Abstract: A process for producing an electrically conductive mixed oxide comprises sintering a power mixture comprising from 30 to 98% by weight of titanium oxide, in terms of the amount of titanium based on the total amount of all the metallic elements, from 1 to 10% by weight of at least one of titanium metal and titanium hydride, in terms of the amount of titanium based on the total amount of all the metallic elements, and from 1 to 60% by weight of at least one of tantalum oxide and niobium oxide, in terms of the amount of tantalum, niobium, or tantalum and niobium based on the total amount of all of the metallic elements. The process provides a sintered solid comprising titanium, at least one of tantalum and niobium, and a stoichiometrically deficient amount of oxygen.

Abstract: The electrolytic cell 1 for producing alkali hydroxide or hydrogen peroxide is divided into the anode compartment 3 and the cathode compartment 4 by the cation exchange membrane 2. The cathode compartment 4 is further divided by the anion exchange membrane 6 into the solution compartment 7 containing a concentrated aqueous solution of alkali hydroxide and the gas compartment accommodating the gas cathode 8. The anion exchange membrane 6 prevents the gas cathode 8 from coming into direct or indirect contact with the aqueous solution of alkali hydroxide. This leads to the extended life of the gas cathode. The above-mentioned arrangement is effective in large-sized electrolytic cells. Thus, the present invention can be applied to industrial electrolysis which has never been achieved with the conventional gas electrode.

Abstract: The underwater propulsion apparatus, which is mounted on a ship, has the anode and cathode electrodes including an anode compartment and cathode compartment whose electrode materials are separated from seawater in a central duct by the ion exchange membranes so that they are protected from poisoning by seawater. In the method utilizing the apparatus, the anode compartment and cathode compartment are supplied with moist hydrogen and moist oxygen, respectively, so as to substantially suppress the evolution of gas in the duct, which lowers the thrusting force.

Abstract: The present invention relates to an electrolytic electrode comprising a core material made of a valve metal, a dense electrically conductive tin oxide layer formed on the core material, an .alpha.-lead dioxide layer formed on the tin oxide layer, and a .beta.-lead dioxide layer formed on the .alpha.-lead dioxide layer. The present invention also relates to a method for preparing the electrolytic electrode.

Abstract: A process of producing a metallic foil by electrolysis by depositing the metallic foil on a cathode by electrolysis from a sulfuric acid acidic solution is disclosed, which comprises using an electrode having a coating of an electrode active material containing a platinum group metal oxide as an anode and carrying out the electrolysis in an electrolyte containing from 1 to 20 ppm of a lead component when a fluorine component does not exist in the electrolyte or an electrolyte containing from 0.2 to 1 ppm of a fluorine component and from 0.1 to 20 ppm of a lead component when a fluorine component exists in the electrolyte. The life of the electrode can be prolonged and a metallic foil can be stably produced by electrolysis for a long period of time by preventing the lead component(s) derived from the raw material from mixing into the metallic foil.

Abstract: Disclosed is an electrode structure for ozone production which comprises a perfluorocarbon sulfonic acid-based ion-exchange membrane as a solid electrolyte and an anode placed on one side of the solid electrolyte and having a lead oxide as an electrode catalyst, wherein a porous, perfluorocarbon sulfonic acid-based ion-exchange resin layer is formed between the electrolyte and the anode. A process for producing the electrode structure for ozone production is also disclosed, which comprises coating one side of a perfluorocarbon sulfonic acid-based ion-exchange membrane as a solid electrolyte with a liquid, perfluorocarbon sulfonic acid-based ion-exchange resin or with a suspension of ion-exchange resin powder, heating-treating the liquid or suspension-formed ion-exchange resin coating to form an ion-exchange resin layer, and then positioning an anode so as to keep it in close contact with the ion-exchange resin layer, the anode having a lead oxide as an electrode catalyst.

Abstract: The present invention relates to an electrolytic electrode comprising a core material made of a valve metal, a plasma flame-coated layer containing the oxides of titanium and tantalum formed on the surface of the core material, an interlayer containing platinum and the oxides of titanium and tantalum formed on the surface of the plasma flame-coated layer, an .alpha.-lead dioxide layer formed on the interlayer, and a .beta.-lead dioxide layer formed on the .alpha.-lead dioxide layer. The present invention also relates to a process for the manufacture thereof.

Abstract: The present invention relates to an electrolytic electrode comprising a metallic core material, a lead plating layer formed on the surface of the metallic core material, an .alpha.-lead dioxide layer formed on the surface of the lead plating layer, and a .beta.-lead dioxide layer formed on the .alpha.-lead dioxide layer. The present invention also relates to methods for the preparation thereof.

Abstract: An electrolytic electrode substrate comprises an electrically conductive substrate and, formed on the surface of the electrically conductive substrate, an oxide layer having a thickness of from 10 to 200 .mu.m, wherein the oxide in the oxide layer comprises a non-stoichiometric composition containing oxygen and at least one metal selected from the group consisting of titanium, tantalum, and niobium. An advantage of the electrode substrate is that it is stable when used in electrolytic processes involving a reversal of current flow. Further, the electrode substrate is stable in the presence of corrosive substances such as a fluorine.

Abstract: An electrolytic electrode comprising a substrate made of a valve metal, an intermediate layer formed on a surface of the substrate containing an oxide of at least one metal selected from the group consisting of niobium, tantalum, titanium, and zirconium, and a coating layer formed on the intermediate layer containing an iridium-tantalum mixed oxide and platinum. In separate embodiments of the invention, the intermediate layer may contain platinum and/or a stabilizing layer formed on the coating layer containing an oxide of at least one metal selected from the group consisting of tin, titanium, tantalum, zirconium, and niobium.

Abstract: A method for producing ozone which comprises electrolyzing water using a fluororesin-type ion-exchange membrane as a solid electrolyte thereby to generate an ozone-containing gas, and cooling the gas thereby to remove a fluorine-containing substance present in the gas generated.

Abstract: A device for continuously measuring the thickness of a foil includes a radiation source opposite a radiation detector, and a movement member which moves the radiation source and detector synchronously in a width-direction of the foil. A signal generator generates a signal indicating a position of a portion of the foil whose thickness is being measured, and a counter having a plurality of integrating channels integrates detection signals output from the detector to generate an integrated count number for each channel. A signal switching member switches each of the plurality of integrating channels of the counter according to signals generated by the signal generator, and a calculator calculates a foil thickness from the integrated counted number for each channel of the counter. This structure allows continuous and precise measurement of the foil's thickness.

Abstract: An electrolytic ozone generator is described, which comprises a feed tank in which water is stored, an ion-exchange column connected to the feed tank, a pump for feeding the stored water in the feed tank to the ion-exchange column, an electrolytic cell connected to the ion-exchange column and containing a solid electrolyte which is an ion-exchange membrane, an anode disposed tightly on one side of the solid electrolyte, and a cathode disposed tightly on the other side of the solid electrolyte, an electromagnetic valve connected to and disposed between the ion-exchange column and the electrolytic cell, and a hydrogen-separating column connected to the electrolytic cell and for separating hydrogen from a gas-liquid mixture sent from the electrolytic cell and circulating the resulting water to the feed tank, and in which the liquid level of the anolyte in the electrolytic cell is sensed, and, in a case wherein said liquid level is below a predetermined value, ion-exchanged water is fed from the ion-exchange colu

Abstract: A method and apparatus for electrolytic ozone generation are described which process comprises feeding raw water to an ozone-generating electrolytic cell partitioned into an anode chamber and a cathode chamber by means of a solid electrolyte, said feeding of raw water being only to the cathode chamber, and conducting electrolysis to thereby produce ozone in the anode chamber.

Abstract: The present invention is directed toward an electrolytic ozonier for treating ozone-containing waste gas and a method of treating ozone-containing waste gas using the ozonier, wherein the method includes evolving oxygen and ozone in an anode compartment of an electrolytic cell by electrolysis of water while evolving hydrogen in a cathode compartment; directing the evolved hydrogen into a waste gas treating section that contains a waste gas decomposition catalyst so as to convert the hydrogen to a harmless form by means of the catalyst; bringing the oxygen and ozone into contact with a medium to be treated in an ozone contactor so as to treat the medium; and subsequently directing waste gas containing oxygen and ozone produced as a result of treatment of the medium into the waste gas treating section where they are brought into either direct or indirect contact with the catalyst so that the ozone in the waste gas is converted into a harmless form.

Abstract: A titanium composite material is disclosed which comprises a titanium or titanium alloy substrate, a base layer formed thereon of a calcium phosphate compound resulting from calcination of a hydrochloric or nitric acid aqueous solution of the calcium phosphate compound, and a covering layer thereon of a calcium phosphate compound formed by sintering a suspension of the calcium phosphate compound applied to the base layer. The composite material is useful as a biological implant. It is produced by activating the surface of the substrate, forming the base layer by calcining the solution coated on the substrate and then forming the covering layer by sintering the suspension coated on the base layer. The covering layer may be hydrothermally treated to increase its crystallinity.

Abstract: A method and apparatus for water treatment is described, using electrolytic zone, which comprises electrolyzing water to generate an ozone-containing gas in the anode compartment of an electrolytic cell, separating the ozone-containing gas from the anolyte, and contacting the separated ozone-containing gas with the water to be treated said water to be treated being different than the water for electrolysis.

Abstract: A cathode for electrolysis, particularly of a sodium chloride aqueous solution by an ion-exchange membrane method, and a process for producing the same, the cathode comprising a conductive base having a nickel surface and having provided thereon (a) at least one platinum group component selected from the group consisting of a platinum group metal, a platinum group metal oxide, and a platinum group metal hydroxide, and (b) at least one cerium component selected from the group consisting of cerium, cerium oxide, and cerium hydroxide, retaining a markedly reduced hydrogen overpotential for an extended period of time and exhibiting excellent resistance to impurities in the electrolytic solution.

Abstract: A titanium or titanium alloy composite having a porous surface layer, which comprises a titanium or titanium alloy substrate and a porous titanium or titanium alloy layer that adheres strongly to said substrate, said porous layer being formed by first providing said substrate with a firmly adhering sinter of a mixture of a titanium or titanium alloy powder and a magnesium powder, and then removing magnesium from the sinter. A process for producing a titanium or titanium alloy composite having a porous surface layer, comprising: providing a coating composition comprising a binder added to a mixture of a titanium or titanium alloy powder and a magnesium powder; applying said composition to the surface of a titanium or titanium alloy substrate; heating the substrate at a temperature of from 650.degree. to 800.degree. C. in vacuo or an inert atmosphere so as to form a sinter of the powders of titanium or titanium alloy and magnesium which firmly adheres to said substrate; and removing magnesium from said sinter.

Abstract: A bipolar-electrode electrolytic cell is disclosed, which is to be used in electrolysis of an electrolytic solution having a high electric resistance and including at least two diaphragms positioned to form a plurality of electrode compartments comprising two outer compartments defined between the side walls of the electrolytic cell and the diaphragms positioned closest to the cell walls having a single electrode and at least one electrode compartment having two same-polar electrodes on both sides thereof, each of said electrodes being placed on a diaphragm such that different-polar electrodes are positioned at opposing sides of the diaphragm, wherein the distance between same-polar electrodes within the same compartment is sufficiently large such that electrolysis therebetween does not substantially occur and wherein two of said electrodes at the terminal ends of the series connected electrolytic cell, an anode and a cathode, being further electrically connected to an anode collector and a cathode collector,