Patents by Inventor Richard Dubettier-Grenier

Richard Dubettier-Grenier has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20170081186
    Abstract: The invention relates to a method fro treating a mixture in order to separate carbon dioxide and hydrogen from said mixture, in which: i) the mixture is cooled and partially condensed and a first liquid is separated from the rest of the mixture in a first phase separator; ii) a gas from or derived from a gas from the first phase separator is treated in a hydrogen pressure swing adsorption module in order to produce a hydrogen-rich gas and a hydrogen-depleted residual gas; and iii) said hydrogen-depleted residual gas or a gas derived from said depleted gas is cooled and partially condensed and a second liquid is separated from the remaining gas in a second phase separator, separate from the first phase separator, wherein the first and/or second liquid being rich in carbon dioxide. The invention also relates to an installation for implementing such a method.
    Type: Application
    Filed: May 11, 2015
    Publication date: March 23, 2017
    Applicant: L'Air Liquide, Societe Anonyme pour I'Etude et I'Exploitation des Procedes Georges Claude
    Inventors: Nicolas CHAMBRON, Richard DUBETTIER-GRENIER, Mathieu LECLERC, Pascal MARTY
  • Patent number: 9534836
    Abstract: An air separation plant is provided that includes a plurality of air compressors, a plurality of air purification units, and one or more cold boxes. In a first mode of operation, a first air compressor is configured to compress air to a higher pressure than a second air compressor. In a second mode of operation, the second air compressor is configured to compress air to a higher pressure than during the first mode of operation.
    Type: Grant
    Filed: June 17, 2011
    Date of Patent: January 3, 2017
    Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Richard Dubettier-Grenier, Alain Guillard
  • Publication number: 20160298900
    Abstract: A process comprises a first set of distillation columns and a second set of distillation columns, a low-pressure column of the first set being connected to a column operating at higher pressure of the second set by means of a gas arriving from the top of the column operating at a higher pressure and/or by means of a fluid arriving from the low-pressure column.
    Type: Application
    Filed: November 7, 2014
    Publication date: October 13, 2016
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'E tude l'Exploition des Procedes Georges Claude
    Inventors: Benoit DAVIDIAN, Richard DUBETTIER-GRENIER
  • Patent number: 9453645
    Abstract: The process can include, during a first and second period of time, sending a first stream of oxygen rich gas from an ASU to a first oxygen consuming unit, the first unit being integrated with a system for the generation of electricity, during the first period of time, sending a second stream of oxygen rich gas from the ASU to a second unit, the second unit being a combustion unit, a first stream of air being supplied to the combustion unit during the first period, removing a second CO2 containing gas from the second unit without sending any of the second CO2 containing gas back to the second unit and during the second period of time, sending no oxygen rich gas from the ASU to the second unit without sending any of the third CO2 containing gas back to the second unit.
    Type: Grant
    Filed: August 28, 2013
    Date of Patent: September 27, 2016
    Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Richard Dubettier-Grenier, Alain Guillard, Dennis McDonald, Sebastien De Limon
  • Publication number: 20160231053
    Abstract: Process for producing gaseous oxygen by cryogenic distillation of air, wherein a portion of the feed air flow is brought to a pressure P1, by means of a first compressor, the suction temperature T0 of which is between 0 and 50° C., the gas at the pressure P1 is cooled, in order to generate an air stream at the pressure P1 and the temperature T1 between 5 and 45° C., a portion of the air compressed in the first compressor undergoes an additional compression step starting from the temperature T1 and pressure P1 to a pressure P2 greater than P1, then is cooled, to the temperature T2 where T2 and T1 differ by less than 10° C.
    Type: Application
    Filed: September 9, 2014
    Publication date: August 11, 2016
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Alexis ASSE, Ingrid BERTHAUME, Alain BRIGLIA, Richard DUBETTIER-GRENIER, Patrick LE BOT, Jean-Marc PEYRON
  • Patent number: 9360251
    Abstract: The invention relates to an integrated device for separating air and heating a gas in the air resulting from said air separation, comprising: an air separation device (9); a heat exchanger (13, 43); a channel for conveying the gas in the air to the heat exchanger; and a channel for conveying water to the heat exchanger, the water-conveying channel being connected to the water inlet or water outlet of a water preheat exchanger (5) or a water deaerator (27). According to the invention, the preheat exchanger and/or the deaerator are connected to an oxy-combustion boiler (19) in order to convey water to and from the boiler, said boiler also being connected to the separation device in order to receive an oxygen-enriched gas (17).
    Type: Grant
    Filed: March 3, 2011
    Date of Patent: June 7, 2016
    Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Richard Dubettier-Grenier, Jean-Pierre Tranier
  • Publication number: 20160131423
    Abstract: In a process for the production of carbon dioxide and hydrogen from a gas flow comprising at least hydrogen, at least one sulfur-comprising component and carbon dioxide originating from a Claus unit fed with a gas comprising at least 50 mol % of oxygen, the gas flow is compressed and dried in order to produce a compressed and dried gas flow and the compressed and dried gas flow is separated at a subambient temperature in order to produce at least a fluid enriched in carbon dioxide with respect to the compressed and dried gas flow and at least a fluid enriched in hydrogen with respect to the compressed and dried gas flow.
    Type: Application
    Filed: February 11, 2014
    Publication date: May 12, 2016
    Inventors: Nicolas CHAMBRON, Richard DUBETTIER-GRENIER, Sylvain GERARD
  • Patent number: 9206041
    Abstract: In a method for the combined production of ammonia synthesis gas and carbon dioxide from a mixture of hydrocarbons, the cooled mixture from a reverse conversion is separated in an adsorption unit by pressure modulation (or PSA) producing a hydrogen-enriched flow having a purity at least equal to 98% and a residual gas, the residual gas is processed to produce carbon dioxide and a gas containing nitrogen and methane and at least a portion of the hydrogen-enriched flow and at least a portion of the gas containing nitrogen and methane are mixed to form an ammonia synthesis gas.
    Type: Grant
    Filed: June 6, 2013
    Date of Patent: December 8, 2015
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés George Claude
    Inventors: Arthur Darde, Richard Dubettier-Grenier
  • Publication number: 20150283503
    Abstract: The invention relates to a method and apparatus for the oxygen purification of a supply gas flow comprising at least 45% CO2 and at least 10% oxygen, said method includes the steps of catalytically oxidizing the supply gas flow in the presence of a fuel and recovering the oxygen-depleted gas flow.
    Type: Application
    Filed: September 18, 2013
    Publication date: October 8, 2015
    Inventors: Nicolas Chambron, Arthur Darde, Richard Dubettier-Grenier, Matthieu Leclerc
  • Publication number: 20150285493
    Abstract: The invention relates to a unit for the purification of a gas flow comprising CO and at least 45% CO2 and a method of operating said unit. In one embodiment, said unit contains a first compressor, a heat exchanger configured to cool the compressed gas flow, a separation chamber configured to separate head gas produced in the heat exchanger, a heater disposed on the line of the head gas originating from the separation chamber, a catalytic oxidation unit for oxidizing the compressed CO in the gas flow originating from the heater, and turbines placed downstream of the catalytic oxidation unit.
    Type: Application
    Filed: September 25, 2013
    Publication date: October 8, 2015
    Inventors: Nicolas Chambron, Arthur Darde, Richard Dubettier-Grenier, Mathie Leclerc
  • Publication number: 20150253075
    Abstract: A process for the separation of air by cryogenic distillation operates either with a product ratio greater than 2.5, in which case nitrogen enriched liquid is sent from a storage tank to the column system and nitrogen enriched gas from the column system is compressed in a first compressor having an inlet temperature of less than ?50° C. and then warmed in the heat exchanger, or with a product ratio less than 2.5, in which case a second nitrogen rich gas removed from the column system is expanded in a turbine having an inlet temperature lower than the ambient temperature or liquefied in a liquefier and nitrogen enriched liquid is sent to the storage tank from the outlet of the turbine and/or from the column system and/or from the liquefier.
    Type: Application
    Filed: September 13, 2013
    Publication date: September 10, 2015
    Inventors: Benoit Davidian, Richard Dubettier-Grenier, Jean-Marc Peyron, Bernard Saulnier
  • Publication number: 20150241121
    Abstract: In a method for producing a first pressurized gas and a second gas on a one-off basis by cryogenic distillation of air, according to a first step, no fluid heats up or cools down in a second heat exchanger, and according to a second step, a flow of pressurized liquid from the double column heats up and vaporizes in the second exchanger to form a gas required on a one-off basis, a flow of air at the second pressure cools in the second exchanger.
    Type: Application
    Filed: August 28, 2013
    Publication date: August 27, 2015
    Inventors: Marie Cognard, Richard Dubettier-Grenier, Sylvain Gerard
  • Publication number: 20150226428
    Abstract: The process can include, during a first and second period of time, sending a first stream of oxygen rich gas from an ASU to a first oxygen consuming unit, the first unit being integrated with a system for the generation of electricity, during the first period of time, sending a second stream of oxygen rich gas from the ASU to a second unit, the second unit being a combustion unit, a first stream of air being supplied to the combustion unit during the first period, removing a second CO2 containing gas from the second unit without sending any of the second CO2 containing gas back to the second unit and during the second period of time, sending no oxygen rich gas from the ASU to the second unit without sending any of the third CO2 containing gas back to the second unit.
    Type: Application
    Filed: August 28, 2013
    Publication date: August 13, 2015
    Inventors: Richard Dubettier-Grenier, Alain Guillard, Dennis McDonald, Sebastien De Limon
  • Publication number: 20150191351
    Abstract: In a method for the combined production of ammonia synthesis gas and carbon dioxide from a mixture of hydrocarbons, the cooled mixture from a reverse conversion is separated in an adsorption unit by pressure modulation (or PSA) producing a hydrogen-enriched flow having a purity at least equal to 98% and a residual gas, the residual gas is processed to produce carbon dioxide and a gas containing nitrogen and methane and at least a portion of the hydrogen-enriched flow and at least a portion of the gas containing nitrogen and methane are mixed to form an ammonia synthesis gas.
    Type: Application
    Filed: June 6, 2013
    Publication date: July 9, 2015
    Inventors: Arthur Darde, Richard Dubettier-Grenier
  • Publication number: 20150176892
    Abstract: In a process for storing liquid rich in carbon dioxide in solid form and subsequently releasing liquid containing mainly carbon dioxide, a solid containing mainly carbon dioxide is formed from at least part of the liquid with or without using indirect heat exchange means, storing the solid containing mainly carbon dioxide, the process steps including subsequently causing at least part of the solid containing mainly carbon dioxide to melt forming a liquid containing mainly carbon dioxide, by direct contact with an auxiliary gas rich in carbon dioxide, wherein the auxiliary gas is at least partially liquefied to form liquid containing mainly carbon dioxide by heat exchange with the melting solid and removing at least part of the liquid containing mainly carbon dioxide.
    Type: Application
    Filed: July 12, 2013
    Publication date: June 25, 2015
    Inventors: Arthur Darde, Richard Dubettier-Grenier, Frederick Lockwood, Paul Terrien, Jean-Pierre Tranier, Xavier Traversac
  • Publication number: 20150174523
    Abstract: In a process for the separation of a stream containing carbon dioxide, water and at least one light impurity including a separation step at subambient temperature, the feed stream is compressed in a compressor comprising at least two stages to form a compressed feed stream, the compressed feed stream is purified in an adsorption unit to remove water and form a dried compressed stream, the dried compressed stream or a stream derived therefrom is cooled to a subambient temperature and separated by partial condensation and/or distillation in a separation apparatus, liquid enriched in carbon dioxide is removed from the separation apparatus, the adsorption unit is regenerated using a regeneration gas and the regeneration gas is formed by separating, by permeation in a permeation unit, the dried compressed stream or a gas derived therefrom, the permeate of the permeation unit constituting the regeneration gas.
    Type: Application
    Filed: July 11, 2013
    Publication date: June 25, 2015
    Inventors: Arthur Darde, Richard Dubettier-Grenier, David J. Hasse, Sudhir S. Kulkarni, Mathieu Leclerc, Paul Terrien
  • Patent number: 9034080
    Abstract: The present invention relates to a process and apparatus for producing a fluid enriched in carbon dioxide starting from a waste gas from a ferrous metallurgy unit.
    Type: Grant
    Filed: December 1, 2011
    Date of Patent: May 19, 2015
    Assignee: L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Alain Briglia, Christophe Szamleski, Olivier De Cayeux, Richard Dubettier-Grenier, Alain Guillard, Xavier Traversac
  • Publication number: 20150121955
    Abstract: The invention relates to a method for air separation by cryogenic distillation in a column system that includes at least a first column operating at a first pressure, and a second column operating at a second pressure that is lower than the first pressure, the head of the first column being thermally connected to the tank of the second column via a vaporizer-condenser, a first portion of a nitrogen-enriched gas is drawn from the head of the first column, compressed in a compressor having an inlet temperature no higher than ?150° C. and condensed in the vaporizer-condenser, an oxygen-rich fluid is drawn from the lower portion of the second column and heated in the exchange line, a nitrogen-rich gas is drawn from the upper portion of the second column and heated in the exchange line, and a second portion of the nitrogen-enriched gas is expanded in a turbine without being compressed.
    Type: Application
    Filed: February 27, 2013
    Publication date: May 7, 2015
    Inventors: Benoit Davidian, Richard Dubettier-Grenier, Alain Guillard, Loic Joly, Patrick Le Bot, Petra Pechova
  • Publication number: 20140360201
    Abstract: In a method for supplying nitrogen to a combustion chamber, gaseous nitrogen (9) is drawn off from an air separation unit (7) at a first pressure, the nitrogen is compressed in at least two stages (C1, C2) of a nitrogen compressor and sent to a combustion chamber (25) at a second pressure, which is the output pressure of the last stage (C3) of the nitrogen compressor, between two stages of the nitrogen compressor the nitrogen is humidified by direct contact in passing through a contactor (17) supplied at its top with water, and the humidified nitrogen is compressed in at least one stage of the nitrogen compressor and sent to the combustion chamber.
    Type: Application
    Filed: November 23, 2012
    Publication date: December 11, 2014
    Inventors: Richard Dubettier-Grenier, Sylvain Gerard, Loic Joly
  • Publication number: 20140230606
    Abstract: Ironmaking method and installation with recirculation of exhaust gas as a reduction gas and whereby part of the exhaust gas is purged upstream and/or downstream of a CO/CO2 separation unit, said purged exhaust gas being subjected to a water gas shift reaction for H2 generation.
    Type: Application
    Filed: September 28, 2012
    Publication date: August 21, 2014
    Inventors: Xavier Traversac, Richard Dubettier-Grenier, Sebastien De Limon, Philippe Court