Abstract: Functionalized nanoparticles are deposited on metal lines inlaid in dielectric to form a metal cap layer that reduces electromigration in the metal line. The functionalized nanoparticles are deposited onto activated metal surfaces, then sintered and annealed to remove the functional agents leaving behind a continuous capping layer. The resulting cap layer is about 1 to 10 nm thick with 30-100% atomic of the nanoparticle material. Various semiconductor processing tools may be adapted for this deposition process without adding footprint in the semiconductor fabrication plant.

Abstract: Functionalized nanoparticles are deposited on metal lines inlaid in dielectric to form a metal cap layer that reduces electromigration in the metal line. The functionalized nanoparticles are deposited onto activated metal surfaces, then sintered and annealed to remove the functional agents leaving behind a continuous capping layer. The resulting cap layer is about 1 to 10 nm thick with 30-100% atomic of the nanoparticle material. Various semiconductor processing tools may be adapted for this deposition process without adding footprint in the semiconductor fabrication plant.

Abstract: In one aspect of the invention, a method for forming an integrated circuit having an at least substantially doped porous dielectric includes forming a semiconductor device. The semiconductor device includes at least a portion of a semiconductor substrate. The method also includes forming a dielectric layer disposed outwardly from the semiconductor substrate and surrounding at least a portion of the semiconductor device. The dielectric layer includes an at least substantially porous dielectric material doped with at least one dopant. In addition, the method includes forming a contact layer disposed outwardly from the dielectric layer and operable to provide electrical connection to the semiconductor device.

Abstract: A method for creating a refractory metal and refractory metal nitride cap effective for reducing copper electromigration and copper diffusion is described. The method includes depositing a refractory metal nucleation layer and nitriding at least the upper portion of the refractory metal layer to form a refractory metal nitride. Methods to reduce and clean the copper lines before refractory metal deposition are also described. Methods to form a thicker refractory metal layer using bulk deposition are also described.

Abstract: Porous dielectric layers are produced by introducing small vertical or columnar gaps in pre-formed layers of dense dielectric. The pores may be formed by a special process that is different from the processes employed to form metal lines and other features on a VLSI device. Further, the columnar gaps may be produced after the planarization process for a particular layer has been completed. Then, after the pores are formed, they are capped by depositing another layer of material. In this manner, the newly porous layer is protected from direct exposure to the pressure of subsequent planarization processes. In alternative embodiments, the processes described herein are applied to introduce pores into a pre-formed layer of semiconductor to produce a porous semiconductor layer.

Abstract: A composition comprises a first component that provides a predetermined response to radiation, and a second component. Upon curing of the composition, portions of the first component bind together portions of the second component to form an inhomogeneous material having physical properties substantially determined by the second component. The function provided by the first component's response to radiation and the macroscopic properties determined by the second component are largely decoupled and thus may be separately optimized. Some embodiments provide photo-patternable low dielectric constant materials that may be advantageously employed in metal interconnect layers in integrated circuits, for example.

Abstract: A method for creating a refractory metal and refractory metal nitride cap effective for reducing copper electromigration and copper diffusion is described. The method includes depositing a refractory metal nucleation layer and nitriding at least the upper portion of the refractory metal layer to form a refractory metal nitride. Methods to reduce and clean the copper lines before refractory metal deposition are also described. Methods to form a thicker refractory metal layer using bulk deposition are also described.

Abstract: In one aspect of the invention, a method for forming an integrated circuit having an at least substantially doped porous dielectric includes forming a semiconductor device. The semiconductor device includes at least a portion of a semiconductor substrate. The method also includes forming a dielectric layer disposed outwardly from the semiconductor substrate and surrounding at least a portion of the semiconductor device. The dielectric layer includes an at least substantially porous dielectric material doped with at least one dopant. In addition, the method includes forming a contact layer disposed outwardly from the dielectric layer and operable to provide electrical connection to the semiconductor device.

Abstract: In one aspect of the invention, a method for forming an integrated circuit having an at least substantially doped porous dielectric includes forming a semiconductor device. The semiconductor device includes at least a portion of a semiconductor substrate. The method also includes forming a dielectric layer disposed outwardly from the semiconductor substrate and surrounding at least a portion of the semiconductor device. The dielectric layer includes an at least substantially porous dielectric material doped with at least one dopant. In addition, the method includes forming a contact layer disposed outwardly from the dielectric layer and operable to provide electrical connection to the semiconductor device.

Abstract: Porous dielectric layers are produced by introducing small vertical or columnar gaps in pre-formed layers of dense dielectric. The pores may be formed by a special process that is different from the processes employed to form metal lines and other features on a VLSI device. Further, the columnar gaps may be produced after the planarization process for a particular layer has been completed. Then, after the pores are formed, they are capped by depositing another layer of material. In this manner, the newly porous layer is protected from direct exposure to the pressure of subsequent planarization processes. In alternative embodiments, the processes described herein are applied to introduce pores into a preformed layer of semiconductor to produce a porous semiconductor layer.

Abstract: According to one embodiment of the invention, a method is provided. The method includes lining, with a conductive liner, a surface of a dielectric layer. The surface defines at least two trenches separated by a platform. Each of the defined trenches includes a conductor that overlies the conductive liner and is positioned within the each of the defined trenches. The conductor is electrically coupled to the conductive liner. The method also includes covering the portion of the conductive liner overlying the platform after lining the surface. The method also includes removing any uncovered portions of the conductive liner while leaving in place the portion of the conductive liner that was covered.

Abstract: According to one embodiment of the invention, a method is provided. The method includes lining, with a conductive liner, a surface of a dielectric layer. The surface defines at least two trenches separated by a platform. Each of the defined trenches includes a conductor that overlies the conductive liner and is positioned within the each of the defined trenches. The conductor electrically coupled to the conductive liner. The method also includes covering the portion of the conductive liner overlying the platform after lining the surface. The method also includes removing any uncovered portions of the conductive liner while leaving in place the portion of the conductive liner that was covered.

Abstract: A structure and process is provided for filling integrated circuit cavities such as contacts and vias. These structures are filled at relatively low temperatures of no more than about 300° C., and preferably between about 20°-275° C., which temperature range permits for the use of low dielectric constant (&kgr;) polymers (i.e., &kgr;<˜3.0). Preferably, the cavities are provided with an elemental titanium-free liner to facilitate cavity filling, and the cavities are filled with CVD aluminum that is introduced into the cavities by way of a forcefill at pressures ranging from atmospheric to about 50 MPa, and preferably no more than about 30 MPa, at temperatures ranging from about 100°-300° C. Cavities filled in the foregoing manner exhibit electrical resistance levels that are up to 30% less than structures filled by conventional practices.

Abstract: An interconnect structure having refractory sidewalls 240 for enhanced yield, performance and reliability. The primary purpose of the refractory metal 240 is to getter sidewall impurities, residual polymers, and corrosive species by-products from the plasma etch and cleanup processes used to pattern interconnects. In a preferred embodiment, the refractory metal 240 reacts with the conducting layer 210 to form an intermetallic 245 which further enhances the endurance of the metallization against stress-induced rupturing and via-induced electromigration. The disclosed structures and methods are particularly advantageous in “zero-overlap” designs, and aggressive pitch patterns where linewidth and corrosion control are critical, but are also advantageous in “Damascene” pattern definition applications.

Abstract: A metallization interconnect structure where the bottom layer of the interlevel section has etch selectivity with respect to the layer beneath it, which in the preferred embodiment is the cap layer of a metallization layer. The etch selectivity allows the dielectric material surrounding the metallization line to be preserved and protected from overetch, which can erode the dielectric material surrounding the metallization line and cause a cavity.

Abstract: In one aspect of the invention, a method for forming an integrated circuit having an at least substantially doped porous dielectric includes forming a semiconductor device. The semiconductor device includes at least a portion of a semiconductor substrate. The method also includes forming a dielectric layer disposed outwardly from the semiconductor substrate and surrounding at least a portion of the semiconductor device. The dielectric layer includes an at least substantially porous dielectric material doped with at least one dopant. In addition, the method includes forming a contact layer disposed outwardly from the dielectric layer and operable to provide electrical connection to the semiconductor device.

Abstract: A structure and process is provided for filling integrated circuit cavities such as contacts and vias. These structures are filled at relatively low temperatures of no more than about 300° C., and preferably between about 20°-275° C., which temperature range permits for the use of low dielectric constant (&kgr;) polymers (i.e., &kgr;<˜3.0). Preferably, the cavities are provided with an elemental titanium-free liner to facilitate cavity filling, and the cavities are filled with CVD aluminum that is introduced into the cavities by way of a forcefill at pressures ranging from atmospheric to about 50 MPa, and preferably no more than about 30 MPa, at temperatures ranging from about 100°- 300° C. Cavities filled in the foregoing manner exhibit electrical resistance levels that are up to 30% less than structures filled by conventional practices.

Abstract: In one embodiment of a horizontal bipolar transistor constructed in accordance with the teachings of this invention, oxygen is implanted into the horizontal bipolar transistor to provide a silicon dioxide layer between the base and the collector and emitter of the horizontal bipolar transistor. This silicon dioxide layer reduces the actual interface area of the base to collector and base to emitter junctions, thereby decreasing the capacitance of the transistor. In addition, the dielectric constant of the silicon dioxide layer is such that the capacitance across the silicon dioxide layer, and thus between the base and the collector and emitter, is minimal relative to the base to collector and base to emitter capacitance provided by the base to collector and base to emitter junctions themselves. In an alternative embodiment, nitrogen ions are implanted to form silicon nitride regions rather than silicon dioxide regions.

Abstract: An interconnect structure having refractory sidewalls 240 for enhanced yield, performance and reliability. The primary purpose of the refractory metal 240 is to getter sidewall impurities, residual polymers, and corrosive species by-products from the plasma etch and cleanup processes used to pattern interconnects. In a preferred embodiment, the refractory metal 240 reacts with the conducting layer 210 to form an intermetallic 245 which further enhances the endurance of the metallization against stress-induced rupturing and via-induced electromigration. The disclosed structures and methods are particularly advantageous in “zero-overlap” designs, and aggressive pitch patterns where linewidth and corrosion control are critical, but are also advantageous in “Damascene” pattern definition applications.

Abstract: A method of fabricating a semiconductor device and the device. The device is fabricated by providing a substrate having a region thereover of electrically conductive material, and a dielectric first sidewall spacer on the region of electrically conductive material. A second sidewall spacer is formed over the first sidewall spacer extending to the substrate from a material which is selectively removal relative to the first sidewall spacer. An electrically conductive region is formed contacting the second sidewall spacer and spaced from the substrate. The second sidewall spacer is selectively removable to form an opening between the substrate and the electrically conductive region. The opening is filled with electrically conductive material to electrically couple the electrically conductive material to the substrate.