Patents by Inventor Sumio Iijima

Sumio Iijima has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8114518
    Abstract: This invention provides an aligned single-layer carbon nanotube bulk structure, which comprises an assembly of a plurality of aligned single-layer carbon nanotube and has a height of not less than 10 ?m, and an aligned single-layer carbon nanotube bulk structure which comprises an assembly of a plurality of aligned single-layer carbon nanotubes and has been patterned in a predetermined form. This structure is produced by chemical vapor deposition (CVD) of carbon nanotubes in the presence of a metal catalyst in a reaction atmosphere with an oxidizing agent, preferably water, added thereto. An aligned single-layer carbon nanotube bulk structure, which has realized high purify and significantly large scaled length or height, its production process and apparatus, and its applied products are provided.
    Type: Grant
    Filed: November 12, 2010
    Date of Patent: February 14, 2012
    Assignee: National Institute of Advanced Industrial Science and Technology
    Inventors: Kenji Hata, Sumio Iijima, Motoo Yumura, Don N. Futaba
  • Patent number: 8093174
    Abstract: A carbon nanohorn (CNH) is oxidized to make an opening in the side of the CNH. A substance to be included, e.g., a metal, is introduced through the opening. The inclusion substance is moved to a tip part of the carbon nanohorn through heat treatment in vacuum or an inert gas. The CNH is further heat treated in an atmosphere containing oxygen in a low concentration to remove the carbon layer in the tip through catalysis of the inclusion substance. This exposes the inclusion substance. If the inclusion substance is a metal which is not moved to a tip part by the heat treatment in vacuum or an inert gas, the carbon part surrounding the fine catalyst particle is specifically burned by a heat treatment in an low oxygen concentration atmosphere, while utilizing the catalysis. Thus, the fine catalyst particle is fixed to the tip part of the CNH.
    Type: Grant
    Filed: January 16, 2008
    Date of Patent: January 10, 2012
    Assignee: NEC Corporation
    Inventors: Ryota Yuge, Masako Yudasaka, Sumio Iijima
  • Patent number: 8084505
    Abstract: The present invention provides: a carbon nanohorn composite including a carbon nanohorn, a substance encapsulated in the carbon nanohorn, and a polyamine adsorbed by chemical reaction firmly to a surface functional group present on the opening part on the surface of the carbon nanohorn, wherein the release amount and release rate of the encapsulated substance can be controlled using the difference in size, substituent or three-dimensional structure of the polyamine, which is used as a plug; a method of controlling the release of the encapsulated substance; and a process for producing the carbon nanohorn composite. The release amount and release rate of the substance encapsulated in the carbon nanohorn composite is controlled by selecting a polyamine molecule, which plugs the opening part formed in the carbon nanohorn by oxidation, by its size, substituent or three-dimensional structure.
    Type: Grant
    Filed: July 3, 2007
    Date of Patent: December 27, 2011
    Assignee: NEC Corporation
    Inventors: Ryota Yuge, Hideki Yorimitsu, Masako Yudasaka, Sumio Iijima
  • Patent number: 8007908
    Abstract: A single walled carbon nanohorn adsorptive material which comprises a single walled carbon nanohorn and a lanthanide metal deposited thereon and has methane absorptivity is produced, whereby a single walled carbon nanohorn adsorptive material which can adsorb much methane and is effective as a methane adsorbing material is provided.
    Type: Grant
    Filed: May 31, 2004
    Date of Patent: August 30, 2011
    Assignees: Japan Science and Technology Agency, NEC Corporation
    Inventors: Sumio Iijima, Katsuyuki Murata, Katsumi Kaneko, Masako Yudasaka
  • Patent number: 8007909
    Abstract: Disclosed is a carbon film which has optical characteristics of retaining a high transparency and being high in refractive index and low in double refractivity, is excellent in electric insulating performance, can be applied to various base materials with good adhesiveness, and can be formed at low temperature. Also disclosed is a laminate including a carbon film and a method for producing the laminate.
    Type: Grant
    Filed: April 15, 2005
    Date of Patent: August 30, 2011
    Assignee: National Institute of Advanced Industrial Science & Technology
    Inventors: Yoshinori Koga, Masataka Hasegawa, Sumio Iijima, Kazuo Tsugawa, Masatou Ishihara
  • Publication number: 20110117365
    Abstract: This invention provides an aligned single-layer carbon nanotube bulk structure, which comprises an assembly of a plurality of aligned single-layer carbon nanotube and has a height of not less than 10 ?m, and an aligned single-layer carbon nanotube bulk structure which comprises an assembly of a plurality of aligned single-layer carbon nanotubes and has been patterned in a predetermined form. This structure is produced by chemical vapor deposition (CVD) of carbon nanotubes in the presence of a metal catalyst in a reaction atmosphere with an oxidizing agent, preferably water, added thereto. An aligned single-layer carbon nanotube bulk structure, which has realized high purify and significantly large scaled length or height, its production process and apparatus, and its applied products are provided.
    Type: Application
    Filed: November 12, 2010
    Publication date: May 19, 2011
    Inventors: Kenji Hata, Sumio IIjima, Motoo Yumura, Don N. Futaba
  • Publication number: 20110082034
    Abstract: An object of the present invention is to provide a nanotube-nanohorn complex having an aspect ratio higher than that of a conventional one, also having high dispersibility, and being capable of growing carbon nanotubes with controlled diameter. A nanotube-nanohorn complex according to the present invention comprises carbon nanohorn and catalyst fine particles supported within the carbon nanohorn. The carbon nanohorn comprise an aperture formed therein. Each of the catalyst fine particles is fitted and fixed in the aperture in a state in which part of the catalyst fine particle is exposed to the exterior of the carbon nanohorn. Carbon nanotubes are grown from the catalyst fine particles.
    Type: Application
    Filed: June 18, 2009
    Publication date: April 7, 2011
    Inventors: Ryota Yuge, Sadanori Hattori, Masako Yudasaka, Sumio Iijima
  • Patent number: 7910888
    Abstract: Provided is an X-ray analyzer capable of significantly suppressing an influence of an external magnetic field on a transition edge sensor (TES). The X-ray analyzer includes: a TES (7) for detecting energy of a received X-ray as a temperature change and outputting the temperature change as a current signal; a superconducting magnetic shield (8) which contains the TES (7) and enters a superconducting state; and a room temperature magnetic shield (9) which covers the superconducting magnetic shield (8) and performs external magnetic field shielding until the superconducting magnetic shield (8) enters the superconducting state, in which the superconducting magnetic shield (8) and the room temperature magnetic shield (9) are concentrically arranged to have a cylindrical shape.
    Type: Grant
    Filed: December 23, 2008
    Date of Patent: March 22, 2011
    Assignee: SII NanoTechnology Inc.
    Inventors: Keiichi Tanaka, Akikazu Odawara, Satoshi Nakayama, Sumio Iijima, Shunji Bandow
  • Publication number: 20110008617
    Abstract: This invention provides an aligned single-walled CNT aggregate comprising a substrate, fine particles of iron catalyst with a density of 1×1011 to 1×1014/cm2 disposed on an alumina co-catalyst above the substrate, and a plurality of single-walled CNTs grown from the fine particles of the iron catalyst, in which the plurality of single-walled CNTs have a specific surface area of 600 m2/g to 2600 m2/g, and a weight density from 0.002 g/cm3 to 0.2 g/cm3, and the alignment degree which satisfies a few of specific conditions. This invention also provides a bulk aligned single-walled carbon nanotube aggregate and a powdered aligned single-walled carbon nanotube aggregate.
    Type: Application
    Filed: December 30, 2008
    Publication date: January 13, 2011
    Inventors: Kenji HATA, Sumio IIJIMA, Motoo YUMURA, Don N. FUTABA
  • Patent number: 7854991
    Abstract: This invention provides an aligned single-layer carbon nanotube bulk structure, which comprises an assembly of a plurality of aligned single-layer carbon nanotube and has a height of not less than 10 ?m, and an aligned single-layer carbon nanotube bulk structure which comprises an assembly of a plurality of aligned single-layer carbon nanotubes and has been patterned in a predetermined form. This structure is produced by chemical vapor deposition (CVD) of carbon nanotubes in the presence of a metal catalyst in a reaction atmosphere with an oxidizing agent, preferably water, added thereto. An aligned single-layer carbon nanotube bulk structure, which has realized high purify and significantly large scaled length or height, its production process and apparatus, and its applied products are provided.
    Type: Grant
    Filed: July 27, 2005
    Date of Patent: December 21, 2010
    Assignee: National Institute of Advanced Industrial Science and Technology
    Inventors: Kenji Hata, Sumio Iijima, Motoo Yumura, Don N. Futaba
  • Publication number: 20100272977
    Abstract: The present invention provides a charge exchange member having a new function, which solves problems of fragility of a diamond thin film and a low electron density of a CNTS that are challenges of a charge exchange foil. The present invention relates to a charge exchange device comprising a diamond thin film and a non-woven carbon nanotube sheet, in which the diamond thin film is deposited on the non-woven carbon nanotube sheet.
    Type: Application
    Filed: April 22, 2010
    Publication date: October 28, 2010
    Applicant: National Institute of Advanced Industrial Science and Technology
    Inventors: Masataka HASEGAWA, Takeshi SAITO, Kazutomo SUENAGA, Sumio IIJIMA
  • Patent number: 7803346
    Abstract: A method for selectively obtaining carbon nanotubes having specific structures by selectively obtaining carbon nanotubes having structures different from the structures of the carbon nanotubes to be vanished by irradiating carbon nanotubes with a light beam of single wavelength so as to have carbon nanotubes in specific electron states in the excited states, and oxidizing and combusting the carbon nanotubes in the excited states by an oxygen or an oxidizing agent so as to vanish the same.
    Type: Grant
    Filed: April 1, 2003
    Date of Patent: September 28, 2010
    Assignees: Japan Science and Technology Agency, NEC Corporation
    Inventors: Sumio Iijima, Masako Yudasaka, Minfang Zhang
  • Publication number: 20100202976
    Abstract: A substance-encapsulating carbon nanohorn aggregate which has improved chemical stability by isolating the encapsulated substance from outside and which is useful as a targeting material which can be led from the outside of the body or as a contrast medium by holding the encapsulated substance in an aggregated form, and a process for producing the same are provided. The substance-encapsulating carbon nanohorn aggregate is characterized in that the encapsulated substance is aggregated in a central part of the carbon nanohorn aggregate or a neighborhood thereof with being isolated from outside. The process includes aggregating a substance to be encapsulated in a central part or a neighborhood thereof by a heat treatment.
    Type: Application
    Filed: June 16, 2008
    Publication date: August 12, 2010
    Inventors: Ryota Yuge, Masako Yudasaka, Toshinari Ichihashi, Sumio Iijima
  • Publication number: 20100196249
    Abstract: An aligned carbon nanotube bulk structure capable of attaining high density and high hardness not found so far. The aligned carbon nanotube bulk structure has a plurality of carbon nanotubes (CNTs) applied with a density-increasing treatment, and having alignment in a predetermined direction, the structure has a degree of anisotropy of 1:3 or more between the direction of alignment and the direction vertical to the direction of alignment, and the intensity by irradiating X-rays along the direction of alignment is higher than the intensity by irradiating X-rays from the direction vertical to the direction of alignment at a (002) peak in X-ray diffraction data, and the degree of alignment thereof satisfies predetermined conditions.
    Type: Application
    Filed: August 25, 2009
    Publication date: August 5, 2010
    Inventors: Kenji Hata, Don N. Futaba, Motoo Yumura, Sumio Iijima
  • Publication number: 20100159222
    Abstract: An aligned carbon nanotube bulk structure in which various properties such as density and hardness are controlled depending on the place is provided. An aligned carbon nanotube bulk structure having different density portions is an aligned carbon nanotube bulk structure provided with a high-density portion applied with a density-increasing treatment and an low-density portion and having a plurality of carbon nanotubes (CNT) aligned in a predetermined direction, in which the structure has 1:3 or more of the degree of anisotropy in the alignment direction and in the direction vertical to the alignment direction and, in the (002) peak of the X-ray diffraction data in the high density region, the intensity of X-ray incident along the orientation direction is higher than that of the X-ray intensity from the direction vertical to the alignment direction, and the degree of alignment is defined by specific conditions.
    Type: Application
    Filed: August 25, 2009
    Publication date: June 24, 2010
    Inventors: Kenji Hata, Don N. Futaba, Motoo Yumura, Sumio Iijima
  • Publication number: 20100099551
    Abstract: A carbon nanohorn (CNH) is oxidized to make an opening in the side of the CNH. A substance to be included, e.g., a metal, is introduced through the opening. The inclusion substance is moved to a tip part of the carbon nanohorn through heat treatment in vacuum or an inert gas. The CNH is further heat treated in an atmosphere containing oxygen in a low concentration to remove the carbon layer in the tip through catalysis of the inclusion substance. This exposes the inclusion substance. If the inclusion substance is a metal which is not moved to a tip part by the heat treatment in vacuum or an inert gas, the carbon part surrounding the fine catalyst particle is specifically burned by a heat treatment in an low oxygen concentration atmosphere, while utilizing the catalysis. Thus, the fine catalyst particle is fixed to the tip part of the CNH.
    Type: Application
    Filed: January 16, 2008
    Publication date: April 22, 2010
    Applicant: NEC CORPORATION
    Inventors: Ryota Yuge, Masako Yodasaka, Sumio Iijima
  • Publication number: 20100075835
    Abstract: A nanocarbon aggregate including a graphite aggregate including a graphene sheet having a petal shape and a nanohorn. The petal-shaped graphite aggregate achieves a reduction in the particulate size and a higher dispersibility by allowing the edge of the petal shape to locally absorb a metal, a metal complex and a metal oxide. The nanocarbon aggregate is used for a catalyst support.
    Type: Application
    Filed: January 29, 2008
    Publication date: March 25, 2010
    Applicant: NEC CORPORATION
    Inventors: Ryota Yuge, Masako Yudasaka, Sumio Iijima
  • Publication number: 20100025222
    Abstract: Provided are a method of forming pores in a graphitic carbon nanomaterial and a method of introducing an oxygen-containing group into the pores, in which the rate of pore formation in the wall of a graphitic carbon nanomaterial can be heightened and the amount of the oxygen-containing group, especially the carboxyl group to be introduced can be significantly increased. The method of forming pores in a graphitic carbon nanomaterial of the invention is characterized by forming pores in the wall of a graphitic carbon nanomaterial in the presence of an oxidizing agent while the nanomaterial is irradiated with a light from a light source including a light having a wavelength at which the oxidizing agent is activated.
    Type: Application
    Filed: November 16, 2007
    Publication date: February 4, 2010
    Applicant: NEC CORPORATION
    Inventors: Sumio Iijima, Masako Yudasaka, Minfang Zhang
  • Publication number: 20090301861
    Abstract: An apparatus for manufacturing carbon nanohorns includes a production chamber configured to irradiate a solid carbon material with a laser beam to produce a product containing carbon nanohorns; and a separation mechanism configured to separate the product produced in the production chamber into a lightweight component and a heavyweight component. The heavyweight component includes carbon nanohorn aggregate with high purity, and high-purity carbon nanotubes can be obtained by collecting the heavyweight component.
    Type: Application
    Filed: April 19, 2007
    Publication date: December 10, 2009
    Inventors: Takeshi Azami, Daisuke Kasuya, Tsutomu Yoshitake, Yoshimi Kubo, Masako Yudasaka, Sumio Iijima, Eiji Fuchita
  • Publication number: 20090297846
    Abstract: An aligned double-walled carbon nanotube bulk structure composed of plural aligned double-walled carbon nanotubes and having a height of 0.1 ?m or more and a double-walled carbon nanotube are produced by chemically vapor depositing (CVD) a carbon nanotube in the presence of a metal catalyst with controlled particle size and thickness, preferably in the presence of moisture. According to this, it is possible to provide a double-walled nanotube which is free from inclusion of the catalyst, has high purity, is easy to control the alignment and growth, is able to achieve the fabrication through the formation of a bulk structure and has excellent electron emission characteristic (particularly, a double-walled carbon nanotube bulk structure) and also to provide a production technology thereof.
    Type: Application
    Filed: November 27, 2006
    Publication date: December 3, 2009
    Inventors: Kenji Hata, Takeo Yamada, Motoo Yumura, Sumio Iijima