Abstract: A filter assembly adapted for insertion into an inner chamber of a pressure vessel, wherein the assembly includes: a spiral wound membrane module including at least one membrane envelope and feed spacer sheet concentrically wound about a central permeate tube extending along an axis (X) forming an inlet scroll face and outlet scroll face and a cylindrical outer peripheral surface, and a brine seal disposed concentrically about a portion of the outer peripheral surface; characterized by the brine seal including: i) a radially extending flexible lip defining a maximum outer diameter adapted to engage the inner chamber of the pressure vessel, ii) an end cap surface covering a portion of the first scroll face, and iii) at least one opening in the end cap surface for permitting fluid to flow through the inlet scroll face and into the feed spacer sheet of the module.

Abstract: A method for making a composite polyamide membrane including a porous support and a thin film polyamide layer including the steps of applying a polyfunctional amine monomer and a combination amine-reactive compounds to a surface of the porous support and reacting the constituents to form a thin film polyamide layer, wherein the amine-reactive compounds include: i) a polyfunctional amine-reactive monomer including two to three amine-reactive moieties selected from acyl halide, sulfonyl halide and anhydride, ii) a polyfunctional amine-reactive monomer including at least four amine-reactive moieties selected from acyl halide, sulfonyl halide and anhydride, and iii) an acid compound including at least on carboxylic acid moiety or salt thereof and at least one amine-reactive moiety selected from acyl halide and sulfonyl halide.

Abstract: A method for making a composite polyamide membrane comprising a porous support and a thin film polyamide layer, wherein the method includes the steps of applying a polar solution comprising a polyfunctional amine monomer and a non-polar solution comprising a polyfunctional acyl halide monomer to a surface of a porous support and interfacially polymerizing the monomers to form a thin film polyamide layer. The method is characterized by including a substituted benzamide monomer within the non-polar solution.

Abstract: A filtration assembly including: a hyperfiltration assembly including: a high pressure vessel including a feed port, concentrate port and permeate port, and a plurality of serially arranged spiral wound hyperfiltration membrane modules; a bioreactor assembly including: a low pressure vessel comprising a first and second port, and a plurality of spiral wound bioreactors located within the low pressure vessel with each bioreactor comprising a flat sheet having two opposing bio-growth surfaces and a feed spacer spirally wound about an axis; and a fluid flow pathway extending from a fluid feed source: into the first port of the low pressure vessel, through the bioreactors and out the second port of the low pressure vessel, and into the feed port of the high pressure vessel, through the membrane modules and out of the concentrate port and permeate port.

Abstract: A filtration assembly including: i) a hyperfiltration assembly including: a high pressure vessel including a feed port, concentrate port and permeate port, and a plurality of serially arranged spiral wound hyperfiltration membrane modules; ii) a bioreactor assembly including: a plurality of spiral wound bioreactors each comprising a flat sheet having two opposing bio-growth surfaces and a feed spacer spirally wound about an axis (Y); and iii) a fluid flow pathway adapted for fluid connection with a fluid feed source and extending in a parallel flow pattern through the bioreactors, and subsequently into the feed port of the high pressure vessel, successively through the spiral wound hyperfiltration membrane modules in a serial flow pattern and out of the concentrate port and permeate port.

Abstract: A submerged water purification system including a plurality of spiral wound hyperfiltration membrane modules each connected in a parallel flow arrangement to a common feed manifold and a common permeate manifold; wherein each module includes at least one feed spacer sheet and one membrane envelop wound about a permeate collection tube having a plurality of openings along its length that are in fluid communication with the membrane envelop, and further including an end cap secured to an end of the module with a manifold junction reversibly connected to the end cap of each module, wherein the manifold junction provides a sealed fluid communication between the feed spacer sheets and permeate collection tubes of each module to the feed manifold and permeate manifold, respectively.

Abstract: A water treatment assembly comprising a spiral wound hyperfiltration membrane module connected to: i) a feed line adapted for connection to a source of pressurized feed water, ii) a permeate line adapted for connection to a dispenser of treated water and iii) a concentrate line adapted for connection with drain; wherein the assembly further includes a pressurizable reservoir with valves for selectively diverting flow of pressurized feed water along the feed line, through the reservoir and returning to the feed line prior to passing through the hyperfiltration membrane module.

Abstract: A hyperfiltration system (10) and method for treating water including: a vessel (20) having a feed inlet (22), a permeate outlet (24), and a concentrate outlet (26); at least one spiral wound membrane element (28) located within the vessel (20); a pump (30) having a low pressure side (32) in fluid communication with a source of feed water (40) through a junction point (42) and a high pressure side (34) in fluid communication with the feed inlet (22); a permeate valve (50) connected to the permeate outlet (24) and adapted to selectively direct permeate flow between a treated water outlet (52) and the junction point (42); a flow path (60) between the concentrate outlet (26) and a discharge (62); and a flow restrictor (64) located along the flow path (60) and adapted to vary resistance to concentrate flow between a high and low value.

Abstract: A spiral wound filtration assembly including: i) a pressure vessel comprising a feed port, concentrate port and permeate port; ii) at least one spiral wound membrane module comprising at least one membrane envelop wound around a permeate tube which forms a permeate pathway to the permeate port; and iii) a bioreactor having a cylindrical outer periphery extending along an axis (Y) from a first end to a second end, an inlet located near the first end, and an outlet located near the second end; wherein the spiral wound membrane module and bioreactor are serially arranged within the pressure vessel.

Abstract: A water treatment assembly (10) and method for its operation, comprising a spiral wound hyperfiltration membrane module (12) connected to: i) a feed line (14) adapted for connection to a source of pressurized feed water, ii) a permeate line (16) adapted for connection to a dispenser of treated water and iii) a concentrate line (18) adapted for connection with a drain; wherein the assembly includes a pressurizable reservoir (22) containing weak acid cation exchange resin (25) and further includes at least one valve for selectively diverting flow of pressurized feed water along the feed line (14), through the reservoir (22) and returning to the feed line (14) prior to passing through the hyperfiltration membrane module (12).

Abstract: A spiral wound filtration assembly including: i) a pressure vessel comprising a feed port, concentrate port and permeate port; ii) at least one spiral wound membrane module comprising at least one membrane envelop wound around a permeate tube which forms a permeate pathway to the permeate port; and iii) a bioreactor having a cylindrical outer periphery extending along an axis (Y) from a first end to a second end, an inlet located near the first end, and an outlet located near the second end; wherein the spiral wound membrane module and bioreactor are serially arranged within the pressure vessel.

Abstract: A spiral wound filtration assembly including: i) a pressure vessel comprising a feed port, concentrate port and permeate port; ii) at least one spiral wound membrane module comprising at least one membrane envelop wound around a permeate tube which forms a permeate pathway to the permeate port; and iii) a bioreactor having a cylindrical outer periphery extending along an axis (Y) from a first end to a second end, an inlet located near the first end, and an outlet located near the second end; wherein the spiral wound membrane module and bioreactor are serially arranged within the pressure vessel.

Abstract: A method for making a composite polyamide membrane comprising a porous support and a thin film polyamide layer, wherein the method includes the step of applying a polyfunctional amine monomer and polyfunctional acyl halide monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the step of applying the polyfunctional acyl halide monomer to the porous support includes the step of combining the polyfunctional acyl halide monomer with a non-polar solvent at a concentration of at least 0.18 weight percent to form a coating solution which is applied to the surface of the porous support, and wherein the interfacial polymerization is conducted in the presence of a tri-hydrocarbyl phosphate compound which is provided in a molar ratio of at least 0.5:1 with the polyfunctional acyl halide monomer. Many additional embodiments are described including membranes made from the subject method and applications for such membranes.

Abstract: A method for making a composite polyamide membrane including a porous support and a thin film polyamide layer, wherein the method includes the step of applying a polyfunctional amine monomer and a tetraacyl acyl halide monomer represented by Formula (I) to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer; wherein A is selected from: oxygen (—O—); carbon (—C—); silicon (—Si—); each of which may be unsubstituted or substituted, e.g. with alkyl groups of 1-4 carbon atoms; or a carbonyl group (—C(O)—), X is the same or different and is selected from a halogen, and Y is selected from halogen and hydroxide.

Abstract: A thin film composite polyamide membrane having a porous support and a thin film polyamide layer comprising a reaction product of m-phenylene diamine (mPD) and trimesoyl chloride (TMC), characterized by the thin film polyamide layer having a critical strain value of less than 10%. In another embodiment, the thin film polyamide layer has a modulus of greater than 0.75 (GPa). In yet another embodiment, the thin film polyamide layer has an equilibrium swelling value of at least 45%. In another embodiment, the thin film polyamide layer has a thickness of at least 230 nm.

Abstract: A thin film composite membrane including a porous support and a thin film polyamide layer characterized by having a dissociated carboxylate content of at least 0.45 moles/kg at pH 9.5 and a method for making a composite polyamide applying a polar solution comprising a polyfunctional amine monomer and a non-polar solution comprising a polyfunctional amine-reactive monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is characterized by the non-polar solution comprising at least 0.025 wt % of an acid compound including at least one carboxylic acid moiety and at least one amine-reactive moiety selected from acyl halide and anhydride.

Abstract: A spiral wound membrane module adapted for hyperfiltration and including at least one membrane envelope and feed spacer sheet wound about a central permeate tube to form an inlet and outlet scroll face and an outer periphery, wherein the feed spacer sheet includes: i) a feed entrance section extending along the permeate collection tube from the inlet scroll face toward the outlet scroll face, ii) a feed exit section extending along the outer periphery from the outlet scroll face toward the inlet scroll face, and iii) a central feed section located between the feed entrance section and the feed exit section; and wherein the feed entrance section has a median resistance to flow in a direction parallel to the permeate collection tube that is less than 25% of the median resistance to flow of the central feed section in a direction perpendicular to the permeate collection tube.

Abstract: A spiral wound membrane module (2) comprising at least one membrane envelope (4) wound about a permeate collection tube (8), wherein the module (2) is characterized by a flow controller (54) located within or fixed to the permeate collection tube (8) that provides a flow resistance that varies as a function of permeate flow.

Abstract: A method for making a composite polyamide membrane comprising the steps of applying a polyfunctional amine monomer and polyfunctional acyl halide monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is includes at least one of the following steps: i) conducting the interfacial polymerization in the presence of a monomer comprising at least one phosphorous-containing functional group or salt thereof and an at least one amine-reactive functional group; and/or ii) applying such a monomer to the thin film polyamide layer.

Abstract: A hyperfiltration system (10) and method for treating water including: a vessel (20) having a feed inlet (22), a permeate outlet (24), and a concentrate outlet (26); at least one spiral wound membrane element (28) located within the vessel (20); a pump (30) having a low pressure side (32) in fluid communication with a source of feed water (40) through a junction point (42) and a high pressure side (34) in fluid communication with the feed inlet (22); a permeate valve (50) connected to the permeate outlet (24) and adapted to selectively direct permeate flow between a treated water outlet (52) and the junction point (42); a flow path (60) between the concentrate outlet (26) and a discharge (62); and a flow restrictor (64) located along the flow path (60) and adapted to vary resistance to concentrate flow between a high and low value.