Patents by Inventor Roderich Raue

Roderich Raue has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4710569
    Abstract: Dyestuffs of the formula ##STR1## wherein F stands for an organic chromophore andZ stands for radicals of the formulae ##STR2## wherein R.sub.1 -R.sub.2 denote hydrogen, alkyl, cycloalkyl, alkenyl, aryl, aralkyl or a heterocyclic structure orR.sub.2 and R.sub.3 represent an optionally substituted amino group or together form a ring orR.sub.1 with R.sub.2 and/or R.sub.3 with R.sub.4 form a ring,A.sup.(-) denotes an anion,Y denotes an anionic group,m denotes 0-2 andn denotes 1-6,and wherein the chromophore and said radicals can carry further substituents, provided that the total number of anionic substituents is smaller than the total number of quaternary and quaternizable amino groups, are used for dyeing cellulose fibres, in particular paper.
    Type: Grant
    Filed: September 10, 1985
    Date of Patent: December 1, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunter Franke, Dieter Ockelmann, Roderich Raue, Peter Wild
  • Patent number: 4670882
    Abstract: Dyestuff laser consisting of a reservoir, with a laser dyestuff solution contained therein, and a pumped light source associated therewith, which is capable of exciting the dyestuff solution to produce an emission, characterized in that the dyestuff solution contains, in a solvent which does not interfere with the emission, a dyestuff which, in the form of the free acid, corresponds to the general formula ##STR1## wherein R.sub.1 to R.sub.4 independently of one another represent hydrogen, alkyl, trifluormethyl, alkoxy, aralkoxy, alkenyloxy, halogen or the carboxyl, cyano, alkylsulphone, aryl-sulphone, carboxamide, sulphonamide or carboxylic acid ester group,R.sub.1 and R.sub.4 can additionally denote a fused-on benzene ring,n represents a number 2 to 6 ando, p, q and r independently of one another represent 0, 1 or 2,in a concentration, preferably of 10.sup.-2 to 10.sup.-5 mol/1, which emits laser radiation.
    Type: Grant
    Filed: February 18, 1982
    Date of Patent: June 2, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut Telle, Rudolf Schieder, Roderich Raue, Udo Eckstein
  • Patent number: 4600776
    Abstract: Cationic enamine dyestuffs of the general formula ##STR1## in which the symbols have the meaning given in the description, are used for dyeing natural and synthetic substrates and compositions which can be dyed with cationic dyestuffs, in particular paper.
    Type: Grant
    Filed: June 11, 1984
    Date of Patent: July 15, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karlheinrich Meisel, Roderich Raue
  • Patent number: 4551265
    Abstract: Fluorescent dyestuffs of the general formula ##STR1## wherein R and R.sup.1 independently of one another represent hydrogen, a salt-forming cation, an alkyl radical with 1 to 16 C atoms or an aryl or aralkyl radical which is optionally substituted by non-chromophoric groups,R.sup.2 to R.sup.5 independently of one another represent hydrogen, alkyl, trifluoromethyl, alkoxy, aralkoxy, alkenoxy, aryloxy, halogen or a carboxyl, cyano, alkyl sulphone, aryl sulphone, aralkyl sulphone, carboxamide, sulphonamide or carboxylic acid ester group,o, p, q and s independently of one another represent 1 or 2 andm and n independently of one another denote 0, 1 or 2, it being possible for the sum of m and n to be 2 to 4,processes for their preparation and their use as laser dyestuffs.
    Type: Grant
    Filed: December 30, 1981
    Date of Patent: November 5, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Brinkwerth, Wolfgang Huffer, Roderich Raue, Rudolf Schieder, Helmut Telle
  • Patent number: 4542223
    Abstract: Methine dyestuffs of the formula ##STR1## are prepared by subjecting a compound ##STR2## to a condensation reaction with a compoundA--CHO (VI)and with 1 to 5 equivalents of an inorganic acid in the presence of 0-30% by weight of an organic solvent and 0-15% by weight of water.
    Type: Grant
    Filed: March 14, 1983
    Date of Patent: September 17, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Roderich Raue, Hans-Peter Kuhlthau, Klaus-Friedrich Lehment
  • Patent number: 4542224
    Abstract: Cationic methine dyestuffs of the formula ##STR1##
    Type: Grant
    Filed: April 4, 1983
    Date of Patent: September 17, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Roderich Raue, Hans-Peter Kuhlthau
  • Patent number: 4513142
    Abstract: A method of preparation of cationic dyestuffs having the formula ##STR1## wherein A, B, R, and R.sup.1 are defined in the specification carried out in the substantial absence of solvent and removing water formed in the reaction.
    Type: Grant
    Filed: August 30, 1982
    Date of Patent: April 23, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Roderich Raue, Volker Huhne, Hans-Peter Kuhlthau
  • Patent number: 4496719
    Abstract: Hydrazone dyestuffs of the formula ##STR1## in which R denotes optionally substituted alkyl,R.sup.1 denotes alkyl and the two radicals can form a closed ring,R.sup.2 denotes optionally substituted alkyl,R.sup.3 denotes alkyl, alkoxy or halogen,R.sup.4 denotes alkyl, halogen, alkoxy, phenoxy, benzyloxy, benzyl, carboxyl, alkyl carboxylate, carboxamide, sulphonamide, alkylsulphonyl, phenylsulphonyl, cyano, nitro, trifluoromethyl, acetyl or benzoyl,B denotes ##STR2## D denotes alkylene, phenylene or naphthylene, E denotes halogen, hydroxyl, alkoxy or ##STR3## Z and Z.sup.1 denote hydrogen or --Y--Z.sup.2, Y denotes alkylene,Z.sup.2 denotes hydrogen, hydroxyl, pyridinium, ##STR4## Z.sup.3, Z.sup.4 and Z.sup.5 denote hydrogen or optionally substituted alkyl,Z.sup.3 also denotes phenyl, benzyl or ##STR5## Y.sup.1 denotes alkylene and s denotes 1-8, orZ and Z.sup.1 as well as Z.sup.3 and Z.sup.
    Type: Grant
    Filed: February 15, 1983
    Date of Patent: January 29, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventor: Roderich Raue
  • Patent number: 4426530
    Abstract: Optical brighteners of the formula ##STR1## wherein B denotes a direct bond or the 1,4-phenylene radical andR.sub.1 and R.sub.2 independently of one another denote hydrogen, optionally substituted alkyl, aralkyl, cycloalkyl or aryl, or together form a fused aromatic ring,or the quaternisation products and protonation products thereof, are outstandingly suitable for the white tinting of polyester fibres or acrylic fibres. They are distinguished by a good build-up capacity and a small tendency to develop a green tone.
    Type: Grant
    Filed: December 30, 1981
    Date of Patent: January 17, 1984
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Berneth, Roderich Raue
  • Patent number: 4419511
    Abstract: To prepare trimethine dyestuffs of the general formula ##STR1## wherein R represents a C.sub.1 - to C.sub.4 -alkyl radical,R.sup.1 represents hydrogen, C.sub.1 - to C.sub.4 -alkyl, benzyl, cyclohexyl, C.sub.1 - to C.sub.4 -alkoxy, benzyloxy, phenoxy, halogen, trifluoromethyl, acetylamino, carboxylic acid C.sub.1 - to C.sub.4 -alkyl esters, carbonamide which may be substituted by C.sub.1 - to C.sub.4 -alkyl and/or phenyl, C.sub.1 - to C.sub.4 -alkylsulphonyl, phenylsulphonyl, cyano, nitro, benzoxazol-2-yl, benzimidazol-2-yl, benzthiazol-2-yl and sulphonamide which may be monosubstituted or disubstituted by C.sub.1 - to C.sub.4 -alkyl, or two radicals R.sup.1 represent a fused benzene ring,n denotes 1 to 4 andA.sup.- denotes an anionic radical, first an alkali metal salt of formic acid is reacted with a mixture of acetic acid and acetic anhydride and the product is then reacted with indoline compounds of the general formula ##STR2## in which R, R.sup.1 and n have the abovementioned meaning.
    Type: Grant
    Filed: January 28, 1982
    Date of Patent: December 6, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventor: Roderich Raue
  • Patent number: 4400321
    Abstract: To prepare concentrated solutions of cationic polyazo dyestuffs of the formula ##STR1## in which R represents hydrogen or methyl andR.sup.1 represents an alkyl radical which has 1 to 3 carbon atoms and is optionally substituted by hydroxyl, alkoxy or halogen,and mixing coupling products thereof with aromatic monoamines, diaminobenzenes of the general formula ##STR2## in which R has the abovementioned meaning,if appropriate mixed with up to 30 mol % of aromatic monoamines of the formula ##STR3## in which R.sup.2 represents hydrogen, C.sub.1 - to C.sub.4 -alkyl, C.sub.1 - toC.sub.4 -alkoxy or C.sub.1 - to C.sub.4 -acylamino andn denotes a number from 1 to 3,are dissolved in aliphatic carboxylic acids which have 2 to 4 carbon atoms and can optionally be substituted by halogen, hydroxyl or alkoxy, and are reacted with 0.5 to 0.75 mol of a salt or ester of nitrous acid per mol of diamine at 0.degree. to 30.degree. C.
    Type: Grant
    Filed: June 17, 1981
    Date of Patent: August 23, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Linhart, Harald Gleinig, Roderich Raue, Hans-Peter Kuhlthau
  • Patent number: 4376728
    Abstract: To prepare dyestuffs of the general formula ##STR1## or color bases of the general formula ##STR2## wherein R.sup.1 and R.sup.2 denote hydrogen, alkyl, alkenyl or aralkyl,R.sup.3 and R.sup.4 denote methyl or ethyl andX denotes an anion,and wherein the rings A and B and the radicals R.sup.1 and R.sup.2 can carry non-ionic substituents and the rings A and B can carry further fused-on rings, an amine of the formula ##STR3## wherein B has the abovementioned meaning, and a compound of the formula ##STR4## wherein R.sup.1, R.sup.3, R.sup.4 and A have the abovementioned meanings andR.sup.5 and R.sup.6 represent hydrogen, alkyl, alkoxy, phenoxy or phenyl,are reacted, in the presence of an acid, with a substance which releases nitrous acid and, if appropriate, the product is then reacted with a compound which forms the radicals R.sup.1' and/or R.sup.2', which represent alkyl, alkenyl or aralkyl which are optionally substituted by non-ionic radicals, and X.
    Type: Grant
    Filed: June 8, 1981
    Date of Patent: March 15, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Roderich Raue, Hans-Peter Kuhlthau
  • Patent number: 4349670
    Abstract: To prepare dyestuffs of the general formula ##STR1## in which R.sup.1 and R.sup.2 represent methyl or ethyl,n represents 0 or 1,B represents the divalent radical of a 5-membered or 6-membered heterocyclic ring system andX.sup.- represents an anion,and whereinthe ring a can be substituted by C.sub.1 - to C.sub.4 -alkyl radicals, C.sub.1 - to C.sub.4 -alkoxy radicals or halogen,compounds of the formula ##STR2## wherein R.sup.1, B and n have the meaning indicated above,m represents 0 or 1 andthe ring a can be substituted by C.sub.1 - to C.sub.4 -alkyl, C.sub.1 - to C.sub.4 -alkoxy or halogen,or of the formula ##STR3## in which B and R.sup.1 have the abovementioned meaning and the ring a can be substituted by C.sub.1 - to C.sub.4 -alkyl, C.sub.1 - to C.sub.4 -alkoxy or halogen,are reacted with arylsulphonic acid esters of the formula ##STR4## wherein R represents hydrogen, C.sub.1 - to C.sub.4 -alkyl or halogen andR.sup.
    Type: Grant
    Filed: July 17, 1980
    Date of Patent: September 14, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Roderich Raue, Heinz Giesecke
  • Patent number: 4338258
    Abstract: Fluorescent dyestuffs of the general formula ##STR1## wherein R and R.sup.1 independently of one another represent hydrogen, a salt-forming cation, an alkyl radical with 1 to 16 C atoms or an aryl or aralkyl radical which is optionally substituted by non-chromophoric groups,R.sup.2 to R.sup.5 independently of one another represent hydrogen, alkyl, trifluoromethyl, alkoxy, aralkoxy, alkenoxy, aryloxy, halogen or a carboxyl, cyano, alkyl sulphone, aryl sulphone, aralkyl sulphone, carboxamide, sulphonamide or carboxylic acid ester group,o, p, q and s independently of one another represent 1 or 2 andm and n independently of one another denote 0, 1 or 2, it being possible for the sum of m and n to be 2 to 4,processes for their preparation and their use as laser dyestuffs.
    Type: Grant
    Filed: September 8, 1980
    Date of Patent: July 6, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Brinkwerth, Wolfgang Huffer, Roderich Raue, Rudolf Schieder, Helmut Telle
  • Patent number: 4326066
    Abstract: Coumarin compounds of the formula ##STR1## in which the substituents have the meanings given inthe description,are valuable whiteners for natural fibre materials, such as wool, or synthetic polycondensates. They can also be used as scintillators and laser dyestuffs.
    Type: Grant
    Filed: January 7, 1980
    Date of Patent: April 20, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Udo Eckstein, Roderich Raue, Carl-Wolfgang Schellhammer
  • Patent number: 4301091
    Abstract: Fluorescent dyestuffs of the formula ##STR1## wherein: R.sub.1 and R.sub.2 independently of one another represent hydrogen, a salt-forming cation, an alkyl radical with 1 to 8 carbon atoms or an aralkyl radical which is optionally substituted by non-chromophoric groups,R.sub.2 to R.sub.5 independently of one another represent hydrogen, alkyl, trifluoromethyl, alkoxy, aralkoxy, alkenyloxy, halogen or the carboxyl, cyano, alkylsulphonyl, arylsulphonyl, carboxamide or sulphonamide group or a carboxylic acid ester group, m and n independently of one another denote 0, 1 or 2 and the sum of m+n must be at least 2, and o, p, q and r independently of one another represent 0, 1 or 2.processes for their preparation, their use for whitening organic materials and a process for the production of a coherent laser emission using the fluorescent dyestuffs according to formula I.
    Type: Grant
    Filed: September 10, 1979
    Date of Patent: November 17, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rudolf Schieder, Helmut Telle, Roderich Raue, Wolfgang Brinkwerth
  • Patent number: 4281112
    Abstract: The preparation of hydrazone dyestuffs of the formula ##STR1## wherein R.sup.13 and R.sup.14 independently of one another represent hydrogen, C.sub.1 -- to C.sub.4 --alkyl, C.sub.1-- to C.sub.4-- alkoxy or halogen, in particular chlorine or bromine, andA.sup.- denotes an anionic radical,by reacting azo bases of the general formula ##STR2## wherein R.sup.13 and R.sup.14 have the above mentioned meaning andR.sup.15 represents hydrogen or the methyl group, with dimethyl sulphate in a mixture of water and an organic solvent and in the presence of an acid-binding agent, is characterized in that (a) aromatic or aliphatic chlorinated hydrocarbons are used as the organic solvents, (b) the reaction is carried out at a temperature of 10.degree.-60.degree. C., (c) a 5-90% excess of dimethyl sulphate is employed and (d) the reaction is allowed to proceed at a pH of 5-10.
    Type: Grant
    Filed: July 17, 1980
    Date of Patent: July 28, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Klaus-Friedrich Lehment, Roderich Raue, Harald Gleinig
  • Patent number: 4274062
    Abstract: Laser light in the wavelength range of 400 - 480 Nm is obtained with a dyestuff laser containing a dyestuff of the general formula ##STR1## wherein E denotes one of the radicals ##STR2## R.sub.1 -R.sub.4 independently of one another denote hydrogen, alkyl, trifluoromethyl, alkoxy, aralkoxy, halogen, alkenyloxy, the carboxyl, cyano, alkylsulphone, arylsulphone, carboxamide or sulphonamide group or the carboxylic acid ester group, or R.sub.1 and R.sub.2, or R.sub.3 and R.sub.4, conjointly represent a fused benzene ring and m and n independently of one another denote 0, 1 or 2, with the proviso that the radical E contains at least one sulphonic acid group if m and n represent 0,and whereinthe radical E can be further substituted, in a solvent which does not interfere with the emission, at a concentration, which emits laser beams, of, preferably, 10.sup.-2 to 10.sup.-5 mols/liter.
    Type: Grant
    Filed: January 3, 1978
    Date of Patent: June 16, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Uwe Brinkmann, Helmut Telle, Roderich Raue, Carl-Wolfgang Schellhammer
  • Patent number: 4271395
    Abstract: Laser light in the wavelength range of 420-480 nm is obtained with a dyestuff laser containing a dyestuff of the general formula ##STR1## wherein R and R.sub.1 independently of one another represent ##STR2## R.sub.2 denotes an optionally substituted alkyl radical with 1-4 C atoms, R.sub.3 and R.sub.4 independently of one another represent hydrogen or optionally substituted C.sub.1 -C.sub.4 -alkyl or conjointly with the nitrogen can form a 5-membered or 6-membered heterocyclic ring andm and n denote 1 or 2, andwhereinthe aromatic radicals contained in the formula can be further substituted, in a solvent which does not interfere with the emission, at a concentration, which emits laser beams, of, preferably, 10.sup.-2 to 10.sup.-5 mols/liter.
    Type: Grant
    Filed: January 3, 1978
    Date of Patent: June 2, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Uwe Brinkmann, Helmut Telle, Roderich Raue
  • Patent number: 4256882
    Abstract: Reactive dyestuffs which in form of the free acid correspond to the following formula ##STR1## wherein R.sub.1, R.sub.2, W.sub.1, Y, Z, Q, as well as A, B and C have the meaning given in claim 1, and their use for the dyeing and printing of fibre material made of polyamide, for example natural and, in particular, synthetic polyamides, and natural and regenerated cellulose in red and bluish-tinged red fluorescent color.
    Type: Grant
    Filed: August 3, 1976
    Date of Patent: March 17, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Adolf Friedrich, Horst Harnisch, Roderich Raue