Patents by Inventor Stefan Hilf

Stefan Hilf has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11965140
    Abstract: Low molecular weight polyalkyl acrylate polymers can be used as high viscosity base fluids. A corresponding method can be used for their preparation. Lubricant compositions may contain such low molecular weight polyalkyl acrylate polymers and the compositions may be used as automatic transmission fluids, manual transmission fluids, continuously variable transmission fluids, gear oil formulations, industrial gear oil formulations, axle fluid formulations, dual clutch transmission fluids, dedicated hybrid transmission fluids, or hydraulic oils.
    Type: Grant
    Filed: December 12, 2019
    Date of Patent: April 23, 2024
    Assignee: Evonik Operations GmbH
    Inventors: Stefan Karl Maier, Michael Neusius, Qi Xiao, Gabriela Fedor, Stefan Hilf, Frank-Olaf Mähling
  • Publication number: 20230383212
    Abstract: Acrylate-olefin copolymers and a method for the preparation of these copolymers are provided. Lubricant compositions can contain the aforementioned copolymers. The copolymers are useful as a lubricant additive or a synthetic base fluid in a lubricating oil composition, preferably in a gear oil composition, a transmission oil composition, a hydraulic oil composition, an engine oil composition, a marine oil composition, an industrial lubricating oil composition or in grease.
    Type: Application
    Filed: May 22, 2023
    Publication date: November 30, 2023
    Applicant: Evonik Operations GmbH
    Inventors: Emily Clare SCHWEIßINGER, Stefan Karl Maier, Katja Nothdurft, Yvonne Groß-Onnebrink, Dieter Janßen, Holger Pletsch, Stefan Hilf, Denise Kleinschmidt, Sebastian Babik
  • Publication number: 20230257673
    Abstract: A polyester is useful as a high viscosity base fluid. A method for its preparation involves isomerizing an alpha-olefin, epoxidizing an internal olefin, reacting an internal epoxide, and isolating the polyester. Lubricant compositions can contain such polyesters and the compositions are useful as automatic transmission fluids, manual transmission fluids, continuously variable transmission fluids, gear oil formulations, industrial gear oil formulations, axle fluid formulations, dual clutch transmission fluids, dedicated hybrid transmission fluids, or as hydraulic oils.
    Type: Application
    Filed: July 1, 2021
    Publication date: August 17, 2023
    Applicant: Evonik Operations GmbH
    Inventors: Stefan Karl MAIER, Peter Altenbuchner, Fabian Ziegler, Christiane Zatocil, Stefan Hilf, Emily Clare Schweißinger, Jens Elsner
  • Publication number: 20230257674
    Abstract: A polyester is useful as a high viscosity base fluid. A method for its preparation involves epoxidizing an alpha-olefin, reacting the alpha-epoxide or diol with a saturated linear aliphatic dicarboxylic acid, and isolating the polyester. Lubricant compositions can contain such polyesters and the compositions are useful as automatic transmission fluids, manual transmission fluids, continuously variable transmission fluids, gear oil formulations, industrial gear oil formulations, axle fluid formulations, dual clutch transmission fluids, dedicated hybrid transmission fluids, or as hydraulic oils.
    Type: Application
    Filed: July 1, 2021
    Publication date: August 17, 2023
    Applicant: Evonik Operations GmbH
    Inventors: Stefan Karl Maier, Peter Altenbuchner, Fabian Ziegler, Christiane Zatocil, Stefan Hilf, Emily Clare Schweißinger, Jens Elsner
  • Patent number: 11618797
    Abstract: The invention relates to acrylate-olefin copolymers and to a method for preparing these polymers. The present invention is also directed to lubricant compositions comprising these copolymers, and to the use of these copolymers as a lubricant additive or a synthetic base fluid in a lubricating oil composition, preferably in a gear oil composition, a transmission oil composition, a hydraulic oil composition, an engine oil composition, a marine oil composition, an industrial lubricating oil composition or in grease.
    Type: Grant
    Filed: December 6, 2021
    Date of Patent: April 4, 2023
    Assignee: Evonik Operations GmbH
    Inventors: Stefan Karl Maier, Dieter Janßen, Fabian Ziegler, Katrin Schöller, Stefan Hilf
  • Publication number: 20220372388
    Abstract: Low molecular weight polyalkyl acrylate polymers can be used as high viscosity base fluids. A corresponding method can be used for their preparation. Lubricant compositions may contain such low molecular weight polyalkyl acrylate polymers and the compositions may be used as automatic transmission fluids, manual transmission fluids, continuously variable transmission fluids, gear oil formulations, industrial gear oil formulations, axle fluid formulations, dual clutch transmission fluids, dedicated hybrid transmission fluids, or hydraulic oils.
    Type: Application
    Filed: December 12, 2019
    Publication date: November 24, 2022
    Applicant: Evonik Operations GmbH
    Inventors: Stefan Karl Maier, Michael Neusius, Qi Xiao, Gabriela Fedor, Stefan Hilf, Frank-Olaf Mähling
  • Publication number: 20220195091
    Abstract: The invention relates to acrylate-olefin copolymers and to a method for preparing these polymers. The present invention is also directed to lubricant compositions comprising these copolymers, and to the use of these copolymers as a lubricant additive or a synthetic base fluid in a lubricating oil composition, preferably in a gear oil composition, a transmission oil composition, a hydraulic oil composition, an engine oil composition, a marine oil composition, an industrial lubricating oil composition or in grease.
    Type: Application
    Filed: December 6, 2021
    Publication date: June 23, 2022
    Applicant: Evonik Operations GmbH
    Inventors: Stefan Karl Maier, Dieter Janßen, Fabian Ziegler, Katrin Schöller, Stefan Hilf
  • Patent number: 10494495
    Abstract: The invention concerns specifically emulsion polymers which are intraparticulately crosslinked via a hetero-Diels-Alder (HDA) mechanism. The crosslinked polymers can then be wholly or partly decrosslinked by thermal processing, for example in the form of a composite matrix, via a retro-Diels-Alder or retro-hetero-Diels-Alder reaction and interparticulately recrosslinked on cooling. This makes it possible to prepare long shelf life prepregs for composites. But it is also possible to thus realize other materials that have thermoset properties at use temperature but thermoplastic processing properties at a higher temperature.
    Type: Grant
    Filed: July 30, 2015
    Date of Patent: December 3, 2019
    Assignee: EVONIK DEGUSSA GmbH
    Inventors: Friedrich Georg Schmidt, Stefan Hilf, Florian Hermes, Dorothea Staschik, Thomas Eurich, Rebecca Pieroth
  • Patent number: 10030105
    Abstract: The invention relates to low molecular mass products and to the use thereof as reversible or permanent low-temperature crosslinkers in Diels-Alder reactions.
    Type: Grant
    Filed: June 29, 2012
    Date of Patent: July 24, 2018
    Assignee: Evonik Degussa GmbH
    Inventors: Friedrich Georg Schmidt, Stefan Hilf, Emmanouil Spyrou, Jiawen Zhou, Nathalie Guimard, Christopher Barner-Kowollik, Kim Klaus Oehlenschlaeger, Andre Hennig
  • Patent number: 9862788
    Abstract: The present invention relates to an innovative (meth)acrylic reactive resin which cures with low odor or odorlessly. The present invention relates more particularly to reactive resins comprising high-boiling, reactive (meth)acrylic monomers from the group of the polar, cyclically substituted esters of (meth)acrylic acid, more particularly glycerol acetal, ketal or carbonate methacrylates. These new components are used as substitutes for MMA, which represents the major part of the odor nuisance in the existing, prior-art reactive resin systems. Using these new components it is possible to obtain resin formulations which have glass transition temperatures similar to, and properties comparable with, MMA-based resins. The innovative reactive resins are able in addition to exhibit more rapid curing than prior-art MMA-based systems. Reactive resins for the purposes of the invention are reactive monomer mixtures or mixtures of monomers and polymers that when used as a 2-component system can be readily cured.
    Type: Grant
    Filed: July 2, 2012
    Date of Patent: January 9, 2018
    Assignee: Evonik Roehm GmbH
    Inventors: Stefan Hilf, Alexander Klein, Heike Heeb, Ingrid Kizewski, Sebastian Grimm, Michael Flittner
  • Publication number: 20170218149
    Abstract: The invention concerns specifically emulsion polymers which are intraparticulately crosslinked via a hetero-Diels-Alder (HDA) mechanism. The crosslinked polymers can then be wholly or partly decrosslinked by thermal processing, for example in the form of a composite matrix, via a retro-Diels-Alder or retro-hetero-Diels-Alder reaction and interparticulately recrosslinked on cooling. This makes it possible to prepare long shelf life prepregs for composites. But it is also possible to thus realize other materials that have thermoset properties at use temperature but thermoplastic processing properties at a higher temperature.
    Type: Application
    Filed: July 30, 2015
    Publication date: August 3, 2017
    Applicant: EVONIK DEGUSSA GMBH
    Inventors: Friedrich Georg SCHMIDT, Stefan HILF, Florian HERMES, Dorothea STASCHIK, Thomas EURICH, Rebecca PIEROTH
  • Patent number: 9670295
    Abstract: A block-copolymer containing at least two different blocks wherein block A contains (meth)acrylate monomers the copolymer having a glass transition temperature of less than 15° C., block B contains (meth)acrylate monomers the copolymer having a glass transition temperature of more than 25° C. being free of thio-containing substances in the polymer chain, characterized in that one block contains at least one photoinitiator chemically bound to the chain.
    Type: Grant
    Filed: March 12, 2013
    Date of Patent: June 6, 2017
    Assignees: Henkel AG & Co. KGaA, Evonik Röhm GmbH
    Inventors: Peter D. Palasz, Maria Xenidou, Kerstin van Wijk, Simon Krause, Stefan Hilf
  • Patent number: 9550851
    Abstract: A method for the reversible crosslinking of, for example, adhesives or coating materials, and a composition stable on storage at room temperature for implementing the crosslinking reaction. The reversible crosslinking method allows very rapid crosslinking even at a low first temperature, and undoing of the crosslinks at higher temperatures, thereby recovering thermoplastic processability and, for example, allowing the originally bonded substrates to be parted from one another again easily. A particular aspect is that a plurality of cycles of crosslinking and undoing of the crosslinks are possible with the present system. A feature of the system used for the reversible crosslinking is that it contains two components, A and B, where component A is a compound having at least two protected dithioester functionalities, preferably cyanodithioester functionalities, and component B is a compound having at least two diene functionalities.
    Type: Grant
    Filed: November 11, 2013
    Date of Patent: January 24, 2017
    Assignee: EVONIK ROEHM GmbH
    Inventors: Christopher Barner-Kowollik, Kim Klaus Oehlenschlaeger, Stefan Hilf, Friedrich Georg Schmidt, Nathalie Guimard, Jan Mueller
  • Publication number: 20160304683
    Abstract: The invention relates to a method for the production of storage-stable prepregs and moulded objects produced therefrom (composite components). The composition used according to the invention for the production of the prepregs here contains A) monomers, in particular (meth)acrylates and/or styrene, B) at least one (meth)acrylate with a residue which contains a conjugated diene, C) a crosslinker having at least two dienophilic groups, and D) at least one suitable initiator. Alternatively, instead of or additionally to the components B) and C), the composition can contain a product C? of a Diels-Alder reaction of the two components B) and C).
    Type: Application
    Filed: November 6, 2014
    Publication date: October 20, 2016
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Friedrich Georg SCHMIDT, Stefan Hilf, Michael Kube, Zuhal Tuncay
  • Patent number: 9169363
    Abstract: In the present process, reversibly crosslinking composites or storage-stable prepregs are produced by means of a hetero Diels-Alder reactions (HDA,) for example of PMMA polymers. At slightly elevated temperature, these prepregs can be reversibly decrosslinked again by a retro hetero Diels-Alder reaction so that they become moldable. The back-reaction to products which are again crosslinked or high molecular weight then takes place at room temperature.
    Type: Grant
    Filed: November 6, 2012
    Date of Patent: October 27, 2015
    Assignee: EVONIK DEGUSSA GmbH
    Inventors: Friedrich Georg Schmidt, Stefan Hilf
  • Publication number: 20150299363
    Abstract: The present invention relates to an innovative method for the reversible crosslinking of, for example, adhesives or coating materials, and to a composition stable on storage at room temperature for implementing this crosslinking reaction. The reversible crosslinking method allows very rapid crosslinking even at a low first temperature, and undoing of the crosslinks at higher temperatures, thereby recovering thermoplastic processability and, for example, allowing the originally bonded substrates to be parted from one another again easily. A particular aspect here is that a plurality of cycles of crosslinking and undoing of the crosslinks are possible with the present system. A feature of the system used for the reversible crosslinking is that it consists of two components, A and B, in which component A is a compound comprising at least two protected dithioester functionalities, preferably cyanodithioester functionalities, and component B is a compound having at least two diene functionalities.
    Type: Application
    Filed: November 11, 2013
    Publication date: October 22, 2015
    Applicant: Evonik Roehm GmbH
    Inventors: Christopher BARNER-KOWOLLIK, Kim Klaus OEHLENSCHLAEGER, Stefan HILF, Friedrich Georg SCHMIDT, Nathalie GUIMARD, Jan MUELLER
  • Patent number: 8987380
    Abstract: The present invention relates to an innovative method for controlling the viscosity of, for example, adhesives or coating formulations. The method for controlling viscosity allows very rapid thermoplastic curing of a formulation even at room temperature and a significant reduction in the viscosity at higher temperatures, thereby regaining the capacity for simple processing and allowing, for example, the originally bonded substrates to be separated from one another again with ease. A particular aspect in this context is that a plurality of cycles of thermoplastic curing and a significant reduction in the viscosity are possible with the present system.
    Type: Grant
    Filed: January 4, 2011
    Date of Patent: March 24, 2015
    Assignee: Evonik Roehm GmbH
    Inventors: Stefan Hilf, Friedrich Georg Schmidt, Andre Hennig, Simon Krause, Christopher Barner-Kowollik, Andrew John Inglis, Leena Nebhani
  • Patent number: 8980999
    Abstract: The present invention relates to innovative materials which are reversibly crosslinkable by means of a thermoreversible mechanism and/or whose viscosity is reversibly adjustable. Through the use of bishydrazones or conjugated bis-Schiff bases as diene components in aza-Diels-Alder reactions, functional materials are generated that feature controllable viscosity and/or reversible crosslinking.
    Type: Grant
    Filed: July 27, 2011
    Date of Patent: March 17, 2015
    Assignee: Evonik Röhm GmbH
    Inventors: Friedrich Georg Schmidt, Stefan Hilf, Christopher Barner-Kowollik, Jiawen Zhou
  • Patent number: 8981010
    Abstract: The invention relates to the use of a powder made of a polymer, which of two or more components with functionalities suitable for Diels-Alder reactions, or of a powder mixture (dry blend) made of powders respectively of at least one of the reactive components, where these together enter into the Diels-Alder reaction with one another and are capable of a retro-Diels-Alder reaction, in a rapid-prototyping process. The invention further relates to moldings produced with use of said polymer powder through a layer-by-layer shaping process in which regions of a powder layer are melted selectively. The molding here can be removed from the powder bed after cooling and hardening of the regions previously melted layer-by-layer.
    Type: Grant
    Filed: June 5, 2012
    Date of Patent: March 17, 2015
    Assignee: Evonik Roehm GmbH
    Inventors: Friedrich Georg Schmidt, Stefan Hilf, Jiawen Zhou, Nathalie Guimard, Christopher Barner-Kowollik, Kim Klaus Oehlenschlaeger
  • Patent number: 8969467
    Abstract: The present invention relates to innovative materials which can be crosslinked by means of two different crosslinking mechanisms, the first crosslinking mechanism being an irreversible crosslinking. The second crosslinking mechanism is a thermoreversible mechanism. As a result of this thermoreversible change in the arc length, properties of the crosslinked material can be decisively changed and controlled, including flexibility, elasticity and other mechanical properties, but also chemical properties, the gas permeability and vapor permeability and storage capacity of the network. In this way it would be possible, for example, to store energy sources such as fuels.
    Type: Grant
    Filed: October 12, 2011
    Date of Patent: March 3, 2015
    Assignee: Evonik Roehm GmbH
    Inventors: Stefan Hilf, Friedrich Georg Schmidt, Christopher Barner-Kowollik, Jiawen Zhou