Patents by Inventor Shigeru Hayashida

Shigeru Hayashida has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5534375
    Abstract: A charge transport layer formed from a composition comprising a mixed solvent containing alkoxybenzene and a charge transport material, or a photoconductive layer formed from a composition comprising alkoxybenzene and an organic photoconductive material are effective for producing electrophotographic members excellent in image without damaging the circumstances as well as stable in maintaining good charging characteristics and dark decay characteristics after repeated use.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: July 9, 1996
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Susumu Kaneko, Kouji Ohkoshi, Keiichi Endo, Seiji Miyaoka, Megumi Matsui, Shigeru Hayashida, Takayuki Akimoto, Mikio Itagaki
  • Patent number: 5496672
    Abstract: Disclosed are a coating solution for forming a charge generation layer, which comprises:(A) a phthalocyanine composition,(B) a binder resin represented by the formula: ##STR1## wherein R represents an alkylene group, R.sup.1 represents an alkyl group; and m, n and k each represent a ratio of recurring unit numbers and are numerals satisfying the relations of k+m+n=1, n>m>0 and 0.3.gtoreq.k.gtoreq.0,(C) at least one of a melamine resin and a benzoguanamine resin in a 1- to 5-fold amount in terms of the weight ratio of the amount of the binder resin, and(D) a solvent having both a hydroxyl group and an ether group in one molecule,and an electrophotographic photoreceptor using the same.
    Type: Grant
    Filed: May 10, 1994
    Date of Patent: March 5, 1996
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Takayuki Akimoto, Shigeru Hayashida, Megumi Matsui, Mikio Itagaki
  • Patent number: 5494767
    Abstract: Disclosed are a phthalocyanine composition which comprises having main diffraction peaks at 7.5.degree., 22.5.degree., 24.3.degree., 25.3.degree. and 28.6.degree. of Bragg angles (2.theta..+-.0.2.degree.) in an X-ray diffraction spectrum with Cu K.alpha., a process for preparing the same, an electrophotographic photoreceptor using the same and a coating solution for a charge generation layer containing the same.
    Type: Grant
    Filed: January 25, 1994
    Date of Patent: February 27, 1996
    Assignee: Hitachi Chemical Company Co., Ltd.
    Inventors: Mikio Itagaki, Shigeru Hayashida, Megumi Matsui, Hiroko Ishikawa, Yoshii Morishita, Takayuki Akimoto
  • Patent number: 5484685
    Abstract: A naphthalocyanine derivative of the formula: ##STR1## wherein M, Y, R.sup.1, k, l, m, n are as defined in the specification, is an effective substance for forming a recording layer on a substrate of an optical recording medium having high sensitivity with good properties.
    Type: Grant
    Filed: May 30, 1991
    Date of Patent: January 16, 1996
    Assignees: Hitachi, Ltd., Hitachi Chemical Co., Ltd.
    Inventors: Seiji Tai, Nobuyuki Hayashi, Koichi Kamijima, Mitsuo Katayose, Takayuki Akimoto, Shigeru Hayashida, Hideo Hagiwara, Susumu Era, Setsuo Kobayashi, Akio Mukoh
  • Patent number: 5449581
    Abstract: Disclosed are a phthalocyanine composition which comprises having main diffraction peaks at 7.5.degree., 24.2.degree. and 27.3.degree. of Bragg angles (2.theta..+-.0.2.degree.) in an X-ray diffraction spectrum with Cu K.alpha., a process for preparing the same, an electrophotographic photoreceptor using the same and a coating solution for forming a charge generation layer containing the same.
    Type: Grant
    Filed: December 28, 1993
    Date of Patent: September 12, 1995
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Megumi Matsui, Shigeru Hayashida, Takayuki Akimoto, Mikio Itagaki
  • Patent number: 5428152
    Abstract: Disclosed are naphthalocyanine compounds having siloxy groups bonded to a central metal silicon. The compounds can be used as a charge generating substance of an electrophotographic plate having high sensitivity to the longer wavelength light of about 800 nm without conducting a special treatment. The naphthalocyanine compounds are represented by the formula: ##STR1## wherein L is a group of the formula R.sub.1 R.sub.2 R.sub.3 SiO--, and R.sub.1, R.sub.2 and R.sub.3 are each a same alkyl group having 1-3 carbon atoms.
    Type: Grant
    Filed: June 10, 1993
    Date of Patent: June 27, 1995
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Shigeru Hayashida, Seiji Tai
  • Patent number: 5403958
    Abstract: Disclosed is an electrophotographic member containing as a charge transport material a fluorine-containing N,N,N',N'-tetraarylbenzidine derivative which is remarkably excellent in solubility in an organic solvent and/or a binder such as polycarbonate resin, etc., can show very excellent electrophotographic properties such as high sensitivity, low residual potential and high durability. Further, a fluorine-containing N,N,N',N'-tetraarylbenzidine derivative usable as a charge transport material, and a process for producing the same are disclosed. Furthermore, a fluorine-containing diarylamine usable for producing the fluorine-containing N,N,N',N'-tetraarylbenzidine derivative, and a process for producing the same are disclosed.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: April 4, 1995
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Yoshii Morishita, Yasushi Sugimoto, Shigeru Hayashida, Hiroko Ishikawa, Yoshiaki Noda, Shigeru Murakami, Munehiro Sato, Yoshinori Saito, Naoji Kurata, Yoshio Sugita
  • Patent number: 5382687
    Abstract: An enamine derivative containing a fluoroalkyl group, a fluoroaryl group or a fluoroaralkyl group is effective as a charge transport material in an electrophotographic member excellent in sensitivity, residual potential, durability and the like electrophotographic properties.
    Type: Grant
    Filed: August 2, 1993
    Date of Patent: January 17, 1995
    Assignee: Hitachi Chemical Company Ltd.
    Inventors: Yoshii Morishita, Shigeru Hayashida, Yasushi Sugimoto, Hiroko Ishikawa, Hiroshi Kobayashi, Takaaki Sonoda
  • Patent number: 5352834
    Abstract: Disclosed is an electrophotographic member containing as a charge transport material a fluorine-containing N,N,N',N'-tetraarylbenzidine derivative which is remarkably excellent in solubility in an organic solvent and/or a binder such as polycarbonate resin, etc., can show very excellent electrophotographic properties such as high sensitivity, low residual potential and high durability. Further, a fluorine-containing N,N,N',N'-tetraarylbenzidine derivative usable as a charge transport material, and a process for producing the same are disclosed. Furthermore, a fluorine-containing diarylamine usable for producing the fluorine-containing N,N,N',N'-tetraarylbenzidine derivative, and a process for producing the same are disclosed.
    Type: Grant
    Filed: June 8, 1992
    Date of Patent: October 4, 1994
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Yoshii Morishita, Yasushi Sugimoto, Shigeru Hayashida, Hiroko Ishikawa, Yoshiaki Noda, Shigeru Murakami, Munehiro Sato, Yoshinori Saito, Naoji Kurata, Yoshio Sugita
  • Patent number: 5304445
    Abstract: Disclosed are a phthalocyanine composition which comprises having main diffraction peaks at 7.5.degree., 22.5.degree., 24.3.degree., 25.3.degree. and 28.6.degree. of Bragg angles (2.theta..+-.0.2.degree.) in an X-ray diffraction spectrum with Cu K.alpha., a process for preparing the same, an electrophotographic photoreceptor using the same and a coating solution for a charge generation layer containing the same.
    Type: Grant
    Filed: February 10, 1993
    Date of Patent: April 19, 1994
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Mikio Itagaki, Shigeru Hayashida, Megumi Matsui, Hiroko Ishikawa, Yoshii Morishita, Takayuki Akimoto
  • Patent number: 5272030
    Abstract: An enamine derivative containing a fluoroalkyl group, a fluoroaryl group or a fluoroaralkyl group is effective as a charge transport material in an electrophotographic member excellent in sensitivity, residual potential, durability and the like electrophotographic properties.
    Type: Grant
    Filed: March 20, 1991
    Date of Patent: December 21, 1993
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Yoshii Morishita, Shigeru Hayashida, Yasushi Sugimoto, Hiroko Ishikawa, Hiroshi Kobayashi, Takaaki Sonoda
  • Patent number: 5233089
    Abstract: A novel enamine derivative is effective as a charge transport material and can provide an electrophotographic plate excellent in sensitivity, photoresponse and durability.
    Type: Grant
    Filed: December 30, 1987
    Date of Patent: August 3, 1993
    Assignee: Hitachi, Ltd.
    Inventors: Yasuo Katsuya, Takayuki Akimoto, Yoshii Morishita, Yasushi Shinbo, Akira Kageyama, Shigeru Hayashida
  • Patent number: 5219706
    Abstract: There are disclosed a novel naphthalocyanine derivative represented by the general formula [I] or [II] shown below, a process for preparing said derivative, an optical information recording medium using said derivative, and a process for preparing thereof: ##STR1## wherein M is a metal, metal oxide, metal hydroxide and the like, R.sup.1 is an alkyl group of 1-22 carbon atoms, n is an integer of 1 to 4, and Y.sub.1 and Y.sub.2 aryloxy group and the like.
    Type: Grant
    Filed: January 21, 1992
    Date of Patent: June 15, 1993
    Assignee: Hitachi, Ltd.
    Inventors: Seiji Tai, Shigeru Hayashida, Nobuyuki Hayashi, Yasushi Iwakabe, Shunichi Numata, Noriyuki Kinjo, Susumu Era, Setsuo Kobayashi, Akio Mukoh, Yoshio Sato
  • Patent number: 5214188
    Abstract: 2,3-dicyanonaphthalene derivatives useful in the synthesis of naphthalocyanine derivatives are disclosed. The 2,3-dicyanonaphthalene derivatives have the formula: ##STR1## wherein each R.sup.1 may be the same or different and represents an alkyl group, substituted alkyl group, or aryl group; and n is an integer from 1 to 4.
    Type: Grant
    Filed: May 2, 1991
    Date of Patent: May 25, 1993
    Assignees: Hitachi, Ltd., Hitachi Chemical Company, Ltd.
    Inventors: Seiji Tai, Shigeru Hayashida, Nobuyuki Hayashi, Hideo Hagiwara, Mitsuo Katayose, Koichi Kamijima, Takayuki Akimoto, Susumu Era, Setsuo Kobayashi, Akio Mukoh
  • Patent number: 5188922
    Abstract: The present invention relates to an optical recording medium laminated having on a substrate a recording layer comprising an organic thin film containing a silicon naphthalocyanine compound represented by the following general formula (I): ##STR1## wherein L and L' each represents a group capable of linking to silicon.
    Type: Grant
    Filed: May 17, 1991
    Date of Patent: February 23, 1993
    Assignees: Hitachi Chemical Company, Ltd., Hitachi, Ltd.
    Inventors: Shigeru Hayashida, Seiji Tai
  • Patent number: 5160487
    Abstract: Disclosed is an electrophotographic member containing as a charge transport material a fluorine-containing N,N,N',N'-tetraarylbenzidine derivative which is remarkably excellent in solubility in an organic solvent and/or a binder such as polycarbonate resin, etc., can show very excellent electrophotographic properties such as high sensitivity, low residual potential and high durability. Further, a fluorine-containing N,N,N',N'-tetraarylbenzidine derivative usable as a charge transport material, and a process for producing the same are disclosed. Furthermore, a fluorine-containing diarylamine usable for producing the fluorine-containing N,N,N',N'-tetraarylbenzidine derivative, and a process for producing the same are disclosed.
    Type: Grant
    Filed: September 4, 1991
    Date of Patent: November 3, 1992
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Yoshii Morishita, Yasushi Sugimoto, Shigeru Hayashida, Hiroko Ishikawa, Yoshiaki Noda, Shigeru Murakami, Munehiro Sato, Yoshinori Saito, Naoji Kurata, Yoshio Sugita
  • Patent number: 5081236
    Abstract: An electrophotographic plate comprising an electroconductive support and a photoconductive layer containing a naphthalocyanine compound having siloxy groups bonded to the central metal silicon as a charge generating substance has high sensitivity to the longer wavelength light of about 800 nm without conducting a special treatment.The naphthalocyanine compound having siloxy groups bonded to the central metal silicon has the following formula: ##STR1## wherein L is a group of the formula: R.sub.1 R.sub.2 R.sub.3 Si--O--; and R.sub.1, R.sub.2 and R.sub.3 are independently hydrogen, an alkyl group or an alkoxy group.
    Type: Grant
    Filed: May 3, 1989
    Date of Patent: January 14, 1992
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Shigeru Hayashida, Seiji Tai
  • Patent number: 5034309
    Abstract: Novel naphthalocyanine derivatives are disclosed in the specification are useful for forming a recording layer in an optical recording medium. These derivatives are represented by the following formula (I): ##STR1## in which k, l, m and n, which may be the same or different, are zero or integers of 1 to 4, k+l+m+n being an integer of 1 or more; R.sup.1 's in a number of (k+l+m+n), which may be the same or different, are alkyl groups, substituted alkyl groups, or aryl groups; M is Si, Ge or Sn; and two Y's, which may be the same or different, are aryloxyl groups, alkoxyl groups, trialkylsiloxyl groups, triarylsiloxyl groups, trialkoxysiloxyl groups, triaryloxysiloxyl groups, trityloxyl groups, or acyloxyl groups. These derivatives are especially useful in the preparation of an optical recording medium.
    Type: Grant
    Filed: June 24, 1988
    Date of Patent: July 23, 1991
    Assignees: Hitachi Chemical Co., Ltd., Hitachi, Ltd.
    Inventors: Seiji Tai, Shigeru Hayashida, Nobuyuki Hayashi, Hideo Hagiwara, Mitsuo Katayose, Koichi Kamijima, Takayuki Akimoto, Susumu Era, Setsuo Kobayashi, Akio Mukoh
  • Patent number: 5021563
    Abstract: A metal naphthalocyanine derivative and process for producing said derivative which is represented by the following formula (I): ##STR1## wherein M represents germanium or tin; L and L' each independently represent a halogen, a hydroxyl group, an alkyl group, an alkoxy group or a siloxy group of the formula R.sub.1 R.sub.2 R.sub.3 SiO-- (wherein R.sub.1, R.sub.2 and R.sub.3 each independently represent a hydrogen atom, an alkyl group, an alkoxy group or an aryl group).
    Type: Grant
    Filed: October 6, 1989
    Date of Patent: June 4, 1991
    Assignees: Hitachi Chemical Company, Ltd., Hitachi, Ltd.
    Inventors: Shigeru Hayashida, Seiji Tai, Nobuyuki Hayashi, Yasushi Iwakabe, Noriyuki Kinjo, Shunichi Numata
  • Patent number: 4952560
    Abstract: An ointment base for external use is provided which contains a water-soluble protein and monohydric alcohol or/and oleginous substance and additionally contains a wetting agent. The present ointment base offers a markedly improved percutaneous absorption of drugs, as compared with the conventional ointment bases.
    Type: Grant
    Filed: April 11, 1988
    Date of Patent: August 28, 1990
    Assignee: Takeda Chemical Industries, Ltd.
    Inventors: Kazuo Kigasawa, Hideaki Ohtani, Makoto Tanaka, Shigeru Hayashida