Patents by Inventor Takaaki Kawahara
Takaaki Kawahara has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6984565Abstract: A first insulating film is formed on a base substrate, then a second insulating film is formed on the first insulating film, the second insulating film having a relative permittivity higher than that of the first insulating film. A gate electrode is formed on the second insulating film. The second insulating film forming includes first to sixth steps, and a cycle consisting of the first to sixth steps is repeated.Type: GrantFiled: August 13, 2004Date of Patent: January 10, 2006Assignee: Renesas Technology Corp.Inventor: Takaaki Kawahara
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Publication number: 20050249876Abstract: An atomic layer deposition (ALD) apparatus capable of forming a conformal ultrathin-film layer with enhanced step coverage is disclosed. The apparatus includes an ALD reactor supporting therein a wafer, and a main pipe coupled thereto for constant supply of a carrier gas. This pipe has two parallel branch pipes. Raw material sources are connected by three-way valves to one branch pipe through separate pipes, respectively. Similarly, oxidant/reducer sources are coupled by three-way valves to the other branch pipe via independent pipes. ALD works by introducing one reactant gas at a time into the reactor while being combined with the carrier gas. The gas is “chemisorped” onto the wafer surface, creating a monolayer deposited. During the supply of a presently selected material gas from its source to a corresponding branch pipe, this gas passes through its own pipe independently of the others. An ALD method is also disclosed.Type: ApplicationFiled: January 14, 2005Publication date: November 10, 2005Applicant: Semiconductor Leading Edge Technologies, Inc.Inventors: Takaaki Kawahara, Kazuyoshi Torii
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Publication number: 20050051857Abstract: A semiconductor device of the present invention comprises: a silicon substrate; a gate insulating film on the silicon substrate; and a gate electrode on the gate insulating film, wherein the gate insulating film includes: a first insulating film; a second insulating film on the first insulating film; and a metal nitride film on the second insulating film. The metal nitride film may be either AlN or Hf3N4. The metal nitride film may include nitrides of two or more different metals.Type: ApplicationFiled: July 30, 2004Publication date: March 10, 2005Applicant: Semiconductor Leading Edge Technologies, Inc.Inventors: Takaaki Kawahara, Kazuyoshi Torii, Hiroshi Kitajima
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Publication number: 20050045970Abstract: A gate insulating film on a silicon substrate includes a SiO2 film and a high-k film. The high-k film contains a transition metal, aluminum, silicon, and oxygen. The concentration of silicon in the high-k film is higher than the concentrations of the transition metal and aluminum in the vicinity of the interface with the SiO2 film and the vicinity of the interface with the gate electrode. Furthermore, it is preferable that the concentration of silicon is the highest at least in one of the vicinity of the interface with the SiO2 film or the vicinity of the interface with the gate electrode, gradually decreases with distance from these interfaces, and becomes the lowest in a central part of the high-k film.Type: ApplicationFiled: August 9, 2004Publication date: March 3, 2005Applicant: Semiconductor Leading Edge Technologies, Inc.Inventors: Tsunetoshi Arikado, Takaaki Kawahara, Kazuyoshi Torii, Hiroshi Kitajima, Seiichi Miyazaki
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Publication number: 20050048728Abstract: A first insulating film is formed on a base substrate, then a second insulating film is formed on the first insulating film, the second insulating film having a relative permittivity higher than that of the first insulating film. A gate electrode is formed on the second insulating film. The second insulating film forming includes first to sixth steps, and a cycle consisting of the first to sixth steps is repeated.Type: ApplicationFiled: August 13, 2004Publication date: March 3, 2005Applicant: Semiconductor Leading Edge Technologies, Inc.Inventor: Takaaki Kawahara
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Publication number: 20040191997Abstract: A method for manufacturing a semiconductor device includes forming a first insulating film on a substrate, forming a second insulating film on the first insulating film, and forming a gate electrode on the second insulating film. Forming the second insulating film includes supplying film-forming materials and adsorbing the film-forming materials on the first insulating film, purging the film-forming materials that have not been adsorbed, supplying oxidants to oxidize the adsorbed film-forming materials, and purging the oxidants that have not contributed to oxidization. Forming the second insulating film is repeated in cycles, continuously, and the purging time of the oxidants in an initial number of the cycles is longer than the purging time of the oxidants in cycles following the initial number of cycles.Type: ApplicationFiled: March 11, 2004Publication date: September 30, 2004Applicant: Semiconductor Leading Edge Technologies, Inc.Inventors: Takaaki Kawahara, Kazuyoshi Torii
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Patent number: 6638880Abstract: In the chemical vapor deposition apparatus, a substrate stage for mounting a substrate is provided inside a reaction chamber of the apparatus. A source gas inlet for introducing a source gas and exhaust outlets and for exhausting the source gas are provided. Exhaust outlet valves provided for exhaust outlets are open and shut successively with time. The direction of the flow of source gas relative to the fixed substrate varies with time. The present chemical vapor deposition apparatus allows the improved evenness of film thickness, the composition ratio, and the like within the substrate surface as well as the reduction of particles of foreign substance generated inside the reaction chamber.Type: GrantFiled: October 19, 2001Date of Patent: October 28, 2003Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Mikio Yamamuka, Takaaki Kawahara, Masayoshi Tarutani, Tsuyoshi Horikawa, Shigeru Matsuno, Takehiko Sato
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Liquid raw material vaporizer, semiconductor device and method of manufacturing semiconductor device
Patent number: 6512885Abstract: A vaporizing chamber is constituted by a vaporizer body and an upper vaporizer cover, and a raw material supply pipe for introducing a liquid raw material into the vaporizing chamber is connected to the upper vaporizer cover. In order to suppress transmission of heat from the vaporizing chambers and to the raw material supply pipe, a heat radiation preventing member is provided on a surface of an external wall of each of the vaporizing chambers and. Consequently, a liquid raw material vaporizer capable of suppressing the generation of a vaporization residue is provided, and a semiconductor device including a CVD film having a stable thickness and a method of manufacturing the semiconductor device are obtained.Type: GrantFiled: September 8, 2000Date of Patent: January 28, 2003Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Mikio Yamamuka, Takaaki Kawahara, Masayoshi Tarutani, Tsuyoshi Horikawa -
Patent number: 6470144Abstract: There are provided a vaporizer for use with a CVD apparatus and a CVD apparatus, capable of long-term, reliable and efficient production of CVD film with good properties, and a semiconductor device manufactured employing the same. The vaporizer for use with a CVD apparatus is comprised of a material introducing tube, a vaporization chamber and a cooling member. The material introducing tube transports a mixture containing a solution of a material for the CVD film and a gas carrying the solution. The vaporization chamber is connected to the material introducing tube to vaporize the material introduced through the material introducing tube. The cooling member cools that portion of the material introducing tube adjacent to the vaporization chamber.Type: GrantFiled: November 19, 1999Date of Patent: October 22, 2002Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Masayoshi Tarutani, Tsuyoshi Horikawa, Takaaki Kawahara, Mikio Yamamuka, Shigeru Matsuno, Takehiko Sato
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Patent number: 6448191Abstract: A method of forming a (Ba, Sr) TiO3 high dielectric constant thin film with sufficient coverage is provided. A Ba material, an Sr material and a Ti material including bis (t-butoxy) bis (dipivaloylmethanate) titanium are dissolved in an organic solvent to obtain a solution material. The solution material is vaporized, so that material gas is obtained. A (Ba, Sr) TiO3 thin film is formed on a substrate by CVD reaction using the material gas.Type: GrantFiled: April 12, 2001Date of Patent: September 10, 2002Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Takaaki Kawahara, Mikio Yamamuka, Tsuyoshi Horikawa, Masayoshi Tarutani, Takehiko Sato, Shigeru Matsuno
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Publication number: 20020023588Abstract: In the chemical vapor deposition apparatus, a substrate stage for mounting a substrate is provided inside a reaction chamber of the apparatus. A source gas inlet for introducing a source gas and exhaust outlets and for exhausting the source gas are provided. Exhaust outlet valves provided for exhaust outlets are open and shut successively with time. The direction of the flow of source gas relative to the fixed substrate varies with time. The present chemical vapor deposition apparatus allows the improved evenness of film thickness, the composition ratio, and the like within the substrate surface as well as the reduction of particles of foreign substance generated inside the reaction chamber.Type: ApplicationFiled: October 19, 2001Publication date: February 28, 2002Applicant: Mitsubishi Denki Kabushiki KaishaInventors: Mikio Yamamuka, Takaaki Kawahara, Masayoshi Tarutani, Tsuyoshi Horikawa, Shigeru Matsuno, Takehiko Sato
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Publication number: 20010039923Abstract: A vaporizing device for CVD source materials comprising a vaporizer for vaporizing introduced CVD source materials through heating, a spray nozzle of which end portion is fixedly attached to the vaporizer for spraying the CVD source materials into the vaporizer, a cooling mechanism for cooling the spray nozzle, and a heat conduction restricting means attached either to the fixing portion, or to proximate of the fixing portion of the spray nozzle or the vaporizer. There can be achieved for an effect that generation of non-vaporized residues and particles can be decreased and that improvements in productivity owing to elongation of continuous operation time and decrease in film forming deficiencies can be achieved.Type: ApplicationFiled: July 6, 2001Publication date: November 15, 2001Inventors: Mikio Yamamuka, Tsuyoshi Horikawa, Takaaki Kawahara, Fusaoki Uchikawa, Shigeru Matsuno, Takehito Sato, Akira Yamada, Masayoshi Tarutani
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Patent number: 6312526Abstract: In the chemical vapor deposition apparatus, a substrate stage for mounting a substrate is provided inside a reaction chamber of the apparatus. A source gas inlet for introducing a source gas and exhaust outlets and for exhausting the source gas are provided. Exhaust outlet valves provided for exhaust outlets are open and shut successively with time. The direction of the flow of source gas relative to the fixed substrate varies with time. The present chemical vapor deposition apparatus allows the improved evenness of film thickness, the composition ratio, and the like within the substrate surface as well as the reduction of particles of foreign substance generated inside the reaction chamber.Type: GrantFiled: November 16, 1999Date of Patent: November 6, 2001Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Mikio Yamamuka, Takaaki Kawahara, Masayoshi Tarutani, Tsuyoshi Horikawa, Shigeru Matsuno, Takehiko Sato
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Publication number: 20010029090Abstract: A method of forming a (Ba, Sr) TiO3 high dielectric constant thin film with sufficient coverage is provided.Type: ApplicationFiled: April 12, 2001Publication date: October 11, 2001Applicant: Mitsubishi Denki Kabushiki KaishaInventors: Takaaki Kawahara, Mikio Yamamuka, Tsuyoshi Horikawa, Masayoshi Tarutani, Takehiko Sato, Shigeru Matsuno
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Patent number: 6273957Abstract: A vaporizing device for chemical vapor deposition (CVD) source materials includes a vaporizer for vaporizing introduced CVD source materials by heating, a spray nozzle of which an end portion is fixedly attached to the vaporizer for spraying the CVD source materials into the vaporizer, a cooling mechanism for cooling the spray nozzle, and a heat conduction restrictor attached to the end portion, proximate of the end portion, or to the vaporizer. Generation of non-vaporized residues and particles is decreased, improving productivity owing to prolongation of continuous operation time of the apparatus and a decrease in film defects.Type: GrantFiled: March 23, 2000Date of Patent: August 14, 2001Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Mikio Yamamuka, Tsuyoshi Horikawa, Takaaki Kawahara, Fusaoki Uchikawa, Shigeru Matsuno, Takehiko Sato, Akira Yamada, Masayoshi Tarutani
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Patent number: 6235649Abstract: A method of forming a (Ba, Sr) TiO3 high dielectric constant thin film with sufficient coverage is provided. A Ba material, an Sr material and a Ti material including bis (t-butoxy) bis (dipivaloylmethanate) titanium are dissolved in an organic solvent to obtain a solution material. The solution material is vaporized, so that material gas is obtained. A (Ba, Sr) TiO3 thin film is formed on a substrate by CVD reaction using the material gas.Type: GrantFiled: November 22, 1999Date of Patent: May 22, 2001Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Takaaki Kawahara, Mikio Yamamuka, Tsuyoshi Horikawa, Masayoshi Tarutani, Takehiko Sato, Shigeru Matsuno
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Patent number: 6179920Abstract: A CVD apparatus for forming a thin film having a high dielectric constant, which is improved to suppress source precipitation and residue generation and to achieve stable formation of a BST thin film, is provided. The apparatus includes a reaction chamber, a source gas supply tube, and a reactive gas supply tube. A jet element for jetting out the gas along the inner walls of the reaction chamber is provided to at least one of the source gas supply tube and the reactive gas supply tube.Type: GrantFiled: September 9, 1998Date of Patent: January 30, 2001Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Masayoshi Tarutani, Tsuyoshi Horikawa, Takaaki Kawahara, Mikio Yamamuka
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Patent number: 6165556Abstract: There is provided a (Ba, Sr) TiO.sub.3 film of higher dielectric constant and less leakage current for serving as a dielectric thin film of a capacitor in a semiconductor memory. DPM (dipivaloylmethanato) compounds of Ba, Sr and Ti are dissolved in THF (tetrahydrofuran) to obtain Ba(DPM).sub.2 /THF, Sr(DPM).sub.2 /THF and TiO(DPM).sub.2 /THF solutions which are used as source material solutions. A (Ba, Sr) TiO.sub.3 film is formed by a CVD method while increasing a relative percentage of a Ti source material flow rate to a sum of Ba source material flow rate and Sr source material flow rate. The film formation is carried out in multiple steps, and annealing is applied in each step after deposition of the film.Type: GrantFiled: November 8, 1999Date of Patent: December 26, 2000Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Takaaki Kawahara, Mikio Yamamuka, Tetsuro Makita, Tsuyoshi Horikawa, Akimasa Yuuki, Teruo Shibano
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Patent number: 6117482Abstract: An object is to provide a method of monitoring a CVD liquid source for forming a thin film having a high dielectric constant, which allows detection of the concentration abnormality and the deterioration of the CVD liquid source. First, the CVD liquid source used as a sources of chemical vapor deposition is prepared by dissolving an organometallic compound of dipivaloyolmethane type in an organic solvent. Secondly, a spectroscopy of the CVD liquid source is performed.Type: GrantFiled: June 2, 1998Date of Patent: September 12, 2000Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Takaaki Kawahara, Tsuyoshi Horikawa, Masayoshi Tarutani, Mikio Yamamuka
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Patent number: 6110283Abstract: A chemical vapor deposition apparatus to reduce generation of contaminants such as residues within the apparatus can be obtained. The chemical vapor deposition apparatus includes a CVD source container, a vaporizer and reaction unit. The vaporizer has a nozzle attached thereto. The nozzle has a tip portion and a thick portion. The reaction unit includes a mixing unit. The mixing unit includes an oxidizer supply pipe as well as a heating portion having a helical side groove and heating means. Reaction unit further includes a reaction chamber surrounded by a wall surface. The inside of the wall surface is covered with an inactive cover layer, and the wall surface is heated to a temperature range of 300-500.degree. C.Type: GrantFiled: August 15, 1997Date of Patent: August 29, 2000Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Mikio Yamamuka, Takaaki Kawahara, Masayoshi Tarutani, Tsuyoshi Horikawa