Abstract: The present invention relates to relates to a polymer formulation for three-dimensionally (3D) printing an article by stereolithography, the formulation comprising a functionalized polymer. The invention further relates to lithographic methods to form 3D objects that incorporate the aforementioned polymer formulation.

Abstract: The present invention relates to functionalized poly(aryl ether sulfones) polymers. The invention further relates to polymer compositions including the functionalized poly(aryl ether sulfone) polymers. Still further, the invention relates to lithographic methods to form three-dimensional (3D) objects that incorporate the aforementioned polymer compositions.

Abstract: The invention pertains to a relates to a copolymer (P1) of poly(aryl ether sulfones) (PAES) and polydimethylsiloxane (PDMS) and to the process for preparing the copolymer (P1) by melt-hydrosilylation.

Abstract: The present invention relates to a polymer composition comprising polyphenylene sulphide (PPS), polyamide 6 (PA6), reinforcing agents, wherein the weight ratio of PPS/PA6 is at least 2, with the proviso that the composition does not comprise an elastomer or comprises an elastomer in an amount not exceeding 1 wt. %. The present invention also relates to articles incorporating the polymer composition and the use of polyamide 6 (PA6) as a heat-aging stabilizer in a polymer composition.

Abstract: The invention pertains to a powdered material (M) comprising at least one poly(arylene sulfide) polymer, in particular to a method for manufacturing a three-dimensional (3D) object, using the powdered material (M) and to 3D object obtainable by selective sintering from this powdered polymer material (M).

Abstract: The invention pertains to a method for manufacturing a three-dimensional (3D) object, using a powdered material (M) comprising at least one poly(arylene sulfide) polymer, in particular to a 3D object obtainable by selective sintering from this powdered polymer material (M).

Abstract: The present disclosure relates to method of making three-dimensional (3D) objects using an additive manufacturing system wherein the part material comprises a polymeric component comprising at least one poly(ether ether ketone) polymer (PEEK) having a weight average molecular weight (Mw) ranging from 75,000 to 100,000 g/mol (as determined by GPC), for example in the form of filaments or spherical particles, for use in additive manufacturing systems to print 3D objects.

Abstract: The present disclosure relates to a method for manufacturing a three-dimensional (3D) object with an additive manufacturing system, comprising a step consisting in printing layers of the three-dimensional object from the part material comprising at least one poly(aryl ether sulfone) (PAES) polymer and at least one per(halo)fluoropolymer (FP), having a melt viscosity measured according to ASTM D3835, at 372° C. and 1000 s?1, using a using a Hastelloy die of 1 mm×10 mm, of at most 1.5×103 Pa·s. The present invention also relates to polymeric part material, e.g. filaments or pellets, comprising such a PAES and a FP, as well as to the use of PAES and PF to prepare pellets or filaments and to print 3D objects.

Abstract: The present disclosure relates to a method for manufacturing a three-dimensional (3D) object with an additive manufacturing system, comprising a step consisting in printing layers of the three-dimensional object from the part material comprising a polymeric component comprising at least one poly(aryl ether sulfone) (PAES) polymer having a number average molecular weight (Mn) of at least 12,000 g/mol and a polydispersity (PDI) of less than 1.7. The present invention also relates to polymeric filaments comprising such a PAES, as well as to the use of this PAES to prepare filaments and to print 3D objects.

Abstract: The invention relates to polyamides comprising at least 1 mol. % of 3-(aminoalkyl)benzoic acid (3-AABa), for example 3-(aminoethyl)benzoic acid (3-AEBa). The present invention also relates to polymer compositions comprising such polyamides, as well as articles comprising the same and methods of using said articles in automotive applications, LED packaging, electric and electronics devices, mobile electronics, gas barrier packaging, plumbing and oil and gas applications.

Abstract: Described herein are end-capped poly(aryl ether sulfone) (“PAES”) polymers and corresponding synthesis methods. The end-capped PAES polymers are end-capped by functionalizing a PAES polymer with a halophthalic diialkyl ester end-capping agent. It was surprisingly discovered that the resulting dialkyl phthalate end-capped PAES polymers could be synthesized with significantly improved end-capping conversion rates, relative to end-capped PAES polymers directly functionalized with traditional phthalic anhydride end-capping agents. It was also surprisingly found that by heating the isopropyl phthalate end-capped PAES polymers, the polymers could be converted to the corresponding phthalic anhydride end-capped PAES polymers, yielding a more efficient synthetic route to phthalic anhydride end-capped PAES polymers.

Abstract: The present invention relates to a polymer composition (C) comprising at least one polyamide (P1), and from 1 to 50 wt. %, based on the total weight of (C), of at least one functionalized polymer (P2), wherein P2 is a poly(aryl ether sulfone) (PAES) having at least one functional group (SO3?), (Mp+)1/p in which Mp+ is a metal cation of p valence. The present invention also relates to articles incorporating the polymer composition (C) and the use of functionalized polymer (P2) as a compatibilizer in the polymer composition (C) comprising two immiscible polymers.

Abstract: A method for manufacturing a three-dimensional (3D) object with an additive manufacturing system, comprising a step consisting in printing layers of the 3D object from the part material comprising a polymeric component comprising, based on the total weight of the polymeric component: from 5 to 95 wt. % of at least one polymer (P1) comprising at least 50 mol. % of recurring units (R1) consisting of an arylene group comprising at least one benzene ring, each recurring unit (R1) being bound to each other through C—C bonds, wherein the recurring units (R1) are such that, based on the total number of moles of recurring units (R1):less than 90 mol. % are rigid rod-forming arylene units (R1-a), and at least 10 mol. % are kink-forming arylene units (R1-b), and from 5 to 95 wt. % of at least one polymer (P2), having a glass transition temperature (Tg) between 140° C. and 265° C., and no melting peak, as measured by differential scanning calorimetry (DSC) according to ASTM D3418.

Abstract: The present disclosure relates to a method for manufacturing a three-dimensional (3D) object with an additive manufacturing system, comprising a step consisting in printing layers of the three-dimensional object from 50 to 99 wt. % of a polymeric material comprising at least one poly(aryl ether ketone) polymer (PAEK), and optionally at least one poly(biphenyl ether sulfone) polymer (PPSU) and/or at least one poly(ether imide) polymer (PEI), and at least one nitride (N), preferably a boron nitride (BN).

Abstract: The present disclosure relates to method for manufacturing three-dimensional (3D) objects using an additive manufacturing system wherein the part material comprises a combination of at least one poly(aryl ether ketone) polymer (PAEK) and at least one poly(aryl ether sulfone) (PAES). In particular, the present disclosure relates to part material incorporating PAEK and PAES, for example in the form of filaments or spherical particles, for use in additive manufacturing systems to print 3D objects.

Abstract: The present disclosure relates to method of making three-dimensional (3D) objects using an additive manufacturing system wherein the part material comprises a polymeric component comprising a poly(biphenyl ether sulfone) polymer (PPSU) having an optimized weight average molecular weight (Mw). In particular, the present disclosure relates to part material incorporating a PPSU of Mw ranging from 48,000 to 52,000 g/mol, for example in the form of filaments or spherical particles, for use in additive manufacturing systems to print 3D objects.

Abstract: The present invention relates to functionalized poly(aryl ether sulfones) (PAES) polymers (P1) and to the process for preparing the PAES polymers (P1). The present invention also relates to a method for preparing block copolymers (P2) using the functionalized poly(aryl ether sulfones) (PAES) polymers (P1) and to the block copolymers (P2) themselves.

Abstract: A polymer composition includes at least two different polymers independently selected from a poly(aryl ether ketone) (PAEK), a poly(aryl ether sulfone) (PAES), a polyarylene sulfide (PAS) and a polyetherimide (PEI), and about 0.05 to about 2 wt. % of at least one alkali metal carbonate. Preferably, the polymer composition is free or substantially free of solvent. A method includes melt mixing at least two different polymers independently selected from a poly(aryl ether ketone) (PAEK), a poly(aryl ether sulfone) (PAES), a polyarylene sulfide (PAS) and a polyetherimide (PEI), and about 0.05 to about 2 wt. % of at least one alkali metal carbonate to form a compatibilized polymer composition.

Abstract: The present invention relates to the use, as water vapour barrier, of a film, of a textile or of a layer of material P, said material P comprising, or even consisting of, at least one copolymer A which is a polyamide of PAXY/XAIS Mn+1/n type or of PAZ/XAISMn+1/n type. It also relates to a construction element comprising a film, a textile or a layer of said material P and a construction material.

Abstract: The present invention relates to (co)polyamides comprising at least 60 mol. % of recurring units of formula (I): (I). The present invention also relates to polymer compositions comprising such (co)polyamides, as well as articles comprising the same and methods of using said articles in high temperature applications requiring sufficient swelling or deformation upon exposure to moisture, such as for example oil and gas extraction processes (e.g. fracturing balls), or as support materials used to print three-dimensional (3D) parts.