Abstract: There is provided a method of manufacturing a lithium ion storage device. A lithium ion storage device produced by the method includes a positive electrode having a positive electrode active material that contains a lithium-containing compound, and a negative electrode having an alloy-based negative electrode active material. A charge potential in a first cycle is higher than charge potentials in second and subsequent cycles.

Abstract: There is provided a lithium ion storage device including a positive electrode having a positive electrode active material that is a lithium-containing compound and is capable of absorbing and desorbing lithium ions, and a negative electrode having a negative electrode active material capable of absorbing and desorbing lithium ions. The irreversible capacity of the positive electrode active material that is a capacity at which lithium ions cannot be reabsorbed after being desorbed from the positive electrode active material is 6% to 40% of a usage capacity of the negative electrode that is a capacity at which lithium ions are reversibly absorbed and desorbed by the negative electrode active material.

Abstract: An electrode laminate unit of an electric storage device includes positive electrodes, negative electrodes and a lithium electrode connected to the negative electrode. When an electrolyte solution is injected into the electric storage device, lithium ions are emitted from the lithium electrode to the negative electrode. A positive and a negative electrode current collector have through-holes that guide the lithium ions in the laminating direction. The aperture ratio of the through-holes at the edge parts where the electrolyte solution is easy to be permeated is set to be smaller than the aperture ratio at central parts in order to suppress the permeation. Thus, the distribution of the electrolyte solution is made uniform, whereby the doping amount is made uniform.

Abstract: In a current collector laminating step, a current-collector laminate unit 30 composed of current-collector materials 31 and 32 and a film material 33 is formed. Resist layers 34 having a predetermined pattern are formed on both surfaces of the current-collector laminate unit 30. An etching process is performed with the resist layers 34 used as a mask, whereby through-holes 20a and 23a are formed on the respective current-collector materials 31 and 32. The resist layers 34 are removed from the current-collector laminate unit 30. Since the etching process is performed on the plural current-collector materials 31 and 32, productivity of an electrode can be enhanced. During the application of the slurry, the film material 33 prevents the leakage of the electrode slurry. Therefore, the current-collector laminate unit 30 can be conveyed in the horizontal direction, whereby the productivity of the electrode can be enhanced.

Abstract: An electric storage device 10 has a positive electrode 13, a negative electrode 14 and a separator 15 provided between the positive electrode 13 and the negative electrode 14. The negative electrode surface 14b is formed to be larger than the positive electrode surface 13b in such a manner that a positive electrode outer edge 13c and a negative electrode outer edge 14c are apart from each other by 2 mm or more. By this configuration, an ion restricting section 15b is formed at the outer peripheral portion of the separator 15. Accordingly, the movement of the lithium ions toward the negative electrode end surface 14a can be restricted, when the device is charged with a large current, whereby the deposition of metal lithium on the negative electrode end surface 14a can be prevented.

Abstract: An electrode laminate unit of an electric storage device includes positive electrodes, negative electrodes and a lithium electrode connected to the negative electrode. When an electrolyte solution is injected into the electric storage device, lithium ions are emitted from the lithium electrode to the negative electrode. A positive and a negative electrode current collector have through-holes that guide the lithium ions in the laminating direction. The aperture ratio of the through-holes at the edge parts where the electrolyte solution is easy to be permeated is set to be smaller than the aperture ratio at central parts in order to suppress the permeation. Thus, the distribution of the electrolyte solution is made uniform, whereby the doping amount is made uniform.

Abstract: In a current collector laminating step, a current-collector laminate unit 30 composed of current-collector materials 31 and 32 and a film material 33 is formed. Resist layers 34 having a predetermined pattern are formed on both surfaces of the current-collector laminate unit 30. An etching process is performed with the resist layers 34 used as a mask, whereby through-holes 20a and 23a are formed on the respective current-collector materials 31 and 32. The resist layers 34 are removed from the current-collector laminate unit 30. Since the etching process is performed on the plural current-collector materials 31 and 32, productivity of an electrode can be enhanced. During the application of the slurry, the film material 33 prevents the leakage of the electrode slurry. Therefore, the current-collector laminate unit 30 can be conveyed in the horizontal direction, whereby the productivity of the electrode can be enhanced.

Abstract: A mixture layer for an electrode is formed on a punched current collector. For example, the mixture layer is made of an active material, conductive assistant, binder, and the like. The mixture layer having the structure described above is formed into a slurry, for example, and applied onto the current collector. The applied mixture layer is dried to fabricate an electrode. The thus formed electrode is used to assemble an electric storage device. Upon the assembly, lithium ions are pre-doped into a negative electrode. The pre-doping time is determined according to air permeability of the electrodes.

Abstract: An electric storage device 10 has a positive electrode 13, a negative electrode 14 and a separator 15 provided between the positive electrode 13 and the negative electrode 14. The negative electrode surface 14b is formed to be larger than the positive electrode surface 13b in such a manner that a positive electrode outer edge 13c and a negative electrode outer edge 14c are apart from each other by 2 mm or more. By this configuration, an ion restricting section 15b is formed at the outer peripheral portion of the separator 15. Accordingly, the movement of the lithium ions toward the negative electrode end surface 14a can be restricted, when the device is charged with a large current, whereby the deposition of metal lithium on the negative electrode end surface 14a can be prevented.