Patents by Inventor Robert Dirk van de Grampel

Robert Dirk van de Grampel has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10017641
    Abstract: A thermoplastic composition comprises, based on the total weight of the thermoplastic composition, 10 to 45 wt. % of a poly(etherimide); 35 to 90 wt. % of a polycarbonate component comprising a polycarbonate homopolymer, a poly(carbonate-siloxane), or a combination thereof; 0.5 to 20 wt. % of a compatibilizer polycarbonate component comprising a poly(carbonate-arylate ester), a phthalimidine copolycarbonate, or a combination thereof; up to 5 wt. % of an ultraviolet light stabilizer; and 0 to 20 wt. % of TiO2, wherein a sample of the composition has a 50% higher notched Izod impact energy value compared to the composition without the compatibilizer component.
    Type: Grant
    Filed: January 12, 2015
    Date of Patent: July 10, 2018
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Paul Dean Sybert, Mark Adrianus Johannes Van Der Mee, Roland Sebastian Assink, Robert Dirk Van De Grampel, Aditya Narayanan, Feng Cao, Kapil Chandrakant Sheth, Hao Zhou, Xiaoyu Sun, Remco Wirtz
  • Publication number: 20180187011
    Abstract: A thermoplastic composition comprises 10 to 50 wt. % of a poly(arylene ether-sulfone), or a combination comprising a poly(arylene ether-sulfone) and a poly(etherimide), 35 to 90 wt. % of a poly(carbonate-siloxane), 0.5 to 25 wt. % of a poly(carbonate-arylate ester) compatibilizer, a poly(carbonate-arylate ester-siloxane) compatibilizer, or a combination comprising at least one of the foregoing, and up to 15 wt. % of an ultraviolet light stabilizer; wherein a sample of the composition has a notched Izod impact energy of at least 200 J/m at 23° C.; and a 40% higher notched Izod impact energy value compared to the composition without the compatibilizer component.
    Type: Application
    Filed: June 24, 2016
    Publication date: July 5, 2018
    Inventors: Hao Zhou, Feng Cao, Mark Adrianus Johannes van der Mee, Roland Sebastian Assink, Robert Dirk van de Grampel, Remco Wirtz
  • Patent number: 10005903
    Abstract: A thermoplastic composition comprises: 35 to 45 weight percent of a branched, end capped polycarbonate, 55 to 70 weight percent of a poly(aliphatic ester-carbonate) having a weight average molecular weight of 15,000 to 25,000, a non-flourinated sulfonate salt flame retardant and a polysiloxane. Weight percent is based on the combined weight of the branched, end capped polycarbonate and poly(aliphatic ester-carbonate).
    Type: Grant
    Filed: March 9, 2015
    Date of Patent: June 26, 2018
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Jean-Francois Morizur, Yaming Niu, Robert Dirk van de Grampel, Miao Shen, Jian Yang
  • Patent number: 10005902
    Abstract: A thermoplastic composition comprises, based on the total weight of the thermoplastic composition, 10 to 45 wt. % of a poly(etherimide); 35 to 90 wt. % of a poly(carbonate-siloxane); 0.5 to 20 wt. % of compatibilizer polycarbonate component comprising a poly(carbonate-arylate ester); up to 15 wt. % of an ultraviolet light stabilizer; and 0 to 30 wt. % of TiO2; wherein a sample of the composition has a notched Izod impact energy of at least 200 J/m at 23° C. measured in accordance to ASTM D256; and an at least 50% higher notched Izod impact energy value compared to the composition without the compatibilizer component measured in accordance to ASTM D256.
    Type: Grant
    Filed: January 12, 2015
    Date of Patent: June 26, 2018
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Paul Dean Sybert, Mark Adrianus Johannes Van Der Mee, Roland Sebastian Assink, Robert Dirk Van De Grampel, Aditya Narayanan, Feng Cao, Kapil Chandrakant Sheth, Hao Zhou, Xiaoyu Sun, Remco Wirtz
  • Patent number: 9994709
    Abstract: A low smoke density thermoplastic composition comprising, based on the total weight of the thermoplastic composition, 70 to 95 wt % of a polycarbonate copolymer comprising first repeating units and second repeating units, wherein the first repeating units are not the same as the second repeating units, and wherein the first repeating units are bisphenol carbonate units of the formula wherein Ra and Rb are each independently C1-12 alkyl, C1-12 alkenyl, C3-8 cycloalkyl, or C1-12 alkoxy, p and q are each independently 0 to 4, and Xa is a single bond, —O—, —S—, —S(O)—, —S(O)2—, —C(O)—, a C1-11 alkylidene of formula —C(Rc)(Rd)— wherein Rc and Rd are each independently hydrogen or C1-10 alkyl, or a group of the formula —C(?Re)— wherein Re is a divalent C1-10 hydrocarbon group; and the second repeating units comprise bisphenol carbonate units that are not the same as the first repeating bisphenol carbonate units, siloxane units, arylate ester units, or a combination of arylate ester units and siloxane units; and
    Type: Grant
    Filed: March 4, 2016
    Date of Patent: June 12, 2018
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Mark Adrianus Johannes van der Mee, Robert Dirk van de Grampel, Roland Sebastian Assink, Paul Dean Sybert
  • Publication number: 20170362432
    Abstract: A thermoplastic composition comprisese: 35 to 45 weight percent of a branched, end capped polycarbonate, 55 to 70 weight percent of a poly(aliphatic ester-carbonate) having a weight average molecular weight of 15,000 to 25,000, a non-flourinated sulfonate salt flame retardant and a polysiloxane. Weight percent is based on the combined weight of the branched, end capped polycarbonate and poly(aliphatic ester-carbonate).
    Type: Application
    Filed: March 9, 2015
    Publication date: December 21, 2017
    Inventors: Jean-Francois Morizur, Yaming Niu, Robert Dirk van de Grampel, Miao Shen, Jian Yang
  • Patent number: 9758670
    Abstract: A composition includes at least one poly(aliphatic ester)-polycarbonate copolymer, a polysiloxane-polycarbonate copolymer, non-bonding glass fibers, and titanium dioxide. The composition exhibits excellent impact properties and an ultra-white color.
    Type: Grant
    Filed: May 16, 2012
    Date of Patent: September 12, 2017
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Andries J. P. Van Zyl, Jian Yang, Robert Dirk Van De Grampel
  • Patent number: 9718956
    Abstract: A aircraft component comprises a polycarbonate composition comprising: a first polycarbonate selected from a polycarbonate homopolymer, a poly(aliphatic ester-carbonate), or a combination thereof; a second polymer different from the first polycarbonate, the second polymer comprising a poly(carbonate-siloxane) copolymer, a polydialkylsiloxane, a silicone graft copolymer, or a combination thereof, wherein siloxane units in the second polymer are present in the polycarbonate composition in an amount of 0.3 to 3 wt. %, based on the total weight of the polycarbonate composition; and 10 to 50 wt. % of glass fiber, based on the total weight of the polycarbonate composition.
    Type: Grant
    Filed: January 14, 2014
    Date of Patent: August 1, 2017
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Mark Adrianus Johannes van der Mee, Remco Wirtz, Roland Sebastian Assink, Robert Dirk van de Grampel
  • Patent number: 9688842
    Abstract: A thermoplastic composition includes a poly(carbonate-arylate ester); and an organophosphorus compound in an amount effective to provide 0.1 to 1.0 wt % phosphorus based on the total weight of the composition, wherein an article molded from the composition has a smoke density after four minutes (Ds-4) of less than or equal to 300 determined according to ISO 5659-2 on a 3 mm thick plaque and a maximum average rate of heat release emission (MAHRE) of less than or equal to 90 kW/m2 determined according to ISO 5660-1 on a 3 mm thick plaque.
    Type: Grant
    Filed: December 18, 2014
    Date of Patent: June 27, 2017
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Mark Adrianus Johannes van der Mee, Robert Dirk van de Grampel, Roland Sebastian Assink, Paul Dean Sybert
  • Patent number: 9688855
    Abstract: A polycarbonate composition comprises: 30 to 95 wt % of one or more bisphenol A polycarbonate homopolymers; and 5 to 70 wt % of a poly(carbonate-siloxane) copolymer with a siloxane content of 10 wt. % to 25 wt. % based on the total weight of the poly(carbonate-siloxane), in an amount effective to provide a total siloxane content of 0.5 wt. % to 17.5 wt. % based on the total weight of the composition; the poly(carbonate-siloxane) copolymer comprising bisphenol carbonate units and siloxane units of the formulas or a combination comprising at least one of the foregoing, wherein E has an average value of 10 to 100, preferably 20 to 60, more preferably 30 to 50; wherein in the poly(carbonate-siloxane) copolymer less than 0.5 mol % of the siloxane units are directly coupled to another siloxane units.
    Type: Grant
    Filed: November 17, 2015
    Date of Patent: June 27, 2017
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Ramon Groote, James Franklin Hoover, Robert Dirk Van De Grampel, Mark Adrianus Johannes Van Der Mee, Remco Wirtz, Jian Yang, Junhua Zhang
  • Publication number: 20170137621
    Abstract: A polycarbonate composition comprises: 30 to 95 wt % of one or more bisphenol A polycarbonate homopolymers; and 5 to 70 wt % of a poly(carbonate-siloxane) copolymer with a siloxane content of 10 wt. % to 25 wt. % based on the total weight of the poly(carbonate-siloxane), in an amount effective to provide a total siloxane content of 0.5 wt. % to 17.5 wt. % based on the total weight of the composition; the poly(carbonate-siloxane) copolymer comprising bisphenol carbonate units and siloxane units of the formulas or a combination comprising at least one of the foregoing, wherein E has an average value of 10 to 100, preferably 20 to 60, more preferably 30 to 50; wherein in the poly(carbonate-siloxane) copolymer less than 0.5 mol % of the siloxane units are directly coupled to another siloxane units.
    Type: Application
    Filed: November 17, 2015
    Publication date: May 18, 2017
    Inventors: Ramon GROOTE, James Franklin HOOVER, Robert Dirk VAN DE GRAMPEL, Mark Adrianus Johannes VAN DER MEE, Remco WIRTZ, Jian YANG, Junhua ZHANG
  • Patent number: 9650496
    Abstract: Interior aircraft components comprise a thermoplastic composition comprising: a first polymer comprising bisphenol A carbonate units and monoaryl arylate units, or a second polymer comprising bisphenol A carbonate units, monoaryl arylate units, and siloxane units, or a combination comprising at least one of the foregoing polymers; and an organophosphorus compound; wherein a sample of the thermoplastic composition has: an OSU integrated 2 minute heat release test value of less than 65 kW-min/m2 and a peak heat release rate of less than 65 kW/m2, an E662 smoke test DsMax value of less than 200, a flame time of less than 15 seconds, a burn length of less than 6 inches, and a drip extinguishing time of less than 5 seconds, an energy in multiaxial impact of 100 J or more and a ductility in multiaxial impact of 100%.
    Type: Grant
    Filed: June 12, 2013
    Date of Patent: May 16, 2017
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Mark Adrianus Johannes van der Mee, Paul Dean Sybert, Robert Dirk van de Grampel, Roland Sebastian Assink
  • Patent number: 9598577
    Abstract: A polycarbonate composition comprises: a first poly(carbonate-siloxane) copolymer, comprising a polysiloxane block with an average block length of 10 to 100, and a siloxane content from 5 wt % to 10 wt %; and a second poly(carbonate-siloxane) copolymer comprising a polysiloxane block with an average block length of 10 to 100, and a siloxane content from 30 wt % to 60 wt %; wherein the weight ratio of the first poly(carbonate-siloxane) copolymer to the second poly(carbonate-siloxane) copolymer is greater than or equal to 2 to less than 8; and a bisphenol A homopolycarbonate, wherein the polycarbonate composition has a total siloxane content of 2.5 wt % to 10 wt % based on the total weight of the composition; and a molded part of 1 mm thickness has a haze of less than 10% as measured by HazeGard (ASTM D1003-00).
    Type: Grant
    Filed: November 17, 2015
    Date of Patent: March 21, 2017
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Ramon Groote, James Franklin Hoover, Robert Dirk Van De Grampel, Mark Adrianus Johannes Van Der Mee, Remco Wirtz, Jian Yang, Junhua Zhang
  • Patent number: 9598578
    Abstract: A polycarbonate composition comprises: a first poly(carbonate-siloxane) copolymer comprising carbonate units and siloxane units, wherein less than 0.5 mol % of the siloxane units are directly coupled to another siloxane unit; the first poly(carbonate-siloxane) copolymer comprising siloxane units with an average block length of about 10 to about 100, and a siloxane content from 5 wt % to 8 wt %; a second poly(carbonate-siloxane) copolymer comprising carbonate units and siloxane units, wherein less than 0.5 mol % of the siloxane units are directly coupled to another siloxane unit; the second poly(carbonate-siloxane) copolymer comprising siloxane units with an average block length of 10 to 100, a siloxane content from 10 wt % to 30 wt %, and wherein the weight ratio of the first poly(carbonate-siloxane) copolymer to the second poly(carbonate-siloxane) copolymer is 2 to 20; and optionally a bisphenol polycarbonate; wherein the polycarbonate composition has a total siloxane content of 2.
    Type: Grant
    Filed: November 17, 2015
    Date of Patent: March 21, 2017
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V
    Inventors: Ramon Groote, James Franklin Hoover, Robert Dirk Van De Grampel, Mark Adrianus Johannes Van Der Mee, Remco Wirtz, Jian Yang, Junhua Zhang
  • Patent number: 9587109
    Abstract: The present disclosure describes polycarbonate-siloxane blends with a constant percentage of siloxane in the formulations. The polycarbonate-siloxane blends achieve improved impact properties, as well as the ability to achieve deep black and bright white colors.
    Type: Grant
    Filed: August 30, 2013
    Date of Patent: March 7, 2017
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Jian Yang, Robert Dirk Van de Grampel, Mark Adrianus Johannes van der Mee, Jon Michael Malinoski, Niles Richard Rosenquist
  • Patent number: 9580559
    Abstract: Disclosed herein are polydiorganosiloxane-polycarbonate block copolymers having desirable optical properties, and methods of making such block copolymers. Also disclosed herein are analytical methods for evaluating hydroxyaryl end-capped polydialkylsiloxane monomers.
    Type: Grant
    Filed: October 2, 2014
    Date of Patent: February 28, 2017
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Niles Richard Rosenquist, Fabrizio Micciche, Jozua de Heer, Robert Dirk van de Grampel, James F. Hoover, Nathalie Gonzalez Vidal
  • Publication number: 20170029618
    Abstract: Polycarbonate blend compositions are disclosed. The compositions include at least one polycarbonate useful for high heat applications. The compositions can include one or more additional polymers. The compositions can include one or more additives. The compositions can be used to prepare articles of manufacture, and in particular, automotive bezels.
    Type: Application
    Filed: April 15, 2015
    Publication date: February 2, 2017
    Inventors: Sarah E. Grieshaber, Tony Farrell, Rob Boonman, Wilhelmus Johannes Daniel Steendam, Maria del Mar Diez Diaz, Robert Dirk van de Grampel, Natacha Forey, Sjoerd van Nispen
  • Publication number: 20170022362
    Abstract: Polycarbonate blend compositions are disclosed. The compositions include at least one polycarbonate useful for high heat applications. The compositions can include one or more additional polymers. The compositions can include one or more additives. The compositions can be used to prepare articles of manufacture, and in particular, automotive bezels.
    Type: Application
    Filed: April 15, 2015
    Publication date: January 26, 2017
    Inventors: Sarah E. Grieshaber, Tony Farrell, Daniel Francis Lowery, Mark Adrianus Johannes van der Mee, Roland Sebastian Assink, Robert Dirk van de Grampel
  • Publication number: 20170022360
    Abstract: Metallized articles comprising polycarbonate compositions are disclosed. The compositions include at least one first polycarbonate useful for high heat applications; and a second Bisphenol A polycarbonate. The compositions can include one or more additives. The compositions can be used to prepare articles of manufacture, and in particular, automotive bezel.
    Type: Application
    Filed: April 15, 2015
    Publication date: January 26, 2017
    Inventors: Tony FARRELL, Mark Adrianus Johannes VAN DER MEE, Roland Sebastian ASSINK, Robert Dirk VAN DE GRAMPEL
  • Publication number: 20170022359
    Abstract: Metallized articles comprising polycarbonate compositions are disclosed. The compositions include at least one first polycarbonate useful for high heat applications, a second polycarbonate that is a Bisphenol A (BPA) polycarbonate-polydimethyl-siloxane copolymer; and optionally a third polycarbonate. The compositions can include one or more additives. The compositions can be used to prepare articles of manufacture, and in particular, automotive bezel.
    Type: Application
    Filed: April 15, 2015
    Publication date: January 26, 2017
    Applicant: Sabic Global Technologies B.V.
    Inventors: Tony Farrell, Mark Adrianus Johannes van der Mee, Roland Sebastian Assink, Robert Dirk van de Grampel, Rob Boonman