Abstract: An object of the present invention is to provide a method for producing a crosslinked polyarylene sulfide (PAS) that reduces a difference in melt viscosity among lots and has excellent quality stability. Further specifically, the present invention provides a method for producing a crosslinked PAS including steps of compression-molding an uncrosslinked PAS in a powder form to obtain a compression-molded material, measuring a porosity of the compression-molded material, grinding the compression-molded product having a specific range of porosity to obtain a pulverized material, granulating the pulverized material to obtain a granulated material, and oxidatively crosslinking the granulated material obtained in the preceding step. Also provided are a method for producing a composition containing the crosslinked PAS, and a method for producing a molded article by melt-molding the composition.

Abstract: A method for producing a crosslinked polyarylene sulfide resin (PAS resin) that reduces a difference in melt viscosity among lots and has excellent quality stability is provided. Further specifically, the method includes steps of compression-molding an uncrosslinked PAS resin in a powder form to obtain a compression-molded material, measuring a true specific gravity of the compression-molded material, grinding the compression-molded product having a specific range of true specific gravity to obtain a pulverized material, granulating the pulverized material to obtain a granulated material, and oxidatively crosslinking the granulated material obtained in the above step. Also provided are a method for producing a composition containing the crosslinked PAS, and a method for producing a molded article by melt-molding the composition.

Abstract: The present invention provides an oxygen generation electrode provided with a catalyst layer having a high specific electric conductivity, and having excellent durability such that even when an acidic electrolyte is electrolyzed, the catalyst components are unlikely to be consumed and long-term electrolysis can be performed. The oxygen generation electrode is an oxygen generation electrode 10 provided with a substrate 2 formed with titanium or a titanium alloy, and a catalyst layer 4 disposed on the substrate 2 and formed with a mixed metal oxide, wherein the catalyst layer 4 satisfies at least any one of the following condition (1) and condition (2). Condition (1): containing ruthenium, tin, and trivalent or higher polyvalent metal element excluding a tetravalent metal element. Condition (2): containing ruthenium and tin, and having a content of ruthenium of 40 mol % or more based on the total content of the ruthenium and tin.

Abstract: Provided are an adsorbent which can be used in water, particularly even under strong acid conditions, and which has excellent adsorptivity, a method for efficiently separating a separation object substance from a liquid containing the separation object substance using the adsorbent, and further a method for producing a liquid having a separation object substance reduced. More specifically, provided are a method for separating a separation object substance and a liquid using polyarylene sulfide resin particles as an adsorbent from the liquid containing the separation object substance, wherein the liquid contains water, and further a method for producing a liquid having a separation object substance reduced, comprising efficiently separating a separation object substance from a liquid containing the separation object substance using an adsorbent which can be used in water, particularly even under strong acid conditions, and which has excellent adsorptivity.

Abstract: Provided are a purification method for a polyarylene sulfide (PAS) that can efficiently reduce the amount of a carboxyalkylamino group-containing compound in the PAS by treating the carboxyalkylamino group-containing compound in the PAS under a low pressure without using a strong acid, and a production method for a PAS having a reduced amount of the carboxyalkylamino group-containing compound in the PAS. The purification method for a PAS includes: a step of obtaining a crude PAS-containing mixture by removing a solvent from a crude reaction product containing the PAS obtained by reacting a polyhalo aromatic compound with a sulfidizing agent in an organic polar solvent; a step of bringing the crude PAS mixture into contact with water and an oxygen atom-containing solvent to convert the crude PAS into porous particles; and a step of bringing the obtained porous particles into contact with carbonated water.

Abstract: The present invention relates to a method for manufacturing a polyarylene sulfide resin comprising: reacting a sulfoxide represented by the following formula (1) with a particular aromatic compound to obtain a poly(arylenesulfonium salt) having a particular constitutional unit; and dealkylating or dearylating the poly(arylenesulfonium salt) to obtain a polyarylene sulfide resin having a particular constitutional unit, wherein R1 represents an alkyl group having 1 to 10 carbon atoms, etc.; Ar1 and Ar2 each independently represent an arylene group optionally having a substituent; and Z represents a direct bond, etc.

Abstract: A body earth structure for a vehicle includes a bolt of which a head portion is swage-joined to an aluminum vehicle body panel. The bolt is provided to fasten an earth terminal to the vehicle. The bolt includes a projection that protrudes toward the vehicle body panel, on a facing surface of the head portion of the bolt. The facing surface is provided to face the vehicle body panel.

Abstract: The present invention relates to a method for manufacturing a polyarylene sulfide resin comprising: reacting a sulfoxide represented by the following formula (1) with a particular aromatic compound to obtain a poly(arylenesulfonium salt) having a particular constitutional unit; and dealkylating or dearylating the poly(arylenesulfonium salt) to obtain a polyarylene sulfide resin having a particular constitutional unit, wherein R1 represents an alkyl group having 1 to 10 carbon atoms, etc.; Ar1 and Ar2 each independently represent an arylene group optionally having a substituent; and Z represents a direct bond, etc.

Abstract: An electrode on valve metal substrate suitable for the evolution of oxygen in electrolytic processes is provided with a coating having a catalytic layer containing platinum group metals and one or more protective layers based on tin oxide modified with a doping element selected from bismuth, antimony or tantalum and with a small amount of ruthenium. The electrode is useful in processes of non-ferrous metal electrowinning.

Abstract: The present invention relates to a method for manufacturing a polyarylene sulfide resin comprising: reacting a sulfoxide represented by the following formula (1) with a particular aromatic compound to obtain a poly(arylenesulfonium salt) having a particular constitutional unit; and dealkylating or dearylating the poly(arylenesulfonium salt) to obtain a polyarylene sulfide resin having a particular constitutional unit, wherein R1 represents an alkyl group having 1 to 10 carbon atoms, etc.; Ar1 and Ar2 each independently represent an arylene group optionally having a substituent; and Z represents a direct bond, etc.

Abstract: A body earth structure for a vehicle includes a bolt of which a head portion is swage-joined to an aluminum vehicle body panel. The bolt is provided to fasten an earth terminal to the vehicle. The bolt includes a projection that protrudes toward the vehicle body panel, on a facing surface of the head portion of the bolt. The facing surface is provided to face the vehicle body panel.

Abstract: The present invention relates to a method for manufacturing a polyarylene sulfide resin comprising: a step of reacting a poly(arylenesulfonium salt) having a constitutional unit represented by the following formula (1) with an aliphatic amide compound to obtain a polyarylene sulfide resin having a constitutional unit represented by the following formula (2): wherein R1 represents a direct bond, -Ar2-, -Ar2-S— or -Ar2-O—; Ar1 and Ar2 each represent an arylene group optionally having a functional group as a substituent; R2 represents an alkyl group having 1 to 10 carbon atoms or an aromatic group optionally having an alkyl group having 1 to 10 carbon atoms as a substituent; and X? represents an anion, wherein R1 and Ar1 are the same as described above.

Abstract: An electrode on valve metal substrate suitable for the evolution of oxygen in electrolytic processes is provided with a coating having a catalytic layer containing platinum group metals and one or more protective layers based on tin oxide modified with a doping element selected from bismuth, antimony or tantalum and with a small amount of ruthenium. The electrode is useful in processes of non-ferrous metal electrowinning.

Abstract: A fuel tank structure is obtained that can prevent or suppress excessive stress concentrating at fixed portions of a separator and an inner wall of a fuel tank main body. A separator for reducing flow noise of fuel is disposed at an interior of a fuel tank that accommodates fuel. Projecting portions that serve as fixed portions that are fixed at two or more places to an inner wall of the fuel tank, are provided at the separator. Deformation portions that allow deformation of the separator are formed between the projecting portions at the separator.

Abstract: The present invention relates to a method for manufacturing a polyarylene sulfide resin comprising: a step of reacting a poly(arylenesulfonium salt) having a constitutional unit represented by the following formula (1) with an aliphatic amide compound to obtain a polyarylene sulfide resin having a constitutional unit represented by the following formula (2): wherein R1 represents a direct bond, —Ar2—, —Ar2—S— or —Ar2—O—; Ar1 and Ar2 each represent an arylene group optionally having a functional group as a substituent; R2 represents an alkyl group having 1 to 10 carbon atoms or an aromatic group optionally having an alkyl group having 1 to 10 carbon atoms as a substituent; and X? represents an anion, wherein R1 and Ar1 are the same as described above.

Abstract: The present invention relates to a method for manufacturing a polyarylene sulfide resin comprising: reacting a sulfoxide represented by the following formula (1) with a particular aromatic compound to obtain a poly(arylenesulfonium salt) having a particular constitutional unit; and dealkylating or dearylating the poly(arylenesulfonium salt) to obtain a polyarylene sulfide resin having a particular constitutional unit, wherein R1 represents an alkyl group having 1 to 10 carbon atoms, etc.; Ar1 and Ar2 each independently represent an arylene group optionally having a substituent; and Z represents a direct bond, etc.

Abstract: The present invention relates to a method for manufacturing a polyarylene sulfide resin comprising: a step of reacting a poly(arylenesulfonium salt) having a constitutional unit represented by the following formula (1) with an aliphatic amide compound to obtain a polyarylene sulfide resin having a constitutional unit represented by the following formula (2): wherein R1 represents a direct bond, —Ar2—, —Ar2—S— or —Ar2—O—; Ar1 and Ar2 each represent an arylene group optionally having a functional group as a substituent; R2 represents an alkyl group having 1 to 10 carbon atoms or an aromatic group optionally having an alkyl group having 1 to 10 carbon atoms as a substituent; and X? represents an anion, wherein R1 and Ar1 are the same as described above.

Abstract: The present invention relates to a method for manufacturing a polyarylene sulfide resin comprising: reacting a sulfoxide represented by the following formula (1) with a particular aromatic compound to obtain a poly(arylenesulfonium salt) having a particular constitutional unit; and dealkylating or dearylating the poly(arylenesulfonium salt) to obtain a polyarylene sulfide resin having a particular constitutional unit, wherein R1 represents an alkyl group having 1 to 10 carbon atoms, etc.; Ar1 and Ar2 each independently represent an arylene group optionally having a substituent; and Z represents a direct bond, etc.

Abstract: An anode for oxygen generation and a manufacturing method for the same used for industrial electrolyses including manufacturing of electrolytic metal foils such as electrolytic copper foil, aluminum liquid contact and continuously electrogalvanized steel plate, and metal extraction is provided. The anode for oxygen generation and a manufacturing method for the same comprises a conductive metal substrate and a catalyst layer containing iridium oxide formed on the conductive metal substrate wherein the coating is baked in a high temperature region of 410° C.-450° C. in an oxidation atmosphere to form the catalyst layer co-existing amorphous and crystalline iridium oxide and the catalyst layer co-existing the amorphous and crystalline iridium oxide is post-baked in a further high temperature region of 520° C.-560° C. in an oxidation atmosphere to crystallize almost all amount of iridium oxide in the catalyst layer.

Abstract: The present invention relates to a method for manufacturing a polyarylene sulfide resin comprising: reacting a sulfoxide represented by the following formula (1) with a particular aromatic compound to obtain a poly(arylenesulfonium salt) having a particular constitutional unit; and dealkylating or dearylating the poly(arylenesulfonium salt) to obtain a polyarylene sulfide resin having a particular constitutional unit, wherein R1 represents an alkyl group having 1 to 10 carbon atoms, etc.; Ar1 and Ar2 each independently represent an arylene group optionally having a substituent; and Z represents a direct bond, etc.