Abstract: An electrochemical device includes a positive electrode having a positive electrode material layer containing a conductive polymer doped with a first anion and a second anion, a negative electrode having a negative electrode material layer storing and releasing lithium ions, and a nonaqueous electrolytic solution having lithium ionic conductivity. The second anion is more easily dedoped from the conductive polymer than the first anion. At an end period of charge of the electrochemical device, a number of moles M1 of the first anion and a number of moles M2 of the second anion respectively doped in the conductive polymer satisfy a relationship of M1<M2. At an end period of discharge of the electrochemical device, a number of moles M3 of the first anion and a number of moles M4 of the second anion respectively doped in the conductive polymer satisfy a relationship of M3>M4.

Abstract: A positive electrode active material for an electrochemical device has a fiber shape or a grain-aggregate shape. The positive electrode active material includes an inner core part having a fiber shape or a grain-aggregate shape, and a superficial part covering at least part of the inner core part. The inner core part contains a first conductive polymer, and the superficial part contains a second conductive polymer that is different from the first conductive polymer.

Abstract: An electrochemical device positive electrode with a lead member includes a positive electrode and a lead member attached to the positive electrode. The positive electrode includes a positive current collector, a carbon layer, and an active layer. The carbon layer is disposed on a surface of the positive current collector, and contains a conductive carbon material. The active layer is supported by the positive current collector via the carbon layer disposed between the active layer and the positive current collector, and contains a conductive polymer. The lead member is in contact with the carbon layer.

Abstract: A method for manufacturing a positive electrode for a power storage device includes the steps of: preparing a current collector that includes a first region and a second region on a surface of the current collector, the first region having a carbon layer formed on the surface, the second region having the surface exposed; and forming a conductive polymer layer selectively on a surface of the carbon layer by immersing the current collector in an electrolytic solution containing a raw material monomer and then conducting electrolytic polymerization of the raw material monomer.

Abstract: According to the present invention, an electrochemical device includes: a positive electrode containing, as a positive electrode active material, a conductive polymer that is to be doped and dedoped with anions, a negative electrode containing a negative electrode active material that occludes and releases lithium ions, and an electrolytic solution containing anions and lithium ions. In a charged state of the electrochemical device, an amount A (mol) of anions that are doped into the conductive polymer and are contained in the positive electrode and an amount B (mol) of the anions contained in the electrolytic solution satisfy a relational expression: 1.1?B/A?2.8.

Abstract: According to the present invention, an electrochemical device includes: a positive electrode containing, as a positive electrode active material, a conductive polymer that is to be doped and dedoped with anions, a negative electrode containing a negative electrode active material that occludes and releases lithium ions, and an electrolytic solution containing anions and lithium ions. In a charged state of the electrochemical device, an amount A (mol) of anions that are doped into the conductive polymer and are contained in the positive electrode and an amount B (mol) of the anions contained in the electrolytic solution satisfy a relational expression: 1.1?B/A?2.8.

Abstract: In an electrochemical device combining a positive electrode including a conductive polymer that is to be doped and dedoped with anions with a negative electrode including a negative electrode material that occludes and releases lithium ions, float characteristics in the electrochemical device can be maintained. The electrochemical device includes: a positive electrode including, as a positive electrode active material, a conductive polymer that is to be doped and dedoped with anions, a negative electrode including a negative electrode active material that occludes and releases lithium ions, and an electrolytic solution containing the anions and the lithium ions. 0<B/A<0.7 is satisfied, where A represents a total amount (mol) of monomer units that constitute the conductive polymer included in the positive electrode and B represents a total amount (mol) of the anions included in the electrochemical device.

Abstract: A method for manufacturing a positive electrode for a power storage device includes the steps of: preparing a current collector that includes a first region and a second region on a surface of the current collector, the first region having a carbon layer formed on the surface, the second region having the surface exposed; and forming a conductive polymer layer selectively on a surface of the carbon layer by immersing the current collector in an electrolytic solution containing a raw material monomer and then conducting electrolytic polymerization of the raw material monomer.

Abstract: An electrochemical device positive electrode with a lead member includes a positive electrode and a lead member attached to the positive electrode. The positive electrode includes a positive current collector, a carbon layer, and an active layer. The carbon layer is disposed on a surface of the positive current collector, and contains a conductive carbon material. The active layer is supported by the positive current collector via the carbon layer disposed between the active layer and the positive current collector, and contains a conductive polymer. The lead member is in contact with the carbon layer.

Abstract: A positive electrode active material for an electrochemical device has a fiber shape or a grain-aggregate shape. The positive electrode active material includes an inner core part having a fiber shape or a grain-aggregate shape, and a superficial part covering at least part of the inner core part. The inner core part contains a first conductive polymer, and the superficial part contains a second conductive polymer that is different from the first conductive polymer.

Abstract: An electrochemical device includes a positive electrode having a positive electrode material layer containing a conductive polymer doped with a first anion and a second anion, a negative electrode having a negative electrode material layer storing and releasing lithium ions, and a nonaqueous electrolytic solution having lithium ionic conductivity. The second anion is more easily dedoped from the conductive polymer than the first anion. At an end period of charge of the electrochemical device, a number of moles M1 of the first anion and a number of moles M2 of the second anion respectively doped in the conductive polymer satisfy a relationship of M1<M2. At an end period of discharge of the electrochemical device, a number of moles M3 of the first anion and a number of moles M4 of the second anion respectively doped in the conductive polymer satisfy a relationship of M3>M4.

Abstract: In an electric storage device, a terminal plate includes an element-connecting part electrically connected to a first electrode at a first end of an electric storage element, and an external terminal connected to this element-connecting part. A sealing member is on the element-connecting part, and includes a hole where the external terminal is inserted. The sealing member and the external terminal seal an opening of an outer jacket. The external terminal includes a tapered part on its outer periphery at a tip, and is partially exposed from the sealing member. The tapered part includes a first end and a second end farther away from the element-connecting part than the first end. An edge of a side wall at the opening of the outer jacket is between the first and second ends of the tapered part in a first direction extending from the bottom to the opening of the outer jacket.

Abstract: An electrochemical capacitor includes electrolytic solution, a capacitor element, and a housing. The electrolytic solution contains cations, anions, solvent formed of materials other than lactones, and a lactone component. The capacitor element includes a negative electrode, a positive electrode, and a separator. The negative electrode includes an electrode layer capable of storing the cations, and the positive electrode includes a polarizable electrode layer and confronts the negative electrode. The separator is disposed between the negative and positive electrodes, and they are layered or wound together. The capacitor element is impregnated with the electrolytic solution. The housing accommodates the capacitor element and the electrolytic solution that contains the lactone component in a quantity ranging from 0.001 wt % to 5 wt % (inclusive) relative to the solvent.

Abstract: A negative electrode for an electrochemical capacitor includes a current collector having electric conductivity, and an electrode layer formed on a surface of the current collector and having cations stored therein. In at least a part of the electrode layer, a value of ratio Ia/Ib of peak value Ia indicating a presence of an anion decomposition compound and peak value Ib indicating a presence of an electrolyte in a spectrum of an atom forming the anion is 0.45 or more and less than 2.55 as measured using X-ray photoelectron spectroscopy.

Abstract: In an electric storage device, a terminal plate includes an element-connecting part electrically connected to a first electrode at a first end of an electric storage element, and an external terminal connected to this element-connecting part. A sealing member is on the element-connecting part, and includes a hole where the external terminal is inserted. The sealing member and the external terminal seal an opening of an outer jacket. The external terminal includes a tapered part on its outer periphery at a tip, and is partially exposed from the sealing member. The tapered part includes a first end and a second end farther away from the element-connecting part than the first end. An edge of a side wall at the opening of the outer jacket is between the first and second ends of the tapered part in a first direction extending from the bottom to the opening of the outer jacket.

Abstract: An electrochemical capacitor includes electrolytic solution, a capacitor element, and a housing. The electrolytic solution contains cations, anions, solvent formed of materials other than lactones, and a lactone component. The capacitor element includes a negative electrode, a positive electrode, and a separator. The negative electrode includes an electrode layer capable of storing the cations, and the positive electrode includes a polarizable electrode layer and confronts the negative electrode. The separator is disposed between the negative and positive electrodes, and they are layered or wound together. The capacitor element is impregnated with the electrolytic solution. The housing accommodates the capacitor element and the electrolytic solution that contains the lactone component in a quantity ranging from 0.001 wt % to 5 wt % (inclusive) relative to the solvent.

Abstract: A negative electrode for an electrochemical capacitor includes a current collector having electric conductivity, and an electrode layer formed on a surface of the current collector and having cations stored therein. In at least a part of the electrode layer, a value of ratio Ia/Ib of peak value Ia indicating a presence of an anion decomposition compound and peak value Ib indicating a presence of an electrolyte in a spectrum of an atom forming the anion is 0.45 or more and less than 2.55 as measured using X-ray photoelectron spectroscopy.

Abstract: The present invention provides an electrolyte highly reliable in charge and discharge in a high voltage condition, and an electrochemical capacitor using the same. The electrolyte of the present invention includes a solvent, an electrolyte salt having an anion having a perfluoro alkyl group represented by a following composition formula, and an acid inducing substance having a fluorine atom for an anion, characterized in that the weight ratio of the acid inducing substance is in a range of 0.0001 to 2.0 wt %: MX+[Q(Rf)yFz]X? (wherein Q is a group 13 or group 15 element in the periodic table, Rf is a perfluoro alkyl group (CnF2n+1), n is a natural number, 1?y<6, 1?z<6, MX+ is a cation of Xth valence, and X is a natural number from 1 to 3).

Abstract: An electrical storage unit includes an electrical storage section whose collector-exposed portion formed on both ends of an element is attached to a terminal plate or an outer case, and a pair of cooling plates making contact with an outer surface of the terminal plate or an outer bottom face of the outer case of the electrical storage section. This enables heat release from the electrical storage section to the cooling plate via a material with high heat conductivity, such as a metal member. Accordingly, the electrical storage section heated in charge and discharge cycles can be efficiently cooled.

Abstract: A negative electrode of an electrochemical capacitor includes an electrode layer using a material capable of reversibly absorbing and releasing a lithium ion. A method for pretreating the negative electrode includes forming a lithium layer on a substrate by a gas phase method or a liquid phase method, and transferring the lithium layer onto a surface of the electrode layer of the negative electrode.