Abstract: A secondary battery includes: a fiber negative electrode having a surface on which a negative electrode active material coating is formed, the coating containing a compound of AaMbXcZd; a fiber positive electrode including a positive electrode active material coating containing nickel hydroxide; an aqueous electrolyte solution; and a separator. The negative electrode coating has an uncoated surface. A is selected from the group consisting of Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, and Ba; M is selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Nb, Mo, Ru, Pd, Ag, Ta, W, Pr, Sm, Eu, and Pb; X is selected from the group consisting of B, Al, Si, P, S, Ga, and Ge; Z is selected from the group consisting of O, S, N, F, Cl, Br, and I; and 0?a?6, 1?b?5, 0?c?4, 0<d?12, and 0?a/b?4.

Abstract: The present invention provides a process for producing a lithium sulfide-carbon composite, the process comprising placing a mixture of lithium sulfide and a carbon material having a specific surface area of 60 m2/g or more in an electrically-conductive mold in a non-oxidizing atmosphere, and applying a pulsed direct current to the mold while pressurizing the mixture in a non-oxidizing atmosphere, thereby subjecting the lithium sulfide and the carbon material to heating reaction; and a lithium sulfide-carbon composite obtained by this process, the composite having a carbon content of 15 to 70 weight %, and a tap density of 0.4 g/cm3 or more when the carbon content is 30 weight % or more, or a tap density of 0.5 g/cm3 or more when the carbon content is less than 30 weight %.

Abstract: Provided is a novel lithium silicate-based material useful as a positive electrode material for lithium ion secondary battery. The lithium silicate-based compound is represented by Li1.5FeSiO4.25. The lithium silicate-based compound is a compound including: lithium (Li); iron (Fe); silicon (Si); and oxygen (O), and expressed by a composition formula, Li1+2?FeSiO4+??c (?0.25???0.25, 0?c?0.5). The lithium silicate-based compound, of which iron (Fe) is trivalent, exerts a remarkable chemical stability as compared to Li2FeSiO4.

Abstract: A production process for lithium-silicate-based compound according to the present invention is characterized in that: a lithium-silicate compound being expressed by Li2SiO3 is reacted with a transition-metal-element-containing substance including at least one member being selected from the group consisting of iron and manganese at 550° C. or less within a molten salt including at least one member being selected from the group consisting of alkali-metal nitrates as well as alkali-metal hydroxides in an atmosphere in the presence of a mixed gas including carbon dioxide and a reducing gas. In accordance with the present invention, it is possible to produce lithium-silicate-based materials, which are useful as a positive-electrode active material for lithium-ion secondary battery, and the like, at low temperatures by means of relatively easy means.

Abstract: Problem: To provide a lithium secondary battery negative electrode active material consisting of a Sn—Sb based sulfide that delivers a high electrode capacity density, excellent output characteristics, and excellent cycle life characteristics and also provide a method for manufacturing the lithium secondary battery negative electrode active material, said method being capable of easily manufacturing the high performance lithium secondary battery negative electrode active material at low cost without requiring a high-temperature processing step and special facilities as required in a glass melting method. Solution: A method for manufacturing a lithium secondary battery negative electrode active material containing a Sn—Sb based sulfide comprises a step of obtaining a Sn—Sb based sulfide precipitate by adding an alkali metal sulfide to a mixed solution of a tin halide and an antimony halide.

Abstract: An object of the present invention is to provide a highly efficient electrical storage device that uses a fiber positive electrode and a fiber negative electrode and in which lithium ion is used as an intercalating species, and to provide a method of fabricating the electrical storage device.

Abstract: The present invention is one which provides a production process for lithium-silicate-system compound, the production process being characterized in that: a lithium-silicate compound being expressed by Li2SiO3 is reacted with a substance including at least one member of transition-metal elements that is selected from the group consisting of iron and manganese at 400-650° C. in a molten salt of a carbonate mixture comprising lithium carbonate and at least one member of alkali-metal carbonates that is selected from the group consisting of potassium carbonate, sodium carbonate, rubidium carbonate and cesium carbonate in a mixed-gas atmosphere including carbon dioxide and a reducing gas; and a positive-electrode active material for lithium-ion secondary battery that comprises a lithium-silicate-system compound being obtained by the aforesaid process.

Abstract: A lithium-ion secondary battery of the present invention comprises a positive electrode including a positive electrode active material composite formed by compositing a lithium silicate-based material and a carbon material, a negative electrode including a negative electrode active material containing a silicon, and an electrolyte. The lithium-ion secondary battery satisfies 0.8<B/A<1.2, where A is irreversible capacity of the positive electrode and B is irreversible capacity of the negative electrode.

Abstract: Problem. Provided is a negative electrode material for a sodium secondary battery and its manufacturing method, and a negative electrode for a sodium secondary battery, and a sodium secondary battery, wherein the negative electrode material can have excellent cycle characteristics while maintaining high discharge capacity. Solution. A negative electrode material for a sodium secondary battery according to the present invention includes sulfide or sulfide composite body containing sulfur and antimony, and as necessary further includes the following component(s) of (i): (i) at least one or more element(s) selected from a group consisting of Sn, As, Bi, Ge, Ga, Pb, and C, wherein when a component(s) of (i) is included, the ratio of each of the above described components is sulfur: 10 to 70 mol %, antimony: 10 to 70 mol %, and (i): 3 to 60 mol %.

Abstract: This binder for use in a positive electrode for a lithium ion secondary battery contains a copolymer of both vinyl alcohol and an alkali-metal-neutralized ethylenically unsaturated carboxylic acid.

Abstract: A lithium silicate-based compound according to the present invention is expressed by a general formula, Li(2?a+b)AaMn(1?x?y)CoxMySiO(4+?)Cl? (In the formula: “A” is at least one element selected from the group consisting of Na, K, Rb and Cs; “M” is at least one member selected from the group consisting of Mg, Ca, Al, Ni, Fe, Nb, Ti, Cr, Cu, Zn, Zr, V, Mo and W; and the respective subscripts appear to be as follows: 0?“a”<0.2; 0?“b”<1; 0<“x”<1; 0?“y”?0.5; ?0.25?“?”?1.25; and 0?“?”?0.05). The lithium silicate-based compound is used as a positive-electrode active material for secondary battery whose discharge average voltage is higher, and which is able to sorb and desorb lithium ions.

Abstract: [Object] The object is to provide a negative electrode material for a lithium secondary battery, wherein a sulfide-based negative electrode with water-resistant properties can exert excellent cycle characteristics and high output performance while maintaining a high discharge capacity and there is no precipitation of lithium dendrites during charge at low temperature. [Means for Solving Problems] A negative electrode material for a lithium secondary battery comprising sulfur and sulfide glass including the following components (i) and (ii): (i) at least one or more elements selected from a group consisting of Sb, As, Bi, Ge, Si, Cu, Zn, Pd, In and Zr; and (ii) at least one or more elements selected from a group consisting of Se, Te, Ga, Sn, Pb, Cd, Al, Fe, Mg, Ca, Co, Ag, Sr, P and Ba, wherein the ratio of the above components is sulfur: 40-80 mol %, (i): 1-50 mol % and (ii): 1-50 mol %, respectively.

Abstract: Provided is a method for mass manufacturing, at low cost, of a fiber positive electrode for a lithium secondary battery, which has excellent charge/discharge cycle characteristics, and which is capable of charging/discharging with high current density, and a main active material of which is a lithium-doped transition metal oxide. The method includes the steps of: (a) forming a tubular coating of either a transition metal oxide or a transition metal hydroxide on a carbon fiber current collector; and (b) performing, in a lithium ion containing solution in a sealed system under presence of an oxidant or a reductant, heat treatment at 100 to 250° C. on the carbon fiber current collector, on which the tubular coating of either the transition metal oxide or the transition metal hydroxide is formed, to obtain a coating of a lithium-doped transition metal oxide on the carbon fiber current collector.

Abstract: A negative electrode active material for an electricity storage device comprises at least SnO as a composition thereof. When a binding energy value of an electron on a Sn 3d5/2 orbital of a Sn atom in the negative electrode active material for an electricity storage device is defined as Pl and a binding energy value of an electron on a Sn 3d5/2 orbital of a metal Sn is defined as Pm, (Pl?Pm) is 0.01 to 3.5 eV.

Abstract: Provided is a hydrogen storage alloy which is characterized in that two or more crystal phases having different crystal structures are layered in a c-axis direction of the crystal structures. The hydrogen storage alloy is further characterized in that a difference between a maximum value and a minimum value of a lattice constant a in the crystal structures of the laminated two or more crystal phases is 0.03 ? or less.

Abstract: Provided is a negative electrode material for an electricity storage device, comprises, a negative electrode active material comprising a compound containing at least SnO and P2O5, and a binder comprising a thermosetting resin. Also provided is a negative electrode for an electricity storage device, comprising a current collector having a surface coated with the negative electrode material for an electricity storage device. Further provided is a method of producing the negative electrode for an electricity storage device, the method comprising the steps of: coating the surface of the current collector with the negative electrode material for an electricity storage device; and carrying out heat treatment of the current collector at 150 to 400° C. under reduced pressure.

Abstract: A compound having a high reduction resistance and being capable of sufficiently performing a function as an electronic conductive additive when added to a positive electrode active material as an electronic conductive additive is provided. In a method for producing a cobalt cerium compound including a step of depositing a hydroxide containing cobalt and cerium in an aqueous solution containing cobalt ions and cerium ions by changing the pH of the aqueous solution and thereafter performing a treatment of oxidizing the hydroxide, the ratio of the cerium ions contained in the aqueous solution containing the cobalt ions and the cerium ions is set to be more than 5% by atom and 70% by atom or less with respect to the sum of the cobalt ions and the cerium ions before the hydroxide is deposited.

Abstract: Provided is a sulfur-modified polyacrylonitrile manufacturing method that is characterized in that a starting base powder that comprises sulfur powder and polyacrylonitrile powder is mixed and the mixture is heated in a non-oxidizing environment while outflow of sulfur vapor is prevented. Also provided are a cathode for lithium batteries that uses, as the active substance, the sulfur-modified polyacrylonitrile manufactured with the method, and a lithium secondary battery that includes the cathode as a component element. This enables the practical use of an inexpensive sulfur-based material as the cathode material for lithium secondary batteries, and in particular, a sulfur-based cathode material that enables higher output and has excellent cycle life characteristics, as well as other characteristics, and secondary lithium batteries using the same can be obtained.

Abstract: Disclosed is a resin composition for positive electrodes of lithium ion cells, which imparts strong adhesiveness and electrolyte injectability and shows good discharge and charge characteristics and input-output characteristics with smaller amount of a binder. The resin composition for positive electrodes of lithium ion cells is a resin composition for positive electrodes of lithium ion cells, which comprises a polyimide precursor whose average thermal linear expansion coefficient in the range of 20° C. to 200° C. after being imidized is 3 to 50 ppm, and/or a polyimide whose average thermal linear expansion coefficient in the range of 20° C. to 200° C. is 3 to 50 ppm, and a positive electrode active compound, wherein the positive electrode active compound is one obtained by coating the surface of a composite oxide containing lithium with a lithium ion conductive material.

Abstract: A lithium silicate-based compound according to the present invention is expressed by a general formula, Li(2?a+b)AaMn(1?x?y)CoxMySiO(4+?)Cl? (In the formula: “A” is at least one element selected from the group consisting of Na, K, Rb and Cs; “M” is at least one member selected from the group consisting of Mg, Ca, Al, Ni, Fe, Nb, Ti, Cr, Cu, Zn, Zr, V, Mo and W; and the respective subscripts appear to be as follows: 0?“a”<0.2; 0?“b”<1; 0<“x”<1; 0?“y”?0.5; ?0.25?“?”?1.25; and 0?“?”?0.05). The lithium silicate-based compound is used as a positive-electrode active material for secondary battery whose discharge average voltage is higher, and which is able to sorb and desorb lithium ions.