Abstract: A pressure-sensitive adhesive is provided that is a dried product of a latex composition, which is formed from an emulsion composition. The latex composition and the emulsion composition are also provided. The emulsion composition has droplets that contain various monomers plus a (meth)acrylate polymer and a hydrogenated hydrocarbon tackifier dissolved in the monomers. Additionally, an article containing a layer of the pressure-sensitive adhesive and a method of forming the pressure-sensitive adhesive are provided. The pressure-sensitive adhesives often have both high peel adhesion and high shear strength (i.e., high cohesive strength or high shear holding power).

Abstract: Pressure sensitive adhesive compositions containing 92 to 99.9 parts of a block copolymer adhesive composition and 0.1 to less than 8 parts of an acrylic adhesive composition are described. Tapes including such adhesives, and methods of making such tapes are also described.

Abstract: Pressure sensitive adhesives comprising a linear block copolymer having a rubbery block and at least one glassy block; a multi-arm block copolymer having at least three arms, each having both a rubbery block and a glassy block; a first high glass transition temperature tackifier compatible with the rubbery blocks; a second high glass transition temperature tackifier having compatible with the glassy blocks; and at least one of a low Tg tackifier, a plasticizer, and combinations thereof, are disclosed. Tapes that include such adhesive, methods of making such tapes, and bonded composites using such adhesives and tapes are also disclosed.

Abstract: A method of making a pressure-sensitive hot melt adhesive. The method includes extruding a melt composition that includes a polymer, wherein the polymer has acidic groups covalently attached thereto, and a metal salt hydrate, wherein the metal salt hydrate has a melting point that is less than the maximum processing temperature.

Abstract: Pressure sensitive adhesive compositions containing 92 to 99.9 parts of a block copolymer adhesive composition and 0.1 to less than 8 parts of an acrylic adhesive composition are described. Tapes including such adhesives, and methods of making such tapes are also described.

Abstract: Pressure sensitive adhesive compositions containing 92 to 99.9 parts of a block copolymer adhesive composition and 0.1 to less than 8 parts of an acrylic adhesive composition are described. Tapes including such adhesives, and methods of making such tapes are also described.

Abstract: There is provided a thermally reversible admixture comprising (a) an ionically crosslinked polymer matrix comprising at least one (meth)acrylic polymer, a first mole fraction of an acid functional polymer, a second mole fraction of a moiety capable of forming an ionic crosslink with the acid functional polymer, wherein the first mole fraction and the second mole fraction are based on the total number of moles of repeat units in the polymer matrix; and (b) 2 to 50 weight percent microspheres.

Abstract: This disclosure provides (meth)acryloyl pressure-sensitive adhesive foams and foam articles having one or more of the following properties: small cells, uniform cell sizes, pressure sensitive adhesive compositions, compliance to irregular substrates and vibration damping, and shock absorbing properties.

Abstract: A method of making a pressure-sensitive hot melt adhesive. The method includes extruding a melt composition that includes a polymer, wherein the polymer has acidic groups covalently attached thereto, and a metal salt hydrate, wherein the metal salt hydrate has a melting point that is less than the maximum processing temperature.

Abstract: This disclosure provides (meth)acryloyl pressure-sensitive adhesive foams and foam articles having one or more of the following properties: small cells, uniform cell sizes, pressure sensitive adhesive compositions, compliance to irregular substrates and vibration damping, and shock absorbing properties.

Abstract: Pressure sensitive adhesives comprising a linear block copolymer having a rubbery block and at least one glassy block; a multi-arm block copolymer having at least three arms, each having both a rubbery block and a glassy block; a first high glass transition temperature tackifier compatible with the rubbery blocks; a second high glass transition temperature tackifier having compatible with the glassy blocks; and at least one of a low Tg tackifier, a plasticizer, and combinations thereof, are disclosed. Tapes that include such adhesive, methods of making such tapes, and bonded composites using such adhesives and tapes are also disclosed.

Abstract: Pressure sensitive adhesive compositions containing 92 to 99.9 parts of a block copolymer adhesive composition and 0.1 to less than 10 parts of an acrylic adhesive composition are described. Tapes including such adhesives, and methods of making such tapes are also described.

Abstract: Water-based adhesive compositions are described that includes epoxy capsules and a polymeric amine that is water soluble or water dispersible. The epoxy capsules include an outer shell material and an epoxy resin encapsulated by the outer shell material. The polymeric amine functions as an epoxy curative and as a binder resin. The compositions are substantially free of other additional organic binders. The compositions are suitable for use as mechanical fastener adhesives.

Abstract: A moisture curable, hot melt composition is described comprising the product of reacted components, the components comprising: (a) a semi-crystalline polyol; (b) an amorphous polyol comprising secondary hydroxyl groups; (c) a secondary aminosilane endcapper comprising secondary amino functionality; (d) an isocyanate; and (e) substantially no tin. A method for the manufacture of the moisture curable, hot melt adhesive and/or sealant composition is described as well as methods for using the adhesive.

Abstract: A laser imageable article includes an imageable layer that comprises the reaction product of a metal precursor and a reactant. The imageable article also includes a first boundary layer on a first side of the imageable layer, the first boundary layer being substantially transparent to laser radiation, and a second boundary layer on a second side of the imageable layer. The imageable layer may be imaged with a laser through the first boundary layer while maintaining the continuity of the first boundary layer. In a preferred embodiment, the imageable layer comprises the reaction product of an ion of one or more metals selected from columns 8, 9, and 10 of the periodic table of elements and a reducing agent selected from hypophosphorus acid and salts thereof, sodium borohydride, and dimethylamine borane. One preferred embodiment of the imageable layer comprises from 1 to 30 mole percent phosphorus and up to 99 mole percent nickel.

Abstract: An article comprises a substrate wherein at least a portion of its surface is provided with a thermosettable adhesive composition prepared from a polyepoxide resin, a curing agent and a plurality of microspheres. The cured composition forms a semi-structural bond with said substrate which is inseparable at the use temperature and is cleanly removable from said substrate when heated to a temperature of greater than the use temperature.

Abstract: A laser imageable article includes an imageable layer that comprises the reaction product of a metal precursor and a reactant. The imageable article also includes a first boundary layer on a first side of the imageable layer, the first boundary layer being substantially transparent to laser radiation, and a second boundary layer on a second side of the imageable layer. The imageable layer may be imaged with a laser through the first boundary layer while maintaining the continuity of the first boundary layer. In a preferred embodiment, the imageable layer comprises the reaction product of an ion of one or more metals selected from columns 8, 9, and 10 of the periodic table of elements and a reducing agent selected from hypophosphorus acid and salts thereof, sodium borohydride, and dimethylamine borane. One preferred embodiment of the imageable layer comprises from 1 to 30 mole percent phosphorus and up to 99 mole percent nickel.

Abstract: Thermosettable adhesive compositions that include a polyepoxide resin, a curing agent, and a plurality of microspheres. The microspheres, polyepoxide resin, and curing agent and the relative amounts thereof, are selected such that upon cure the composition is capable of forming a semi-structural bond to a substrate and is cleanly thermally removable from the substrate.

Abstract: A thermosetting adhesive comprising a polyepoxide resin, a curing agent such as an imidazole and polymeric or elastomeric microspheres is removable when heated to a temperature greater than the use temperature of from about room temperature to about 185° C.

Abstract: A method of imaging an article comprising a metal/metal oxide imageable layer with a laser beam. In particular, the present invention relates to a method for imparting a color image on the article. The method includes: a) providing an article including a substrate and an imageable layer, the imageable layer comprising a metal/metal oxide layer; b) imagewise applying a laser beam to the article; and c) in the portion of the article having the laser applied thereto, imparting a color to the metal/metal oxide layer different from the color in the non-imaged portion. Preferably, the imageable layer comprises aluminum/aluminum oxide. Also presented are imageable articles, and the resulting imaged articles.