Patents by Inventor Stefan Hilf

Stefan Hilf has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8969467
    Abstract: The present invention relates to innovative materials which can be crosslinked by means of two different crosslinking mechanisms, the first crosslinking mechanism being an irreversible crosslinking. The second crosslinking mechanism is a thermoreversible mechanism. As a result of this thermoreversible change in the arc length, properties of the crosslinked material can be decisively changed and controlled, including flexibility, elasticity and other mechanical properties, but also chemical properties, the gas permeability and vapor permeability and storage capacity of the network. In this way it would be possible, for example, to store energy sources such as fuels.
    Type: Grant
    Filed: October 12, 2011
    Date of Patent: March 3, 2015
    Assignee: Evonik Roehm GmbH
    Inventors: Stefan Hilf, Friedrich Georg Schmidt, Christopher Barner-Kowollik, Jiawen Zhou
  • Patent number: 8916635
    Abstract: The present invention relates to an innovative method for the reversible crosslinking of, for example, adhesives or coating materials. The reversible crosslinking method allows very rapid crosslinking even at room temperature and undoing of the crosslinks at higher temperatures, thereby regaining the capacity for thermoplastic processing and allowing the originally bonded substrates to be separated from one another again with ease. A particular aspect in this context is that a plurality of cycles of crosslinking and undoing of the crosslinks are possible with the present system.
    Type: Grant
    Filed: January 4, 2011
    Date of Patent: December 23, 2014
    Assignee: Evonik Roehm GmbH
    Inventors: Friedrich Georg Schmidt, Simon Krause, Andre Hennig, Stefan Hilf, Christopher Barner-Kowollik, Andrew John Inglis, Leena Nebhani, Ozcan Altintas
  • Publication number: 20140323001
    Abstract: In the present process, reversibly crosslinking composites or storage-stable prepregs are produced by means of a hetero Diels-Alder reactions (HDA,) for example of PMMA polymers. At slightly elevated temperature, these prepregs can be reversibly decrosslinked again by a retro hetero Diels-Alder reaction so that they become moldable. The back-reaction to products which are again crosslinked or high molecular weight then takes place at room temperature.
    Type: Application
    Filed: November 6, 2012
    Publication date: October 30, 2014
    Applicant: Evonik Degussa GmbH
    Inventors: Friedrich Georg Schmidt, Stefan Hilf
  • Publication number: 20140323648
    Abstract: The present invention relates to a novel method for photoinduced crosslinking of, for example, adhesives or coating compositions. More particularly, the present invention relates to a novel, irreversible crosslinking mechanism in which it is possible to obtain, through irradiation with visible light, specific photoactive systems via photoenol reactions controlled high-reactivity diene intermediates which crosslink polymers containing double bonds by means of a Diels-Alder reaction.
    Type: Application
    Filed: December 14, 2012
    Publication date: October 30, 2014
    Applicant: EVONIK INDUSTRIES AG
    Inventors: Friedrich Georg Schmidt, Stefan Hilf, Christopher Barner-Kowollik, Nathalie Guimard, Kim Klaus Oehlenschlaeger, Jan Mueller
  • Publication number: 20140163165
    Abstract: The invention relates to low molecular mass products and to the use thereof as reversible or permanent low-temperature crosslinkers in Diels-Alder reactions.
    Type: Application
    Filed: June 29, 2012
    Publication date: June 12, 2014
    Applicant: Evonik Degussa GmbH
    Inventors: Friedrich Georg Schmidt, Stefan Hilf, Emmanouil Spyrou, Jiawen Zhou, Nathalie Guimard, Christopher Barner-Kowollik, Kim Klaus Oehlenschlaeger, Andre Hennig
  • Publication number: 20140128536
    Abstract: The present invention relates to an innovative (meth)acrylic reactive resin which cures with low odour or odourlessly. The present invention relates more particularly to reactive resins comprising high-boiling, reactive (meth)acrylic monomers from the group of the polar, cyclically substituted esters of (meth)acrylic acid, more particularly glycerol acetal, ketal or carbonate methacrylates. These new components are used as substitutes for MMA, which represents the major part of the odour nuisance in the existing, prior-art reactive resin systems. Using these new components it is possible to obtain resin formulations which have glass transition temperatures similar to, and properties comparable with, MMA-based resins. The innovative reactive resins are able in addition to exhibit more rapid curing than prior-art MMA-based systems. Reactive resins for the purposes of the invention are reactive monomer mixtures or mixtures of monomers and polymers that when used as a 2-component system can be readily cured.
    Type: Application
    Filed: July 2, 2012
    Publication date: May 8, 2014
    Applicant: Evonik Roehm GmbH
    Inventors: Stefan Hilf, Alexander Klein, Heike Heeb, Ingrid Kizewski, Sebastian Grimm, Michael Flittner
  • Publication number: 20140121327
    Abstract: The invention relates to the use of a powder made of a polymer, which of two or more components with functionalities suitable for Diels-Alder reactions, or of a powder mixture (dry blend) made of powders respectively of at least one of the reactive components, where these together enter into the Diels-Alder reaction with one another and are capable of a retro-Diels-Alder reaction, in a rapid-prototyping process. The invention further relates to moldings produced with use of said polymer powder through a layer-by-layer shaping process in which regions of a powder layer are melted selectively. The molding here can be removed from the powder bed after cooling and hardening of the regions previously melted layer-by-layer.
    Type: Application
    Filed: June 5, 2012
    Publication date: May 1, 2014
    Applicant: Evonik Roehm GmbH
    Inventors: Friedrich Georg Schmidt, Stefan Hilf, Jiawen Zhou, Nathalie Guimard, Christopher Barner-Kowollik, Kim Klaus Oehlenschlaeger
  • Publication number: 20130303678
    Abstract: The present invention relates to innovative materials which can be crosslinked by means of two different crosslinking mechanisms, the first crosslinking mechanism being an irreversible crosslinking. The second crosslinking mechanism is a thermoreversible mechanism. As a result of this thermoreversible change in the arc length, properties of the crosslinked material can be decisively changed and controlled, including flexibility, elasticity and other mechanical properties, but also chemical properties, the gas permeability and vapour permeability and storage capacity of the network. In this way it would be possible, for example, to store energy sources such as fuels.
    Type: Application
    Filed: October 12, 2011
    Publication date: November 14, 2013
    Applicant: Evonik Roehm GmbH
    Inventors: Stefan Hilf, Friedrich Georg Schmidt, Christopher Barner-Kowollik, Jiawen Zhou
  • Publication number: 20130289164
    Abstract: The present invention comprises a novel formulation for marking trafficways, for example roads, which when compared with the prior art have improved mechanical properties and improved heat resistance during curing. The invention also relates to improved reactive resins for other applications than roadmarkings. The present invention in particular relates to reactive resins which comprise core-shell particles.
    Type: Application
    Filed: December 15, 2011
    Publication date: October 31, 2013
    Applicant: Evonik Roehm GmbH
    Inventors: Stefan Hilf, Dirk Poppe, Alexander Klein, Heike Heeb, Armin Steffan
  • Publication number: 20130172480
    Abstract: The present invention relates to innovative materials which are reversibly crosslinkable by means of a thermoreversible mechanism and/or whose viscosity is reversibly adjustable. Through the use of bishydrazones or conjugated bis-Schiff bases as diene components in aza-Diels-Alder reactions, functional materials are generated that feature controllable viscosity and/or reversible crosslinking.
    Type: Application
    Filed: July 27, 2011
    Publication date: July 4, 2013
    Applicant: Evonik Roehm GmbH
    Inventors: Friedrich Georg Schmidt, Stefan Hilf, Christopher Barner-Kowollik, Jiawen Zhou
  • Publication number: 20120309895
    Abstract: The present invention relates to an innovative method for the reversible crosslinking of, for example, adhesives or coating materials. The reversible crosslinking method allows very rapid crosslinking even at room temperature and undoing of the crosslinks at higher temperatures, thereby regaining the capacity for thermoplastic processing and allowing the originally bonded substrates to be separated from one another again with ease. A particular aspect in this context is that a plurality of cycles of crosslinking and undoing of the crosslinks are possible with the present system.
    Type: Application
    Filed: January 4, 2011
    Publication date: December 6, 2012
    Applicant: Evonik Roehm GmbH
    Inventors: Friedrich Georg Schmidt, Simon Krause, Andre Hennig, Stefan Hilf, Christopher Barner-Kowollik, Andrew John Inglis, Leena Nebhani, Oezcan Altintas
  • Publication number: 20120289657
    Abstract: The present invention relates to an innovative method for controlling the viscosity of, for example, adhesives or coating formulations. The method for controlling viscosity allows very rapid thermoplastic curing of a formulation even at room temperature and a significant reduction in the viscosity at higher temperatures, thereby regaining the capacity for simple processing and allowing, for example, the originally bonded substrates to be separated from one another again with ease. A particular aspect in this context is that a plurality of cycles of thermoplastic curing and a significant reduction in the viscosity are possible with the present system.
    Type: Application
    Filed: January 4, 2011
    Publication date: November 15, 2012
    Applicant: Evonik Roehm GmbH
    Inventors: Stefan Hilf, Friedrich Georg Schmidt, Andre Hennig, Simon Krause, Christopher Barner-Kowollik, Andrew John Inglis, Leena Nebhani