Patents by Inventor Shinji Sakaguchi

Shinji Sakaguchi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5700620
    Abstract: Disclosed is a radiation ray sensitive resin composition comprising a water-insoluble, alkali-soluble resin, a water-insoluble, alkali-soluble low-molecular compound and a radiation ray sensitive component, in which said radiation ray sensitive component contains a mixture composed of (A) a napthoquinonediazide sulfonic acid diester of water-insoluble, alkali-soluble low-molecular compounds having three and/or four phenolic hydroxyl groups and (B) a napthoquinonediazide sulfonic acid ester of a water-insoluble, alkali-soluble low-molecular compound having from 5 to 7 phenolic hydroxyl groups, in an amount of 30% or more of said radiation ray sensitive component. The composition is a positive type photoresist having a high resolution and small film thickness dependence. This has a broad latitude for development and leaves a small resist residue after development. This has high heat resistance and is therefore highly resistant to dry etching.
    Type: Grant
    Filed: July 8, 1996
    Date of Patent: December 23, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinji Sakaguchi, Toshiaki Aoai, Kenichiro Sato
  • Patent number: 5683851
    Abstract: Provided is a positive photoresist composition comprising (A) an alkali-soluble resin prepared by condensation of aldehydes and a mixture of phenols, which comprises (i) thymol, isothymol or a thymol-isothymol mixture and (ii) one or more of a phenol compound represented by the following formula (I); ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are the same or different, and each of them represents a hydrogen atom or a methyl group, and optionally, as a third monomer, (iii) a phenol compound other than m-cresol; (B) 1,2-naphthoquinonediazide-5-(and/or -4-)sulfonic acid esters as photosensitive agent; and (C) a low molecular weight compound having from 12 to 50 carbon atoms in all and from 2 to 8 phenolic hydroxy groups.
    Type: Grant
    Filed: January 17, 1997
    Date of Patent: November 4, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shiro Tan, Shinji Sakaguchi
  • Patent number: 5652081
    Abstract: Provided is a positive working photoresist composition which comprises an alkali-soluble resin and a 1,2-quinonediazide compound, with the resin being a novolak resin obtained by the condensation reaction of monomers comprising specified phenol compounds with formaldehyde.
    Type: Grant
    Filed: September 5, 1996
    Date of Patent: July 29, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shiro Tan, Shinji Sakaguchi, Yasumasa Kawabe
  • Patent number: 5639587
    Abstract: A positive photoresist composition is disclosed, which comprises an alkali-soluble resin, at least one of 1,2-naphthoquinonediazidesulfonic monoesters of specific polyhydroxy compounds, and at least one of 1,2-naphthoquinonediazidesulfonic ester of specific polyhydroxy compounds. The positive photoresist composition exhibits remarkably improved sensitivity and resolution, and broad development latitude regardless of the film thickness, and further, low film thickness dependence of resist performances.
    Type: Grant
    Filed: March 14, 1996
    Date of Patent: June 17, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kenichiro Sato, Koji Shirakawa, Shinji Sakaguchi
  • Patent number: 5629128
    Abstract: A positive photoresist composition is described, which comprises an alkali-soluble resin and 1,2-naphthoquinone-diazido-5-(and/or -4-)sulfonate of a polyhydroxy compound represented by the following formula (I): ##STR1## wherein R.sub.1 to R.sub.11 are the same or different and each represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an alkoxyl group, an acyl group or a cycloalkyl group, provided that at least one of R.sub.1 to R.sub.11 is a cycloalkyl group; A represents -CH(R.sub.12)-, in which R.sub.12 represents a hydrogen atom or an alkyl group; and m represents 2 or 3.
    Type: Grant
    Filed: September 20, 1995
    Date of Patent: May 13, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koji Shirakawa, Kenichiro Sato, Kunihiko Kodama, Yasumasa Kawabe, Shinji Sakaguchi
  • Patent number: 5609983
    Abstract: There is provided a positive working photosensitive composition suitable for photosensitive lithographic printing plate or photoresist for fine processing, which comprises a quinonediazide ester compound having the structure characterized by containing in the same molecule both quinonediazide structure and N-sulfonylamide [--C(.dbd.O)--NHSO.sub.2 --] or sulfonamide [--NHSO.sub.2 --] structure which are positioned independently of each other.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: March 11, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Kawamura, Kenichiro Sato, Shinji Sakaguchi
  • Patent number: 5609982
    Abstract: The present invention provides a positive-working photoresist composition comprising an alkali-soluble resin and a 1,2-naphthoquinonediazide-5-(and/or -4-)sulfonic ester of a specific water-insoluble alkali-soluble low molecular compound, wherein the high-performance liquid chromatography of the ester with an ultraviolet ray at 254 nm shows that the patterns corresponding to the diester components and complete ester component of the ester each fall within the specific range and a positive-working photoresist composition comprising a water-insoluble alkali-soluble resin, a water-insoluble alkali-soluble low molecular compound, and an ionization-sensitive radioactive compound which comprises a mixture of a naphthoquinone-diazidesulfonic diester of a water-insoluble alkali-soluble low molecular compound having three phenolic hydroxyl groups as an ionization-sensitive radioactive compound (A) and a naphthoquinonediazidesulfonic diester of a water-insoluble alkali-soluble low molecular compound having four phenoli
    Type: Grant
    Filed: December 16, 1994
    Date of Patent: March 11, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kenichiro Sato, Yasumasa Kawabe, Toshiaki Aoai, Shinji Sakaguchi
  • Patent number: 5565300
    Abstract: A photoresist composition is disclosed containing an alkali-soluble resin and a photosensitive substance obtained by reaction of a polyhydroxy compound and (a) a 1,2-naphthoquinonediazido-5-(and/or -4-)sulfonyl chloride(s), said photosensitive substance being a mixture of photosensitive compounds (1) to (3):(1) a photosensitive compound having at least one hydroxyl group per molecule and having a number ratio of 1,2-naphthoquinonediazido-5-(and/or -4-)sulfonyl chloride sulfonate groups to hydroxyl groups within the range of from 3 to 20, contained in the photosensitive substance in an amount of 50 wt % or more;(2) a photosensitive compound where all the hydroxyl groups in the polyhydroxy compound have been 1,2-naphthoquinonediazidosulfonyl-esterified, contained in the photosensitive substance in an amount of 30 wt % to 0 wt %; and(3) a photosensitive compound having three or more hydroxyl groups which have not been 1,2-naphthoquinonediazidosulfonyl-esterified per molecule, contained in the photosensitive subs
    Type: Grant
    Filed: January 30, 1991
    Date of Patent: October 15, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuya Uenishi, Shinji Sakaguchi, Tadayoshi Kokubo
  • Patent number: 5340686
    Abstract: A positive-type photoresist composition is described as including:(1) an alkali-soluble phenol novolak having a degree of dispersion of from 1.5 to 4.0;(2) a 1,2-quinone diazide compound; and(3) from 2 to 30% by weight, based on the above-mentioned novolak, of a low molecular weight compound having a total of from 12 to 50 carbon atoms per molecule and 2 to 8 phenolic hydroxyl groups per molecule. The degree of dispersion is determined from a weight-average molecular weight of the novolak and a number-average molecular weight of the novolak, both the weight-average and number-average molecular weights being obtained by gel penetration chromatography (GPC) defined by using standard polystyrene as a reference, such that the degree of dispersion is a ratio of the weight-average molecular weight to the number average molecular weight.The positive-type photoresist composition of the present invention is excellent in development latitude and has a high sensitivity and a high resolving power.
    Type: Grant
    Filed: December 28, 1993
    Date of Patent: August 23, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinji Sakaguchi, Shiro Tan, Tadayoshi Kokubo
  • Patent number: 5248582
    Abstract: A positive type photoresist composition which comprises an alkali soluble novolak resin and at least one light-sensitive material represented by the following general formulae (I) to (IV) to provide a resist pattern with high resolution, high reproduction fidelity, desirable sectional shape, wide latitude of development, high heat resistance and high storage stability: ##STR1## (wherein X represents --CO--, or --SO.sub.2 --; p represents an integer from 2 to 4; R's may be the same or different, each being --H, --OH, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted acyl group, a substituted or unsubstituted acyloxy group, ##STR2## provided that R always contains at least one of ##STR3## ; R.sub.
    Type: Grant
    Filed: December 8, 1992
    Date of Patent: September 28, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuya Uenishi, Shinji Sakaguchi, Tadayoshi Kokubo
  • Patent number: 5173389
    Abstract: A positive-working photoresist composition is disclosed, which comprises (1) a light-sensitive material obtained by reacting a polyhydroxy compound containing at least one group represented by the following general formula (I) per molecule with at least one of 1,2-naphthoquinonediazido-5-sulfonyl chloride and 1,2-naphthoquinonediazido-4-sulfonyl chloride, and (2) an alkali-soluble novolak resin: ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom or a C.sub.1 -C.sub.4 straight or branched alkyl or alkoxy group, provided that R.sub.1 and R.sub.2 do not represent hydrogen atoms at the same time; and X represents a divalent organic group.
    Type: Grant
    Filed: April 26, 1990
    Date of Patent: December 22, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuya Uenishi, Shinji Sakaguchi, Tadayoshi Kokubo
  • Patent number: 4883739
    Abstract: A light-sensitive resin composition comprising a light-sensitive substance represented by the formula (A) shown below and an alkali-soluble resin: ##STR1## wherein R.sub.1 to R.sub.8 are independently hydrogen, a hydroxyl group, a halogen atom, an alkyl group, an alkoxy group, an aralkyl group, an aryl group, an amino group, a monoalkylamino group, a dialkylamino group, an acylamino group, an alkylcarbamoyl group, an arylcarbamoyl group, an alkylsulfamoyl group, an arylsulfamoyl group, a carboxyl group, a cyano group, a nitro group, an acyl group, an alkyloxycarbonyl group, an aryloxycarbonyl group, an acyloxy group, -OD, or ##STR2## (wherein R is hydrogen, or an alkyl group, and D is a 1,2-naphthoquinonediazido-5-sulfonyl group or a 1,2-naphthoquinonediazido-4-sulfonyl group);R.sub.9 to R.sub.12 are independently hydrogen or a lower alkyl group; andZ is oxygen or a single bond; provided that at least one of R.sub.1 to R.sub.
    Type: Grant
    Filed: September 16, 1988
    Date of Patent: November 28, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinji Sakaguchi, Shiro Tan
  • Patent number: 4659607
    Abstract: A retouchable mat film comprising a hydrophobic support which has formed thereon a mat layer containing silicon dioxide as a matting agent is disclosed. The mat layer further includes a mixture of poly(methyl methacrylate) or a copolymer containing at least 80 wt % of methyl methacrylate and a hydrophilic polymer as a binder. This mat film withstands several retouching operations in ink.
    Type: Grant
    Filed: December 2, 1985
    Date of Patent: April 21, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinzi Kataoka, Yukio Shinagawa, Shinji Sakaguchi
  • Patent number: 4626495
    Abstract: A photographic image receiving element for a silver salt diffusion transfer process which comprises a hydrolyzable first alkali impermeable polymer layer applied on a base and an image receiving layer thereon comprising a hydrolyzable second alkali impermeable polymer layer containing silver precipitation nuclei which is prepared by hydrolyzing at least a part of the hydrolyzable second alkali impermeable polymer layer so as to be alkali permeable, the improvement wherein at least one hydrophilic copolymer layer containing at least one of gum arabic and arabic acid is coated between said first alkali impermeable polymer layer and said image receiving layer, and said first alkali impermeable polymer layer contains at least one compound represented by formula (I) or formula (II) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.
    Type: Grant
    Filed: August 20, 1984
    Date of Patent: December 2, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shinji Sakaguchi
  • Patent number: 4588673
    Abstract: A retouchable mat film comprising a hydrophobic support which has formed thereon a mat layer containing silicon dioxide as a matting agent is disclosed. The mat layer further includes a mixture of poly(methyl methacrylate) or a copolymer containing at least 80 wt % of methyl methacrylate and a hydrophilic polymer as a binder. This mat film withstands several retouching operations in ink.
    Type: Grant
    Filed: February 22, 1985
    Date of Patent: May 13, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinzi Kataoka, Yukio Shinagawa, Shinji Sakaguchi
  • Patent number: 4585725
    Abstract: An image-receiving element for a silver salt diffusion transfer process is described, having an excellent storability before and after development; said element has at least one hydrophilic polymer layer between a layer of a first hydrolyzable alkali-impermeable polymer and an alkali-permeable image-receiving layer which is obtained by hydrolysis at least a part of a layer of the second alkali-impermeable polymer, and which contains silver depositing nuclei, said first layer contains at least one diffusible organic solvent-soluble compound for modifying the photographic properties of a silver transfer image to be formed in the alkali-permeable polymer layer by photographic processing.
    Type: Grant
    Filed: August 15, 1984
    Date of Patent: April 29, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shinji Sakaguchi
  • Patent number: 4511644
    Abstract: A photographic element comprised of a support having provided thereon at least one silver halide emulsion layer, the element containing a development inhibitor precursor. The development inhibitor precursor is represented by the following general formula (I): ##STR1## wherein A represents an unsubstituted or substituted phenyl group or a 5-membered or 6-membered nitrogen-containing heterocyclic ring; R.sup.1 represents a hydrogen atom or a monovalent substituent; and R.sup.2 represents an organic ballasting group. The element is capable of providing color images having improved image quality particularly with respect to having a low density in the Dmin areas. The photographic element can be processed over a wide range of processing temperatures. Further, the element can be preserved for long periods of time without having a reduction in the density in the Dmax areas.
    Type: Grant
    Filed: December 9, 1983
    Date of Patent: April 16, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Shinji Sakaguchi, Osamu Takahashi, Ashita Murai
  • Patent number: 4506001
    Abstract: A photographic recording material is disclosed. The material is comprised of a transparent support base and a number of layers positioned on that base. A dye ligand or a dye ligand-forming substance is positioned on the base and is associated with a light-sensitive silver halide emulsion. In addition, the material contains a mordant layer, an alkaline processing composition, and a means for releasing the composition throughout the photographic recording material in an integrated manner or as a different system. The mordant layer contains a coordination polymer composed of a ligand represented by a general formula (I) defined within the application and a metal ion. The invention makes it possible to immobilize a metal ion using inexpensive, easily available metal-chelatable ligands.
    Type: Grant
    Filed: April 3, 1984
    Date of Patent: March 19, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinji Sakaguchi, Hisashi Okamura, Shigeru Nakamura
  • Patent number: 4431731
    Abstract: An internal latent image silver halide emulsion is disclosed comprising core/shell silver halide particles having a chemically sensitized surface which are composed of a core of silver halide doped with metal ions and/or subjected to chemical sensitization and a shell which covers said core as far as to do at least the sensitive sites of said core and a binder, wherein said silver halide emulsions contain a polymer containing a repeating unit represented by the following general formula (I) in an amount of 2 mg to 1000 mg per mole of silver as the weight of said repeating units in said polymer: ##STR1## wherein R.sup.1 represents a hydrogen atom or an alkyl group and Q represents a group selected from the group consisting of the following (1)-(4): ##STR2## wherein q represents an integer of 2 to 4, ##STR3## wherein R.sup.2 and R.sup.3 each represents a hydrogen atom or an alkyl group, ##STR4## wherein Z.sup.
    Type: Grant
    Filed: February 17, 1982
    Date of Patent: February 14, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadao Sugimoto, Ichizo Toya, Shigeharu Urabe, Shinji Sakaguchi
  • Patent number: 4431730
    Abstract: A process for the preparation of an internal latent image type silver halide emulsion containing silver halide grains comprising a central core of silver halide doped with metal ions, chemically sensitized or a combination thereof and an outer shell of silver halide covering at least light-sensitive sites of the central core characterized in that the surface of the silver halide grains are chemically sensitized in the presence of a polymer containing the repeating unit represented by general formula (I) ##STR1## wherein symbols R.sup.1 and Q are defined in the specification.
    Type: Grant
    Filed: February 17, 1982
    Date of Patent: February 14, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeharu Urabe, Shinji Sakaguchi, Ichizo Toya, Tadao Sugimoto