Abstract: Ethylene and hexene-1 are produced from butene-1 by metathesis of butene-1 and isomerization of the hexene-3 produced therein to hexene-1. The initial starting material is a mixed butene stream wherein butene-1 is isomerized to butene-2 with isobutylene being separated therefrom, followed by isomerization of butene-2 to butene-1, with the butene-1 being the feed to the metathesis.

Abstract: A catalytic cracking unit is disclosed which provides for separation and quenching of the effluent with a total kinetic residence time of from 0.1 to 0.6 seconds.

Abstract: A pyrolysis heater particularly for the cracking of hydrocarbons in the production of olefins has a burner arrangement in the firebox which directly heats the hearth of the firebox such that it becomes a radiant surface. This improves the heat flux in the lower portion of the firebox and produces a more uniform vertical heat flux profile over the firebox elevation. The base burners may fire horizontally across the hearth or may comprise porous ceramic burners as a part of the hearth. The base burners operate along with vertically firing hearth burners and optional wall burners in the upper portion of the firebox.

Abstract: A pyrolysis heater has the inlet sections of the process coils grouped together and the outlet sections of these same process coils also grouped together. High heat liberation hearth burners are located adjacent to the inlet sections of the coils and lower heat liberation burners are located adjacent to the outlet sections. The secondary fuel tips of the burners are inclined toward the adjacent heater wall. The high heat liberation hearth burners adjacent to the inlet coils are arranged in spaced apart pairs with the secondary burner tips of each of the pair being inclined toward the other burner of the pair.

Abstract: The C3 to C6 cut from a cracking process containing propylene, butane, 1-butene, 2-butene and acetylenic and diene components including butadiene are preferentially converted to propylene. The cut is simultaneously fractionated and catalytically hydrogenated to hydrogenate the acetylenic and diene components. The fractionation and subsequent separation recovers a C4 component comprising a mixture of isobutene, 1-butene and 2-butene. This C4 component is then further simultaneously fractionated and catalytically hydrogenated and hydroisomerized to hydrogenate remaining butadiene, remove isobutene overhead and convert 1-butene to 2-butene leaving a bottoms of 2-butene. The 2-butene is then injected with ethylene and catalytically metathesized to form propylene.

Abstract: The performance of an endothermic catalytic dehydrogenation process is increased without requiring additional catalyst regeneration and reheat air flow and compression by partially prereacting the preheated hydrocarbon feed and then reheating the partially dehydrogenated effluent from the prereactor to the same hydrocarbon preheat temperature prior to the main catalytic reactor. The preferable source of the heat for reheating is the effluent air from the reheat and regeneration of the catalyst in the main reactor. This same effluent air is used to regenerate the catalyst in the prereactor as needed.

Abstract: Cyclohexane is catalytically oxidized to produce cyclohexanol and cyclohexanone and precursors of these products. The oxidation is carried out in a liquid oxidation reactor at high oxygen concentrations (greater than 30% and preferably greater than 90% oxygen concentration) and at relatively low temperatures (less than 160.degree. C.). The use of the liquid oxidation reactor permits the use of these high oxygen concentrations without forming dangerously high levels of oxygen in the overhead gas phase. The result is an increased yield and selectivity of the desired products.

Abstract: A process for producing liquid fuels from heavy hydrocarbons such as residual oil in which the cracking temperatures are in the range of 800.degree. F. to 1200.degree. F., and the residence times are between 0.05 seconds and 0.50 seconds.

Abstract: Cyclohexane is catalytically oxidized to produce cyclohexanol and cyclohexanone and precursors of these products. The product is then catalytically hydrogenated while the product is still at reaction temperature to produce additional cyclohexanol and cyclohexanone from the precursors. The oxidation is carried out in a liquid oxidation reactor at high oxygen concentrations (greater than 30% and preferably greater than 90% oxygen concentration) and at relatively low temperatures (less than 160.degree. C.). The use of the liquid oxidation reactor permits the use of these high oxygen concentrations without forming dangerously high levels of oxygen in the overhead gas phase. The result is an increased yield and selectivity of the desired products. The hydrogenation is carried out in a reactor using a catalyst of palladium supported on carbon.

Abstract: Catalytic dehydrogenation wherein feed is passed in one direction through the bed in a first cycle and heating gas is passed in an opposite direction in a second cycle to provide the endothermic heat of reaction and regenerate catalyst. The operation is controlled to balance properly heat absorbed during dehydrogenation and heat input during regeneration; e.g., by having catalyst of different activities over the length of the bed.

Abstract: A catalytic cracking unit is disclosed which provides for quenching of a riser reactor effluent downstream of a rough cut separator and upstream of a cyclone separator.

Abstract: A catalytic cracking unit is disclosed which provides for separation and quenching of a catalytic cracking effluent.

Abstract: A staged catalytic cracking process and apparatus is disclosed where each stage has a catalyst to oil ratio of at least 15 and there are individual hydrocarbon feeds to each stage and product removal from each stage. There is a residence time profile with the first stage having a short residence time and the successive stages having progressively longer residence times. Further, there is a feed profile with the lighter components of the total feed going to the first stage and the heavier components being fed to the later stages. The apparatus has a generally vertical orientation which permits it to be incorporated into existing cracking units for upgrading and also easily provides for both short and long residence times.

Abstract: The present invention relates to a process for the production of olefins from light paraffins. Specifically, the present invention relates to a process for the production of olefins from ethane, propane, butane, isobutane, pentane and isopentane, preferably utilizing moderate or high activity dehydrogenation catalysts at kinetic residence times of from about 0.1 to about 2.0 seconds, and at temperatures of from about 900.degree. F. to about 1600.degree. F. The present invention further relates to the production of an olefin from its corresponding paraffin, and a process for the production of a mixture of olefins.

Abstract: Process for catalytic dehydrogenation of a mixture of light paraffins including passing accelerated catalyst with an acceleration gas into a mixing zone for contact with mixed paraffin feedstock, passing the feedstock/catalyst into a reaction zone, separating the effluent from the spent catalyst solids, quenching the effluent and separating and recycling at least a portion of the unreacted light feedstock for use as an acceleration gas to accelerate the fresh catalyst wherein the kinetic residence time from contact of the catalyst and feedstock to quench is between 0.1 and 2.0 seconds.

Abstract: A process for the production of olefins and aromatics from hydrocarbon feedstocks by catalytically cracking alone or cracking and dehydrogenating the hydrocarbons in the presence of an entrained stream of catalytic heat carrying solids at short residence times to preferentially produce olefins having three or more carbon atoms and/or to produce aromatics, especially benzene.

Abstract: There is disclosed an improved solids regeneration apparatus for hydrocarbon cracking. The apparatus comprises an entrained bed heater adapter for spouted bed circulation of solids.

Abstract: A gas-particulate solids separation assembly having a mixed phase solids-gas elongated inlet terminating in a divergent section and horizontally disposed cylcone separators downstream of the separator gas outlets adapted to receive quench oil.

Abstract: An apparatus for cracking hydrocarbon with hot particulate solids wherein a curtain of hot particulate solids is delivered to a thermal reactor through peripheral openings and hydrocarbon feed is delivered to the reactor through the curtain of hot particulate solids at an angle.

Abstract: An apparatus for delivering fluidization gas to a bed of particulate solids to selectively, locally fluidize the solids above a delivery conduit in communication with a reaction chamber. Also an apparatus is disclosed for intimately mixing hydrocarbon feed with the particulate solids at the end of the delivery conduit in the reaction chamber.