Patents by Inventor Richard Dubettier-Grenier
Richard Dubettier-Grenier has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11852408Abstract: In a method for separating air by cryogenic distillation using a column system consisting of a higher pressure column operating at a first pressure and a lower pressure column operating at a second pressure, a first air flow constituting between 75% and 98% of the air sent to the column system compressed to a third pressure above the first pressure, is sent to the higher pressure column, a second air flow constituting between 5% and 25% of the air sent to the column system is compressed to a fourth pressure above the second pressure but lower than the third pressure, is sent to the lower pressure column, a third column separates an argon-enriched flow and the air sent to the lower pressure column constitutes between 10% and 25% of the total air sent to the column system.Type: GrantFiled: May 5, 2021Date of Patent: December 26, 2023Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Jean-Pierre Tranier, Richard Dubettier-Grenier, Maxime Rozieres
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Publication number: 20230375266Abstract: In a process for the recovery of cold from a methane-rich fluid for the cooling of a flow rich in carbon dioxide, cold is provided to a first heat exchanger for the cooling of the flow by the evaporation of an intermediate fluid by exchange of heat with the methane-rich fluid in order to form at least one condensed intermediate fluid flow at at least one pressure level; at least a part of the intermediate fluid evaporated in a second heat exchanger is condensed at at least one pressure into at least one flow.Type: ApplicationFiled: May 18, 2023Publication date: November 23, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Martin RAVENTOS, Richard DUBETTIER-GRENIER, Mathieu LECLERC, Thomas MOREL
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Publication number: 20230023477Abstract: A process for separating carbon dioxide from a waste gas of a fluid catalytic cracking installation including converting at least a portion of the carbon monoxide of the waste gas into carbon dioxide to form a flow enriched in carbon dioxide, separating at least a portion of the flow enriched in carbon dioxide to form a gas enriched in carbon dioxide and depleted in nitrogen and a gas rich in nitrogen and depleted in carbon dioxide, and at least a portion of the gas enriched in carbon dioxide and depleted in nitrogen is separated by way of separation at a temperature of less than 0° C. to form a fluid rich in carbon dioxide and a fluid depleted in carbon dioxide and sending a gas containing at least 90% oxygen to combustion.Type: ApplicationFiled: December 10, 2020Publication date: January 26, 2023Inventors: Guillaume RODRIGUES, Richard DUBETTIER-GRENIER
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Patent number: 11541348Abstract: In a process for separating carbon dioxide from a waste gas (3) of a fluid bed catalytic cracking installation (1) containing carbon dioxide, nitrogen and possibly carbon monoxide, the waste gas (3) is separated by adsorption to form a gas enriched in carbon dioxide and depleted in nitrogen (29) and a gas rich in nitrogen and depleted in carbon dioxide (31), and at least a portion of the gas enriched in carbon dioxide and depleted in nitrogen is separated in a separation device (30) by way of separation at a temperature of less than 0° C. by partial condensation and/or by distillation to form a fluid rich in carbon dioxide (35) and a fluid depleted in carbon dioxide (37).Type: GrantFiled: December 18, 2020Date of Patent: January 3, 2023Assignee: L'Air Liquide, Société Anonyme our l'Étude et l'Exploitation des Procédés Georges ClaudeInventors: Guillaume Rodrigues, Richard Dubettier-Grenier
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Publication number: 20210364233Abstract: In a method for separating air by cryogenic distillation using a column system consisting of a higher pressure column operating at a first pressure and a lower pressure column operating at a second pressure, a first air flow constituting between 75% and 98% of the air sent to the column system compressed to a third pressure above the first pressure, is sent to the higher pressure column, a second air flow constituting between 5% and 25% of the air sent to the column system is compressed to a fourth pressure above the second pressure but lower than the third pressure, is sent to the lower pressure column, a third column separates an argon-enriched flow and the air sent to the lower pressure column constitutes between 10% and 25% of the total air sent to the column system.Type: ApplicationFiled: May 5, 2021Publication date: November 25, 2021Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventors: Jean-Pierre TRANIER, Richard DUBETTIER-GRENIER, Maxime ROZIERES
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Publication number: 20210187435Abstract: In a process for separating carbon dioxide from a waste gas (3) of a fluid bed catalytic cracking installation (1) containing carbon dioxide, nitrogen and possibly carbon monoxide, the waste gas (3) is separated by adsorption to form a gas enriched in carbon dioxide and depleted in nitrogen (29) and a gas rich in nitrogen and depleted in carbon dioxide (31), and at least a portion of the gas enriched in carbon dioxide and depleted in nitrogen is separated in a separation device (30) by way of separation at a temperature of less than 0° C. by partial condensation and/or by distillation to form a fluid rich in carbon dioxide (35) and a fluid depleted in carbon dioxide (37).Type: ApplicationFiled: December 18, 2020Publication date: June 24, 2021Inventors: Guillaume RODRIGUES, Richard DUBETTIER-GRENIER
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Patent number: 10890375Abstract: A method for producing liquefied natural gas and a stream of liquid nitrogen including step a): producing gaseous nitrogen in an air separation unit; step b): liquefying a stream of natural gas in a natural gas liquefaction unit including a main heat exchanger and a system for producing cold; step c): liquefying the nitrogen stream resulting from step a) in the main exchanger of the natural gas liquefaction unit in parallel with the liquefied natural gas in step b); wherein all the cold necessary for liquefying the stream of nitrogen and for liquefying the natural gas is supplied by the system for producing cold of the natural gas liquefaction unit.Type: GrantFiled: November 8, 2016Date of Patent: January 12, 2021Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Nicolas Chambron, Richard Dubettier-Grenier, Loic Joly, Vianney Meunier, Christophe Szamlewski
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Publication number: 20200333069Abstract: A method for separating air by cryogenic distillation, wherein air is compressed in a first compressor, cooled in a heat exchanger and then separated in a system of columns, liquid oxygen is vaporized in the heat exchanger countercurrent to a flow of pressurized gas which pseudo-condenses, a flow of gas which is air or a gas delivered from the system of columns is expanded in a cryogenic expansion turbine having a single wheel, the turbine having an inlet temperature lower than ?100° C., a gas which is air or a gas delivered from the system of columns is compressed in a first booster compressor having a single wheel, with an inlet temperature higher than ?50° C., a gas which is air or a gas delivered from the system of columns.Type: ApplicationFiled: August 30, 2018Publication date: October 22, 2020Inventors: Richard DUBETTIER-GRENIER, Patrick LE BOT
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Patent number: 10605523Abstract: A process comprises a first set of distillation columns and a second set of distillation columns, a low-pressure column of the first set being connected to a column operating at higher pressure of the second set by means of a gas arriving from the top of the column operating at a higher pressure and/or by means of a fluid arriving from the low-pressure column.Type: GrantFiled: November 7, 2014Date of Patent: March 31, 2020Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Benoit Davidian, Richard Dubettier-Grenier
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Patent number: 10392251Abstract: The invention relates to a method for treating a mixture in order to separate carbon dioxide and hydrogen from said mixture, in which: i) the mixture is cooled and partially condensed and a first liquid is separated from the rest of the mixture in a first phase separator; ii) a gas from or derived from a gas from the first phase separator is treated in a hydrogen pressure swing adsorption module in order to produce a hydrogen-rich gas and a hydrogen-depleted residual gas; and iii) said hydrogen-depleted residual gas or a gas derived from said depleted gas is cooled and partially condensed and a second liquid is separated from the remaining gas in a second phase separator, separate from the first phase separator, wherein the first and/or second liquid being rich in carbon dioxide. The invention also relates to an installation for implementing such a method.Type: GrantFiled: May 11, 2015Date of Patent: August 27, 2019Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Nicolas Chambron, Richard Dubettier-Grenier, Mathieu Leclerc, Pascal Marty
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Publication number: 20180372404Abstract: A method for producing liquefied natural gas and a stream of liquid nitrogen including step a): producing gaseous nitrogen in an air separation unit; step b): liquefying a stream of natural gas in a natural gas liquefaction unit including a main heat exchanger and a system for producing cold; step c): liquefying the nitrogen stream resulting from step a) in the main exchanger of the natural gas liquefaction unit in parallel with the liquefied natural gas in step b); wherein all the cold necessary for liquefying the stream of nitrogen and for liquefying the natural gas is supplied by the system for producing cold of the natural gas liquefaction unit.Type: ApplicationFiled: November 8, 2016Publication date: December 27, 2018Inventors: Nicolas CHAMBRON, Richard DUBETTIER-GRENIER, Loic JOLY, Vianney MEUNIER, Christophe SZAMLEWSKI
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Publication number: 20180363977Abstract: A process for separating the components of a gas mixture comprising methane, nitrogen, and at least one hydrocarbon having at least two carbon atoms, or a mixture of these hydrocarbons, including the following steps: a) demonization of the gas mixture with at least one demethenization column; b) extraction of a liquid comprising at least 85 mol % of the hydrocarbons having at least two carbon atoms, partial condensation of a gas mixture in order to obtain a liquid, at least a portion of which is treated in order to be extracted as denitrogenated natural gas product and a second gas; d) introduction of the second gas and/or the gas mixture into a nitrogen removal column, obtained from which are a gas and a liquid, e) treatment of the gas in a nitrogen removal system in order to produce a gas stream comprising 5 mol % at most of nitrogen.Type: ApplicationFiled: October 1, 2015Publication date: December 20, 2018Inventors: Bertrand DEMOLLIENS, Richard DUBETTIER-GRENIER, Ludovic GRANADOS, Julie GRAVE, Michele MURINO, Jean-Marc PEYRON, Paul TERRIEN, Marie-Pascal VICTOR
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Patent number: 10054366Abstract: Blast furnace installation having top gas recycling and process for operating same, in which the oxygen concentration of the oxidizing gas injected into the blast furnace is regulated as a function of the flow rate of the recycled top gas.Type: GrantFiled: December 20, 2011Date of Patent: August 21, 2018Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Philippe Blostein, Michel Devaux, Richard Dubettier-Grenier
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Patent number: 10012435Abstract: In a method for producing a first pressurized gas and a second gas on a one-off basis by cryogenic distillation of air, according to a first step, no fluid heats up or cools down in a second heat exchanger, and according to a second step, a flow of pressurized liquid from the double column heats up and vaporizes in the second exchanger to form a gas required on a one-off basis, a flow of air at the second pressure cools in the second exchanger.Type: GrantFiled: August 28, 2013Date of Patent: July 3, 2018Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Marie Cognard, Richard Dubettier-Grenier, Sylvain Gerard
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Patent number: 10012434Abstract: In a process for the production of carbon dioxide and hydrogen from a gas flow comprising at least hydrogen, at least one sulfur-comprising component and carbon dioxide originating from a Claus unit fed with a gas comprising at least 50 mol % of oxygen, the gas flow is compressed and dried in order to produce a compressed and dried gas flow and the compressed and dried gas flow is separated at a subambient temperature in order to produce at least a fluid enriched in carbon dioxide with respect to the compressed and dried gas flow and at least a fluid enriched in hydrogen with respect to the compressed and dried gas flow.Type: GrantFiled: February 11, 2014Date of Patent: July 3, 2018Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Nicolas Chambron, Richard Dubettier-Grenier, Sylvain Gerard
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Patent number: 9976803Abstract: Process for producing gaseous oxygen by cryogenic distillation of air, wherein a portion of the feed air flow is brought to a pressure P1, by means of a first compressor, the suction temperature T0 of which is between 0 and 50° C., the gas at the pressure P1 is cooled, in order to generate an air stream at the pressure P1 and the temperature T1 between 5 and 45° C., a portion of the air compressed in the first compressor undergoes an additional compression step starting from the temperature T1 and pressure P1 to a pressure P2 greater than P1, then is cooled, to the temperature T2 where T2 and T1 differ by less than 10° C.Type: GrantFiled: September 9, 2014Date of Patent: May 22, 2018Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATTION DES PROCEDES GEORGES CLAUDEInventors: Alexis Asse, Ingrid Berthaume, Alain Briglia, Richard Dubettier-Grenier, Patrick Le Bot, Jean-Marc Peyron
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Patent number: 9895653Abstract: In a process for the separation of a stream containing carbon dioxide, water and at least one light impurity including a separation step at subambient temperature, the feed stream is compressed in a compressor comprising at least two stages to form a compressed feed stream, the compressed feed stream is purified in an adsorption unit to remove water and form a dried compressed stream, the dried compressed stream or a stream derived therefrom is cooled to a subambient temperature and separated by partial condensation and/or distillation in a separation apparatus, liquid enriched in carbon dioxide is removed from the separation apparatus, the adsorption unit is regenerated using a regeneration gas and the regeneration gas is formed by separating, by permeation in a permeation unit, the dried compressed stream or a gas derived therefrom, the permeate of the permeation unit constituting the regeneration gas.Type: GrantFiled: July 11, 2013Date of Patent: February 20, 2018Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Arthur Darde, Richard Dubettier-Grenier, David J. Hasse, Sudhir S. Kulkarni, Mathieu LeClerc, Paul Terrien
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Patent number: 9739485Abstract: The invention relates to a unit for the purification of a gas flow comprising CO and at least 45% CO2 and a method of operating said unit. In one embodiment, said unit contains a first compressor, a heat exchanger configured to cool the compressed gas flow, a separation chamber configured to separate head gas produced in the heat exchanger, a heater disposed on the line of the head gas originating from the separation chamber, a catalytic oxidation unit for oxidizing the compressed CO in the gas flow originating from the heater, and turbines placed downstream of the catalytic oxidation unit.Type: GrantFiled: September 25, 2013Date of Patent: August 22, 2017Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges ClaudeInventors: Nicolas Chambron, Arthur Darde, Richard Dubettier-Grenier, Mathieu Leclerc
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Patent number: 9696087Abstract: A method for separating air is provided, in which a flow of oxygen-rich liquid is sent to a top of a pure oxygen column, having a pure oxygen reboiler, in which said flow is purified in order to form a vessel liquid containing at least 98 mol % of oxygen and the vessel liquid is drawn off as a product. A supercharged airflow at a second pressure is sent to the pure oxygen reboiler and to a liquid oxygen vaporizer; a nitrogen-rich gas is drawn from the top of the medium-pressure column and sent to an intermediate reboiler of the low-pressure column and the condensed gas is sent to the top of the medium-pressure column; and a nitrogen-rich gas or air is sent to a vessel reboiler of the low-pressure column and the liquid that condenses therein is sent to the medium-pressure column.Type: GrantFiled: April 5, 2012Date of Patent: July 4, 2017Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges ClaudeInventors: Benoit Davidian, Richard Dubettier-Grenier, Loïc Joly
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Patent number: 9644533Abstract: In a method for supplying nitrogen to a combustion chamber, gaseous nitrogen (9) is drawn off from an air separation unit (7) at a first pressure, the nitrogen is compressed in at least two stages (C1, C2) of a nitrogen compressor and sent to a combustion chamber (25) at a second pressure, which is the output pressure of the last stage (C3) of the nitrogen compressor, between two stages of the nitrogen compressor the nitrogen is humidified by direct contact in passing through a contactor (17) supplied at its top with water, and the humidified nitrogen is compressed in at least one stage of the nitrogen compressor and sent to the combustion chamber.Type: GrantFiled: November 23, 2012Date of Patent: May 9, 2017Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges ClaudeInventors: Richard Dubettier-Grenier, Sylvain Gerard, Loïc Joly