Patents by Inventor Shoji Arai

Shoji Arai has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240322820
    Abstract: A signal transmission circuitry is a circuitry that transmits a signal from a first system on a transmission side to a second system on a reception side. The first system includes an inductor, a first current source controlled by a first switch, a second current source connected in series with the first current source via the inductor and controlled by a second switch, a third switch connected in parallel with the first current source and controlling connection with a ground point, and a fourth switch connected in parallel with the second current source and controlling connection with the ground point.
    Type: Application
    Filed: August 24, 2023
    Publication date: September 26, 2024
    Inventors: Bowen DANG, Makoto ARAI, Shoji OOTAKA, Takeshi MURASAKI, Takaya KITAHARA
  • Patent number: 7759440
    Abstract: The present invention relates to a polymerizable monomer represented by the general formula (1), wherein R1 is a hydrogen atom, a halogen atom, a hydrocarbon group or a fluorine-containing alkyl group; R2 is a straight-chain or branched alkyl group, a cyclic alkyl group, an aromatic group, or a substituent having at least two of these groups, the R2 being optionally partially fluorinated; R3 is a hydrogen atom, a hydrocarbon group that is optionally branched, a fluorine-containing alkyl group, or a cyclic group having an aromatic or alicyclic structure, the R3 optionally containing a bond of an oxygen atom or carbonyl group; and n is an integer of 1-2.
    Type: Grant
    Filed: July 13, 2006
    Date of Patent: July 20, 2010
    Assignees: Central Glass Company, Limited, F-Tech, Inc.
    Inventors: Satoru Miyazawa, Kazuhiko Maeda, Kenji Tokuhisa, Shoji Arai
  • Patent number: 7470808
    Abstract: A process for producing a fluorine-containing acrylic acid ester represented by CH2?C(Rf)(COOR) characterized in that 1-bromo-1-perfluoroalkylethene represented by CH2?CBr—Rf, or 1,2-dibromo-1-perfluoroalkylethane represented by CH2CBr—CHBr—Rf is allowed to react with an alcohol represented by ROH in the presence of a palladium catalyst, carbon monoxide, and two or more kinds of bases. The fluorine-containing acrylic acid ester is a useful compound having wide applications in materials for pharmaceuticals and functional polymers.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: December 30, 2008
    Assignees: Tosoh F-Tech, Inc., Sagami Chemical Research Center
    Inventors: Takamasa Fuchikami, Noriko Wakasa, Kenji Tokuhisa, Hideyuki Mimura, Shoji Arai
  • Patent number: 7220878
    Abstract: The present invention concerns a method for purifying/separating a 2-fluoro-3-oxoalkylcarboxylic acid ester from a reaction mixture resulting from the fluorination of a 3-oxoalkylcarboxylic acid ester. The method involves depleting the reaction mixture of a hydrogen fluoride byproduct; and subsequently, separating the 2-fluoro-3-oxoalkylcarboxylic acid ester by distillation. The 2-fluoro-3-oxoalkylcarboxylic acid ester obtained by the method of the invention is highly pure and is thus suitable for use as an intermediate for the production of pharmacological products or agricultural chemicals.
    Type: Grant
    Filed: September 27, 2001
    Date of Patent: May 22, 2007
    Assignee: Tosoh F-Tech, Inc.
    Inventors: Norihisa Kondo, Hideyuki Mimura, Kosuke Kawada, Shoji Arai
  • Patent number: 7208641
    Abstract: A method for producing 2,2,2-trifluoroethanol in which a ?-hydroxybutyric acid salt is reacted with 1,1,1-trifluoro-2-chloroethane to generate 2,2,2-trifluoroethanol is provided. This method leads to increased yields of 2,2,2 -trifluoroethanol, facilitates the separation of salt byproducts and allows the recycling of an aprotic polar solvent. The present invention concerns a method for producing 2,2,2-trifluoroethanol in which a ?-hydroxybutyric acid salt is reacted with 1,1,1-trifluoro-2-chloroethane in an aprotic polar solvent to generate 2,2,2-trifluoroethanol. This method is characterized in that the ?-hydroxybutyric acid salt used contains no more than 6 wt % of 4,4?-oxybis(butyric acid).
    Type: Grant
    Filed: September 13, 2002
    Date of Patent: April 24, 2007
    Assignee: Tosoh F-Tech, Inc.
    Inventors: Noritaka Nagasaki, Tsuyoshi Kawamura, Kazunori Nukui, Shoji Arai
  • Publication number: 20060252897
    Abstract: The present invention relates to a polymerizable monomer represented by the general formula (1), wherein R1 is a hydrogen atom, a halogen atom, a hydrocarbon group or a fluorine-containing alkyl group; R2 is a straight-chain or branched alkyl group, a cyclic alkyl group, an aromatic group, or a substituent having at least two of these groups, the R2 being optionally partially fluorinated; R3 is a hydrogen atom, a hydrocarbon group that is optionally branched, a fluorine-containing alkyl group, or a cyclic group having an aromatic or alicyclic structure, the R3 optionally containing a bond of an oxygen atom or carbonyl group; and n is an integer of 1-2.
    Type: Application
    Filed: July 13, 2006
    Publication date: November 9, 2006
    Applicants: Central Glass Company, Limited, F-Tech, Inc.
    Inventors: Satoru Miyazawa, Kazuhiko Maeda, Kenji Tokuhisa, Shoji Arai
  • Patent number: 7094850
    Abstract: The present invention relates to a polymerizable monomer represented by the general formula (1), wherein R1 is a hydrogen atom, a halogen atom, a hydrocarbon group or a fluorine-containing alkyl group; R2 is a straight-chain or branched alkyl group, a cyclic alkyl group, an aromatic group, or a substituent having at least two of these groups, the R2 being optionally partially fluorinated; R3 is a hydrogen atom, a hydrocarbon group that is optionally branched, a fluorine-containing alkyl group, or a cyclic group having an aromatic or alicyclic structure, the R3 optionally containing a bond of an oxygen atom or carbonyl group; and n is an integer of 1–2.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: August 22, 2006
    Assignee: Central Glass Company, Limited
    Inventors: Satoru Miyazawa, Kazuhiko Maeda, Kenji Tokuhisa, Shoji Arai
  • Publication number: 20060183937
    Abstract: An ?-pentafluoroethyl acrylic acid derivative represented by the general formula [I]: [wherein R represents a hydrogen atom, a non-substituted or substituted aromatic ring, or a straight or branched alkyl group having 1 to 20 carbon(s) which may have a cyclic moiety optionally substituted with at least one substituent (halogen atom, hydroxyl group, straight or branched alkoxy group having 1 to 10 carbon(s) which may have a cyclic moiety, non-substituted or substituted aromatic group)].
    Type: Application
    Filed: March 24, 2004
    Publication date: August 17, 2006
    Inventors: Kenji Tokuhisa, Hideyuki Mimura, Kosuke Kawada, Shoji Arai
  • Publication number: 20060122423
    Abstract: A process for producing a fluorine-containing acrylic acid ester represented by CH2?C(Rf)(COOR) characterized in that 1-bromo-1-perfluoroalkylethene represented by CH2?CBr—Rf, or 1,2-dibromo-1-perfluoroalkylethane represented by CH2CBr—CHBr—Rf is allowed to react with an alcohol represented by ROH in the presence of a palladium catalyst, carbon monoxide, and two or more kinds of bases. The fluorine-containing acrylic acid ester is a useful compound having wide applications in materials for pharmaceuticals and functional polymers.
    Type: Application
    Filed: March 24, 2004
    Publication date: June 8, 2006
    Inventors: Takamasa Fuchikami, Noriko Wakasa, Kenji Tokuhisa, Hideyuki Mimura, Shoji Arai
  • Patent number: 7019162
    Abstract: A process for producing a 2-fluoro-3-oxoalkylcarboxylic acid ester by fluorinating 3-oxoalkylcarboxylic acid ester with a fluorine gas is provided. The process is characterized in that the concentration of 3-oxoalkylcarboxylic acid ester in the reaction mixture for fluorination is maintained at 3 wt % or higher. Also provided is a process for purifying 2-fluoro-3-oxoalkylcarboxylic acid ester characterized in that 2-fluoro-3-oxoalkylcarboxylic acid ester is produced at high yield and with less impurities by washing fluorinated 3-oxoalkylcarboxylic acid ester with 3 or more times as much water as the amount of reaction mixture. According to the processes of the present invention, not only is the generation of unwanted by-products minimized, but fluorinated 3-oxoalkylcarboxylic acid ester can be purified in an efficient manner.
    Type: Grant
    Filed: December 25, 2001
    Date of Patent: March 28, 2006
    Assignee: Tosoh F-Tech, Inc.
    Inventors: Norihisa Kondo, Hideyuki Mimura, Kazunori Nukui, Kosuke Kawada, Shoji Arai
  • Patent number: 6894197
    Abstract: A method for producing fluorinated alcohols from fluorinated alkyl halides can produce fluorinated alcohols at high product yield and at high selectivity in a single-step reaction. The method eliminates the need to use heavy metals and other toxic compounds that are difficult to handle or process. Specifically, the method produces a fluorinated alcohol represented by the following general formula (2): Rf(A)OH??(2) wherein Rf represents a perfluoroalkyl group having 1 to 10 carbon atoms; and A represents a straight-chained or branched saturated hydrocarbon group having 3 to 10 carbon atoms. The method is characterized in that it allows a fluorinated alkyl halide represented by the following general formula (1) to react with an alkali metal salt of 4-hydroxybutyrate in a gamma-butyrolactone solvent: Rf(A)X??(1) wherein Rf and A are as defined above; and X represents a halogen atom.
    Type: Grant
    Filed: July 1, 2002
    Date of Patent: May 17, 2005
    Assignee: Tosoh F-Tech, Inc.
    Inventors: Hideyuki Mimura, Kosuke Kawada, Shoji Arai
  • Publication number: 20040254406
    Abstract: The invention provides a process for the preparation of 2,2,2-trifluoroethanol by reacting a &ggr;-hydroxybutyric acid salt with 1,1,1-trifluoro-2-chloroethane which brings about an increase in the yield of 2,2,2-trifluoroethanol and enables easy separation of by-product salts and recovery and recycling of an aprotic polar solvent. The invention relates to a process for the preparation of 2,2,2-trifluoroethanol by reacting a &ggr;-hydroxybutyric acid salt with 1,1,1-trifluoro-2-chloroethane in an aprotic polar solvent, characterized by using a &ggr;-hydroxybutyric acid salt having a 4,4′-oxydibutyric acid content of 6 wt % or below.
    Type: Application
    Filed: March 12, 2004
    Publication date: December 16, 2004
    Inventors: Noritaka Nagasaki, Tsuyoshi Kawamura, Kazunori Nukui, Shoji Arai
  • Publication number: 20040249190
    Abstract: The present invention concerns a method for purifying/separating a 2-fluoro-3-oxoalkylcarboxylic acid ester from a reaction mixture resulting from the fluorination of a 3-oxoalkylcarboxylic acid ester. The method involves depleting the reaction mixture of a hydrogen fluoride byproduct; and subsequently, separating the 2-fluoro-3-oxoalkylcarboxylic acid ester by distillation. The 2-fluoro-3-oxoalkylcarboxylic acid ester obtained by the method of the invention is highly pure and is thus suitable for use as an intermediate for the production of pharmacological products or agricultural chemicals.
    Type: Application
    Filed: March 24, 2004
    Publication date: December 9, 2004
    Inventors: Norihisa Kondo, Hideyuki Mimura, Kosuke Kawada, Shoji Arai
  • Publication number: 20040236046
    Abstract: The present invention relates to a polymerizable monomer represented by the general formula (1), 1
    Type: Application
    Filed: June 30, 2004
    Publication date: November 25, 2004
    Applicants: Central Glass Company, Limited, F-Tech, Inc.
    Inventors: Satoru Miyazawa, Kazuhiko Maeda, Kenji Tokuhisa, Shoji Arai
  • Patent number: 6784312
    Abstract: The present invention relates to a polymerizable monomer represented by the general formula (1), wherein R1 is a hydrogen atom, a halogen atom, a hydrocarbon group or a fluorine-containing alkyl group; R2 is a straight-chain or branched alkyl group, a cyclic alkyl group, an aromatic group, or a substituent having at least two of these groups, the R2 being optionally partially fluorinated; R3 is a hydrogen atom, a hydrocarbon group that is optionally branched, a fluorine-containing alkyl group, or a cyclic group having an aromatic or alicyclic structure, the R3 optionally containing a bond of an oxygen atom or carbonyl group; and n is an integer of 1-2.
    Type: Grant
    Filed: July 19, 2002
    Date of Patent: August 31, 2004
    Assignees: Central Glass Company, Limited, F-Tech, Inc.
    Inventors: Satoru Miyazawa, Kazuhiko Maeda, Kenji Tokuhisa, Shoji Arai
  • Publication number: 20040152926
    Abstract: A method for producing fluorinated alcohols from fluorinated alkyl halides can produce fluorinated alcohols at high product yield and at high selectivity in a single-step reaction. The method eliminates the need to use heavy metals and other toxic compounds that are difficult to handle or process.
    Type: Application
    Filed: March 1, 2004
    Publication date: August 5, 2004
    Inventors: Hideyuki Mimura, Kosuke Kawada, Shoji Arai
  • Publication number: 20040054217
    Abstract: A process for producing a 2-fluoro-3-oxoalkylcarboxylic acid ester by fluorinating 3-oxoalkylcarboxylic acid ester with a fluorine gas is provided. The process is characterized in that the concentration of 3-oxoalkylcarboxylic acid ester in the reaction mixture for fluorination is maintained at 3 wt % or higher. Also provided is a process for purifying 2-fluoro-3-oxoalkylcarboxylic acid ester characterized in that 2-fluoro-3-oxoalkylcarboxylic acid ester is produced at high yield and with less impurities by washing fluorinated 3-oxoalkylcarboxylic acid ester with 3 or more times as much water as the amount of reaction mixture. According to the processes of the present invention, not only is the generation of unwanted by-products minimized, but fluorinated 3-oxoalkylcarboxylic acid ester can be purified in an efficient manner.
    Type: Application
    Filed: June 26, 2003
    Publication date: March 18, 2004
    Inventors: Norihisa Kondo, Hideyuki Mimura, Kazunori Nukui, Kosuke Kawada, Shoji Arai
  • Publication number: 20030078352
    Abstract: The present invention relates to a polymerizable monomer represented by the general formula (1), 1
    Type: Application
    Filed: July 19, 2002
    Publication date: April 24, 2003
    Applicant: Central Glass Company, Limited
    Inventors: Satoru Miyazawa, Kazuhiko Maeda, Kenji Tokuhisa, Shoji Arai
  • Patent number: 6087499
    Abstract: A novel process is provided for producing a 5-perfluoroalkyl-5,6-dihydrouracil represented by General Formula (1): ##STR1## (where R.sup.1 and R.sup.2 are independently hydrogen, methyl, or ethyl, and Rf is a perfluoroalkyl of 1 to 10 carbons). The process comprises reacting .alpha.-perfluoroalkylacrylic acid represented by General Formula (2):CH.sub.2 =C(Rf)--COOH (2)with a urea derivative represented by General Formula (3):R.sup.1 NHCONHR.sup.2 (3)in the presence of acetic anhydride with formed acetic acid being removed out of the reaction system during the reaction. The .alpha.-perfluoroalkylacrylic acid may be added successively. A process for producing a 5-perfluoroalkyl-5-bromo-6-hydrouracil by General Formula (4) is also provided: ##STR2## (where R.sup.1, R.sup.2, and Rf are as defined above) wherein the reaction of a 5-perfluoroalkyl-5,6-dihydrouracil produced by the above process with bromine is conducted in water as the solvent.
    Type: Grant
    Filed: August 5, 1998
    Date of Patent: July 11, 2000
    Assignee: F-Tech Incorporated
    Inventors: Kazuhiko Tokoyoda, Koji Kato, Masami Takemitsu, Hiroaki Mizumoto, Shoji Arai
  • Patent number: 5672782
    Abstract: A process for producing a polymer having sulfonic acid groups is provided which comprises treating a polymer having sulfonate salt groups with a ion-exchange resin to change the sulfonate salt groups into sulfonate acid groups with porous-type strongly acidic cation exchange resin. A process for producing a tertiary alcohol is also provided which comprises hydration of olefin by use of the aforementioned polymer as the catalyst. By the process, a tertiary alcohol is produced by hydration of olefin with high selectivity at low cost.
    Type: Grant
    Filed: August 16, 1994
    Date of Patent: September 30, 1997
    Assignee: Tosoh Corporation
    Inventors: Akitaka Hattori, Kazuhiro Nakamura, Tomohiro Washiyama, Takao Kato, Toshihiro Saito, Shoji Arai