.sup.1 --R.sup.3)--Si--(OR.sup.2).sub.3. Each of R.sup.2 and R.sup.3 is a C.sub.1 -C.sub.6 alkyl group such as methyl, ethyl, or propyl. R.sup.1 can be chosen from a wide variety of organic functional groups such as epoxy, glycidoxy, amino, and pyrrole. The most preferred silane is 3-glycidoxypropyltrimethoxysilane.

Abstract: Conductive polymers are prepared from a stabilized solution containing a monomer, an Fe(III) oxidizing agent, and a mixed solvent. The solvents are selected to stabilize the Fe(III) oxidizing agent and monomer in solution while allowing highly conducting polymers to be produced upon evaporating the lower-boiling solvent. The higher-boiling solvent does not appreciably complex with Fe(III), while the lower-boiling solvent forms a weak complex with Fe(III). The mixed-solvent system of the present invention may be used for preparing a conductive polymer counter electrode in a solid tantalum capacitor by polymerizing the monomer inside a porous tantalum pellet.

Abstract: Conductive polymers are prepared from a stabilized solution containing a monomer, an Fe(III) oxidizing agent, and a mixed solvent. The solvents are selected to stabilize the Fe(III) oxidizing agent and monomer in solution while allowing highly conducting polymers to be produced upon evaporating the lower-boiling solvent. The higher-boiling solvent does not appreciably complex with Fe(III), while the lower-boiling solvent forms a weak complex with Fe(III). The mixed-solvent system of the present invention may be used for preparing a conductive polymer counter electrode in a solid tantalum capacitor by polymerizing the monomer inside a porous tantalum pellet.

Abstract: The present invention provides a manganese nitrate coating having high conductivity and solid tantalum anode capacitors having low ESR by using an oven atmosphere which effectively treats all of the anodes in the oven. The manganese nitrate coating of the present invention is produced under highly oxidizing conditions by providing one or more oxidizing agents more active than nitrogen dioxide in the atmosphere of the oven during pyrolysis of manganese nitrate. The oxidizing agents include nitric acid, hydrogen peroxide, ozone, and mixtures thereof.