Abstract: Systems and methods are provided for mechanically encapsulating an infrared transmitting optical fiber, removing any power coupled to the cladding of the infrared optical fiber, and bridging the thermal properties between the optical fiber and the mechanical ferrule used. Embodiments of the present disclosure have several advantages over prior systems. For example, in an embodiment, the transmitting ferrule does not require epoxy to mount the fiber to the ferrule, isolates the front face of the fiber, and allows for high power to be incident on the connector without damage by reducing the thermal induced stress and managing any stray light coupled to the core.

Abstract: A method for making high optical quality multicomponent chalcogenide glasses without refractive index perturbations due to striae, phase separation or crystal formation using a sealed ampoule with chemical components enclosed inside, a two-zone furnace, a convection heating/mixing step, and multiple fining steps. Initially, the sealed ampoule is oriented vertically within the two-zone furnace and heated to melt the chemical components contained within, and a temperature gradient is created between the top zone and the bottom zone such that the bottom zone has a higher temperature. This temperature gradient causes convection currents within the viscous liquid until it is sufficiently mixed due to the convective flow. Then the temperature gradient is reversed such that the top zone now has a higher temperature and the convective flow ceases. The furnace temperatures are then reduced over a period of time, with holds at multiple temperatures for fining and cooling to form a solid glass.

Abstract: The present invention provides for synthesizing high optical quality multicomponent chalcogenide glasses without refractive index perturbations due to striae, phase separation or crystal formation using a two-zone furnace and multiple fining steps. The top and bottom zones are initially heated to the same temperature, and then a temperature gradient is created between the top zone and the bottom zone. The fining and cooling phase is divided into multiple steps with multiple temperature holds.

Abstract: Systems and methods are provided for mechanically encapsulating an infrared transmitting optical fiber, removing any power coupled to the cladding of the infrared optical fiber, and bridging the thermal properties between the optical fiber and the mechanical ferrule used. Embodiments of the present disclosure have several advantages over prior systems. For example, in an embodiment, the transmitting ferrule does not require epoxy to mount the fiber to the ferrule, isolates the front face of the fiber, and allows for high power to be incident on the connector without damage by reducing the thermal induced stress and managing any stray light coupled to the core.

Abstract: The present invention provides a method for synthesizing high optical quality multicomponent chalcogenide glasses without refractive index perturbations due to striae, phase separation or crystal formation using a two-zone furnace and multiple fining steps. The top and bottom zones are initially heated to the same temperature, and then a temperature gradient is created between the top zone and the bottom zone. The fining and cooling phase is divided into multiple steps with multiple temperature holds.

Abstract: A method for making a gradient index infrared transmitting optic by thermally treating a preform, where the preform comprises two or more infrared transmitting glasses having different compositions and optical properties, where there is an interface between adjacent glasses, where during the thermal treatment one or more chemical elements from the glasses diffuses through one or more interface resulting in a diffused gradient index optical element comprising a gradient in the chemical element concentration, and where the optical element has a gradient in refractive index and dispersion. Also disclosed is the related infrared transmitting optical element made by this method.

Abstract: Infrared transmitting glasses bonded into an optical element without interlayer voids by stacking at least two different infrared transmitting glasses inside a vessel where each glass has a different refractive index, a different dispersion, or both, and where the glasses all have similar viscosities, thermal expansion coefficients, and glass transition temperatures; placing a weight on top of the stack; applying a vacuum to the vessel; applying an isostatic pressure of at least 1500 psi; and after releasing the isostatic pressure, annealing at a temperature within 10° C. of the glass transition temperature at a pressure between 0 and 1000 psi. Applying the vacuum, applying the isostatic pressure, and annealing are done sequentially and with no intermediate transitions to ambient temperature or pressure.

Abstract: A method for bonding infrared transmitting glasses into an optical element without interlayer voids by stacking at least two different infrared transmitting glasses inside a vessel where each glass has a different refractive index, a different dispersion, or both, and where the glasses all have similar viscosities, thermal expansion coefficients, and glass transition temperatures; placing a weight on top of the stack; applying a vacuum to the vessel; applying an isostatic pressure of at least 1500 psi; and after releasing the isostatic pressure, annealing at a temperature within 10° C. of the glass transition temperature at a pressure between 0 and 1000 psi. Applying the vacuum, applying the isostatic pressure, and annealing are done sequentially and with no intermediate transitions to ambient temperature or pressure. Also disclosed is the related optical element made by this method.

Abstract: A method of making an optical fiber with multiple openings comprising the steps of fabricating an extrusion die using additive manufacturing such that the extrusion die has a plurality of channels that combine inside the die into another set of channels, extruding a glass, forming a fiber optic preform having a plurality of longitudinal openings that run the entire length, attaching a barrier layer for pressure application, and stretching the preform into an optical fiber with multiple openings. An extrusion die comprising an additive manufactured material, having a proximal side having openings and having a distal side having openings, wherein the openings of the proximal side are of feed channels, wherein the openings of the distal side are of forming channels, and wherein in side the body of the die, two of the feed channels combine the forming channels.

Abstract: A method of preparing a fine powder of calcium lanthanoid sulfide is disclosed. The method includes spraying soluble calcium and lanthanoid salts into at least one precipitating solution to form a precipitate comprising insoluble calcium and lanthanoid salts, optionally, oxidizing the precipitate comprising insoluble calcium and lanthanoid salts, and sulfurizing the optionally oxidized precipitate to form a fine powder of calcium lanthanoid sulfide. An alternative method for forming the powder is by flame pyrolysis. The calcium lanthanoid sulfide powder produced by either method can have an impurity concentration of less than 100 ppm, a carbon concentration of less than 200 ppm, a BET surface area of at least 50 m2/g, and an average particle size of less than 100 nm.

Abstract: The present invention provides a method for making a high strength, small grain size ceramic having a trans-granular fracture mode by rapid densification of a green body and subsequent cooling of the densified ceramic. The ceramic may include dislocations, defects, dopants, and/or secondary phases that are formed as a result of the process and resulting in stress fields capable of redirecting or arresting cracks within the material. This ceramic can maintain transparency from ultraviolet to mid-wave infrared.

Abstract: A striae-free chalcogenide glass with uniform refractive index.

Abstract: A transparent composite armor is made of tens to hundreds or even thousands of thin layers of material each with a thickness of 10-500 ?m. An appropriate amount of impedance mismatch between the layers causes some reflection at each interface but limit the amplitude of the resulting tensile wave below the tensile strength of the constituent materials. The result is an improvement in ballistic performance and that will result is a significant impact in reducing size, weight, and volume of the armor.

Abstract: A method to synthesize striae-free chalcogenide glass using melt processing. A striae-free chalcogenide glass with uniform refractive index.

Abstract: A compact multispectral imaging system comprising a set of optical elements capable of simultaneously focusing light from one or more spectral bands (SWIR, MWIR, and LWIR) to a common focal plane and a detector capable of capturing the multispectral image, wherein the optical elements comprise optics made from new optical materials or in combination with existing optical materials that transmit in multispectral wavelength regions.

Abstract: Methods for producing nanostructured, hydrophobic, superhydrophobic, or hydrophilic, transmissive, anti-reflective surfaces are described. The method for providing a hydrophilic surface includes steps of providing a substrate that is transmissive at at least one wavelength in the infrared to ultraviolet range of the electromagnetic spectrum and comprises at least one surface including nanostructures of a size smaller than the at least one wavelength; and functionalizing the at least one surface with hydroxyl groups thereon. A hydrophobic or superhydrophobic surface can be provided by contacting the at least one surface with a hydrophobic fluoropolymer for a time sufficient to apply at least a monolayer of fluorine-containing material to the at least one surface. These methods provide devices having excellent transmittance and anti-reflectance properties and which are resistant to seawater.

Abstract: A method of purifying a spinel powder includes contacting a spinel powder with an acid solution to form an acid-washed spinel composition and contacting the acid-washed spinel composition with a basic solution to form a purified composition. The purified powder is suited to formation of low-absorption shaped bodies, such as windows for high intensity laser devices.

Abstract: A method for making a gradient index infrared transmitting optic by thermally treating a preform, where the preform comprises two or more infrared transmitting glasses having different compositions and optical properties, where there is an interface between adjacent glasses, where during the thermal treatment one or more chemical elements from the glasses diffuses through one or more interface resulting in a diffused gradient index optical element comprising a gradient in the chemical element concentration, and where the optical element has a gradient in refractive index and dispersion. Also disclosed is the related infrared transmitting optical element made by this method.

Abstract: A method for bonding infrared transmitting glasses into an optical element without interlayer voids by stacking at least two different infrared transmitting glasses inside a vessel where each glass has a different refractive index, a different dispersion, or both, and where the glasses all have similar viscosities, thermal expansion coefficients, and glass transition temperatures; placing a weight on top of the stack; applying a vacuum to the vessel; applying an isostatic pressure of at least 1500 psi; and after releasing the isostatic pressure, annealing at a temperature within 10° C. of the glass transition temperature at a pressure between 0 and 1000 psi. Applying the vacuum, applying the isostatic pressure, and annealing are done sequentially and with no intermediate transitions to ambient temperature or pressure. Also disclosed is the related optical element made by this method.

Abstract: Method of Making particles including a YAG core and a coating of sintering aid deposited thereon. The particles and agglomerates thereof maybe formed as a powder. The coated YAG-containing particles are well-suited to production of polycrystalline YAG-containing ceramics. The coated YAG-containing particles may be fabricated using a novel fabrication method which avoids the need for formation of a homogeneous powder mixture of YAG and sintering aid. The mixture may be sprayed into a drying column and dried to produce coated particles. Alternatively, the YAG particles and sintering aid or sintering aid precursor solution may be separately introduced to the drying column and dried to form coated YAG-containing particles.