Abstract: The present disclosure provides a core-sheath filament. The core-sheath filament includes an adhesive core and a non-tacky sheath, wherein the sheath exhibits a melt flow index of less than 15 grams per 10 minutes. The present disclosure also provides a method of printing an adhesive. The method includes a) melting a core-sheath filament in a nozzle to form a molten composition, and b) dispensing the molten composition through the nozzle onto a substrate. Steps a) and b) are carried out one or more times to form a printed adhesive. The core-sheath filament includes an adhesive core and a non-tacky sheath. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process using a core-sheath filament, the article including a printed adhesive based on the digital object.

Abstract: Described are adhesive compositions containing a block copolymer component that includes a midblock segment and a plurality of end block segments, each end block segment comprising polystyrene, a (meth)acrylic functional additive having a glass transition temperature of from 50° C. to 160° C., a first tackifier compatible with the midblock segment and containing a hydrocarbon, and a second tackifier compatible with the end block segments and containing a polyphenylene ether. These compositions are useful in providing pressure-sensitive adhesives that are melt processible, display a high temperature resistance, and effectively bond to low surface energy substrates.

Abstract: Pressure-sensitive adhesive compositions and articles that include a layer of the pressure-sensitive adhesive compositions are provided. The pressure-sensitive adhesive compositions are particularly well suited for use with substrates that have been considered to have difficult to bond to surfaces such as those routinely encountered in the automotive industry. For example, the pressure-sensitive adhesive can be adhered to clear coat compositions, painted surfaces, and various polymeric materials having low energy surfaces (e.g., surfaces having a surface energy no greater than 35 dynes per centimeter).

Abstract: Methods of bonding a pressure-sensitive adhesive to a substrate are provided. The methods include heating a styrenic block copolymer composition to provide an adhesive melt composition, wherein the styrenic block copolymer composition contains a hard segment block with a glass transition temperature of from 90° C. to 220° C.; masticating the adhesive melt composition; delivering the adhesive melt composition onto the substrate at a temperature that exceeds the glass transition temperature of the hard segment block by from 20° C. to 150° C.; and cooling the adhesive melt composition to obtain a bonded pressure-sensitive adhesive. Optionally, the substrate can be a non-film substrate, or the styrenic block copolymer composition can be provided in a core-sheath filament that includes a styrenic block copolymer core and a sheath that is non-tacky at ambient temperature.

Abstract: A core-sheath filament including a crosslinkable adhesive core that can be cured using ultraviolet or visible light radiation. These crosslinkable adhesive core compositions can provide very high bond strength and are capable of replacing traditional mechanical fasteners in many industrial applications. Core-sheath filaments including such crosslinkable compositions, crosslinked compositions, articles containing these compositions, and methods of making the articles are provided. The crosslinkable compositions contain pendant aromatic ketone groups or pendant (meth)acryloyl groups that, upon exposure to ultraviolet radiation, result in the formation of crosslinks within the polymeric material. The crosslinked compositions can function as pressure-sensitive adhesives.

Abstract: Tape constructions having a pressure sensitive adhesive containing a block copolymer component that includes a midblock segment and a plurality of end block segments, each end block segment comprising polystyrene, a (meth)acrylic functional additive having a glass transition temperature of from 50° C. to 160° C., a first tackifier compatible with the midblock segment and containing a hydrocarbon, and a second tackifier compatible with the end block segments and containing a polyphenylene ether that can be incorporated into articles. The pressure sensitive adhesive is subjected to electron beam radiation.

Abstract: An adhesive article including: a coextruded polymeric backing that includes: a first layer including an amorphous polyamide, the first layer having first and second opposing major surfaces; and a second layer including a polar-modified polyolefin, the second layer having first and second opposing major surfaces; wherein the first major surface of the second layer is in contact with the second major surface of the first layer; and an acrylic pressure sensitive adhesive layer in contact with the first major surface of the first layer of the backing.

Abstract: A core-sheath filament including a crosslinkable adhesive core that can be cured using ultraviolet or visible light radiation. These crosslinkable adhesive core compositions can provide very high bond strength and are capable of replacing traditional mechanical fasteners in many industrial applications. Core-sheath filaments including such crosslinkable compositions, crosslinked compositions, articles containing these compositions, and methods of making the articles are provided. The crosslinkable compositions contain pendant aromatic ketone groups or pendant (meth)acryloyl groups that, upon exposure to ultraviolet radiation, result in the formation of crosslinks within the polymeric material. The crosslinked compositions can function as pressure-sensitive adhesives.

Abstract: Provided are systems for dispensing a filament adhesive. The dispensing systems include a dispensing head with a barrel including one or more heating elements, and a rotatable screw received in the barrel, the rotatable screw including at least one mixing element. An inlet extends through a side of the barrel for receiving the filament adhesive. An outlet at a distal end of the barrel for dispensing the filament adhesive in molten form. The dispensing system further includes a filament adhesive having a configuration to be received into the inlet of the dispensing head. Using the provided dispensing systems, and optionally with the assistance of a computer, adhesives can be precisely applied to pre-determined locations on a substrate.

Abstract: Provided are dispensing devices and methods for a filament adhesive. The dispensing devices use a barrel including one or more heating elements, and a rotatable screw received in the barrel, the rotatable screw optionally including at least one mixing element. An inlet extends through a side of the barrel for receiving the filament adhesive, the inlet including a beveled nip point to prevent breakage of the filament adhesive as it is drawn into the barrel. An outlet at a distal end of the barrel for dispensing the filament adhesive in molten form. Using the provided dispensing devices, and optionally with the assistance of a computer, adhesives can be precisely applied to pre-determined locations on a substrate.

Abstract: The present disclosure relates to a co-extruded multilayer adhesive assembly comprising: a) a heat-activatable adhesive resin layer comprising a (co)polymer of one or more monomers selected from the group consisting of olefins; and b) a pressure sensitive adhesive polymeric foam layer comprising a rubber-based elastomeric material; wherein the heat-activatable adhesive resin layer is in direct contact with the pressure sensitive adhesive foam layer, and wherein the surface of the heat-activatable adhesive resin layer which is in direct contact with the pressure sensitive adhesive foam layer and the surface of the pressure sensitive adhesive foam layer which is indirect contact with the heat-activatable adhesive resin layer are free of any chemical or physical adhesion-promoting surface treatment. The present disclosure also relates to a method of manufacturing such a co-extruded multilayer adhesive assembly and uses thereof.

Abstract: Provided are adhesive articles that include a barrier layer that is substantially impermeable to oxygen gas at ambient temperature and pressure along with a heat-bondable layer, which could be a discrete layer adjacent to the barrier layer or integral with the barrier layer. The adhesive article further includes a backing extending across and coupled to the barrier layer and an adhesive layer extending across and coupled to the backing opposite the barrier layer. The barrier layer reduces or eliminates migration of plasticizers from the bonded seal into the adhesive article, limiting deterioration of tape performance over time.

Abstract: Described are adhesive compositions containing a block copolymer component that includes a midblock segment and a plurality of end block segments, each end block segment comprising polystyrene, a (meth)acrylic functional additive having a glass transition temperature of from 50° C. to 160° C., a first tackifier compatible with the midblock segment and containing a hydrocarbon, and a second tackifier compatible with the end block segments and containing a polyphenylene ether. These compositions are useful in providing pressure-sensitive adhesives that are melt processible, display a high temperature resistance, and effectively bond to low surface energy substrates.

Abstract: The present disclosure provides a core-sheath filament. The core-sheath filament includes an adhesive core and a non-tacky sheath, wherein the sheath exhibits a melt flow index of less than 15 grams per 10 minutes. The present disclosure also provides a method of printing an adhesive. The method includes a) melting a core-sheath filament in a nozzle to form a molten composition, and b) dispensing the molten composition through the nozzle onto a substrate. Steps a) and b) are carried out one or more times to form a printed adhesive. The core-sheath filament includes an adhesive core and a non-tacky sheath. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process using a core-sheath filament, the article including a printed adhesive based on the digital object.

Abstract: There is provided a pressure sensitive adhesive demonstrating adhesion to low energy surfaces which is a radiation-crosslinked mixture of a first component comprising a blend of a nonfunctionalized polysiloxane and a silicate-based tackifier; and a second component comprising a blend of a styrenic block copolymer and a tackifier compatible with the styrenic block copolymer. In some embodiments the weight ratio of nonfunctionalized polysiloxane to styrenic block copolymer.in the mixture is between 0.20 and 1.15. In some embodiments the tackifier compatible with the styrenic block copolymer is a blend of hydrogenated hydrocarbon resin tackifier and terpene-based tackifier in a weight ratio of greater than 0.75 hydrogenated hydrocarbon resin tackifier to terpene-based tackifier.

Abstract: A multilayer pressure sensitive adhesive assembly comprising a polymeric foam layer and a first pressure sensitive adhesive layer adjacent to the polymeric foam layer. The polymeric foam comprises a multi-arm block copolymer having the formula Qn-Y, with Q representing an arm of the multi-arm block copolymer, n being at least 3, and Y being the residue of a multifunctional coupling agent; a polymeric plasticizer having a weight average molecular weight Mw of at least 10,000 g/mol; and at least one hydrocarbon tackifier having a VOC value of less than 1000 ppm. The first pressure sensitive adhesive comprises a linear block copolymer having the formula M-(G)p, with M being a rubbery block and p being 1 or 2; at least one second hydrocarbon tackifier; and a (meth)acrylate copolymer having a Tg higher than 25° C. and a weight average molecular weight (Mw) between 1000 and 100,000 Daltons.

Abstract: A multilayer pressure sensitive adhesive assembly comprising a polymeric foam layer and a first pressure sensitive adhesive layer adjacent to the polymeric foam layer. The polymeric foam comprises a plurality of activated carbon particles distributed therein, and the first pressure sensitive adhesive comprises: a linear block copolymer having the formula M-(G)p, wherein M is a rubbery block; each G is a glassy block comprising a polymerized monovinyl aromatic monomer; and p is 1 or 2; at least one hydrocarbon tackifier; and a (meth)acrylate copolymer having a Tg higher than 25° C. and a weight average molecular weight (Mw) comprised between 1000 and 100.000 Daltons, and comprising: (meth)acrylic acid ester monomer units having a Tg higher than 25° C. when homopolymerized.

Abstract: Pressure-sensitive adhesive compositions and articles that include a layer of the pressure-sensitive adhesive compositions are provided. The pressure-sensitive adhesive compositions are particularly well suited for use with substrates that have been considered to have difficult to bond to surfaces such as those routinely encountered in the automotive industry. For example, the pressure-sensitive adhesive can be adhered to clear coat compositions, painted surfaces, and various polymeric materials having low energy surfaces (e.g., surfaces having a surface energy no greater than 35 dynes per centimeter).

Abstract: A pressure-sensitive adhesive is provided that is a dried product of a latex composition, which is formed from an emulsion composition. The latex composition and the emulsion composition are also provided. The emulsion composition has droplets that contain various monomers plus a (meth)acrylate polymer and a hydrogenated hydrocarbon tackifier dissolved in the monomers. Additionally, an article containing a layer of the pressure-sensitive adhesive and a method of forming the pressure-sensitive adhesive are provided. The pressure-sensitive adhesives often have both high peel adhesion and high shear strength (i.e., high cohesive strength or high shear holding power).

Abstract: Described herein is a foam adhesive article comprising: a closed cell foam layer comprising an extruded thermoplastic polymer foam and particles distributed therein, wherein the particles comprise a plurality of hollow particles, wherein the hollow particles comprise at least one of thermoplastic expanded polymeric particles, glass particles, and mixtures thereof; and a plurality of sorbent particles. Also disclosed herein are precursor compositions and methods of making such constructions.