Abstract: The present disclosure relates to a power production system that is adapted to achieve high efficiency power production with complete carbon capture when using a solid or liquid hydrocarbon or carbonaceous fuel. More particularly, the solid or liquid fuel first is partially oxidized in a partial oxidation reactor. The resulting partially oxidized stream that comprises a fuel gas is quenched, filtered, cooled, and then directed to a combustor of a power production system as the combustion fuel. The partially oxidized stream is combined with a compressed recycle CO2 stream and oxygen. The combustion stream is expanded across a turbine to produce power and passed through a recuperator heat exchanger. The expanded and cooled exhaust stream is scrubbed to provide the recycle CO2 stream, which is compressed and passed through the recuperator heat exchanger and the POX heat exchanger in a manner useful to provide increased efficiency to the combined systems.

Abstract: The present invention provides methods and system for power generation using a high efficiency combustor in combination with a CO2 circulating fluid. The methods and systems advantageously can make use of a low pressure ratio power turbine and an economizer heat exchanger in specific embodiments. Additional low grade heat from an external source can be used to provide part of an amount of heat needed for heating the recycle CO2 circulating fluid. Fuel derived CO2 can be captured and delivered at pipeline pressure. Other impurities can be captured.

Abstract: The present invention provides methods and system for power generation using a high efficiency combustor in combination with a CO2 circulating fluid. The methods and systems advantageously can make use of a low pressure ratio power turbine and an economizer heat exchanger in specific embodiments. Additional low grade heat from an external source can be used to provide part of an amount of heat needed for heating the recycle CO2 circulating fluid. Fuel derived CO2 can be captured and delivered at pipeline pressure. Other impurities can be captured.

Abstract: SO2 and/or NOx are removed from gaseous CO2 at elevated pressure(s) in the presence of molecular oxygen and water and, when SO2 is to be removed, NOx, to convert SO2 to sulfuric acid and/or NOx to nitric acid. The sulfuric acid and/or nitric acid is/are then removed from the gaseous carbon dioxide to produce SO2-free, NOx-lean carbon dioxide gas. The invention has particular application in the removal of SO2 and/or NOx from carbon dioxide flue gas produced in an oxyfuel combustion process, for example, in a pulverized coal fired power station.

Abstract: The present invention relates to a cryogenic air separation process that provides high pressure oxygen for an oxy-fired combustion of a fuel (e.g., a carbonaceous fuel). The air separation process can be directly integrated into a closed cycle power production process utilizing a working fluid, such as CO2. Beneficially, the air separation process can eliminate the need for inter-cooling between air compression stages and rather provide for recycling the adiabatic heat of compression into a process step in a further methods wherein an additional heat supply is beneficial.

Abstract: A first contaminant selected from oxygen and carbon monoxide is removed from impure liquid carbon dioxide using a mass transfer separation column system which is reboiled by indirect heat exchange against crude carbon dioxide fluid, the impure liquid carbon dioxide having a greater concentration of carbon dioxide than the crude carbon dioxide fluid. The invention has particular application in the recovery of carbon dioxide from flue gas generated in an oxyfuel combustion process or waste gas from a hydrogen PSA process. Advantages include reducing the level of the first contaminant to not more than 1000 ppm.

Abstract: A combustor apparatus is provided, comprising a mixing arrangement for mixing a carbonaceous fuel with enriched oxygen and a working fluid to form a fuel mixture. A combustion chamber is at least partially defined by a porous perimetric transpiration member, at least partially surrounded by a pressure containment member. The combustion chamber has longitudinally spaced apart inlet and outlet portions. The fuel mixture is received by the inlet portion for combustion within the combustion chamber at a combustion temperature to form a combustion product. The combustion chamber directs the combustion product longitudinally toward the outlet portion.

Abstract: The present disclosure provides methods, assemblies, and systems for power production that can allow for increased efficiency and lower cost components arising from the control, reduction, or elimination of turbine blade mechanical erosion by particulates or chemical erosion by gases in a combustion product flow. The methods, assemblies, and systems can include the use of turbine blades that operate with a blade velocity that is significantly reduced in relation to conventional turbines used in typical power production systems. The methods and systems also can make use of a recycled circulating fluid for transpiration protection of the turbine and/or other components. Further, recycled circulating fluid may be employed to provide cleaning materials to the turbine.

Abstract: A method of power production using a high pressure/low pressure ratio Brayton Power cycle with predominantly N2 mixed with CO2 and H2O combustion products as the working fluid is provided. The high pressure can be in the range 80 bar to 500 bar. The pressure ratio can be in the range 1.5 to 10. The natural gas fuel can be burned in a first high pressure combustor with a near stoichiometric quantity of pressurised preheated air and the net combustion gas can be mixed with a heated high pressure recycle N2+CO2+H2O stream which moderates the mixed gas temperature to the value required for the maximum inlet temperature to a first power turbine producing shaft power.

Abstract: The present invention relates to systems, apparatuses, and methods for providing a reliable, high purity source of CO2 that is used in the recovery of formation deposits, such as fossil fuels. At least a portion of the fossil fuels recovered may be directly combusted or extracted using the same process used to provide the pure source of CO2 without the need to first remove CO2, sulfur, other fossil fuels, or other impurities.

Abstract: A superheater in a power plant that superheats steam to operation conditions exceeding an operating limit of an associated steam-producing boiler. The superheater combusts oxygen and fuel with cooled recycled combustion gas to produce a CO2-rich combustion product gas stream at a fixed temperature. The combustion gas is used as the heat transfer fluid in the superheater's heat exchanger. The CO2-rich flue gas stream allows for efficient capture of substantially pure CO2. The superheater may be retrofitted to an existing power plant as a separate component, external to the boiler. The plant may thus have its electrical power output increased, while its overall CO2 emissions per nit of generated power is decreased, even when inexpensive, readily-available fossil fuels are used as the primary fuel for filing the boiler and/or the superheater.

Abstract: Carbon dioxide and oxygen are separated from a feed gas, preferably derived from flue gas from an oxyfuel combustion process, by diffusion across at least one membrane in a membrane separation system to produce separated carbon dioxide gas comprising oxygen, which is fed to the oxyfuel combustion process to improve the performance of the process.

Abstract: Impure carbon dioxide (“CO2”) comprising a first contaminant selected from the group consisting of oxygen (“O2”) and carbon monoxide (“CO”) is purified by separating expanded impure carbon dioxide liquid in a mass transfer separation column system. The impure carbon dioxide may be derived from, for example, flue gas from an oxyfuel combustion process or waste gas from a hydrogen (“H2”) PSA system.

Abstract: The present invention provides methods and system for power generation using a high efficiency combustor in combination with a CO2 circulating fluid. The methods and systems advantageously can make use of a low pressure ratio power turbine and an economizer heat exchanger in specific embodiments. Additional low grade heat from an external source can be used to provide part of an amount of heat needed for heating the recycle CO2 circulating fluid. Fuel derived CO2 can be captured and delivered at pipeline pressure. Other impurities can be captured.

Abstract: A combustor apparatus is provided, comprising a mixing arrangement for mixing a carbonaceous fuel with enriched oxygen and a working fluid to form a fuel mixture. A combustion chamber is at least partially defined by a porous perimetric transpiration member, at least partially surrounded by a pressure containment member. The combustion chamber has longitudinally spaced apart inlet and outlet portions. The fuel mixture is received by the inlet portion for combustion within the combustion chamber at a combustion temperature to form a combustion product. The combustion chamber further directs the combustion product longitudinally toward the outlet portion.

Abstract: Hydrogen (H2) gas and crude carbon dioxide (CO2) gas are separated from a gaseous mixture thereof. Combustible gas(es) in the crude CO2 gas are combusted to produce heat, at least a portion of which is recovered by indirect heat exchange with at least a portion of the separated H2 gas or a gas derived therefrom. The invention may be integrated with coal-fired power stations to reduce or eliminate emission of harmful components into the atmosphere.

Abstract: A first contaminant selected from oxygen and carbon monoxide is removed from impure liquid carbon dioxide using a mass transfer separation column system which is reboiled by indirect heat exchange against crude carbon dioxide fluid, the impure liquid carbon dioxide having a greater concentration of carbon dioxide than the crude carbon dioxide fluid. The invention has particular application in the recovery of carbon dioxide from flue gas generated in an oxyfuel combustion process or waste gas from a hydrogen PSA process. Advantages include reducing the level of the first contaminant to not more than 1000 ppm.

Abstract: Impure carbon dioxide (“CO2”) comprising a first contaminant selected from the group consisting of oxygen (“O2”) and carbon monoxide (“CO”) is purified by separating expanded impure carbon dioxide liquid in a mass transfer separation column system. The impure carbon dioxide may be derived from, for example, flue gas from an oxyfuel combustion process or waste gas from a hydrogen (“H2”) PSA system.

Abstract: A combustor apparatus is provided, comprising a mixing arrangement for mixing a carbonaceous fuel with enriched oxygen and a working fluid to form a fuel mixture. A combustion chamber is at least partially defined by a transpiration member. The transpiration member is at least partially surrounded by a pressure containment member. The combustion chamber has opposed inlet and outlet portions. The inlet portion of the combustion chamber is configured to receive the fuel mixture for the fuel mixture to be combusted at a combustion temperature. The combustion chamber is further configured to direct the resulting combustion product toward the outlet portion. The transpiration member directs a transpiration substance therethrough toward the combustion chamber for buffering interaction between the combustion product and the transpiration member. Associated systems, apparatuses, and methods are also provided.

Abstract: A first contaminant selected from oxygen and carbon monoxide is removed from impure liquid carbon dioxide using a mass transfer separation column system which is reboiled by indirect heat exchange against crude carbon dioxide fluid, the impure liquid carbon dioxide having a greater concentration of carbon dioxide than the crude carbon dioxide fluid. The invention has particular application in the recovery of carbon dioxide from flue gas generated in an oxyfuel combustion process or waste gas from a hydrogen PSA process. Advantages include reducing the level of the first contaminant to not more than 1000 ppm.