Abstract: A lipophilic/hydrophilic polymer is prepared from a mixture of reactants that includes a polymerizable ethylenically unsaturated alkoxysilane, a polymerizable ethylenically unsaturated hydrophilic monomer, and a polymerizable ethylenically unsaturated lipophilic monomer. The lipophilic/hydrophilic polymer includes at least a pendant and/or terminal alkoxysilane group. An anti-fingerprint coating composition includes the lipophilic/hydrophilic polymer.

Abstract: A lipophilic/hydrophilic polymer is prepared from a mixture of reactants that includes a polymerizable ethylenically unsaturated alkoxysilane, a polymerizable ethylenically unsaturated hydrophilic monomer, and a polymerizable ethylenically unsaturated lipophilic monomer. The lipophilic/hydrophilic polymer includes at least a pendant and/or terminal alkoxysilane group. An anti-fingerprint coating composition includes the lipophilic/hydrophilic polymer.

Abstract: A catalyst composition is provided. The composition comprises at least 30 percent by weight of a catalyst compound based on the total weight of solids in the catalyst composition; and a polymer prepared from ethylenically unsaturated monomers. The polymer either (i) has a backbone derived from substantially hydrophilic monomers and/or monomers containing groups that may be rendered substantially hydrophilic after polymerization, and a plurality of side chains along the backbone derived from substantially hydrophobic monomers, or (ii) has a backbone derived from substantially hydrophobic monomers and a plurality of side chains along the backbone derived from substantially hydrophilic monomers and/or monomers containing groups that may be rendered substantially hydrophilic after polymerization. The catalyst compound is contained within or encapsulated by the polymer. Methods of preparing the catalyst composition and curable compositions containing the catalyst composition are also provided.

Abstract: A catalyst composition is provided. The composition comprises at least 30 percent by weight of a catalyst compound based on the total weight of solids in the catalyst composition; and a polymer prepared from ethylenically unsaturated monomers. The polymer either (i) has a backbone derived from substantially hydrophilic monomers and/or monomers containing groups that may be rendered substantially hydrophilic after polymerization, and a plurality of side chains along the backbone derived from substantially hydrophobic monomers, or (ii) has a backbone derived from substantially hydrophobic monomers and a plurality of side chains along the backbone derived from substantially hydrophilic monomers and/or monomers containing groups that may be rendered substantially hydrophilic after polymerization. The catalyst compound is contained within or encapsulated by the polymer. Methods of preparing the catalyst composition and curable compositions containing the catalyst composition are also provided.

Abstract: Coating compositions comprising a polyurea formed from a reaction mixture comprising: (a) a first component comprising an isocyanate, the first component having a viscosity of ?2000 centipoise at a temperature ?7° C.; and (b) a second component comprising an amine. Substrates coated at least in part with such a composition are also disclosed. Footwear coated at least in part with polyurea are also disclosed.

Abstract: Coating compositions comprising a polyurea formed from a reaction mixture comprising: (a) a first component comprising an isocyanate, the first component having a viscosity of ?2000 centipoise at a temperature ?7° C.; and (b) a second component comprising an amine. Substrates coated at least in part with such a composition are also disclosed. Footwear coated at least in part with polyurea are also disclosed.

Abstract: A coating composition is disclosed comprising polyurea formed from a reaction mixture comprising isocyanate and a triamine/aspartate reaction product resulting from a Michael addition reaction of a triamine with a dialkyl maleate and/or a dialkyl fumarate. The reaction product has a viscosity of less than 2000 cPs, and the triamine has the structure: wherein each n is the same or different and is any integer. Substrates coated with these polyurea coatings comprising this reaction product are also disclosed.

Abstract: The present invention is directed to a coating composition comprising polyurea formed from a reaction mixture comprising: (a) a first component comprising isocyanate, wherein said isocyanate comprises an isocyanate functional prepolymer formed from a reaction mixture comprising isocyanate and a material comprising a phosphorus-containing polyol; and (b) a second component comprising an amine.

Abstract: The present invention is directed to a coating composition comprising polyurea formed from a reaction mixture comprising: (a) a first component comprising isocyanate, wherein said isocyanate comprises an isocyanate functional prepolymer formed from a reaction mixture comprising isocyanate and a material comprising a phosphorus-containing polyol; and (b) a second component comprising an amine.

Abstract: A coating composition is disclosed comprising polyurea formed from a reaction mixture comprising isocyanate and a triamine/aspartate reaction product resulting from a Michael addition reaction of a triamine with a dialkyl maleate and/or a dialkyl fumarate. The reaction product has a viscosity of less than 2000 cPs, and the triamine has the structure: wherein each n is the same or different and is any integer. Substrates coated with these polyurea coatings comprising this reaction product are also disclosed.

Abstract: A metallic substrate coated at least in part with a multilayer coating composite, comprising at least one of an electrocoat layer, a base coat layer, and a clearcoat layer; and a polyurea formed from a reaction mixture comprising isocyanate and a (meth)acrylated amine reaction product of a monoamine and a poly(meth)acrylate is disclosed. The ratio of equivalents of isocyanate groups to equivalents of amine groups in the polyurea is greater than 1 and the isocyanate functional component and the (meth)acrylated amine functional component can be applied to the substrate at a volume mixing ratio of 1:1. A building comprising a building component coated at least in part with such a polyurea is also disclosed, as is a substrate coated at least in part with such a polyurea, wherein the ratio of equivalents or isocyanate to equivalents of amine groups is greater than 1.3:1.

Abstract: Coating compositions comprising a polyurea formed from a reaction mixture comprising isocyanate and an acrylated amine are disclosed. The (meth)acrylated amine is the reaction product of a polyamine and a (meth)acrylate; when the (meth)acrylate comprises a poly(meth)acrylate, the reaction product further comprises a mono(meth)acrylate and/or a monoamine. Methods for using the coatings, and substrates coated therewith, are also disclosed.

Abstract: The reaction product of a triamine and a dialkyl maleate and/or dialkyl fumarate, wherein the reaction product has a viscosity of less than 2000 cPs is disclosed. Polyurea coatings comprising this reaction product are also disclosed, as are substrates coated with the same.

Abstract: Coating compositions comprising a polyurea formed from a reaction mixture comprising isocyanate and a (meth)acrylated amine are disclosed. The (meth)acrylated amine is the reaction product of a polyamine and a mono(meth)acrylate; the ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 and the isocyanate and the (meth)acrylated amine reaction product can be applied to a substrate at a volume mixing ratio of 1:1. Methods for using the coatings, and substrates coated therewith are also disclosed.

Abstract: The present invention is directed to curable, two-package compositions comprising a first and second reactive package. The first reactive package comprises: a) a polyamine component comprising: i) an aspartic ester functional polyamine; and ii) an aromatic polyamine; and b) a rheology modifier. The second reactive package comprises a polyisocyanate, and the curable composition, upon mixing of the reactive packages, demonstrates a gel time of at least 10 minutes.

Abstract: The present invention is directed to a coating composition comprising polyurea formed from a reaction mixture comprising: (a) a first component comprising isocyanate and (b) a second component comprising an amine; and wherein the reaction mixture comprises an anti-oxidant compound a hindered amine light stabilizing compound, or combinations thereof.

Abstract: Curable film-forming compositions comprising a film-forming resin and an organic sol of particles are provided. The sol of particles may be prepared by providing a suspension of particles in an aqueous medium; adding a first organic liquid compatible with the aqueous medium to form an admixture; reacting the particles with a first and a second modifying compound; adding a second organic liquid compatible with the liquid portion of the admixture wherein the second organic liquid is different from the first organic liquid; and maintaining the admixture at a temperature and pressure and for a time sufficient to substantially remove the water and the first organic liquid. The film-forming resin comprises an active hydrogen-functional polymer having low functionality; i.e., a functional group equivalent weight greater than 380 g/equivalent, and a crosslinking agent, yet surprisingly offers outstanding mar and scratch resistance.

Abstract: Coating compositions comprising a polyurea formed from a reaction mixture comprising isocyanate and a (meth)acrylated amine are disclosed. The (meth)acrylated amine is the reaction product of a polyamine and a mono(meth)acrylate; the ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 and the isocyanate and the (meth)acrylated amine reaction product can be applied to a substrate at a volume mixing ratio of 1:1. Methods for using the coatings, and substrates coated therewith are also disclosed.

Abstract: Coating compositions comprising a polyurea formed from a reaction mixture comprising: (a) a first component comprising an isocyanate, the first component having a viscosity of ?2000 centipoise at a temperature ?7° C.; and (b) a second component comprising an amine. Substrates coated at least in part with such a composition are also disclosed. Footwear coated at least in part with polyurea are also disclosed.

Abstract: A composition that includes a non-gelled copolymer that contains residues having structural units (I): where n is an integer from 1 to 10,000; R1 is linear or branched C1 to C4 alkyl; R2 is selected from the group consisting of methyl, linear, cyclic or branched C2 to C20 alkyl, alkenyl, aryl, alkaryl and aralkyl, and R3 is a group resulting from a post polymerization reaction selected from transesterification, transamidification and hydrolysis with a compound selected from hydroxy functional compounds and amine functional compounds. The composition may contain co-reactive functional groups and may be a thermosetting composition. A substrate may be coated with the thermosetting composition singly or as part of a multi-layer composite coating that includes a base coat layer and a substantially pigment free top coat layer.