Abstract: A pump share-type urea water supply system includes a first supply valve and a second supply valve. A urea water tank is connected with the respective supply valves by a urea water supply path that includes a first supply path for the first supply valve and a second supply path for the second supply valve. The second supply path has a larger capacity than the first supply path by a predetermined volume. A suck-back control controls opening and closing of the respective supply valves such that a first estimated valve-opening time of the first supply valve for suck-back control in the first supply valve and supply path is shorter than a second estimated valve-opening time of the second supply valve for suck-back control in the second supply valve and in-the-second supply path by at least a first control time corresponding to the predetermined volume.

Abstract: A control apparatus for an internal combustion engine having an exhaust gas purification device which is arranged in an exhaust passage and includes a NOx storage reduction (NSR) catalyst. The control apparatus, when the air fuel ratio of the air-fuel mixture is shifted from a lean air fuel ratio to the stoichiometric air fuel ratio, determines a predetermined NOx amount so as to be larger when the temperature detected by the first detection unit is high in comparison with when the detected temperature is low, and when the storage amount of NOx in the NSR catalyst is larger than the predetermined NOx amount, performs the rich spike processing and then controls the air fuel ratio to the stoichiometric air fuel ratio, whereas when otherwise, controls the air fuel ratio to the stoichiometric air fuel ratio without performing the rich spike processing.

Abstract: The NOx storage catalyst and the NOx selective reduction catalyst are arranged in the engine exhaust passage. In the engine low load operating region, a combustion is performed in the combustion chamber under a lean base air-fuel ratio and the air-fuel ratio in the combustion chamber is made rich when NOx should be released from the NOx storage catalyst. In the engine medium load operating region, the base air-fuel ratio is made smaller, a degree of richness of the air-fuel ratio is made smaller, and a period in which the air-fuel ratio is made rich is made shorter so that an amount of ammonia which is produced per unit time when the air-fuel ratio is made rich falls compared with the time of engine low load operation.

Abstract: A three way catalyst and an NOx storage catalyst are arranged in an engine exhaust passage. In an engine low load operating region, a combustion is performed under a lean air-fuel ratio, and when NOx should be released from the NOx storage catalyst, the air-fuel ratio in a combustion chamber is made rich. In an engine medium load operating region, the base air-fuel ratio is made lower as compared with the engine low load operating region, and the air-fuel ratio in the combustion chamber is made rich at a shorter period as compared with the engine low load operating region. When the operating state of the engine is switched from the engine low load operating region to the engine medium load operating region, the air-fuel ratio in the combustion chamber is temporarily made rich, and the degree of richness of the air-fuel ratio at this time is stepwise lowered.

Abstract: In an engine exhaust passage, in order from an exhaust upstream side, an NOx storage and reduction catalyst, NO oxidation catalyst, NO2 reduction catalyst, and selective reduction catalyst may be arranged. An air-fuel ratio of an exhaust gas which flows into the NOx storage and reduction catalyst may be temporarily switched to a rich air-fuel ratio which may be adapted for generating ammonia from NOx which may be stored in the NOx storage and reduction catalyst. The ammonia, which may be generated by the NOx storage and reduction catalyst, may be held at the selective reduction catalyst. The NOx which flows into the selective reduction catalyst may be reduced by the ammonia. The NO oxidation catalyst and NO2 reduction catalyst may be used to make an NO ratio of the exhaust gas which flows into the selective reduction catalyst approach an optimum ratio of the selective reduction catalyst.

Abstract: In order to suppress ammonia from flowing out during regeneration treatment of a filter carrying an SCR catalyst, the prevent invention provides an exhaust emission control system of an internal combustion engine, including a first stage catalyst having an oxidation function, a fuel supply device configured to supply fuel to the first stage catalyst, a filter provided in the exhaust passage downstream of the first stage catalyst and carrying a selective redaction type NOx catalyst, an ammonia supply device configured to supply ammonia to the filter, a filter-regeneration-treatment executing unit configured to execute filter regeneration treatment, and a control unit configured to supply, when the filter regeneration treatment is not executed, the ammonia in an amount corresponding to an amount of the NOx emitted from the internal combustion engine, and to supply, when the filter regeneration treatment is executed, the ammonia in an amount corresponding to an amount of the NOx obtained by subtracting, from the

Abstract: In an exhaust gas purification system for an internal combustion engine provided with a filter supporting an SCR catalyst, the present invention is intended to suppress HC and CO from being discharged to the outside at the time of the execution of filter regeneration processing, and to carry out the filter regeneration processing in an efficient manner. In the present invention, a post-catalyst having an oxidation function is arranged in an exhaust passage at the downstream side of the filter. Then, when the temperature of the post-catalyst is lower than a predetermined activation temperature at the time the execution of the filter regeneration processing is requested, the temperature of the post-catalyst is raised by carrying out control of raising the temperature of the exhaust gas discharged from the internal combustion engine, and control increasing the flow rate of the exhaust gas, before the execution of the filter regeneration processing.

Abstract: An object of the invention is to suppress deposition of ash in a wall-flow particulate filter while curtailing drops in a trapping rate of PM. To attain the above object, the invention provides a wall-flow particulate filter delimited by porous partition walls having pores of a size that allows ash and ash aggregates to pass therethrough. In the filter, a coat layer having pores smaller than the pores of the partition walls is provided, at a region of the partition walls, from an upstream end thereof up to a position before a downstream end thereof.

Abstract: A particulate filter arranged in an engine exhaust passage is provided with alternately arranged exhaust gas inflow and outflow passages and porous partition walls which separate these passages from each other. In each partition wall, a coated zone where a coated layer with an average pore size smaller than that of a partition wall substrate is used to cover the substrate surface and a non-coated zone downstream of the coated zone where the substrate surface is not covered by said coated layer, are defined, and the ash in the exhaust gas can pass through the partition wall in the non-coated zone. Judgment processing which judges if a particulate matter trapping rate of the particulate filter has fallen below an allowable lower limit value is performed. PM removal processing is performed when it is judged that the particulate matter trapping rate has fallen below the allowable lower limit value.

Abstract: To estimate an amount of reducing agent adsorbed to a selective reduction type NOx catalyst with a higher degree of precision, an amount of variation over a predetermined time in a reducing agent amount adsorbed to a selective reduction type NOx catalyst is calculated from an upper limit value of a reducing agent amount that is adsorbed to the selective reduction type NOx catalyst when the reducing agent is supplied continuously by a supply unit, which is calculated on the basis of a temperature of the selective reduction type NOx catalyst, and the reducing agent amount adsorbed to the selective reduction type NOx catalyst, whereupon a reducing agent amount adsorbed to the selective reduction type NOx catalyst following the elapse of the predetermined time is estimated by adding the variation amount to the reducing agent amount adsorbed to the selective reduction type NOx catalyst.

Abstract: A hydrogen storage alloy is provided which has an extremely low Co content, and can maintain the drain (power) performance (especially pulse discharge characteristics), activity (degree of activity), and life performance at high levels. The hydrogen storage alloy is manufactured by weighing and mixing every material for the hydrogen storage alloy so as to provide an alloy composition represented by the general formula MmNiaMnbAlcCod or MmNiaMnbAlcCodFee, and controlling the manufacturing method and manufacturing conditions so that both the a-axis length and the c-axis length of the crystal lattice are in a predetermined range. Although it is sufficient if the a-axis length of the crystal lattice is 499 pm or more and the c-axis length is 405 pm or more, by further specifying the a-axis length and c-axis length depending on the values of ABx, a hydrogen storage alloy having high durability can be provided.

Abstract: An object is to suppress the occurrence of a failure in supply of urea water as much as possible in filling control of urea water in a pump share-type urea water supply system with two supply valves. In the pump share-type urea water supply system with a first supply valve and a second supply valve, a urea water tank is connected with the respective supply valves by a urea water supply path. The urea water supply path includes a first supply path for the first supply valve and a second supply path for the second supply valve. The second supply path has a larger capacity than the capacity of the first supply path by a predetermined volume.

Abstract: An object is to suppress the occurrence of a failure in supply of urea water as much as possible in suck-back control of urea water in a pump share-type urea water supply system with two supply valves. In the pump share-type urea water supply system with a first supply valve and a second supply valve, a urea water tank is connected with the respective supply valves by a urea water supply path. The urea water supply path includes a first supply path for the first supply valve and a second supply path for the second supply valve. The second supply path has a larger capacity than the capacity of the first supply path by a predetermined volume.

Abstract: A three way catalyst and an NOx storage catalyst are arranged in an engine exhaust passage. In an engine low load operating region, a combustion is performed under a lean air-fuel ratio, and when NOx should be released from the NOx storage catalyst, the air-fuel ratio in a combustion chamber is made rich. In an engine medium load operating region, the base air-fuel ratio is made lower as compared with the engine low load operating region, and the air-fuel ratio in the combustion chamber is made rich at a shorter period as compared with the engine low load operating region. When the operating state of the engine is switched from the engine low load operating region to the engine medium load operating region, the air-fuel ratio in the combustion chamber is temporarily made rich, and the degree of richness of the air-fuel ratio at this time is stepwise lowered.

Abstract: An object of the present invention is to suppress a reduction in a NOx purification ratio accompanying filter regeneration processing in an exhaust gas purification system for an internal combustion engine that includes a filter carrying an SCR catalyst. In the present invention, the temperature of the filter is increased following completion of the filter regeneration processing by increasing the temperature of exhaust gas discharged from the internal combustion engine, and in so doing, HC adhered to the filter is removed.

Abstract: In order to suppress ammonia from flowing out during regeneration treatment of a filter carrying an SCR catalyst, the prevent invention provides an exhaust emission control system, of an internal combustion engine, including a first stage catalyst having an oxidation function, a fuel supply device configured to supply fuel to the first stage catalyst, a filter provided in the exhaust passage downstream of the first stage catalyst and carrying a selective redaction type NOx catalyst, an ammonia supply device configured to supply ammonia to the filter, a filter-regeneration-treatment executing unit configured to execute filter regeneration treatment, and a control unit configured to supply, when the filter regeneration treatment is not executed, the ammonia in an amount corresponding to an amount of the NOx emitted from the internal combustion engine, and to supply, when the filter regeneration treatment is executed, the ammonia in an amount corresponding to an amount of the NOx obtained by subtracting, from th

Abstract: In an exhaust gas purification system for an internal combustion engine provided with a filter supporting an SCR catalyst, the present invention is intended to suppress HC and CO from being discharged to the outside at the time of the execution of filter regeneration processing, and to carry out the filter regeneration processing in an efficient manner. In the present invention, a post-catalyst having an oxidation function is arranged in an exhaust passage at the downstream side of the filter. Then, when the temperature of the post-catalyst is lower than a predetermined activation temperature at the time the execution of the filter regeneration processing is requested, the temperature of the post-catalyst is raised by carrying out control of raising the temperature of the exhaust gas discharged from the internal combustion engine, and control increasing the flow rate of the exhaust gas, before the execution of the filter regeneration processing.

Abstract: An object of the present invention is to appropriately remove, from an exhaust gas, HC, CO, and ammonia flowing out from a filter (SCRF) on which an SCR catalyst is carried. In the present invention, a post-catalyst 8 is provided for an exhaust gas passage of an internal combustion engine on a downstream side from SCRF along with a flow of the exhaust gas. The post-catalyst 8 is constructed to include an adsorption reduction part 81c which adsorbs ammonia and which reduces NOx by using ammonia as a reducing agent, a first oxidation part 81b which oxidizes ammonia, and a second oxidation part 82 which oxidizes HO and CO.

Abstract: An object of the present invention is to suppress HC, CO, and NOx from being discharged to the outside when a filter regeneration process is executed in an exhaust gas purification system for an internal combustion engine provided with a filter including an SCR catalyst carried thereon. In the present invention, a post-catalyst is provided for an exhaust gas passage disposed on a downstream side from the filter. The post-catalyst has an oxidizing function, and the post-catalyst has such a function that the production of N2 based on the oxidation of ammonia is facilitated in a predetermined first temperature area. Further, when the filter regeneration process is executed, the temperature of the post-catalyst is adjusted to be in the first temperature area while adjusting the temperature of the filter to be in a predetermined second temperature area lower than a filter regeneration temperature during a certain period of time.

Abstract: Disclosed is copper powder having an average primary particle size D of 0.15 to 0.6 ?m, having a ratio of D to DBET, D/DBET, of 0.8 to 4.0 wherein DBET is a sphere-equivalent average particle diameter calculated from a BET specific surface area, and having no layer for preventing agglomeration on the surface thereof. The copper powder is suitably produced by a method which includes a step of mixing (1) hydrazine and (2) a reactant mixture including a monovalent or divalent copper source and a liquid medium which includes water and an organic solvent having water miscibility and capable of reducing the surface tension of water, to reduce the copper source to form copper particles.