Abstract: A solid electrolyte membrane for a solid-state battery and a battery comprising the same is provided. The battery may comprise lithium metal as a negative electrode active material. The solid electrolyte membrane comprises an inhibiting layer, which is preferably capable of inhibiting growth of lithium dendrite, because it includes an effective amount of a dendrite growth-inhibiting material, which is capable of ionizing lithium deposited in the form of metal. Thus, when lithium metal is used as a negative electrode for a solid-state battery comprising the solid electrolyte membrane, it is possible to delay and/or inhibit growth of lithium dendrite, and thus to effectively prevent an electrical short-circuit caused by dendrite growth.

Abstract: The present disclosure relates to an electrode for an all solid-state battery and a manufacturing method thereof, and a mixture of a polymer-based solid electrolyte and a conductive material is filled between electrode active material particles that constitute an electrode active material layer, to increase the contact between the electrode active material particles and the conductive material through a solvent annealing process included in a manufacturing process, thereby improving ionic conductivity in the electrode and capacity in the electrode.

Abstract: A solid electrolyte membrane and method of preparing, including a plurality of polymer filaments arranged crossed as a 3-dimensional structure in the form of a net of nonwoven fabric-like shape, and a plurality of inorganic solid electrolytes inserted and uniformly distributed in the structure. By this structural feature, a large amount of solid electrolyte particles are uniformly distributed and filled in the electrolyte membrane, contact between the particles is good, and ionic conduction paths are sufficiently provided. Additionally, the durability of the solid electrolyte membrane is improved by the 3-dimensional structure, and the flexibility and strength increase. The nonwoven fabric composite solid electrolyte membrane has an effect in preventing inorganic solid electrolyte particle from being disconnected therefrom.

Abstract: The present disclosure relates to an all solid-state battery cell and a method for manufacturing the same. The gaps between the electrode active material particles forming the electrode active material layer are filled with a mixture of a polymeric solid electrolyte with a conductive material, and an organic solid electrolyte membrane is interposed between the positive electrode and the negative electrode. The method comprises a solvent annealing process to improve the contact between the electrode active material particles and the conductive material and to improve the contact between the electrode active material layer and the organic solid electrolyte membrane, thereby providing an all solid-state battery cell with improved ion conductivity and capacity realization.

Abstract: A solid electrolyte membrane and a solid-state battery including the same are provided. The solid electrolyte membrane includes composite particles having pores filled with a phase transformation material as fillers, which provides high ion conductivity and mechanical strength of the solid electrolyte membrane, while minimizing the amount of the phase transformation material.

Abstract: Disclosed are an electrode having a three-dimensional structure, the electrode including: a porous nonwoven web including a plurality of polymer fibers that form an interconnected porous network; an active material composite positioned among the polymer fibers and including active material particles and a first conductive material; and a second conductive material positioned on an outer surface of the active material composite, wherein the interconnected porous network is filled homogeneously with the active material composite and the second conductive material to form a super lattice structure, and an electrochemical device including the electrode having a three-dimensional structure.

Abstract: An electrode for a solid state battery is provided. The electrode active material layer of the electrode shows improved mechanical properties, such as elasticity or rigidity, of the electrode layer through the crosslinking of a binder resin. Thus, it is possible to inhibit or reduce the effect of swelling and/or shrinking of the electrode active material during charging/discharging. Therefore, the interfacial adhesion between the electrode active material layer and an electrolyte layer and the interfacial adhesion between the electrode active material layer and a current collector are maintained to a high level to provide a solid state battery having excellent cycle characteristics.

Abstract: Provided is a composite solid electrolyte membrane for an all-solid-state secondary battery, including: a phase transformation layer containing a plasticizer and a lithium salt; a porous polymer sheet layer; and a solid polymer electrolyte layer, wherein the phase transformation layer, the porous polymer sheet layer and the solid polymer electrolyte layer are stacked successively, and the phase transformation layer is disposed in such a manner that it faces a negative electrode when manufacturing an electrode assembly. An all-solid-state secondary battery including the composite solid electrolyte membrane is also provided. The composite solid electrolyte membrane for an all-solid-state secondary battery reduces the interfacial resistance with an electrode, increases ion conductivity, and improves the safety of a battery.

Abstract: The solid electrolyte membrane according to the present disclosure interrupts migration of lithium ions by the formation of an ion conduction-interrupting layer in the electrolyte membrane through the phase separation of polymers under a high-temperature condition, including an increase in the internal temperature of a battery. Since a battery is prevented from thermal runaway and explosion through the formation of the ‘ion conduction-interrupting layer’ (also referred to as ‘interrupting layer’), it is possible to improve the heat resistance and safety of the battery.

Abstract: The present disclosure relates to a positive electrode for a solid electrolyte battery which includes: a positive electrode current collector; a first positive electrode active material layer formed on at least one surface of the positive electrode current collector and including a first positive electrode active material, a first solid electrolyte and a first electrolyte salt; and a second positive electrode active material layer formed on the first positive electrode active material layer and including a second positive electrode active material, a second solid electrolyte, a second electrolyte salt and a plasticizer, wherein the plasticizer has a melting point of 30-130° C. The present disclosure also relates to a solid electrolyte battery including the positive electrode.

Abstract: The solid electrolyte membrane according to the present disclosure forms an ion conduction-interrupting layer therein by polymer phase separation under a high temperature condition, such as an increase in internal temperature of a battery, and thus interrupts lithium ion transport. Therefore, it is possible to prevent thermal runaway and explosion of a battery by the formed ion conduction-interrupting layer (also referred to as interrupting layer), and thus to improve the heat resistance and safety of the battery.

Abstract: A solid electrolyte membrane and method of preparing, including a plurality of polymer filaments arranged crossed as a 3-dimensional structure in the form of a net of nonwoven fabric-like shape, and a plurality of inorganic solid electrolytes inserted and uniformly distributed in the structure. By this structural feature, a large amount of solid electrolyte particles are uniformly distributed and filled in the electrolyte membrane, contact between the particles is good, and ionic conduction paths are sufficiently provided. Additionally, the durability of the solid electrolyte membrane is improved by the 3-dimensional structure, and the flexibility and strength increase. The nonwoven fabric composite solid electrolyte membrane has an effect in preventing inorganic solid electrolyte particle from being disconnected therefrom.

Abstract: Provided is a solid electrolyte membrane for a solid-state battery, including at least two solid electrolyte layers and at least one volume-swelling layer, wherein the volume-swelling layer is disposed between the solid electrolyte layers. The solid electrolyte membrane includes (a) an ion conductive solid electrolyte material, and the volume-swelling layer includes (b) inorganic particles, wherein the inorganic particles form an alloy with lithium and include a metal, metal oxide or both. Thus, it is possible to provide a solid electrolyte membrane for a solid-state battery fundamentally prevented from a short-circuit by inhibiting growth of lithium dendrite.

Abstract: The present disclosure relates to a solid electrolyte battery including a negative electrode including: a negative electrode current collector; a first negative electrode active material layer formed on at least one surface of the negative electrode current collector and including a first negative electrode active material, a first solid electrolyte and a first electrolyte salt; and a second negative electrode active material layer formed on the first negative electrode active material layer and including a second negative electrode active material, a second solid electrolyte, a second electrolyte salt and a plasticizer having a melting point of 30-130° C., the solid electrolyte battery is activated at a temperature between the melting point of the plasticizer and 130° C., and a solid electrolyte interface (SEI) layer is formed on the surface of the second negative electrode active material.

Abstract: Disclosed are a solid-liquid hybrid electrolyte membrane including a plurality of solid polymer particles and a small amount of liquid electrolyte, wherein the solid polymer particles are packed, while being in contact with one another, and include a porous structure having a pore structure formed among the solid polymer particles, and the liquid electrolyte surrounds the inside of the pores of the porous structure, the portions in which the solid polymer particles are in surface contact with one another, or the surfaces of the solid polymer particles, and a method for manufacturing the same. It is possible to provide a solid-liquid hybrid electrolyte membrane, which can be deformed by external pressurization, by using no solid electrolyte. It is also possible to provide a solid-liquid hybrid electrolyte membrane showing low resistance by using no binder polymer.

Abstract: Provided is provided a lithium metal battery which includes a composite solid electrolyte membrane interposed between a lithium metal negative electrode and a positive electrode, wherein the composite solid electrolyte membrane includes: a phase transformation layer containing a plasticizer and a lithium salt; a porous polymer sheet layer; and a solid polymer electrolyte layer, the phase transformation layer, the porous polymer sheet layer and the solid polymer electrolyte layer stacked successively, and the phase transformation layer is disposed in such a manner that it faces the lithium metal negative electrode. The lithium metal battery shows reduced resistance at the interface with an electrode and increased ion conductivity, has improved safety, and provides improved energy density of an electrode.

Abstract: A solid electrolyte membrane and method of preparing, including a plurality of polymer filaments arranged crossed as a 3-dimensional structure in the form of a net of nonwoven fabric-like shape, and a plurality of inorganic solid electrolytes inserted and uniformly distributed in the structure. By this structural feature, a large amount of solid electrolyte particles are uniformly distributed and filled in the electrolyte membrane, contact between the particles is good, and ionic conduction paths are sufficiently provided. Additionally, the durability of the solid electrolyte membrane is improved by the 3-dimensional structure, and the flexibility and strength increase. The nonwoven fabric composite solid electrolyte membrane has an effect in preventing inorganic solid electrolyte particle from being disconnected therefrom.

Abstract: A flexible secondary battery includes: a first electrode including a first electrode current collector extended longitudinally, a first electrode active material layer formed on the outside of the first electrode current collector, and a first insulation coating layer formed on the outside of the first electrode active material layer; and a second electrode including a second electrode current collector extended longitudinally, a second electrode active material layer formed on the outside of the second electrode current collector, and a second insulation coating layer formed on the outside of the second electrode active material layer, wherein the first electrode and the second electrode are wound in such a manner that they are disposed alternately in contact with each other.

Abstract: In a solid electrolyte membrane according to the present disclosure, an ion conduction blocking layer is formed in the electrolyte membrane by a polymer material having low ionic conductivity by phase separation of polymer under the high temperature condition such as an increase in the internal temperature of a battery, to block the movement of lithium ions. The formed ion conduction blocking layer (hereinafter referred to as blocking layer) prevents thermal runaway and consequential explosions of the battery, thereby improving the heat resistance safety of the battery.

Abstract: A lithium metal electrode includes a current collector having a surface irregularity structure, a lithium metal layer disposed outside of the surface irregularity structure except the uppermost surface of the surface irregularity structure in the current collector, an electron-insulating protective layer disposed outside of the lithium metal layer, and a lithium ion-isolating layer disposed (1) on the uppermost surface of the surface irregularity structure of the current collector, or (2) on the uppermost surface of the surface irregularity structure of the current collector, on the uppermost surface of the lithium metal layer, and on the uppermost surface of the electron-insulating protective layer, wherein the electron-insulating protective layer includes a non-porous layer transporting lithium ions and having no pores, and a polymer porous layer disposed outside thereof. A lithium secondary battery and flexible secondary battery including the lithium metal electrode are also provided.