Abstract: An apparatus for controlling a molten salt electrolyzer in which an electrolytic bath in a solid form as contained in the electrolyzer is melted to automatically attain a state allowing electrolysis, which apparatus comprises detecting means for detecting the changes in state of the electrolyzer by means of detectors fitted to the electrolyzer, and adjusting means for adjusting, after using the detecting means, the liquid electrolytic bath levels to a state allowing electrolysis.

Abstract: The invention provides a method and apparatus for current control in gas generators capable of generating a fluorine or fluoride gas by and in which the electrolysis can be maintained in an optimum condition, stable operation is possible and no manpower is demanded. According to the method of current control in gas generators for generating a fluorine or fluoride gas by electrolysis of an electrolytic bath 5 comprising a hydrogen fluoride-containing mixed molten salt using a carbon electrode as the anode 4a, the range of voltage fluctuation between the cathode 4b and anode 4a as occurring when a certain current is applied to the gas generator is measured, and current application is continued while varying the current amount to be applied according to the voltage fluctuation range.

Abstract: A conductive diamond electrode including a conductive substrate comprising a carbonaceous material, a conductive diamond catalyst layer formed on a surface of the conductive substrate, and a carbon fluoride formed on an exposed portion present on the surface of the conductive substrate. The formed carbon fluoride prevents the conductive substrate from contacting with an electrolytic solution, thereby suppressing corrosion of the substrate. A long life of the electrode can be attained.

Abstract: It is a task of the present invention to provide an electrolytic apparatus for producing fluorine or nitrogen trifluoride by electrolyzing a hydrogen fluoride-containing molten salt, the electrolytic apparatus being advantageous in that the electrolysis can be performed without the occurrence of the anode effect even at a high current density and without the occurrence of an anodic dissolution. In the present invention, this task has been accomplished by an electrolytic apparatus for producing fluorine or nitrogen trifluoride by electrolyzing a hydrogen fluoride-containing molten salt at an applied current density of from 1 to 1,000 A/dm2, the electrolytic apparatus using a conductive diamond-coated electrode as an anode.

Abstract: It is an object of the present invention to produce a carbon electrode having a texture with decreased pores and having relatively high mechanical strength by only being subjected to a process where a specified metal fluoride is mixed with a carbon material, then the mixture is baked, and to provide a carbon electrode for producing gaseous nitrogen trifluoride having a long life without the polarization of the carbon electrode even in any case of an NH4F—KF—HF series and an NH4F—HF series. The carbon electrode for producing gaseous nitrogen trifluoride of the present invention has a dense texture with an average pore size of 0.5 ?m or less. It is preferable that the carbon electrode contains a carbonaceous material, and at least one of more kinds selected from magnesium fluoride and aluminum fluoride which have a melting point not lower than the baking temperature of the carbonaceous material.

Abstract: A diamond electrode having a prolonged life by combining a conventional diamond electrode having a relatively short life with other components is provided. A diamond electrode for electrolysis includes an electrode substrate, at least the surface of which comprises Magneli phase titanium oxide, and conductive diamond supported as an electrode catalyst on a surface of the electrode. The electrode catalyst may contain a titanium oxide powder. Magneli phase titanium oxide improves conductivity without forming a stable oxide layer on the substrate surface.

Abstract: The present invention provides an electrolytic anode for use in electrolytically synthesizing a fluorine-containing substance by using an electrolytic bath containing a fluoride ion including: an electroconductive substrate having a sure including an electroconductive carbonaceous material; and an electroconductive carbonaceous film having a diamond structure, the electroconductive carbonaceous film coating a part of the electroconductive carbonaceous substrate, and a method for electrolytically synthesizing a fluorine-containing substance using the electrolytic anode.

Abstract: A carbon material for producing endohedral metallofullerenes in a high yield is made of a mixture of a metal or metal compound with a carbonaceous material and is used in producing a endohedral metallofullerenes, wherein said carbon material contains a metal carbide and a bulk density of said carbon material is set to 1.80 g/cm3 or less.

Abstract: A conductive diamond electrode including a conductive substrate comprising a carbonaceous material, a conductive diamond catalyst layer formed on a surface of the conductive substrate, and a carbon fluoride formed on an exposed portion present on the surface of the conductive substrate. The formed carbon fluoride prevents the conductive substrate from contacting with an electrolytic solution, thereby suppressing corrosion of the substrate. A long life of the electrode can be attained.

Abstract: Since the system for supplying gas comprises a storage container, a compressor which pressurizes fluorine gas in the storage container, and a pressurized storing container which presses fit and stores the fluorine gas, by supplying fluorine gas or the like to the destination from this system for supplying gas, it is not necessary to change gas source such as a gas cylinder or the like. In this way, fluorine gas or the like can be supplied to the destination inexpensively and safely.

Abstract: A gas generator is provided in which the filter life is prolonged and the pressure regulating valve is thereby protected for a prolonged periods. The gas generator is intended for electrolyzing an electrolyte in an electrolytic cell to generate a gas or gases and comprises at least one absorber for absorbing an unnecessary by-products generated from the gas generator, a filter for removing the mist generated from the absorber, and at least one pressure regulating valve for adjusting the pressure in the electrolytic cell, wherein the filter is inserted downstream from the absorber and, further, the pressure regulating valve is disposed downstream from the filter.

Abstract: A method for producing a semiconductor diamond containing boron by the high pressure synthesis method, wherein a graphite material to be converted to the semiconductor diamond is mixed with boron or a boron compound, formed and fired, in such a way that the resultant graphite material contains a boron component uniformly dispersed therein and has an enhanced bulk density, a high purity and a reduced content of hydrogen.

Abstract: An apparatus for controlling a molten salt electrolyzer in which an electrolytic bath in a solid form as contained in the electrolyzer is melted to automatically attain a state allowing electrolysis, which apparatus comprises detecting means for detecting the changes in state of the electrolyzer by means of detectors fitted to the electrolyzer, and adjusting means for adjusting, after using the detecting means, the liquid electrolytic bath levels to a state allowing electrolysis.

Abstract: An F2 gas generating apparatus for generating a high purity F2 gas by subjecting an electrolytic bath made of KF.2HF to electrolysis is characterized by comprising a preparing system for preparing KF.2HF from KF or KF.HF, an HF supplying system for supplying HF into the electrolytic bath and the preparing system, and an F2 gas generating system for generating the F2 gas by subjecting KF.2HF prepared by the preparing system to electrolysis.

Abstract: The invention provides a method and apparatus for current control in gas generators capable of generating a fluorine or fluoride gas by and in which the electrolysis can be maintained in an optimum condition, stable operation is possible and no manpower is demanded. According to the method of current control in gas generators for generating a fluorine or fluoride gas by electrolysis of an electrolytic bath 5 comprising a hydrogen fluoride-containing mixed molten salt using a carbon electrode as the anode 4a, the range of voltage fluctuation between the cathode 4b and anode 4a as occurring when a certain current is applied to the gas generator is measured, and current application is continued while varying the current amount to be applied according to the voltage fluctuation range.

Abstract: A fluorine gas generating apparatus for generating fluorine gas of high purity by electrolysis of a mixed molten-salt comprising hydrogen fluoride, the fluorine gas generating apparatus comprising an electrolytic cell which is separated into an anode chamber 5 and a cathode chamber 7 by a partition wall 28, and pressure keeping means 50 for supplying gas to the anode chamber 5 and the cathode chamber 7, respectively, to keep an interior of the anode chamber 5 and an interior of the cathode chamber 7 at a certain pressure.

Abstract: A diamond electrode having a prolonged life by combining a conventional diamond electrode having a relatively short life with other components is provided. A diamond electrode for electrolysis includes an electrode substrate, at least the surface of which comprises Magneli phase titanium oxide, and conductive diamond supported as an electrode catalyst on a surface of the electrode. The electrode catalyst may contain a titanium oxide powder. Magneli phase titanium oxide improves conductivity without forming a stable oxide layer on the substrate surface.

Abstract: The present invention relates to an electrolytic apparatus for molten salt having an electrolytic cell to electrolyze an electrolytic bath consists of a mixed molten salt comprises a first heat exchanging means to heat and/or cool the electrolytic cell body, and an outer flame disposed outside of the first heat exchanging means with space and to seal the first exchanging means, and a heat insulating zone capable of decompression or vacuum formed inside the outer flame. Further, an electric insulating material and a gas sealing material which are placed in the electrolytic cell required the electric insulating and the gas sealing simultaneously.

Abstract: A fluorine gas generator for generating fluorine gas by electrolysis of an electrolytic bath comprising a hydrogen fluoride-containing mixed molten salt in which generator the electrolytic bath will not corrode the upstream line even upon interruption of HF feeding or in case of emergency is provided. The generator has a hydrogen fluoride gas feed line for feeding hydrogen fluoride gas into the electrolytic bath, a first automatic valve disposed on the hydrogen fluoride gas feed line and capable of being closed on the occasion of interruption of hydrogen fluoride gas feeding, and an inert gas substitution means for eliminating the hydrogen fluoride gas remaining in the line on the side downstream from the first automatic valve on the hydrogen fluoride gas feed line and substituting an inert gas therefor when hydrogen fluoride gas feeding is interrupted.

Abstract: A fluorine gas generator for generating fluorine gas by electrolysis of an electrolytic bath comprising a hydrogen fluoride-containing mixed molten salt in which generator the position of the electrolytic bath liquid surface in the electrolytic cell can be safely controlled even during suspension of electrolysis therein is provided. The generator comprises an anode chamber and a cathode chamber separated from each other by a partition wall and is provided with electrolytic bath liquid level controlling means for controlling the electrolytic bath liquid level in at least one of the anode chamber and cathode chamber during suspension of fluorine gas generation.