Publication number: 20200277491
Abstract: The invention relates to a flame-retardant polyamide composition containing: as component A) 1 to 96 wt. % of one or more thermoplastic polyamides; as component B) 2 to 25 wt. % of a diorganylphosphinic acid salt of formula (I), wherein R1 and R2 are the same or different and C1-C18 alkyl is linear, branched or cyclical, C6-C18 aryl, C7-C18 arylalkyl and/or C7-C18 alkylaryl; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; as component C) 2 to 20 wt. % of at least a further polymer component, selected from the classes of thermoplastic polyester and polyester elastomers; as component D) 0 to 20 wt. % of a salt of the phosphorous acid of general formula (II), [HP(?O)O2]2?Mm+??(II) in which M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K; as component E) 0 to 20 wt.
Type:
Application
Filed:
October 9, 2018
Publication date:
September 3, 2020
Applicant:
CLARIANT PLASTICS & COATINGS LTD
Inventors:
Sebastian HÖROLD, Elke SCHLOSSER, Eva-Maria LEUSCHNER
Publication number: 20190225773
Abstract: The invention relates to a novel flame retardant-stabilizer combination for thermoplastic polymers, comprising, as component A, from 25 to 99.9% by weight of a phosphinic acid salt of the formula (I) wherein R1, R2 are the same or different and are each C1-C18-alkyl, linear or branched, C6-C18-aryl, C7-C18-arylalkyl or C7-C18-alkylaryl, or R1 and R2 form one or more rings with each other, M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; as component B, from 0 to 75% by weight of a synergist or of a phosphorus/nitrogen flame retardant and, as component C, from 0.
Type:
Application
Filed:
September 6, 2017
Publication date:
July 25, 2019
Applicant:
CLARIANT PLASTICS & COATINGS LTD
Inventors:
Harald BAUER, Sebastian HÖROLD, Martin SICKEN
Publication number: 20190225772
Abstract: The invention relates to a novel flame retardant-stabilizer combination for thermoplastic polymers, comprising, as component A, from 25 to 99.9% by weight of a phosphinic acid salt of the formula (I) wherein R1, R2 are the same or different and are each C1-C8-alkyl, linear or branched, C6-C18-aryl, C7-C18-arylalkyl or C7-C18-alkylaryl, or R1 and R2 form one or more rings with each other, M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; as component B, from 0 to 75% by weight of a synergist or of a phosphorus/nitrogen flame retardant and, as component C, from 0.1 to 30% by weight of telomeric phosphinic acid salts as component D, from 0 to 20% by weight of organo phosphonic acid salt, as component E, from 0 to 5% by weight of phosphonic acid salt, the sum of the components always being 100% by weight, and wherein the angle of repose of said flame retardant-stabilizer combination is between 5° and 45°.
Type:
Application
Filed:
September 6, 2017
Publication date:
July 25, 2019
Applicant:
CLARIANT PLASTICS & COATINGS LTD
Inventors:
Harald BAUER, Sebastian HÖROLD, Martin SICKEN
Publication number: 20190153197
Abstract: A novel flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20 to 99% by weight of a dialkylphosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof in which R1, R2 are the same or different and are each C1-C6-alkyl, linear or branched; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C20-alkylarylene or C7-C20-arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component B 1 to 80% by weight of a salt of the phosphorous acid with the general formula (III) [HP(?O)O2]2?Mm+ (III) in which M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K and m is 1 to 4, as component C 0 to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus/nitrogen flame retardant, as component D 0 to 10% by weight of a zinc salt and/or of a basic or amphoteric oxide, hydroxide, carbo
Type:
Application
Filed:
November 15, 2018
Publication date:
May 23, 2019
Applicant:
CLARIANT INTERNATIONAL LTD
Inventors:
Werner KRAUSE, Harald BAUER, Martin SICKEN, Sebastian HÖROLD, Wolfgang WANZKE, Elke SCHLOSSER