Abstract: Some embodiments relate to a semiconductor device manufacturing process. In the process, a substrate is provided, and a sacrificial layer is formed over the substrate. An opening is patterned through the sacrificial layer, and the opening is filled with conductive material. The sacrificial layer is removed while the conductive material is left in place. A first dielectric layer is formed along sidewalls of the conductive material that was left in place.

Abstract: Some embodiments relate to a semiconductor device manufacturing process. In the process, a substrate is provided, and a sacrificial layer is formed over the substrate. An opening is patterned through the sacrificial layer, and the opening is filled with conductive material. The sacrificial layer is removed while the conductive material is left in place. A first dielectric layer is formed along sidewalls of the conductive material that was left in place.

Abstract: The disclosure is directed to a method for lithographic patterning. The method may include: exposing a photoresist to a radiant energy; developing the photoresist in a first developer, thereby creating an opening within the photoresist including sidewalls having a slant; and developing the photoresist in a second developer immediately after the developing of the photoresist in the first developer, thereby reducing the slant of the sidewalls of the opening. Where the photoresist is a positive tone development (PTD) photoresist, the first developer may include a positive developer, and the second developer may include a negative developer. Where the photoresist is a negative tone development (NTD) photoresist, the first developer may include a negative developer, and the second developer may include a positive developer.

Abstract: The present invention relates to a novel formulation, comprising Anacardic acid or its derivatives and phytohormones (1-NAA and GA3), which promotes the increase in fiber yield and improvement in fiber quality. The in-vitro ovule culture assay was used to check the effect of formulation on initiation and development of cotton fiber. Increased initiation and length of cotton fibers was observed in the cultured ovules treated with the formulation which were validated by biochemical assays. The formulation was applied directly onto the at least 70 plants of Gossypium hirsutum genotypes in three replicates with control plants treated with phytohormones only. The formulation was applied by spraying on buds, flowers and bolls. The treated plants show significant increase in boll weight, fiber length, fineness and fiber strength. Thus, the formulation may serve as an important plant growth stimulator leading to the increase in fiber yield and improvement in fiber quality in cotton plants.

Abstract: Methodologies and a device for reducing capacitance and improving profile control are provided. Embodiments include forming metal vias in a first dielectric layer; forming a graded interlayer dielectric over the metal vias; forming a metal layer in the graded ILD over one of the metal vias; and forming a hydrogenated amorphous silicon carbon film over the metal layer.

Abstract: During formation of a trench silicide contact, a sacrificial layer is incorporated into the trench directly over source/drain junctions prior to metallization of the trench. Selective removal of the sacrificial layer widens the trench proximate to the source/drain junctions, increasing the contact area and correspondingly decreasing the contact resistance between the source/drain junctions and a silicide layer.

Abstract: A method can include applying a patterned mask over a semiconductor structure, the semiconductor structure having a dielectric layer, forming using the patterned mask a material formation trench intermediate first and second spaced apart metal formations formed in the dielectric layer, and disposing a dielectric material formation in the material formation trench.

Abstract: The present invention relates to a novel formulation, comprising Anacardic acid or its derivatives and phytohormones (1-NAA and GA3), which promotes the increase in fiber yield and improvement in fiber quality. The in-vitro ovule culture assay was used to check the effect of formulation on initiation and development of cotton fiber. Increased initiation and length of cotton fibers was observed in the cultured ovules treated with the formulation which were validated by biochemical assays. The formulation was applied directly onto the at least 70 plants of Gossypium hirsutum genotypes in three replicates with control plants treated with phytohormones only. The formulation was applied by spraying on buds, flowers and bolls. The treated plants show significant increase in boll weight, fiber length, fineness and fiber strength. Thus, the formulation may serve as an important plant growth stimulator leading to the increase in fiber yield and improvement in fiber quality in cotton plants.

Abstract: Some embodiments relate to a semiconductor device manufacturing process. In the process, a substrate is provided, and a sacrificial layer is formed over the substrate. An opening is patterned through the sacrificial layer, and the opening is filled with conductive material. The sacrificial layer is removed while the conductive material is left in place. A first dielectric layer is formed along sidewalls of the conductive material that was left in place.

Abstract: A method can include applying a patterned mask over a semiconductor structure, the semiconductor structure having a dielectric layer, forming using the patterned mask a material formation trench intermediate first and second spaced apart metal formations formed in the dielectric layer, and disposing a dielectric material formation in the material formation trench.

Abstract: A method of forming a dual damascene metal interconnect for a semiconductor device. The method includes forming a layer of low-k dielectric, forming vias through the low-k dielectric layer, depositing a sacrificial layer, forming trenches through the sacrificial layer, filling the vias and trenches with metal, removing the sacrificial layer, then depositing an extremely low-k dielectric layer to fill between the trenches. The method allows the formation of an extremely low-k dielectric layer for the second level of the dual damascene structure while avoiding damage to that layer by such processes as trench etching and trench metal deposition. The method has the additional advantage of avoiding an etch stop layer between the via level dielectric and the trench level dielectric.

Abstract: A method of reducing defects in and improving reliability of Back-End-Of-Line (BEOL) metal fill includes providing a starting metallization structure for semiconductor device(s), the metallization structure including a bottom layer of contact(s) surrounded by a dielectric material. The starting metallization structure further includes an etch-stop layer over the bottom layer, a layer of dielectric material over the etch-stop layer, a first layer of hard mask material over the dielectric layer, a layer of work function hard mask material over the first hard mask layer, a second layer of hard mask material over the work function hard mask layer, via(s) to the first hard mask layer and other via(s) into the etch-stop layer. The method further includes protecting the other via(s) while removing the second hard mask layer and the layer of work function hard mask material, and filling the vias with metal.

Abstract: A method can include applying a patterned mask over a semiconductor structure, the semiconductor structure having a dielectric layer, forming using the patterned mask a material formation trench intermediate first and second spaced apart metal formations formed in the dielectric layer, and disposing a dielectric material formation in the material formation trench.

Abstract: Methodologies and a device for reducing capacitance and improving profile control are provided. Embodiments include forming metal vias in a first dielectric layer; forming a graded interlayer dielectric over the metal vias; forming a metal layer in the graded ILD over one of the metal vias; and forming a hydrogenated amorphous silicon carbon film over the metal layer.

Abstract: Metal filling processes for semiconductor devices and methods of fabricating semiconductor devices. One method includes, for instance: obtaining a wafer with at least one contact opening; depositing a metal alloy into at least a portion of the at least one contact opening; separating the metal alloy into a first metal layer and a second metal layer; depositing a barrier stack over the wafer; forming at least one trench opening; forming at least one via opening; and depositing at least one metal material into the trench openings and via openings. An intermediate semiconductor device is also disclosed.

Abstract: Back end of line via formation for semiconductor devices and methods of fabricating the semiconductor devices. One method includes, for instance: obtaining a wafer with a substrate and at least one contact in the substrate; depositing at least one lithography stack over the substrate; performing lithography to pattern at least one via opening; depositing a block co-polymer coating over the wafer into the at least one via opening; performing an ashing to remove excess block co-polymer material and form block co-polymer caps; and performing a thermal bake to separate the block co-polymer caps into a first material and a second material. An intermediate semiconductor device is also disclosed.

Abstract: Back end of line via formation for semiconductor devices and methods of fabricating the semiconductor devices. One method includes, for instance: obtaining a wafer with a substrate and at least one contact in the substrate; depositing at least one lithography stack over the substrate; performing lithography to pattern at least one via opening; depositing a block co-polymer coating over the wafer into the at least one via opening; performing an ashing to remove excess block co-polymer material and form block co-polymer caps; and performing a thermal bake to separate the block co-polymer caps into a first material and a second material. An intermediate semiconductor device is also disclosed.

Abstract: Metal filling processes for semiconductor devices and methods of fabricating semiconductor devices. One method includes, for instance: obtaining a wafer with at least one contact opening; depositing a metal alloy into at least a portion of the at least one contact opening; separating the metal alloy into a first metal layer and a second metal layer; depositing a barrier stack over the wafer; forming at least one trench opening; forming at least one via opening; and depositing at least one metal material into the trench openings and via openings. An intermediate semiconductor device is also disclosed.

Abstract: The present invention provides a process for the preparation of linagliptin, a compound of Formula I, the process comprising deprotecting a compound of Formula II wherein R1 and R2 together with the nitrogen to which they are attached form a phthalimido group, wherein the aromatic ring of the phthalimido group is substituted with one or more R3 substituents selected from the group consisting of halogen, alkyl, nitro and amino; or R1 is H and R2 is selected from the group consisting of trialkylsilyl, 2-trialkylsilylethoxycarbamates, acetyl, trihaloacetyl, 9-fluorenylmethoxycarbonyl, trityl, alkylsulfonyl, arylsulfonyl, diphenylphosphine and sulfonylethoxycarbonyl.

Abstract: Integrated circuits and methods for fabricating integrated circuits are provided. In one example, a method for fabricating an integrated circuit includes depositing an organic dielectric material overlying a semiconductor substrate for forming an organic interlayer dielectric (OILD) layer. An opening is formed in the OILD layer and a conductive metal fill is deposited in the opening for forming a metal line and/or a via.