Abstract: A cathode active material for a lithium secondary battery has a structure of a lithium-nickel-based oxide. A crystallite size in a (104) plane is in a range from 50 nm to 100 nm, and a slab ratio is in a range from 0.4 to 0.45. An active capacity of the cathode active material can be improved, and an elution amount of doping elements during washing process can be reduced, thereby improving capacity properties of a lithium secondary battery.

Abstract: The apparatus for diluting exhaust gas according to an exemplary embodiment of the present invention includes a stagnant air forming unit configured to form stagnant air by decelerating a flow velocity of introduced exhaust gas, an ejector unit connected to a front end of the stagnant air forming unit and configured to discharge the exhaust gas to a front, and a dilution unit coupled to a front end of the ejector unit.

Abstract: A cathode active material for a lithium secondary battery includes a coating element and lithium-nickel metal oxide particles. A coating area defined as (AC/ANi)*100 1 is 25% or more. AC is an area of a region where a content of the coating element is 1.6 wt % or more based on a total weight of the lithium-nickel metal oxide particles in a quantitative map (Q-map) image obtained through a scanning electron microscope-energy dispersive X-ray spectroscopy (SEM-EDS), and ANi is an area of a region where nickel is present in the Q-map image obtained through the SEM-EDS.

Abstract: A cathode active material for a lithium secondary battery includes a lithium-nickel metal oxide particle having a form of a secondary particle in which a plurality of primary particles are aggregated therein. The lithium-nickel metal oxide particle includes a penetration region formed in an area extending from a surface to a point 70% or less of a radius of the particle in a direction to a center of the particle. The penetration region includes a tungsten compound at an interface between the primary particles. A relative standard deviation (RSD) value calculated from results of measuring a tungsten content from the surface of the secondary particle to a depth of 10 10 nm 10 times at different points using an X-ray Photoelectron Spectroscopy (XPS) is in a range from 10% to 40%.

Abstract: A cathode active material for a lithium secondary battery includes a lithium-nickel-based metal oxide particle, and a coating formed on a surface of the lithium-nickel-based metal oxide particle. The coating includes a water-soluble polymer and an oxygen scavenger compound. Oxygen generated from the cathode active material can be directly removed by the coating.

Abstract: The cathode active material for a lithium secondary battery according to embodiments of the present invention includes a lithium-transition metal composite oxide particle including a plurality of primary particles, and the lithium-transition metal composite oxide particle includes a lithium-sulfur-containing portion formed between the primary particles. Thereby, it is possible to improve life-span properties and capacity properties by preventing the layer structure deformation of the primary particles and removing residual lithium.

Abstract: A cathode active material for a lithium secondary battery includes a lithium-aluminum-titanium oxide formed on a surface of a lithium metal oxide particle having a specific formula. The cathode active material may have an improved structural stability even in a high temperature condition.

Abstract: A cathode active material for a lithium secondary battery includes a lithium metal oxide particle, and an organic poly-phosphate or an organic poly-phosphonate formed on at least portion of a surface of the lithium metal oxide particle. Chemical stability of the lithium metal oxide particle may be improved and surface residues may be reduced by the organic poly-phosphate or the organic poly-phosphonate.

Abstract: The cathode active material for a lithium secondary battery according to embodiments of the present invention includes lithium-transition metal composite oxide particles including a plurality of primary particles, and the lithium-transition metal composite oxide particles have a lithium-potassium-containing portion formed between the primary particles. Thereby, it is possible to improve life-span properties and capacity properties by preventing the layer structure deformation of the primary particles and removing residual lithium.

Abstract: A cathode active material for a lithium secondary battery includes a lithium metal oxide particle, and an organic poly-phosphate or an organic poly-phosphonate formed on at least portion of a surface of the lithium metal oxide particle. Chemical stability of the lithium metal oxide particle may be improved and surface residues may be reduced by the organic poly-phosphate or the organic poly-phosphonate.

Abstract: A method of manufacturing a cathode active material for a lithium secondary battery according to embodiments of the present invention includes performing a first heat treatment on a first mixture of a transition metal precursor and a lithium precursor at a first calcination temperature to obtain a preliminary lithium-transition metal composite oxide particle; and performing a second heat treatment on a second mixture obtained by adding the lithium precursor to the preliminary lithium-transition metal composite oxide particle at a second calcination temperature which is lower than the first calcination temperature to form a lithium-transition metal composite oxide particle.

Abstract: A cathode active material for a lithium secondary battery includes a lithium-aluminum-titanium oxide formed on a surface of a lithium metal oxide particle having a specific formula. The cathode active material may have an improved structural stability even in a high temperature condition.

Abstract: A cathode active material for a lithium secondary battery includes a lithium metal oxide particle and a thio-based compound formed on at least portion of a surface of the lithium metal oxide particle. The thio-based compound has a double bond that contains a sulfur atom. Chemical stability of the lithium metal oxide particle may be improved and surface residues may be reduced by the thio-based compound.

Abstract: A cathode active material for a lithium secondary battery includes a lithium metal oxide particle and a thio-based compound formed on at least portion of a surface of the lithium metal oxide particle. The thio-based compound has a double bond that contains a sulfur atom. Chemical stability of the lithium metal oxide particle may be improved and surface residues may be reduced by the thio-based compound.

Abstract: A method of manufacturing a cathode active material for a lithium secondary battery according to embodiments of the present invention includes performing a first heat treatment on a first mixture of a transition metal precursor and a lithium precursor at a first calcination temperature to obtain a preliminary lithium-transition metal composite oxide particle; and performing a second heat treatment on a second mixture obtained by adding the lithium precursor to the preliminary lithium-transition metal composite oxide particle at a second calcination temperature which is lower than the first calcination temperature to form a lithium-transition metal composite oxide particle.

Abstract: In a method of manufacturing a cathode active material for a lithium secondary battery, a preliminary lithium metal oxide particle is prepared. The preliminary lithium metal oxide particle is cleaned using a boron compound cleaning solution. A cathode active material for a lithium secondary particle includes a lithium metal oxide particle where a ratio of a B+ peak intensity relative to a sum of peak intensities of Li+, B+ and LiB+ fragments by a TOF-SIMS analysis is in a range from 0.03% to 1.5%.

Abstract: In a method of manufacturing a cathode active material for a lithium secondary battery, a preliminary lithium metal oxide particle is prepared. The preliminary lithium metal oxide particle is cleaned using a boron compound cleaning solution. A cathode active material for a lithium secondary particle includes a lithium metal oxide particle where a ratio of a B+ peak intensity relative to a sum of peak intensities of Li+, B+ and LiB+ fragments by a TOF-SIMS analysis is in a range from 0.03% to 1.5%.

Abstract: A cathode active material for a lithium secondary battery according to an embodiment of the present invention includes a lithium-transition metal oxide particle. The lithium-transition metal oxide particle has a FWHM ratio measured by an in-situ X-ray Diffraction spectroscopy (XRD) and defined by Equation 1 of 400% or less. Life-span properties of a lithium secondary battery can be improved by preventing deformation of a lattice structure and/or a crystal structure in the lithium-transition metal composite oxide particles.

Abstract: A cathode active material for a lithium secondary battery includes a lithium metal oxide particle and a thio-based compound formed on at least portion of a surface of the lithium metal oxide particle. The thio-based compound has a double bond that contains a sulfur atom. Chemical stability of the lithium metal oxide particle may be improved and surface residues may be reduced by the thio-based compound.

Abstract: A cathode active material for a lithium secondary battery according to an embodiment of the present invention includes a lithium metal oxide particle that contains tungsten and has a secondary shape in which a plurality of primary particles are aggregated. The lithium metal oxide particle includes a sulfur-containing portion formed between the primary particles in an inner region of the lithium metal oxide particle.