Patents by Inventor Tetsuo Shimizu

Tetsuo Shimizu has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6835782
    Abstract: A polymer having a structure of the formula: in which X, Y and Z represent independently each other H, F, Cl, Br or I, provided that at least one of X, Y and Z is F; R represents a straight or branched fluorinated alkylene group which may contain an oxygen atom; x and y represent mole percentages and x is from 1 to 100% by mole; A is —CN, —NCO, —COOR′ in which R′ is H or an alkyl group having 1 to 10 carbon atoms, an acid anhydride group or an unsaturated hydrocarbon group; and M is a repeating unit derived from a copolymerizable monomer is treated with a crosslinking agent selected from ammonia, diamines and polyol compounds and crosslinked through the side functional groups of the polymer. This crosslinking method can be carried out at room temperature and provides a transparent fluoropolymer having better heat resistance than conventional transparent thermoplastic resins.
    Type: Grant
    Filed: January 14, 2002
    Date of Patent: December 28, 2004
    Assignee: Daikin Industries, Ltd.
    Inventors: Shigeru Morita, Takuya Arase, Tetsuo Shimizu
  • Publication number: 20040236047
    Abstract: The present invention provides a TFE resin molding material which has electric characteristics, particularly low dielectric dissipation factor, in a microwave area, can also lower extrusion pressure as the material is of low molecular weight and can provide a molded article excellent in surface smoothness. The material is especially useful as a coating material for a coaxial cable for equipment in which microwave is used, including satellite transmitting equipment and a cell phone base station. A tetrafluoroethylene resin molding material excellent in high frequency electric characteristics, which provides a molded article having a dielectric constant of at most 2.2 and a dielectric dissipation factor of at most 1.60×10−4 under 12 GHz, and a standard specific gravity of at least 2.192 and less than 2.3 is provided. As the tetrafluoroethylene resin, a tetrafluoroethylene homopolymer or a copolymer of 99.9 to 99.9999% by mole of tetrafluoroethylene and 0.0001 to 0.
    Type: Application
    Filed: January 27, 2003
    Publication date: November 25, 2004
    Inventors: Makato Ono, Michio Asano, Yoshinori Nanba, Shunji Kasai, Hiroyuki Yoshimoto, Shinichi Yano, Tetsuo Shimizu
  • Patent number: 6818800
    Abstract: The present invention is to provide a method for providing a low-molecular radical which comprises releasing a radical having a lower molecular weight from a super-stable perfluoroalkyl-based radical followed by generating the above super-stable perfluoroalkyl-based radical. The invention is a method for providing a low-molecular radical which comprises a super-stable radical generating reaction for generating a super-stable perfluoroalkyl-based radical from a radical-carrying molecule and a radical releasing reaction for releasing the low-molecular radical from said super-stable perfluoroalkyl-based radical, said radical-carrying molecule being generated as a result of said radical releasing reaction.
    Type: Grant
    Filed: November 12, 2002
    Date of Patent: November 16, 2004
    Assignees: National Institute of Advanced Industrial Science and Technology, Daikin Industries, Ltd.
    Inventors: Taizo Ono, Eiji Hayashi, Haruhiko Fukaya, Tetsuo Shimizu
  • Patent number: 6818074
    Abstract: A steel sheet composition contains appropriate amounts of C, Si, Mn, P, S, Al and N and 0.5 to 3.0% Cu. A composite structure of the steel sheet has a ferrite phase or a ferrite phase and a tempered martensite phase as a primary phase, and a secondary phase containing retained austenite in a volume ratio of not less than 1%. In place of the Cu, at least one of Mo, Cr, and W may be contained in a total amount of not more than 2.0%. This composition is useful in production of a high-ductility hot-rolled steel sheet, a high-ductility cold-rolled steel sheet and a high-ductility hot-dip galvanized steel sheet having excellent press formability and excellent stain age hardenability as represented by a &Dgr;TS of not less than 80 MPa, in which the tensile strength increases remarkably through a heat treatment at a relatively low temperature after press forming.
    Type: Grant
    Filed: June 6, 2002
    Date of Patent: November 16, 2004
    Assignee: JFE Steel Corporation
    Inventors: Saiji Matsuoka, Tetsuo Shimizu, Kei Sakata, Osamu Furukimi
  • Patent number: 6814819
    Abstract: The present invention provides a steel sheet having a chemical composition comprising 0.15% or less C, 2.0% or less Si, 3.0% or less Mn, P, S, Al and N in adjusted amounts, from 0.5 to 3.0% Cu, or one or more of Cr, Mo and W in a total amount of 2.0% or less, and having a composite structure comprising ferrite and martensite having an area ratio of 2% or more. The steel sheet is in the form of a high-strength hot-rolled steel sheet, a high-strength cold-rolled steel sheet, or a hot-dip galvanized steel sheet. There is thus available a steel sheet excellent in press-formability and in strain age hardening property as represented by a &Dgr;TS of 80 MPa or more.
    Type: Grant
    Filed: May 2, 2003
    Date of Patent: November 9, 2004
    Assignee: JFE Steel Corporation
    Inventors: Saiji Matsuoka, Tetsuo Shimizu, Kei Sakata, Osamu Furukimi
  • Publication number: 20040197566
    Abstract: The present invention provides a polytetrafluoroethylene molded article, particularly a PTFE molded article for high-frequency insulation, which is excellent in various electric properties and mechanical properties in a high frequency range of 3 to 30 GHz. The present invention also provides PTFE fine powder, which is excellent in extrusion moldability and capable of providing the molded article, and a process for preparing the same. More specifically, the present invention relates to a polytetrafluoroethylene fine powder having a standard specific gravity of 2.180 to 2.225, which is obtained by contacting polytetrafluoroethylene fine powder having a standard specific gravity of 2.180 to 2.225 with a fluorine radical source, wherein tan &dgr; at 12 GHz of a film comprising the powder, which is obtained by cooling at 5 to 50° C./second after baking, is at most 2.0×10−4.
    Type: Application
    Filed: January 30, 2004
    Publication date: October 7, 2004
    Inventors: Tetsuo Shimizu, Michio Asano, Makoto Ono, Yoshinori Nanba, Shunji Kasai, Shinichi Yano, Hiroyuki Yoshimoto
  • Publication number: 20040187982
    Abstract: A hot-rolled steel strip having superior low temperature toughness and weldability, which is suitably used as a starting material for high strength electric resistance welding pipe, is provided at a low cost without constructing new production facilities and increasing cost. The hot-rolled steel strip is low carbon steel containing at least one of about 0.5.% or less of Cu, about 0.5% or less of Ni, and about 0.5% or less of Mo, wherein Pcm represented by the following equation (1) is 0.
    Type: Application
    Filed: March 24, 2004
    Publication date: September 30, 2004
    Applicant: JFE Steel Corporation, a corporation of Japan
    Inventors: Hiroshi Nakata, Nobuyuki Kageyama, Koji Iwata, Tetsuo Shimizu, Chikara Kami
  • Patent number: 6774196
    Abstract: To provide a novel PFA-based fluorine-containing copolymer having improved impermeability to liquid chemicals while retaining the excellent heat resistance, stress cracking resistance and processability inherent in PFA-based fluororesins, a material and a molded article useful in the field of semiconductor production apparatus and the like, using the copolymer. The present invention provides a fluorine-containing copolymer comprising 90 to 99.4% by mole of a repeating unit derived from tetrafluoroethylene, 0.5 to 5% by mole of a repeating unit derived from at least one lower perfluoro(alkyl vinyl ether) represented by the formula (1): CF2═CF—O—Rf1  (1) in which Rf1 is a perfluoroalkyl group having 2 to 4 carbon atoms, and 0.
    Type: Grant
    Filed: May 28, 2002
    Date of Patent: August 10, 2004
    Assignee: Daikin Industries, Ltd.
    Inventors: Takahiro Taira, Takahisa Aoyama, Katsuhide Otani, Tetsuo Shimizu
  • Publication number: 20040127756
    Abstract: The present invention is to provide a method for producing a highly branched perfluoroolefin conveniently in a high yield, a novel highly branched perfluoroolefin, a method for producing a super-stable perfluoroalkyl radical and a novel super-stable perfluoroalkyl radical.
    Type: Application
    Filed: October 16, 2003
    Publication date: July 1, 2004
    Applicants: NATIONAL INSTITUTE OF ADVANCED IND. SCIENCE AND TECH., DAIKIN INDUSTRIES, LTD.
    Inventors: Taizo Ono, Masakazu Nishida, Masaharu Okazaki, Kazumi Toriyama, Tetsuo Shimizu
  • Publication number: 20040108024
    Abstract: The present invention provides a steel sheet having a chemical composition comprising 0.15% or less C, 2.0% or less Si, 3.0% or less Mn, P, S, Al and N in adjusted amounts, from 0.5 to 3.0% Cu, or one or more of Cr, Mo and W in a total amount of 2.0% or less, and having a composite structure comprising ferrite and martensite having an area ratio of 2% or more. The steel sheet is in the form of a high-strength hot-rolled steel sheet, a high-strength cold-rolled steel sheet, or a hot-dip galvanized steel sheet. There is thus available a steel sheet excellent in press-formability and in strain age hardening property as represented by a &Dgr;TS of 80 MPa or more.
    Type: Application
    Filed: May 2, 2003
    Publication date: June 10, 2004
    Applicant: Kawasaki Steel Corporation, a corporation of Japan
    Inventors: Saiji Matsuoka, Tetsuo Shimizu, Kei Sakata, Osamu Furukimi
  • Patent number: 6740375
    Abstract: A fluorine-containing adhesive material comprising a fluorine-containing ethylenic polymer having a carbonate group and/or a carboxylic acid halide group at a chain end or a side chain of the polymer, wherein a total of a number of the carbonate groups and/or carboxylic acid halide groups is at less than 150 per 1×106 main chain carbon atoms, can directly impart the firm adherability to a substrate such as a metal, a glass or a resin while maintaining excellent properties such as chemical resistance, solvent resistance, weatherability and soil releasability possessed by a fluorine-containing polymer.
    Type: Grant
    Filed: May 8, 2002
    Date of Patent: May 25, 2004
    Assignee: Daikin Industries, Ltd.
    Inventors: Shigehito Sagisaka, Taketo Kato, Takeshi Inaba, Takuya Arase, Tetsuo Shimizu
  • Patent number: 6737164
    Abstract: Composite materials for cooking apparatuses which are produced by applying, to a substrate, a material comprising a fluorine-containing polymer having an excellent adhesive property to the substrate without necessitating complicated steps and are excellent in heat resistance, non-sticking property, stain-proofing property, water- and oil-repelling property, stain-removing property, chemical resistance, rust-preventing property, antibacterial property, resistance to energy ray and abrasion resistance. The composite materials for cooking apparatuses are produced by applying, to the substrate, the material comprising a fluorine-containing ethylenic polymer having functional group which is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, and (b) 70 to 99.
    Type: Grant
    Filed: September 3, 1999
    Date of Patent: May 18, 2004
    Assignee: Daikin Industries, Ltd.
    Inventors: Takayuki Araki, Yoshito Tanaka, Masahiro Kumegawa, Noritoshi Oka, Hisato Sanemasa, Tetsuo Shimizu
  • Patent number: 6716497
    Abstract: A heat resistant scattering-preventing composite material is produced by applying, to a substrate, a material comprising a fluorine-containing ethylenic polymer having functional group which is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers which do not have said functional group. The heat resistant scattering-preventing composite material is produced by applying, to the substrate, the material comprising the fluorine-containing polymer having an excellent adhesive property to the substrate without necessitating complicated steps.
    Type: Grant
    Filed: November 19, 1999
    Date of Patent: April 6, 2004
    Assignee: Daikin Industries, Ltd.
    Inventors: Takayuki Araki, Yoshito Tanaka, Masahiro Kumegawa, Noritoshi Oka, Hisato Sanemasa, Tetsuo Shimizu
  • Patent number: 6713183
    Abstract: To provide a fluorine-containing adhesive which maintains thermal resistance, chemical resistance, weather resistance and electric insulating property and has strong adhesive property directly to substrates particularly metal and glass, and an adhesive film and laminated article which are obtained by using the fluorine-containing adhesive. There is used a fluorine-containing ethylenic polymer having hydroxyl which is prepared by copolymerizing 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having hydroxyl and 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers copolymerizable with the above-mentioned monomer.
    Type: Grant
    Filed: June 5, 1998
    Date of Patent: March 30, 2004
    Assignee: Daikin Industries, Ltd.
    Inventors: Takayuki Araki, Yoshito Tanaka, Masahiro Kumegawa, Noritoshi Oka, Tetsuo Shimizu
  • Patent number: 6710214
    Abstract: The present invention is to provide a method for producing a highly branched perfluoroolefin conveniently in a high yield, a novel highly branched perfluoroolefin, a method for producing a super-stable perfluoroalkyl radical and a novel super-stable perfluoroalkyl radical. The present invention is a production method of a perfluoroolefin which comprises reacting a hexafluoropropene trimer with a trialkylperfluoroalkylsilane in an aprotic polar solvent using a fluoride ion as a catalyst.
    Type: Grant
    Filed: November 12, 2002
    Date of Patent: March 23, 2004
    Assignees: National Institute of Advanced Industrial Science and Technology, Daikin Industries, Ltd.
    Inventors: Taizo Ono, Masakazu Nishida, Masaharu Okazaki, Kazumi Toriyama, Tetsuo Shimizu
  • Publication number: 20040019176
    Abstract: There are provided a curable fluorine-containing polymer which can realize a high hardness by photo-curing while maintaining a low refractive index, an antireflection film possessing improved scratch resistance and abrasion resistance while maintaining a reflection reducing effect, and an antireflection-treated article provided with such an antireflection film.
    Type: Application
    Filed: February 26, 2003
    Publication date: January 29, 2004
    Inventors: Takayuki Araki, Mihoko Ohashi, Yoshito Tanaka, Tetsuo Shimizu
  • Patent number: 6680124
    Abstract: A fluorine-containing adhesive material comprising a fluorine-containing ethylenic polymer having a carbonate group and/or a carboxylic halide group at a chain end or a side chain of polymer, wherein a total of a number of the carbonate groups and/or carboxylic halide groups is at least 150 relative to 1×106 main chain carbons, can directly impart the firm adherability to a substrate such as a metal, a glass or a resin while maintaining excellent properties such as resistance to chemicals, resistance to solvent, weatherability and resistance to stain possessed by a fluorine-containing polymer.
    Type: Grant
    Filed: November 6, 2000
    Date of Patent: January 20, 2004
    Assignee: Daikin Industries Ltd.
    Inventors: Takayuki Araki, Takahiro Kitahara, Shigehito Sagisaka, Taketo Kato, Takeshi Inaba, Kazuo Ishiwari, Tetsuo Shimizu, Hidenori Ozaki, Tatsuya Higuchi
  • Publication number: 20040007297
    Abstract: The present invention provides a steel sheet having a chemical composition comprising 0.15% or less C, 2.0% or less Si, 3.0% or less Mn, P, S, Al and N in adjusted amounts, from 0.5 to 3.0% Cu, or one or more of Cr, Mo and W in a total amount of 2.0% or less, and having a composite structure comprising ferrite and martensite having an area ratio of 2% or more. The steel sheet is in the form of a high-strength hot-rolled steel sheet, a high-strength cold-rolled steel sheet, or a hot-dip galvanized steel sheet. There is thus available a steel sheet excellent in press-formability and in strain age hardening property as represented by a &Dgr;TS of 80 MPa or more.
    Type: Application
    Filed: May 2, 2003
    Publication date: January 15, 2004
    Applicant: Kawasaki Steel Corporation, a corporation of Japan
    Inventors: Saiji Matsuoka, Tetsuo Shimizu, Kei Sakata, Osamu Furukimi
  • Patent number: 6676774
    Abstract: The present invention provides a steel sheet having a chemical composition comprising 0.15% or less C, 2.0% or less Si, 3.0% or less Mn, P, S, Al and N in adjusted amounts, from 0.5 to 3.0% Cu, or one or more of Cr, Mo and W in a total amount of 2.0% or less, and having a composite structure comprising ferrite and martensite having an area ratio of 2% or more. The steel sheet is in the form of a high-strength hot-rolled steel sheet, a high-strength cold-rolled steel sheet, or a hot-dip galvanized steel sheet. There is thus available a steel sheet excellent in press-formability and in strain age hardening property as represented by a &Dgr;TS of 80 MPa or more.
    Type: Grant
    Filed: December 31, 2001
    Date of Patent: January 13, 2004
    Assignee: JFE Steel Corporation
    Inventors: Saiji Matsuoka, Tetsuo Shimizu, Kei Sakata, Osamu Furukimi
  • Patent number: 6677044
    Abstract: A composite material having sliding property is produced by applying, to a substrate, a material comprising a fluorine-containing ethylenic polymer having functional group which is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers having no functional group mentioned above. The composite material having sliding property which is produced by applying, to the substrate, the material comprising the fluorine-containing polymer having an excellent adhesive property to the substrate without necessitating complicated steps.
    Type: Grant
    Filed: November 16, 1999
    Date of Patent: January 13, 2004
    Assignee: Daikin Industries, Ltd.
    Inventors: Takayuki Araki, Yoshito Tanaka, Masahiro Kumegawa, Noritoshi Oka, Hisato Sanemasa, Tetsuo Shimizu