Patents by Inventor Shigenobu Kawakami

Shigenobu Kawakami has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4967028
    Abstract: The present invention relates to an improved electrical insulating oil composition which has excellent electrical characteristics and is suitable for use in impregnating electrical appliances in which plastic dielectric material is used, and further relates to electrical appliances impregnated with such a composition. The electrical insulating oil composition is produced by bringing a by-product oil fraction mainly containing components having boiling points in the range of 260.degree. to 330.degree. C. (atmospheric pressure basis) into liquid-liquid contact with an organic polar solvent; said by-product oil fraction being formed by alkylating benene or toluene with ethylene in the presence of an alkylation catalyst and then distilling the alkylation product; and said electrical insulating oil composition being characterized in that the ratio of the integrated intensity as chemical shift at 120 to 155 ppm of the spectrum measured by .sup.
    Type: Grant
    Filed: May 6, 1988
    Date of Patent: October 30, 1990
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Atsushi Sato, Shigenobu Kawakami, Keiji Endo, Hideyuki Dohi
  • Patent number: 4902841
    Abstract: A method for producing an electrical insulating oil composition composed of benzyltoluene and ditolymethane. The composition is excellent in low-temperature characteristics and contains substantially no chlorine. The method comprises the steps of reacting monocyclic aromatic hydrocarbon with diarylmethane which has been prepared without using a chlorinated hydrocarbon as a starting material, at a temperature of -10.degree. to 550.degree. C. in the presence of a disperoportionation catalyst to prepare a reaction product containing benzyltoluene and ditolylmethane, and recovering benzyltoluene and ditolylmethane from said reaction product by distillation.
    Type: Grant
    Filed: March 8, 1988
    Date of Patent: February 20, 1990
    Assignee: Nippon Petrochemicals Company, Ltd.
    Inventors: Shigenobu Kawakami, Keiji Endo, Hideyuki Dohi, Atsushi Sato
  • Patent number: 4899009
    Abstract: A method for producing m-benzyltoluene with a high yield and excellent selectivity without producing undesirable heavier by-products. The method is characterized in that toluene and diphenylmethane are allowed to react at a reaction temperature in the range of 170.degree. to 400.degree. C. in the presence of a crystalline synthetic zeolite catalyst in which the molar ratio of SiO.sub.2 /Al.sub.2 O.sub.3 is 20 or higher and the openings of main pores are formed by ten-membered oxygen rings.
    Type: Grant
    Filed: June 9, 1989
    Date of Patent: February 6, 1990
    Assignee: Nippon Petrochemicals Co. Ltd.
    Inventors: Shigenobu Kawakami, Keiji Endo, Hideyuki Dohi, Atsushi Sato
  • Patent number: 4870221
    Abstract: An improved oil-filled capacitor which is excellent in low temperature characteristics. The oil-filled capacitor is composed of at least partially a plastics material and is impregnated with an electrical insulating oil which oil is characterized in that it comprises 0 to 100% by weight of a fraction A containing components boiling within the range of 268.degree. to 275.degree. C. (atmospheric pressure basis) and 100 to 0% by weight of a fraction B containing components boiling within the range of 280.degree. to 310.degree. C. (atmospheric pressure basis) which fractions are recovered by distillation from the heavy by-product oil that is produced in the preparation of ethylbenzene by alkylating benzene with ethylene in the presence of an alkylation catalyst and the ratio of the integrated intensity as chemical shift at 120 to 155 ppm of the spectrum measured by C.sup.
    Type: Grant
    Filed: September 16, 1987
    Date of Patent: September 26, 1989
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Atsushi Sato, Shigenobu Kawakami, Keiji Endo, Hideyuki Dohi
  • Patent number: 4804729
    Abstract: The present invention provides an electrical insulating material which comprises an ethylene copolymer prepared by subjecting, to a high-pressure radical polymerization, ethylene or a mixture of ethylene and at most 3 mol % of another monomer in the presence of one- to three-ring aromatic compound having at least two carbon-carbon double bonds, which are different from each other in reactivity in radical polymerization, in one molecule at a polymerization pressure of 500 to 4,000 kg/cm.sup.2 at a polymerization temperature of 50.degree. to 400.degree. C., with the ethylene copolymer containing 0.005 to 1 mol % of a unit derived from the aromatic compound.
    Type: Grant
    Filed: July 6, 1987
    Date of Patent: February 14, 1989
    Assignee: Nippon Petrochemicals, Co., Ltd.
    Inventors: Yuichi Orikasa, Shinji Kojima, Takashi Inoue, Atsushi Sato, Shigenobu Kawakami, Kaoru Yamamoto
  • Patent number: 4803238
    Abstract: A compounding oil for polymers which can be used as a plasticizer, process oil, thinner, softening agent, extender or the like. The compounding oil of the invention comprises a fraction mainly containing triaryldialkanes and having boiling points in the range of 350.degree. to 450.degree. C., which fraction is prepared by disproportionating a by-product oil fraction at temperatures in the range of 20.degree. to 500.degree. C. in the presence of a disproportionation catalyst, said by-product oil fraction mainly containing diarylalkanes, having boiling points in the range of 260.degree. to 320.degree. C., and being obtained from the process to prepare alkylated monocyclic aromatic hydrocarbons by alkylating monocyclic aromatic hydrocarbons with olefins in the presence of an alkylation catalyst.
    Type: Grant
    Filed: October 29, 1987
    Date of Patent: February 7, 1989
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Atsushi Sato, Keiji Endo, Shigenobu Kawakami, Eiichi Matsuzaka, Satoshi Narui
  • Patent number: 4802058
    Abstract: The present invention relates to a method for refining an electrical insulating oil by refining a heavy by-product oil obtained in the preparation of ethylbenzene or ethyltoluene. The method comprises distilling off the lighter components from the by-product oil, then dehydrogenating, distilling and hydrogenating.
    Type: Grant
    Filed: March 9, 1988
    Date of Patent: January 31, 1989
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Shigenobu Kawakami, Keiji Endo, Hideyuki Dohi, Atsushi Sato
  • Patent number: 4761508
    Abstract: The present invention is concerned with a novel intermediate 1,1-(3-ethylphenyl)phenylethylene represented by the formula (I) and its manufacturing method, and according to the present invention, Ketoprofen can be synthesized at a low cost and in a high yield.
    Type: Grant
    Filed: July 22, 1986
    Date of Patent: August 2, 1988
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Isoo Shimizu, Yasuo Matsumura, Shigenobu Kawakami, Atsushi Sato
  • Patent number: 4750083
    Abstract: An electrical insulating oil composition which is excellent in low temperature characteristics and suitable for use in impregnating capacitors, and comprises (a) m-ethylbiphenyl, (b) p-ethylbiphenyl, (c) m-isopropylbiphenyl and (d) p-isopropylbiphenyl, and is characterized in that the total amount of the ethylbiphenyls is not less than 40% by weight and the proportion of solid phase in the composition at a temperature of -40.degree. C. is not more than 45% by weight, the solid quantity of each component being calculated according to the following equation of solid-liquid equilibrium: ##EQU1## wherein X.sub.1 is the equilibrium mole fraction of a component i in the liquid phase of the composition, .DELTA.H.sub.i.sup.f is the heat of fushion (cal.mol.sup.-1) of the component i, T.sub.i.sup.f is the melting point (K) of the component i, T is the temperature (K) of the system, and R is the gas constant (cal.mol.sup.-1.K.sup.-1).
    Type: Grant
    Filed: September 4, 1987
    Date of Patent: June 7, 1988
    Assignee: Nippon Petrochemicals Company, Ltd.
    Inventors: Atsushi Sato, Shigenobu Kawakami, Keiji Endo, Hideyuki Dohi
  • Patent number: 4748209
    Abstract: The present invention provides a method for improving impulse destructive strength of an electrical insulating material which is characterized by employing, as the electrical insulating material, a random copolymer of a styrene series monomer and ethylene or a combination of ethylene and another ethylenic unsaturated monomer, or a composition in which the copolymer is blended with an ethylene series polymer, the copolymer being prepared by introducing, into a reaction system, the styrene series monomer selected from the group of styrene and single-ring substituted styrenes, ethylene or the combination of ethylene and the ethylenic unsaturated monomer and a polymerization initiator, the latter being introduced thereinto separately from at least the styrene series monomer, and subjecting these monomers to a high-pressure radical copolymerization under a polymerization pressure of 500 to 4,000 kg/cm.sup.2 at a polymerization temperature of 50.degree. to 400.degree. C.
    Type: Grant
    Filed: June 8, 1987
    Date of Patent: May 31, 1988
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Yuichi Orikasa, Shinji Kojima, Takashi Inoue, Kaoru Yamamoto, Atsushi Sato, Shigenobu Kawakami
  • Patent number: 4736007
    Abstract: A novel ethylene copolymer useful for electric insulating materials is obtained by a high-pressure radical polymerization at a pressure of 500 to 4,000 kg/cm.sup.2 at a temperature of 130.degree. to 400.degree. C. and which comprises 95.0 to 99.995 mol % of an ethylene unit, 0.005 to 2 mol % of a comonomer unit represented by the formula (I) ##STR1## wherein Ar is ##STR2## R.sub.1 is an alkylene group having 1 or 2 carbon atoms, each of R.sub.2 and R.sub.3 is a hydrogen atom, or a straight-chain or a side-chain alkyl group having 1 to 4 carbon atoms, and 0 to 3 mol % of an ethylenic unsaturated monomer unit, said ethylene copolymer having a density of 0.910 to 0.940 g/cm.sup.3 and a melt index of 0.05 to 100 g/10 minutes.
    Type: Grant
    Filed: November 28, 1986
    Date of Patent: April 5, 1988
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Yuichi Orikasa, Shinji Kojima, Takashi Inoue, Kaoru Yamamoto, Atsushi Sato, Shigenobu Kawakami
  • Patent number: 4734824
    Abstract: An electrical insulating oil which is suitable for use in impregnating electrical appliances such as capacitors, cables and transformers, especially those in which plastic materials are used partially or totally as dielectrics or insulating materials, and electrical appliances that are impregnated with the above electrical insulating oil. The electrical insulating oil of the invention contains at least one monoolefin and/or diolefin having three condensed or non-condensed aromatic rings.
    Type: Grant
    Filed: June 23, 1986
    Date of Patent: March 29, 1988
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Atsushi Sato, Keiji Endo, Shigenobu Kawakami, Hitoshi Yanagishita, Shozo Hayashi
  • Patent number: 4731483
    Abstract: The present invention provides a method for preparing 3-ethylbenzophenone in a high purity which comprises the steps of alkylating benzene with ethylene with the aid of an alkylating catalyst to obtain an alkylated product composed mainly of unreacted benzene, ethylbenzene, polyethylbenzenes and heavier by-products; subjecting the alkylated product to distillation in order to recover therefrom a fraction which has a temperature range of boiling points within the range of 275.degree. to 310.degree. C. (in terms of atmospheric pressure); dehydrogenating the recovered fraction at a reaction temperature within the range of 200.degree. to 700.degree. C.
    Type: Grant
    Filed: September 8, 1986
    Date of Patent: March 15, 1988
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Isoo Shimizu, Yasuo Matsumura, Shigenobu Kawakami, Atsushi Sato
  • Patent number: 4717759
    Abstract: The present invention provides an ethylene copolymer comprising 85.0 to 99.995 mol % of an ethylene unit, 0.005 to 5 mol % of a comonomer unit represented by the formula (I) ##STR1## wherein Ar is ##STR2## R.sub.1 is a hydrogen atom or a methyl group, each of R.sub.2 and R.sub.3 is a hydrogen atom, a chlorine atom or a straight-chain or a side-chain alkyl group having 1 to 4 carbon atoms, and 0 to 10 mol % of an ethylenic unsaturated monomer unit, the ethylene copolymer having a density of 0.860 to 0.970 g/cm.sup.3 and a melt index of 0.05 to 100 g/10 minutes.
    Type: Grant
    Filed: November 4, 1985
    Date of Patent: January 5, 1988
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Yuichi Orikasa, Shinji Kojima, Takashi Inoue, Kaoru Yamamoto, Atsushi Sato, Shigenobu Kawakami
  • Patent number: 4716084
    Abstract: An oil-impregnated capacitor made by winding at least one plastic film impregnated with an electrical insulating oil comprising 1-phenyl-1-methylphenylethane in which 1-phenyl-1-(4-methylphenyl)ethane and 1-phenyl-1-(2-methyl)ethane are present in amounts of not less than 70 percent and not more than 15 percent, respectively, based on the total weight of the 1-phenyl-1-methylphenylethane.
    Type: Grant
    Filed: April 18, 1986
    Date of Patent: December 29, 1987
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Atsushi Sato, Shigenobu Kawakami, Keiji Endo, Hideyuki Dohi
  • Patent number: 4681980
    Abstract: A novel method for improving electrical insulating hydrocarbon. The electrical insulating substance is obtained by dehydrogenating aromatic hydrocarbons having two aromatic nuclei. The electrical insulating substance itself or a mixture of it with other electrical insulating oils is suitable for use in impregnation of electrical appliances.
    Type: Grant
    Filed: November 6, 1985
    Date of Patent: July 21, 1987
    Assignee: Nippon Petrochemicals Company Limited
    Inventors: Atsushi Sato, Keiji Endo, Shigenobu Kawakami, Hitoshi Yanagishita, Shozo Hayashi
  • Patent number: 4670348
    Abstract: An electrical appliance impregnated with a curable impregnant composition comprising as the curable ingredient at least one aromatic olefin and/or diolefin having a plurality of condensed- or noncondensed-type aromatic rings.
    Type: Grant
    Filed: December 31, 1984
    Date of Patent: June 2, 1987
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Atsushi Sato, Keiji Endo, Hideyuki Dohi, Shigenobu Kawakami
  • Patent number: 4661165
    Abstract: A solvent for the dye of pressure-sensitive recording paper which solvent has no offensive odor and both the color developing rate and the density of developed color are excellent. The solvent is characterized in that it comprises a fraction having boiling points in the range of 270.degree. to 350.degree. C. which is prepared by distilling the heavier products obtained from the process for producing ethyltoluene by alkylating toluene with ethylene in the presence of synthetic zeolite catalyst.
    Type: Grant
    Filed: June 18, 1985
    Date of Patent: April 28, 1987
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Shigenobu Kawakami, Eiichi Matsuzaka, Satoshi Narui, Naoya Takahashi
  • Patent number: 4642730
    Abstract: An improved electrical insulating oil and oil-filled electrical appliances impregnated therewith. The electrical insulating oil can be produced inexpensively but has excellent electrical characteristics and it comprises a fraction having boiling points in the range of 350.degree. to 450.degree. C. that is prepared by disproportionating diarylalkane or a hydrocarbon mixture mainly containing the same at temperatures in the range of 20.degree. to 500.degree. C. in the presence of a disproportionation catalyst, said diarylalkane having boiling points in the range of 260.degree. to 320.degree. C.
    Type: Grant
    Filed: July 30, 1985
    Date of Patent: February 10, 1987
    Assignee: Nippon Petrochemicals Company, Ltd.
    Inventors: Atsushi Sato, Keiji Endo, Shigenobu Kawakami, Eiichi Matsuzaka, Satoshi Narui
  • Patent number: 4639833
    Abstract: An improved electrical insulating oil and oil-filled electrical appliances impregnated therewith. The electrical insulating oil has a low viscosity, low pour point and other excellent electrical characteristics and it comprises an isomer mixture of dibenzylbenzenes in which the quantity of p-dibenzylbenzene is not more that 10% by weight and the weight ratio of m-dibenzylbenzene/o-dibenzylbenzene is not lower than 3.
    Type: Grant
    Filed: August 12, 1985
    Date of Patent: January 27, 1987
    Assignee: Nippon Petrochemicals Company, Ltd.
    Inventors: Atsushi Sato, Keiji Endo, Shigenobu Kawakami, Hideyuki Dohi