Patents by Inventor Roderich Raue

Roderich Raue has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5578711
    Abstract: Dyestuffs of the formula ##STR1## in which D is the radical of an aromatic or heterocyclic diazo component andK is the radical of an aromatic or heterocyclic coupling component, or is the radical of an active methylene compound,are obtained in an ecologically advantageous manner by reacting an aromatic or heterocyclic diazo components of the formulaD--NH.sub.2and a coupling component of the formulaH--Kwith a nitrite, for example NaNO.sub.2, in the presence of CO.sub.2 at a pressure of 5-100 at. The process is suitable in particular for the preparation of concentrated dye-stuff solutions, because expensive operations, such as, for example, pressure permeation and reverse osmosis, can be omitted.
    Type: Grant
    Filed: September 14, 1995
    Date of Patent: November 26, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Roderich Raue, Alfred Brack, Karl-Heinrich Lange
  • Patent number: 5541299
    Abstract: Dyestuffs of the formula ##STR1## in which D is the radical of an aromatic or heterocyclic diazo component andK is the radical of an aromatic or heterocyclic coupling component, or is the radical of an active methylene compound,are obtained in an ecologically advantageous manner by reacting an aromatic or heterocyclic diazo components of the formulaD--NH.sub.2and a coupling component of the formulaH--Kwith a nitrite, for example NaNO.sub.2, in the presence of CO.sub.2 at a pressure of 5-100 at. The process is suitable in particular for the preparation of concentrated dye-stuff solutions, because expensive operations, such as, for example, pressure permeation and reverse osmosis, can be omitted.
    Type: Grant
    Filed: September 23, 1994
    Date of Patent: July 30, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Roderich Raue, Alfred Brack, Karl-Heinrich Lange
  • Patent number: 5502171
    Abstract: Dyestuffs of the formula ##STR1## in which D is the radical of an aromatic or heterocyclic diazo component andZ is the radical of an aromatic or heterocyclic coupling component,are obtained in an ecologically advantageous manner by reacting an aromatic or heterocyclic diazo components of the formulaD--NH.sub.2and a coupling component of the formulaH--Z.sub.1with a nitrite, in the presence of CO.sub.2 at a pressure of 5-100 at. The process is suitable in particular for the preparation of concentrated dyestuff solutions, because expensive operations, such as, for example, pressure permeation and reverse osmosis, can be omitted.
    Type: Grant
    Filed: May 16, 1995
    Date of Patent: March 26, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Roderich Raue, Alfred Brack, Karl-Heinrich Lange
  • Patent number: 5328993
    Abstract: The new cationic triazatrimethine dyestuffs of the formula ##STR1## wherein the substituents B, Z, R.sup.2 and An.sup..crclbar. have the meaning given in the description, are suitable for dyeing and printing naturally occurring and synthetic materials.
    Type: Grant
    Filed: April 15, 1993
    Date of Patent: July 12, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hauke Furstenwerth, Karl-Heinrich Lange, Roderich Raue, Alfred Brack
  • Patent number: 5292881
    Abstract: New naphthalimides, useful as additives in toners for controlling the charge and conductivity, of the formula ##STR1## in which R represents C.sub.1 - to C.sub.22 -alkyl,R.sup.1 and R.sup.2 independently of one another in each case represent C.sub.1 - to C.sub.4 -alkyl, or R.sup.1 and R.sup.2, together with the nitrogen atom in between, form a pyrrolidine, piperidine or morpholine ring,n represents 2 or 3 andX.sup..crclbar. represent one equivalentof a benzoate or naphthoate, which is optionally substituted by chlorine, bromine, methyl, methoxy, hydroxyl, cyano and/or hydroxycarbonyl,of a benzenesulphonate which is substituted by hydroxyl, amino or nitro,of a naphthalenesulphonate which is optionally substituted by hydroxyl, amino or a sulphonic acid group, orof a fluorine-substituted anion of a C.sub.4 - to C.sub.18 -alkanecarboxylic or -alkanesulphonic acid.
    Type: Grant
    Filed: February 19, 1992
    Date of Patent: March 8, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Berneth, Horst Harnisch, Roderich Raue, Jurgen-Rolf Hassdenteufel, Matthias Kocher
  • Patent number: 5233048
    Abstract: Color formers of the general formula ##STR1## in which --independently of one another-- R.sup.1 and R.sup.2 are hydrogen, halogen, alkyl, aralkyl etc.,Y.sup.1 and Y.sup.2 are alkyl, aryl, cycloalkyl or aralkyl,X.sup.1 is alkyl, alkenyl, cycloalkyl, aralkyl etc.,X.sup.2 is H, alkyl, alkenyl, cycloalkyl etc.X.sup.1 with X.sup.2 with the inclusion of the nitrogen atom carrying them can form a saturated or unsaturated 5- or 6-membered heterocyclic ring, andfurther isocyclic or heterocyclic rings can be fused with the rings A, B and C, upon incorporation in recording materials based on acid developers, show a particularly advantageous migration behaviour. Deep blue, green-blue, green, violet or red shades which have excellent sublimation and light fastness are obtained.
    Type: Grant
    Filed: September 8, 1992
    Date of Patent: August 3, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Udo Eckstein, Roderich Raue
  • Patent number: 5208341
    Abstract: The new carbonylaminostyryls of the formula (I) ##STR1## in which the substituents R.sub.1, A, B and Z have the meaning given in the description, are especially suitable for the production of recording materials which can be used for pressure-sensitive copying, or of thermoreactive or electrochromic recording materials.
    Type: Grant
    Filed: October 4, 1991
    Date of Patent: May 4, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karin Hassenruck, Roderich Raue
  • Patent number: 5030612
    Abstract: Thermal dye sublimation transfer recording element for receiving sublimable basic dye-precursors, comprising a support having thereon a dye-developing layer containing a dye-developing copolymer having sulfonic acid side-groups that can react with the basic dye-precursor to produce a dye image, characterized in that said dye-developing vinyl copolymer comprises plasticizing comonomers, the weight percentage of plasticizing comonomers in the dye-developing vinyl copolymer being such that the glass transition temperature of the dye-developing vinyl copolymer is between 30.degree. C. and 90.degree. C.
    Type: Grant
    Filed: February 27, 1990
    Date of Patent: July 9, 1991
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Herman J. Uytterhoeven, Roderich Raue, Siegfried Korte
  • Patent number: 5013627
    Abstract: Positively charged electrophotographic toners contain, besides customary resin and pigment particles, an additive which increases the cationic charge and has the general formula(X.sup.1).sup.- K.spsp.+.sup.1 -Y.sup.1 -A-Y.sup.2 -K.spsp.+.sup.2 (X.sub.2).sup.- (I)wherein the symbols have the meaning mentioned in the description.
    Type: Grant
    Filed: August 7, 1989
    Date of Patent: May 7, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Harnisch, Roderich Raue
  • Patent number: 5013857
    Abstract: Process for the preparation of sulpho-free triphenylmethane dyestuffs of the formula ##STR1## in which R.sup.1 -R.sup.3 denote hydrogen, C.sub.1 -C.sub.6 -alkyl, preferably methyl, or halogen, preferably chlorine,Y denotes hydrogen or NX.sup.5 X.sup.6,X.sup.1 -X.sup.6 denote hydrogen, C.sub.1 -C.sub.6 -alkyl, preferably methyl, ethyl, benzyl or phenyl andZ.sup.
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: May 7, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Berneth, Roderich Raue
  • Patent number: 4997740
    Abstract: The invention relates to positively charged electrophotographic toners which, in addition to customary resin and pigment particles, contain an additive which intensifies the cationic charge, of the general formula ##STR1## wherein R.sup.1 and R.sup.2 independently of one another represent H, C.sub.1 -C.sub.22 -alkyl, allyl, cyclohexyl, phenyl-C.sub.1 -C.sub.2 -alkyl or phenyl andAn.sup.- denotes an anion,wherein the ring A and the cyclic and acyclic radicals can carry 1-2 nonionic substituents.
    Type: Grant
    Filed: November 17, 1989
    Date of Patent: March 5, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Harnisch, Roderich Raue, Klaus Wunderlich
  • Patent number: 4927729
    Abstract: Heteropolyacid salts of the formula ##STR1## R.sup.1 and R.sup.2 independently of one another stand for hydrogen, chlorine, bromine, hydroxyl, C.sub.1 - to C.sub.4 -alkoxy, nitro or carboxyl,A stand for C.sub.1 - to C.sub.5 -alkylene or --C.sub.6 H.sub.4 --CH.sub.2 -- (m- or p-),m stands for 0 or 1,n stands for 1 or 2,K.sup..sym. stands for ##STR2## R.sup.3 stands for C.sub.1 - to C.sub.24 -alkyl, carbamoyl-C.sub.1 - to C.sub.2 -alkyl, C.sub.1 - to C.sub.4 -alkoxycarbonyl-C.sub.1 - to C.sub.2 -alkyl, benzyl, cyclohexyl or allyl,R.sup.4 stands for C.sub.1 - to C.sub.4 -alkyl or a single bond linked to D,R.sup.5 stands for C.sub.1 - to C.sub.4 -alkyl,D stands for --CH.sub.2 --, --CH.sub.2 --CO--, --CH.sub.2 --CO--NH-- or --CH.sub.2 --CO--NH--CH.sub.2 --,W stands for ##STR3## CO or for single bond, Z stands for --CH.sub.2 --, ##STR4## --O--, --S--, --SO.sub.2 -- or a single bond and X.sup..crclbar.
    Type: Grant
    Filed: November 3, 1988
    Date of Patent: May 22, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Harnisch, Roderich Raue
  • Patent number: 4897223
    Abstract: Color-forming agents of the general formula ##STR1## wherein X denotes hydroxyl, alkoxy, alkenyloxy, aralkoxy, cycloalkoxy, aryloxy, acyloxy, alkoxycarbonyloxy, alkylamino, dialkylamino, acylamino, aralkylamino or arylamino,Q denotes cyano, alkoxycarbonyl, aryloxycarbonyl, aralkoxycarbonyl, carbamoyl, N-alkylcarbamoyl, N,N-dialkylcarbamoyl, N-alkyl-N-aryl-carbamoyl, acyl, alkoxysulphonyl, aralkoxysulphonyl, sulphamoyl, N-alkylsulphamoyl, N,N-dialkylsulphamoyl, alkylsulphonyl, arylsulphonyl or aralkylsulphonyl andR denotes alkyl, alkenyl or aralkyl,further isocyclic or heterocyclic rings can be fused on to the rings A, B, C and D, and the cyclic and acyclic radicals and the rings A, B, C and D can carry further substituents, are used for the preparation of pressure-sensitive recording materials.
    Type: Grant
    Filed: March 1, 1988
    Date of Patent: January 30, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Udo Eckstein, Hubertus Psaar, Roderich Raue
  • Patent number: 4869989
    Abstract: A dry toner for developing latent electrostatic images in electrostatic recording and printing methods contains, as charge-control substance, a pigment of the formula ##STR1## in which A.sup.- represents an anion of a heteropolyacid based on tungsten and/or molybdenum with phosphorus, vanadium, cobalt, aluminium, manganese, chromium and/or nickel or a copper(I) hexacyanoferrate anion,R.sup.1 and R.sup.3, independently of one another, represent hydrogen, alkyl or aralkyl,R.sup.2 and R.sup.4 independently of one another, represent hydrogen, alkyl, aralkyl or aryl, orR.sup.1, R.sup.2, R.sup.3 and R.sup.4, independently of one another, through linking to the o-position of the benzene ring, represent members of a five- or six-membered ring, orR.sup.1 and R.sup.2 or R.sup.3 and R.sup.
    Type: Grant
    Filed: April 12, 1988
    Date of Patent: September 26, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Roderich Raue, Hubertus Psaar
  • Patent number: 4849306
    Abstract: Dry toners for developing latent electrostatic images in electrostatic recording and printing methods contain, as charge-control substance, a pigment of the formulaF.sup.+ A.sup.- (I)in whichF represent a cationic radical of a methine dyestuff andA.sup.- represents an anion of a heteropolyacid based on tungsten and/or molybdenum with phosphorus, silicon, vanadium, cobalt, aluminum, manganese, chromium and/or nickel or a copper(I) hexacyanoferrate anion.
    Type: Grant
    Filed: February 22, 1988
    Date of Patent: July 18, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Roderich Raue, Hubertus Psaar, Horst Berneth
  • Patent number: 4847177
    Abstract: A dry toner for developing latent electrostatic images in electrostatic copying and printing processes contains, as charge-control substance, a pigment of the formula ##STR1## in which A.sup.- represents a silicomolybdate anion,R.sup.1 and R.sup.3 represent, independently of each other, hydrogen, alkyl or aralkyl,R.sup.2 and R.sup.4 represent, independently of each other, hydrogen, alkyl, aralkyl or aryl, orR.sup.1, R.sup.2, R.sup.3 and R.sup.4 represent, independently of each other, members of a five- or six-membered ring produced by linkage with the o-position of the benzene ring orR.sup.1 and R.sup.2 or R.sup.3 and R.sup.4 jointly represent members of a five- or six-membered ring,B represents oxygen, sulphur or N--R,R represents hydrogen, alkyl or aryl andD represents CH, C--CN or N,in which the two benzene rings may be fused with a further benzene ring and then NR.sup.3 R.sup.
    Type: Grant
    Filed: April 12, 1988
    Date of Patent: July 11, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Roderich Raue, Hubertus Psaar
  • Patent number: 4841052
    Abstract: Positively charged electrophotographic toners contain, in addition to conventional resin and pigment particles, an additive reinforcing the cationic charge, of the general formula ##STR1## in which R.sup.1 and R.sup.2 each represent hydrogen, chlorine,bromine, hydroxyl, C.sub.1 -C.sub.4 -alkoxy or carboxyl,A represents C.sub.1 -C.sub.5 -alkylene or --C.sub.6 H.sub.4 --CH.sub.2 -- (m or p),m represents 0 or 1,n represents 1 or 2K.sup..sym. represents ##STR2## R.sup.3 represents C.sub.1 -C.sub.18 -alkyl, carbamoyl-C.sub.1 -C.sub.2 -alkyl, C.sub.1 -C.sub.4 -alkoxycarbonyl-C.sub.1 -C.sub.2 -alkyl, benzyl, cyclohexyl or allyl,R.sup.4 represents C.sub.1 -C.sub.4 -alkyl or a single bond linked to D,R.sup.5 represents C.sub.1 -C.sub.4 -alkyl,D represents --CH.sub.2, --CH.sub.2 --CO--, --CH.sub.2 --CO--NH-- orW represents ##STR3## --CO-- or a single bond,Z represents --CH.sub.2 --, ##STR4## --O--, --S--, --SO.sub.2 -- or a single bond and An.sup..crclbar. represents an anion.
    Type: Grant
    Filed: July 28, 1988
    Date of Patent: June 20, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Harnisch, Roderich Raue
  • Patent number: 4812379
    Abstract: Postively charged electrophotographic toners contain, in addition to conventional resin and pigment particles, an additive reinforcing the cationic charge, of the general formula ##STR1## in which R.sup.1 and R.sup.2 each represent hydrogen, chlorine, bromine, hydroxyl, C.sub.1 -C.sub.4 -alkoxy or carboxyl,A represents C.sub.1 -C.sub.5 -alkylene or --C.sub.6 H.sub.4 --CH.sub.2 --(m or p),m represents 0 to 1,n represents 1 or 2K.sup..sym. represents ##STR2## R.sup.3 represents C.sub.1 -C.sub.18 -alkyl, carbamoyl-C.sub.1 -C.sub.2 -alkyl, C.sub.1 -C.sub.4 -alkoxycarbonyl-C.sub.1 -C.sub.2 -alkyl, benzyl, cyclohexyl or allyl,R.sup.4 represents C.sub.1 -C.sub.4 -alkyl or a single bond linked to D,R.sup.5 represents C.sub.1 -C.sub.4 -alkyl,D represent --CH.sub.2, --CH.sub.2 --CO--, --CH.sub.2 --CO--NH--or --CH.sub.2 --CO--NH--CH.sub.2 --W represents ##STR3## --CO--or a single bond, Z represents --CH.sub.2 --, ##STR4## --O--, --S--, --SO.sub.2 --or a single bond and An.sup..crclbar. represents an anion.
    Type: Grant
    Filed: February 3, 1987
    Date of Patent: March 14, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Harnisch, Roderich Raue
  • Patent number: 4808719
    Abstract: Compounds of the general formula ##STR1## wherein R represents hydrogen or alkyl andA represents a radical of the formula ##STR2## wherein the rings D can carry up to 4 alkyl radicals,R.sup.1 and R.sup.2 independently of one another represent alkyl, alkenyl, cycloalkyl, aryl or aralkyl andR.sup.3 represents hydrogen, alkyl or aryl,and the said cyclic and acyclic radicals and the rings B and C may carry nonionic substituents, are used as color-forming agents.
    Type: Grant
    Filed: June 9, 1987
    Date of Patent: February 28, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hubertus Psaar, Roderich Raue
  • Patent number: 4760132
    Abstract: Cationic hydrazone dyestuffs of the general formula ##STR1## in which R.sub.1 stands for hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 - to C.sub.4 -alkoxy, nitro or halogen,R.sub.2 stands for hydrogen, C.sub.1 - to C.sub.4 -alkyl, C.sub.1 - to C.sub.4 -alkoxy, halogen or phenylazo,R.sub.3 stands for C.sub.1 - to C.sub.3 -alkyl andA.sup.- stands for an anion,are prepared by quaternarizing azo bases of the general formula ##STR2## wherein R.sub.1, R.sub.2 and R.sub.3 have the abovementioned meaning, with dialkyl sulphates of the general formula(R.sub.3 --O).sub.2 SO.sub.2 IIIin whichR.sub.3 has the abovementioned meaning,in the presence of water and alkali metal sulphate or alkaline earth metal sulphate and, where appropriate, by replacing the alkylsulphate anion by another anion.
    Type: Grant
    Filed: December 16, 1986
    Date of Patent: July 26, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Lothar Dorsch, Dietmar Kalz, Volker Huhne, Roderich Raue