Abstract: Methods and related apparatuses and mixtures are described for detecting hydrogen sulfide in a formation fluid downhole. A detection mixture is combined with the formation fluid downhole. The detection mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and charged nanoparticles sized so as to inhibit significant aggregation of the metal sulfide so as to enable spectroscopic detection of the metal sulfide downhole. The combined mixture and formation fluid is then spectroscopically interrogated so as to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the formation fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.

Abstract: A formation fluid sampling tool is provided with reactants which are carried downhole and which are combined in order to generate heat energy which is applied to the formation adjacent the borehole. By applying heat energy to the formation, the formation fluids are heated, thereby increasing mobility, and fluid sampling is expedited.

Abstract: A gas separation and detection tool for performing in situ analysis of borehole fluid is described. The tool operates by introducing a reagent to a test sample and causing the resulting mixture to flow through a microfluidic channel where optical testing is performed. The optical testing detects a change in a characteristic of the reagent in response to expose to one or more particular substances in the test sample. The test sample may be borehole fluid, a mixture of borehole fluid and scrubbing fluid subsequently mixed with reagent, a mixture of reagent and gas separated from borehole fluid, or a mixture of scrubbing fluid and gas separated from borehole fluid which is subsequently mixed with reagent. A membrane may be employed to separate one or more target gasses from the borehole fluid.

Abstract: A microfluidic system for performing fluid analysis is described having: (a) a submersible housing having a fluid analysis means and a power supply to provide power to said system; and (b) a substrate for receiving a fluid sample, having embedded therein a fluid sample inlet, a reagent inlet, a fluid sample outlet, and a mixing region in fluid communication with the fluid sample inlet, the reagent inlet, and the fluid sample outlet, and wherein the substrate includes a fluid drive means for moving the fluid sample through the substrate, and wherein the substrate interconnects with the housing. At least a portion of the fluid analysis means may be embedded in the substrate.

Abstract: The present invention provides methods and apparatus for separating and/or analyzing fluids of interest. According to principles of the present invention, fluid analysis is accomplished with microfluidic devices and may be reported in real-time or near real-time in a subterranean environment. In addition or alternative to oilfield applications, the principles of the present invention contemplate separation in a laboratory or other environment for biological sample separation and analytical chemistry applications. The present invention is capable of separating liquid-liquid mixtures or emulsions in a microfluidic device without fouling.

Abstract: The present invention provides methods and apparatus for separating and/or analyzing fluids of interest. According to principles of the present invention, fluid analysis is accomplished with microfluidic devices and may be reported in real-time or near real-time in a subterranean environment. In addition or alternative to oilfield applications, the principles of the present invention contemplate separation in a laboratory or other environment for biological sample separation and analytical chemistry applications. The present invention is capable of separating liquid-liquid mixtures or emulsions in a microfluidic device without fouling.

Abstract: Methods and related apparatuses and mixtures are described for detecting hydrogen sulfide in a formation fluid downhole. A detection mixture is combined with the formation fluid downhole. The detection mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and charged nanoparticles sized so as to inhibit significant aggregation of the metal sulfide so as to enable spectroscopic detection of the metal sulfide downhole. The combined mixture and formation fluid is then spectroscopically interrogated so as to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the formation fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.

Abstract: A formation fluid sampling tool is provided with reactants which are carried downhole and which are combined in order to generate heat energy which is applied to the formation adjacent the borehole. By applying heat energy to the formation, the formation fluids are heated, thereby increasing mobility, and fluid sampling is expedited.