Abstract: The present disclosure relates to semiconductor structures and, more particularly, to via structures and via patterning using oblique angle deposition processes. The method includes: depositing a material on a lower wiring layer; forming one or more openings in the material; filling the one or more openings with a conductive material; growing via structures on the conductive material; forming interlevel dielectric material on the via structures; and forming an upper wiring layer on the interlevel dielectric material and in contact with the via structures.

Abstract: The present disclosure generally relates to semiconductor structures and, more particularly, to smooth sidewall structures and methods of manufacture. The method includes: forming a plurality of mandrel structures; forming a first spacer material on each of the plurality of mandrel structures; forming a second spacer material over the first spacer material; and removing the first spacer material and the plurality of mandrel structures to form a sidewall structure having a sidewall smoothness greater than the plurality of mandrel structures.

Abstract: The present disclosure relates to semiconductor structures and, more particularly, to via structures and via patterning using oblique angle deposition processes. The method includes: depositing a material on a lower wiring layer; forming one or more openings in the material; filling the one or more openings with a conductive material; growing via structures on the conductive material; forming interlevel dielectric material on the via structures; and forming an upper wiring layer on the interlevel dielectric material and in contact with the via structures.

Abstract: Methods of fabricating an interconnect structure. A hardmask is deposited over a dielectric layer, and a block mask is formed that is arranged over an area on the hardmask. After forming the block mask, a first mandrel and a second mandrel are formed on the hardmask. The first mandrel is laterally spaced from the second mandrel, and the area on the hardmask is arranged between the first mandrel and the second mandrel. The block mask may be used to provide a non-mandrel cut separating the tips of interconnects subsequently formed in the dielectric layer.

Abstract: A first layer on a substrate includes an insulator material portion adjacent an energy-reactive material portion. The energy-reactive material portion evaporates upon application of energy during manufacturing. Processing patterns the first layer to include recesses extending to the substrate in at least the energy-reactive material portion. The recesses are filled with a conductor material, and a porous material layer is formed on the first layer and on the conductor material. Energy is applied to the porous material layer to: cause the energy to pass through the porous material layer and reach the energy-reactive material portion; cause the energy-reactive material portion to evaporate; and fully remove the energy-reactive material portion from an area between the substrate and the porous material layer, and this leaves a void between the substrate and the porous material layer and adjacent to the conductor material.

Abstract: This disclosure is directed to an integrated circuit (IC) structure. The IC structure may include a semiconductor structure including two source/drain regions; a metal gate positioned on the semiconductor structure adjacent to and between the source/drain regions; a metal cap with a different metal composition than the metal gate and having a thickness in the range of approximately 0.5 nanometer (nm) to approximately 5 nm positioned on the metal gate; a first dielectric cap layer positioned above the semiconductor structure; an inter-layer dielectric (ILD) positioned above the semiconductor structure and laterally abutting both the metal cap and the metal gate, wherein an upper surface of the ILD has a greater height above the semiconductor structure than an upper surface of the metal gate; a second dielectric cap layer positioned on the ILD and above the metal cap; and a contact on and in electrical contact with the metal cap.

Abstract: Methods of lithographic patterning to form interconnect structures for a chip. A hardmask layer is formed on a dielectric layer. A sacrificial layer is formed on the hardmask layer. First opening and second openings are formed in the sacrificial layer that extend through the sacrificial layer to the hardmask layer. A resist layer is formed on the sacrificial layer. An opening is formed in the resist layer that is laterally located between the first opening in the first sacrificial layer and the second opening in the first sacrificial layer. The resist layer is comprised of a metal oxide resist material that is removable selective to the hardmask layer.

Abstract: Methods of lithographic patterning a dielectric layer. A first resist layer is formed on a hardmask layer, and a second resist layer is formed on the first resist layer. The second resist layer is patterned to form a first opening, which is transferred from the second resist layer to the first resist layer. The second resist layer is removed from the first resist layer after the first opening is transferred from the second resist layer to the first resist layer. The first resist layer is patterned to form a second opening laterally displaced in the first resist layer from the first opening. The first resist layer is comprised of a metal oxide photoresist that is removable selective to the hardmask layer. The hardmask layer and the dielectric layer may be subsequently patterned using first resist layer.

Abstract: A first layer on a substrate includes an insulator material portion adjacent an energy-reactive material portion. The energy-reactive material portion evaporates upon application of energy during manufacturing. Processing patterns the first layer to include recesses extending to the substrate in at least the energy-reactive material portion. The recesses are filled with a conductor material, and a porous material layer is formed on the first layer and on the conductor material. Energy is applied to the porous material layer to: cause the energy to pass through the porous material layer and reach the energy-reactive material portion; cause the energy-reactive material portion to evaporate; and fully remove the energy-reactive material portion from an area between the substrate and the porous material layer, and this leaves a void between the substrate and the porous material layer and adjacent to the conductor material.

Abstract: Interconnect structures and methods for forming an interconnect structure. A dielectric layer of a metallization level is deposited and a trench is patterned in the dielectric layer. A sacrificial layer is formed in the trench in the dielectric layer. The sacrificial layer is patterned to form a first trench and a second trench separated from the first trench by a section of the sacrificial layer. A first metal interconnect is formed in the first trench, a second metal interconnect is formed in the second trench, and a porous cap layer is formed over the first metal interconnect, the second metal interconnect, and the section of the sacrificial layer. After forming the porous cap layer, the section of the sacrificial layer is removed.

Abstract: In an exemplary method, a first dielectric layer is formed on a substrate. A second dielectric layer is formed on the first dielectric layer. The second dielectric layer is a carbon rich film and different from the first dielectric layer. A trench is formed through the first and second dielectric layers. A conductive line is formed in the trench. A third dielectric layer is formed on the second dielectric layer and conductive line. The material of the third dielectric layer is different from the second dielectric layer. A via opening is formed through the third dielectric layer and stops at the second dielectric layer with a portion of the conductive line exposed to the via opening. At the bottom of the via opening, a recess is formed in the second dielectric layer adjacent to the conductive line. The via opening and recess are filled with a conductive material contacting the conductive line.

Abstract: A litho-litho-etch double patterning method including forming a resist layer by coating a substrate with a resist composition; exposing the resist layer to a first radiant energy density of UV rays; forming a first pattern in the resist layer by developing the resist layer with a positive developer; exposing the resist layer to a second radiant energy density of UV rays; and forming a second pattern in the resist layer by developing the resist layer with a negative developer, the second pattern including one or more features of the first pattern.

Abstract: Methods of forming an interconnect of an IC are disclosed. The methods etch a wire trench opening partially into an ILD layer using a hard mask, and form a metal liner sidewall spacer on sidewalls of the wire trench opening, prior to etching via openings that create a via-wire opening with the wire trench opening. The metal liner sidewall spacer protects against chamfering during the via etch and/or removal of an etch stop layer over conductive structures in an underlying ILD layer. In one embodiment, a barrier liner is deposited over the metal liner sidewall spacer, creating a double layered sidewall spacer on the sidewalls of the wire trench opening portion of the via-wire opening. A conductor is deposited to form a unitary via-wire conductive structure. An interconnect includes the double layered sidewall spacer on the sidewalls of a wire trench opening portion of the via-wire conductive structure.

Abstract: Interconnect structures and methods for forming an interconnect structure. First and second metallization structures are formed in an intralayer dielectric layer. The intralayer dielectric layer is removed to form a cavity with an entrance between the first and second metallization structures. A dielectric layer is deposited on surfaces surrounding the cavity, over the first metallization structure, and over the second metallization structure. A sacrificial material is formed inside the cavity after the dielectric layer is deposited. A cap layer is deposited on the dielectric layer over the first metallization structure, the dielectric layer over the second metallization structure, and the sacrificial material inside the cavity to close the entrance to the cavity. After the cap layer is deposited, the sacrificial material is removed from the cavity. The dielectric layer and cap layer cooperate to encapsulate an air gap inside the cavity.

Abstract: An integrated circuit (IC) structure including an interconnect structure is disclosed. The interconnect structure may include a first etch stop layer (ESL) positioned between an initial via layer and a first metal layer of the interconnect structure. The ESL may be positioned adjacent to and surround a metal wire in the first metal layer. A method of forming an interconnect structure is also disclosed. The method may include forming an opening in a first dielectric layer above a substrate; forming a sacrificial semiconductor material in the opening; forming an ESL on the first dielectric layer and sacrificial semiconductor material; forming a second dielectric layer on the ESL; forming an opening in the second dielectric layer to expose a portion of the ESL; removing the exposed portion of the ESL; removing the sacrificial semiconductor material; and forming a conductive material in the openings to form an interconnect structure.

Abstract: A litho-litho-etch double patterning method including forming a resist layer by coating a substrate with a resist composition; exposing the resist layer to a first radiant energy density of UV rays; forming a first pattern in the resist layer by developing the resist layer with a positive developer; exposing the resist layer to a second radiant energy density of UV rays; and forming a second pattern in the resist layer by developing the resist layer with a negative developer, the second pattern including one or more features of the first pattern.

Abstract: A first layer on a substrate includes an insulator material portion adjacent an energy-reactive material portion. The energy-reactive material portion evaporates upon application of energy during manufacturing. Processing patterns the first layer to include recesses extending to the substrate in at least the energy-reactive material portion. The recesses are filled with a conductor material, and a porous material layer is formed on the first layer and on the conductor material. Energy is applied to the porous material layer to: cause the energy to pass through the porous material layer and reach the energy-reactive material portion; cause the energy-reactive material portion to evaporate; and fully remove the energy-reactive material portion from an area between the substrate and the porous material layer, and this leaves a void between the substrate and the porous material layer and adjacent to the conductor material.

Abstract: Interconnect structures and methods for forming an interconnect structure. A sacrificial layer is formed on a substrate and an interconnect opening is formed that extends vertically through the sacrificial layer into the substrate. The interconnect opening is filled with a conductor to form a conductive feature. After filling the interconnect opening with the conductor, a dielectric layer is formed on the sacrificial layer. After the dielectric layer is formed on the sacrificial layer, the sacrificial layer is removed to form an air gap layer arranged vertically between the dielectric layer and the substrate.

Abstract: The present disclosure describes a method or forming vertical natural capacitor (VNCAP) and the resulting device. The method includes applying a patterned mask over an insulation layer. The method includes forming using the patterned mask, a dielectric trench in the insulation layer. The method includes depositing a high dielectric constant k (high k) layer in the dielectric trench. The method includes forming a first trench and a second trench in the high k dielectric layer. The high k dielectric layer is disposed between the first trench and the second trench. The method includes depositing metal in the first trench and the second trench.

Abstract: A reflective mask with an embedded absorber pattern is provided. The reflective mask may include a low thermal expansion material (LTEM) substrate. A pair of reflective stacks may be included, each reflective stack having a first respective top surface extending from the LTEM substrate to a first extent. A fill stack is between the pair of reflective stacks, the fill stack having a second top surface extending from the LTEM substrate to a second extent, the second extent being below the first extent of the pair of reflective stacks. An extended portion of each of the pair of reflective stacks is above the fill stack thereby forming a recess well between the pair of reflective stacks, the recess well having substantially vertical walls separated by the second top surface of the fill stack. An absorber layer lining the recess well.