Publication number: 20140128516
Abstract: A flame retardant-stabiliser combination for thermoplastic polymers, containing as component A: 50 to 90% by weight of a monoaryl phosphinic acid salt of the general formula (I), where R1 is an unsubstituted or substituted C6-C15 aryl group or a C7-C16 alkyl aryl group or a C7-C16 aryl alkyl group; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonized nitrogen base; as component B: 5 to 50 wt % of a nitrogen-containing synergist and/or a phosphorus/nitrogen flame retardant; as component C: 0 to 10 wt % of magnesium oxide, calcium oxide, zinc oxide, manganese oxide, tin oxide, aluminium hydroxide, boehmite, magnesium hydroxide, hydrotalcite, hydrocalumite, calcium hydroxide, zinc hydroxide, tin oxide hydrate, manganese hydroxide, zinc borate, zinc hydroxystannate and/or zinc stannate; as component D: 0 to 3 wt % of a mixture of a phosphonite or a phosphonite/phosphate mixture, and as component E: 0 to 3 wt % of an ester or salt of long-chain aliphatic carbonic acids having
Type:
Application
Filed:
February 14, 2012
Publication date:
May 8, 2014
Applicant:
CLARIANT FINANCE (BVI) LIMITED
Inventors:
Sebastian Hoerold, Harald Bauer
Publication number: 20130210975
Abstract: The invention relates to a novel flameproof agent stabiliser combination for thermoplastic and duroplastic polymers, containing, as component A 25 - 97.7 wt % of a dialkylphosphinic acid salt of formula (I) and/or a diphosphinic acid salt of formula (II) and/or polymers thereof, wherein R1, R2 are the same or different and represent C1-C6-alkyl, linear or branched and/or aryl; R3 represents C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C20-alkylarylene or C7-C20-arylalkylene; M represents Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m represents 1-4; n represents 1-4; x represents 1-4, as component B 2-45 wt. % of a monoalkylphosphinic acid salt of general formula (Ill), wherein R4 represents C1-C6-alkyl, linear or branched; M represents Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; representing, as component C 0.3 - 30 wt.
Type:
Application
Filed:
April 20, 2011
Publication date:
August 15, 2013
Applicant:
Clariant Finance (BVI) Limited
Inventors:
Sebastian Hoerold, Harald Bauer, Michael Hill
Publication number: 20130190432
Abstract: A novel flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20 to 99% by weight of a dialkylphosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof in which R1, R2 are the same or different and are each C1-C6-alkyl, linear or branched; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C20-alkylarylene or C7-C20-arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component B 1 to 80% by weight of a salt of the phosphorous acid with the general formula (III) [HP(?O)O2]2?Mm+ (III) in which M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K and m is 1 to 4, as component C 0 to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus/nitrogen flame retardant, as component D 0 to 10% by weight of a zinc salt and/or of a basic or amphoteric oxide, hydroxide, carbo
Type:
Application
Filed:
September 30, 2011
Publication date:
July 25, 2013
Applicant:
CLARIANT FINANCE (BVI) LIMITED
Inventors:
Werner Krause, Harald Bauer, Martin Sicken, Sebastian Hoerold, Wolfgang Wanzke, Elke Schlosser
Publication number: 20130131239
Abstract: The invention relates to a method for producing mixtures of alkylphosphonous acid and dialkylphosphinic acid salts, characterised in that a) a phosphinic acid source (I) is reacted with olefins (II) in the presence of a catalyst A to obtain a mixture of alkylphosphonous acid (III) and dialkylphosphinic acid (IV) or salts or esters thereof, and b) the thus obtained mixture of alkylphosphonous acid (III) and dialkylphosphinic acid (IV) or the salts or esters thereof is reacted with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base to obtain the corresponding mixtures of alkylphosphonous acid salt (V) and dialkylphosphinic acid salt (VI) of said metals and/or a nitrogen compound, (V) (VI), wherein Y represents Mg, Ca, AI, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na; K and/or a nitrogen compound and n represents ¼, ?, ½, 1.
Type:
Application
Filed:
April 20, 2011
Publication date:
May 23, 2013
Applicant:
CLARIANT FINANCE (BVI) LIMITED
Inventors:
Michael Hill, Sebastian Hoerold, Werner Krause, Martin Sicken
Publication number: 20130131235
Abstract: The invention relates to a flameproof agent stabiliser combination containing, as component A 40-99 wt. % of a phosphinic acid salt of formula (I) and/or a diphosphinic acid salt of formula (II) and/or polymers thereof, wherein R1, R2 are the same or different and represent C1-C18-alkyl linear, branched or cyclic, C6-C18-aryl, C7-C18-arylalkyl and/or C7-C18-alkylaryl; R3 represents C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C18-alkylarylene or C7-C18-arylalkylene; M represents Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protoned nitrogen base; m represents 1-4; n represents 1-4; x represents 1-4, as component B 1-60 wt. % of a phosphinic acid salt of general formula (III) wherein R4 represents C1-C18-alkyl linear, branched or cyclic, C6-C18-aryl, C7-C18-arylalkyl or C7-C18-alkylaryl and M represents Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base, as component C 0-50 wt.
Type:
Application
Filed:
April 20, 2011
Publication date:
May 23, 2013
Applicant:
CLARIANT FINANCE (BVI) LIMITED
Inventors:
Sebastian Hoerold, Harald Bauer
Publication number: 20110021676
Abstract: The invention relates to a process for producing flame-retardant, non-corrosive, highly flawable polyamides and polyesters, which comprises using a flame retardant mixture made of a phosphinic salt of the formula (I), where M?Al, Mg, Ca, Ti, or Na (component A) in which R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; n is from 1 to 3, and, as component B, a metal salt of an organic acid, and/or an inorganic zinc, calcium, magnesium, potassium, sodium, aluminum, titanium, tin, antimony, bismuth, or barium compound, where the amount of component A present in the flame retardant mixture is from 70 to 99.5% by weight and the amount of component B present in the flame retardant mixture is from 0.5 to 30% by weight.
Type:
Application
Filed:
February 25, 2009
Publication date:
January 27, 2011
Applicant:
Clariant Finance (BVI) Limited
Inventors:
Sebastian Hoerold, Ottmar Schacker, Harald Bauer, Werner Krause, Daniela Eisenhauer
Publication number: 20090088512
Abstract: The invention relates to flame-retardant compounded polyester materials, comprising as component A, from 40 to 64.9% by weight of thermoplastic polyester, as component B, from 5 to 10% by weight of polycarbonate, as component C, from 10 to 15% by weight of phosphinic salt of the formula (I) and/or diphosphinic salt of the formula (II), and/or polymers of these in which R1 and R2 are identical or different and are H or C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, or -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; and x is from 1 to 4, as component D, from 5 to 10% by weight of melamine polyphosphate, as component E, from 15 to 30% by weight of reinforcing materials, and, as component F, from 0.1 to 2% by weight of further additives, where the total of the components by weight is 100% by weight.
Type:
Application
Filed:
August 29, 2008
Publication date:
April 2, 2009
Inventors:
Elke Schlosser, Sebastian Hoerold, Ute Schwarz, Stefan Reinemann