Abstract: Glass compositions and glass articles comprising the glass compositions are disclosed. In one embodiment, a glass composition includes from about 65 mol. % to about 70 mol. % SiO2; from about 9 mol. % to about 14 mol. % Al2O3; and from about 0 mol. % to about 11 mol. % B2O3 as glass network formers. The glass composition also includes from about 5 mol. % to less than 10 mol. % alkali oxide R2O, wherein R is at least one of Li, Na, and K. The glass composition also includes from about 3 mol. % to about 11 mol. % of divalent oxide MO, wherein M is at least one of Mg, Ca, Ba, SrO and Zn. The glass composition has a coefficient of thermal expansion which is less than or equal to 55×10-7/° C. and is amenable to strengthening by ion-exchange. The glass composition is well suited for use as the glass cladding layers of a laminated glass article.

Abstract: Disclosed herein are glass-ceramics having crystalline phases including ?-spodumene ss and either (i) pseudobrookite or (ii) vanadium or vanadium containing compounds so as to be colored and opaque glass-ceramics having coordinates, determined from total reflectance—specular included—measurements, in the CIELAB color space of the following ranges: L*=from about 20 to about 45; a*=from about ?2 to about +2; and b*=from about ?12 to about +1. Such CIELAB color space coordinates can be substantially uniform throughout the glass-ceramics. In each of the proceeding, ?-quartz ss can be substantially absent from the crystalline phases. If present, ?-quartz ss can be less than about 20 wt % or, alternatively, less than about 15 wt % of the crystalline phases. Also Further crystalline phases might include spinel ss (e.g., hercynite and/or gahnite-hercynite ss), rutile, magnesium zinc phosphate, or spinel ss (e.g., hercynite and/or gahnite-hercynite ss) and rutile.

Abstract: Ion exchangeable glasses containing SiO2, Al2O3, Na2O, MgO, B2O3, and P2O5 are provided. The compressive stresses of these ion exchanged glasses are greater than 900 megapascals (MPa) at a depth of 45 or 50 microns (?m) with some glasses exhibiting a compressive stress of at least 1 gigaPascals (GPa). The ion exchange rates of these glasses are much faster than those of other alkali aluminosilicate glasses and the ion exchanged glass is resistant damage to impact damage. A method of ion exchanging the glass is also provided.

Abstract: A silicate glass that is tough and scratch resistant. The toughness is increased by minimizing the number of non-bridging oxygen atoms in the glass. In one embodiment, the silicate glass is an aluminoborosilicate glass in which ?15 mol %?(R2O+R?O—Al2O3—ZrO2)—B2O3?4 mol %, where R is one of Li, Na, K, Rb, and Cs, and R? is one of Mg, Ca, Sr, and Ba.

Abstract: Disclosed herein are methods for ion exchanging, e.g., chemically strengthening, a substrate, the methods comprising applying a first electrode to at least one first region on a first surface of the substrate and applying a second electrode to at least one second region on an opposing second surface of the substrate, wherein the substrate comprises mobile ions, e.g., metal ions chosen from alkali metal ions, alkaline earth metal ions, transition metal ions, and combinations thereof; applying voltage between the first and second electrodes sufficient to cause the mobile ions to migrate away from the at least one first region on the first surface; and treating the substrate by ion exchange, e.g., chemically strengthening the substrate. Also disclosed herein are substrates, e.g., glass, glass-ceramic, and ceramic substrates, produced by the methods disclosed herein.

Abstract: Disclosed herein are glass-ceramics having crystalline phases including ?-spodumene ss and either (i) pseudobrookite or (ii) vanadium or vanadium containing compounds so as to be colored and opaque glass-ceramics having coordinates, determined from total reflectance—specular included—measurements, in the CIELAB color space of the following ranges: L*=from about 20 to about 45; a*=from about ?2 to about +2; and b*=from about ?12 to about +1. Such CIELAB color space coordinates can be substantially uniform throughout the glass-ceramics. In each of the proceeding, ?-quartz ss can be substantially absent from the crystalline phases. If present, ?-quartz ss can be less than about 20 wt % or, alternatively, less than about 15 wt % of the crystalline phases. Also Further crystalline phases might include spinel ss (e.g., hercynite and/or gahnite-hercynite ss), rutile, magnesium zinc phosphate, or spinel ss (e.g., hercynite and/or gahnite-hercynite ss) and rutile.

Abstract: Embodiments of a glass-based article including a first surface and a second surface opposing the first surface defining a thickness (t) of about 3 millimeters or less (e.g., about 1 millimeter or less), and a stress profile, wherein all points of the stress profile between a thickness range from about 0·t up to 0.3·t and from greater than about 0.7·t up to t, comprise a tangent with a slope having an absolute value greater than about 0.1 MPa/micrometer, are disclosed. In some embodiments, the glass-based article includes a non-zero metal oxide concentration that varies along at least a portion of the thickness (e.g., 0·t to about 0.3·t) and a maximum central tension in the range from about 80 MPa to about 100 MPa. In some embodiments, the concentration of metal oxide or alkali metal oxide decreases from the first surface to a value at a point between the first surface and the second surface and increases from the value to the second surface. The concentration of the metal oxide may be about 0.

Abstract: A scratch resistant alkali aluminoborosilicate glass. The glass is chemically strengthened and has a surface layer that is rich in silica with respect to the remainder of the glass article. The chemically strengthened glass is then treated with an aqueous solution of a mineral acid other than hydrofluoric acid, such as, for example, HCl, HNO3, H2SO4, or the like, to selective leach elements from the glass and leave behind a silica-rich surface layer. The silica-rich surface layer improves the Knoop scratch threshold of the ion exchanged glass compared to ion exchanged glass that are not treated with the acid solution as well as the post-scratch retained strength of the glass.

Abstract: A group of glass compositions in the Li2O—Al2O3—SiO2—B2O3 family that can be chemically strengthened in single or multiple ion exchange baths containing at least one of NaNO3 and KNO3 for a short time (2-4 hours) to develop a deep depth of layer (DOL). In some instances, the DOL is at least 70 ?m; in others, at least about 100 ?m. The ion exchanged glasses have a high damage resistance (indentation fracture toughness ranging form greater than 10 kgf to greater than 50 kgf) that is better than or at least comparable to that of sodium aluminosilicate glasses.

Abstract: A scratch resistant alkali aluminoborosilicate glass. The glass is chemically strengthened and has a surface layer that is rich in silica with respect to the remainder of the glass article. The chemically strengthened glass is then treated with an aqueous solution of a mineral acid other than hydrofluoric acid, such as, for example, HCl, HNO3, H2SO4, or the like, to selective leach elements from the glass and leave behind a silica-rich surface layer. The silica-rich surface layer improves the Knoop scratch threshold of the ion exchanged glass compared to ion exchanged glass that are not treated with the acid solution as well as the post-scratch retained strength of the glass.

Abstract: A glass article includes a glass core layer and a glass cladding layer adjacent to the core layer. An average coefficient of thermal expansion (CTE) of the core layer is greater than an average CTE of the cladding layer. An effective 109.9 P temperature of the glass article is at most about 750° C.

Abstract: A method of making a strengthened, antimicrobial glass article that includes: providing a glass article comprising a primary surface and ion-exchangeable alkali metal ions; providing a first molten salt bath comprising 60 to 95 wt. % alkali metal ions that are larger in size than the ion-exchangeable alkali metal ions; providing a second molten salt bath comprising alkali metal ions and about 1 to 10 wt. % silver ions; submersing the glass article in the first bath to exchange a portion of the ion-exchangeable alkali metal ions with a portion of the ions in the first bath to define a compressive stress layer extending from the primary surface to a DOL; and submersing the glass article in the second bath to exchange alkali metal ions in the compressive stress layer with a portion of the silver ions in the second bath to impart an antimicrobial property at the primary surface.

Abstract: An ion exchangeable glass that is free of lithium and comprising 0.1-10 mol % P2O5 and at least 5 mol % Al2O3. The presence of P2O5 enables the glass to be ion exchanged more quickly and to a greater depth than comparable glasses that do not contain P2O5.

Abstract: A method of making a glass sheet includes treating a refractory block material comprising at least one multivalent component with a vehicle comprising at least one redox altering component or precursor. The method also includes flowing molten glass over the refractory block material, wherein the treatment of the refractory block material with the vehicle comprising at least one redox altering component or precursor reduces the amount of oxygen production resulting from interaction between the at least one multivalent component and the molten glass.

Abstract: A method of chemically strengthening a glass. The method includes heating an ion exchange solution to a temperature less than about 360° C., and contacting the glass and the strengthening solution at the temperature for a duration from about 0.5 hours to about 24 hours. The ion exchange solution includes a primary nitrate and at least one monovalent or divalent cation nitrate component in an amount from about 1 wt. % to about 10 wt. %.

Abstract: A glass and an enclosure, including windows, cover plates, and substrates for mobile electronic devices comprising the glass. The glass has a crack initiation threshold that is sufficient to withstand direct impact, has a retained strength following abrasion that is greater than soda lime and alkali aluminosilicate glasses, and is resistant to damage when scratched. The enclosure includes cover plates, windows, screens, and casings for mobile electronic devices and information terminal devices.

Abstract: Methods and apparatus provide for: a glass substrate having a first strain to failure characteristic, a first elastic modulus characteristic, and a flexural strength; and a coating applied over the glass substrate to produce a composite structure in order to increase a hardness thereof, where the coating has a second strain to failure characteristic and a second elastic modulus characteristic, where the first strain to failure characteristic is higher than the second strain to failure characteristic, and one of: (i) the first elastic modulus characteristic is above a minimum predetermined threshold such that any reduction of the flexural strength of the glass substrate resulting from application of the coating is mitigated; and (ii) the first elastic modulus characteristic is below a maximum predetermined threshold such that any reduction of the strain to failure of the glass substrate resulting from application of the coating is mitigated.

Abstract: According to one embodiment, a glass article may include SiO2, Al2O3, Li2O and Na2O. The glass article may have a softening point less than or equal to about 810° C. The glass article may also have a high temperature CTE less than or equal to about 27×10?6/° C. The glass article may also be ion exchangeable such that the glass has a compressive stress greater than or equal to about 600 MPa and a depth of layer greater than or equal to about 25 ?m after ion exchange in a salt bath comprising KNO3 at a temperature in a range from about 390° C. to about 450° C. for less than or equal to approximately 15 hours.

Abstract: A scratch resistant alkali aluminoborosilicate glass. The glass is chemically strengthened and has a surface layer that is rich in silica with respect to the remainder of the glass article. The chemically strengthened glass is then treated with an aqueous solution of a mineral acid other than hydrofluoric acid, such as, for example, HCl, HNO3, H2SO4, or the like, to selective leach elements from the glass and leave behind a silica-rich surface layer. The silica-rich surface layer improves the Knoop scratch threshold of the ion exchanged glass compared to ion exchanged glass that are not treated with the acid solution as well as the post-scratch retained strength of the glass.

Abstract: Disclosed herein are glass-ceramics having crystalline phases including ?-spodumene ss and either (i) pseudobrookite or (ii) vanadium or vanadium containing compounds so as to be colored and opaque glass-ceramics having coordinates, determined from total reflectance—specular included—measurements, in the CIELAB color space of the following ranges: L*=from about 20 to about 45; a*=from about ?2 to about +2; and b*=from about ?12 to about +1. Such CIELAB color space coordinates can be substantially uniform throughout the glass-ceramics. In each of the proceeding, ?-quartz ss can be substantially absent from the crystalline phases. If present, ?-quartz ss can be less than about 20 wt % or, alternatively, less than about 15 wt % of the crystalline phases. Also Further crystalline phases might include spinel ss (e.g., hercynite and/or gahnite-hercynite ss), rutile, magnesium zinc phosphate, or spinel ss (e.g., hercynite and/or gahnite-hercynite ss) and rutile.