Abstract: Disclosed is a grain-finished leather-like sheet including: a fiber base material; and a polyurethane skin film stacked, as a surface layer, directly on the fiber base material or via another polyurethane layer, wherein the polyurethane skin film contains at least one of a diketopyrrolopyrrole-based red pigment and an ?-type phthalocyanine-based blue pigment, the grain-finished leather-like sheet further includes a clear polyurethane film layer coating the polyurethane skin film, and the grain-finished leather-like sheet has a grade of color difference, determined using a Grey scale for assessing staining, of 4-5 or more, when 0.03 g of oleic acid is added dropwise to a surface of the clear polyurethane film layer, and thereafter a white cotton fabric is reciprocated 100 times on the surface, using a crockmeter.

Abstract: Disclosed is a leather-dike sheet including a fiber base material and a colored resin layer laminated on the fiber base material, wherein the colored resin layer includes an intermediate layer and a skin layer laminated on the intermediate layer, wherein the skin layer is a layer containing polyurethane and a black pigment of 3 g/m2 or more, and the intermediate layer is a layer containing polyurethane and a black pigment, and in the L*a*b* color system, a leather-like sheet having a lightness value of L*?30 is used.

Abstract: Disclosed is a grain-finished leather-like sheet including a polyurethane skin film containing a polyether-based polyurethane, wherein the polyurethane skin film contains a quinacridone-based red pigment, and is colored in a red color having an L* value of ?80, an a* value of ?20, and a b* value of ?15 in an L*a*b* color system, and the number of cycles of a flexing endurance test at which cracking occurs in a surface of the polyurethane skin film is 100000 or more, when the flexing endurance test is performed on the grain-finished leather-like sheet under an environment of 20° C. using a flexometer after the grain-finished leather-like sheet has been irradiated with carbon arc at a black panel temperature of 63° C. for 100 hours with an irradiance of 500±50 W/m2, using ultraviolet carbon arc lamp light compliant with JIS B 7751.

Abstract: Disclosed is a grain-finished leather-like sheet including: a fiber base material; a polyurethane intermediate layer stacked on the fiber base material; and a polyurethane skin film stacked directly on the polyurethane intermediate layer or via another polyurethane layer, wherein the polyurethane skin film contains a silicone-modified polyurethane, and the grain-finished leather-like sheet has an uneven surface whose skewness (Ssk), kurtosis (Sku), and maximum height (Sz) of surface roughness in accordance with ISO 25178 respectively satisfy ?0.4?Ssk??0.2, 3?Sku?4, 60 ?m?Sz?150 ?m.

Abstract: Disclosed is a grain-finished leather-like sheet including: a fiber base material; and a polyurethane skin film stacked, as a surface layer, directly on the fiber base material or via another polyurethane layer, wherein the polyurethane skin film contains at least one of a diketopyrrolopyrrole-based red pigment and an ?-type phthalocyanine-based blue pigment, the grain-finished leather-like sheet further includes a clear polyurethane film layer coating the polyurethane skin film, and the grain-finished leather-like sheet has a grade of color difference, determined using a Grey scale for assessing staining, of 4-5 or more, when 0.03 g of oleic acid is added dropwise to a surface of the clear polyurethane film layer, and thereafter a white cotton fabric is reciprocated 100 times on the surface, using a crockmeter.

Abstract: Disclosed herein is a method for producing an elastically stretchable artificial leather, which includes the steps of forming microfiberizable fibers into a web, entangling the obtained web to produce an entangled nonwoven fabric, converting the microfiberizable fibers in the nonwoven fabric to microfine fibers thereby producing a substrate for artificial leather, producing an artificial leather from the obtained substrate for artificial leather, bringing the obtained artificial leather into close contact with an elastomer sheet stretched in a machine direction by 5 to 40%, shrinking the artificial leather in the machine direction simultaneously with the elastomer sheet by relaxing elongation of the elastomer sheet to obtain an artificial leather in shrunk state, heat treating the artificial leather in shrunk state, and then peeling the heat treated artificial leather off from the elastomer sheet.

Abstract: Disclosed is a grain-finished leather-like sheet including: a fiber base material; a polyurethane intermediate layer stacked on the fiber base material; and a polyurethane skin film stacked directly on the polyurethane intermediate layer or via another polyurethane layer, wherein the polyurethane skin film contains a silicone-modified polyurethane, and the grain-finished leather-like sheet has an uneven surface whose skewness (Ssk), kurtosis (Sku), and maximum height (Sz) of surface roughness in accordance with ISO 25178 respectively satisfy ?0.4?Ssk??0.2, 3?Sku?4, 60 ?m?Sz?150 ?m.

Abstract: Disclosed is a grain-finished leather-like sheet including a polyurethane skin film containing a polyether-based polyurethane, wherein the polyurethane skin film contains a quinacridone-based red pigment, and is colored in a red color having an L* value of ?80, an a* value of ?20, and a b* value of ?15 in an L*a*b* color system, and the number of cycles of a flexing endurance test at which cracking occurs in a surface of the polyurethane skin film is 100000 or more, when the flexing endurance test is performed on the grain-finished leather-like sheet under an environment of 20° C. using a flexometer after the grain-finished leather-like sheet has been irradiated with carbon arc at a black panel temperature of 63° C. for 100 hours with an irradiance of 500±50 W/m2, using ultraviolet carbon arc lamp light compliant with JIS B 7751.

Abstract: Disclosed is a production method of a napped artificial leather including the steps of: providing a fiber sheet including a non-woven fabric of ultrafine fibers with a fineness of 1 dtex or less that has been impregnated with a first elastic polymer; napping one or both surfaces of the fiber sheet to form a napped surface thereon; applying, to the napped surface, a resin solution containing a second elastic polymer having solubility in a predetermined solvent; and applying the predetermined solvent to the surface to which the resin solution is applied. Also disclosed is a napped artificial leather including a fiber sheet obtained by impregnating a first elastic polymer into a non-woven fabric that is an entangled body of ultrafine fibers with a fineness of 1 dtex or less, wherein the fiber sheet includes, on one or both surfaces thereof, a napped surface obtained by the ultrafine fibers, and a second elastic polymer is fixed to basal portions of the napped ultrafine fibers.

Abstract: A production method of an elastically stretchable artificial leather which includes a step of making microfiberizable fibers into a web; a step of entangling the obtained web to produce an entangled nonwoven fabric; a step of converting the microfiberizable fibers in the nonwoven fabric to microfine fibers, thereby producing a substrate for artificial leather; a step of producing an artificial leather by using the obtained substrate for artificial leather; and a step wherein the obtained artificial leather is brought into close contact with an elastomer sheet stretched in a machine direction by 5 to 40%; the artificial leather is allowed to shrink in the machine direction simultaneously with allowing the elastomer sheet to shrink in the machine direction by relaxing elongation of the elastomer sheet; the artificial leather is heat-treated in shrunk state; and then the artificial leather is peeled off from the elastomer sheet.

Abstract: Disclosed herein is a method for producing an elastically stretchable artificial leather, which includes the steps of forming microfiberizable fibers into a web, entangling the obtained web to produce an entangled nonwoven fabric, converting the microfiberizable fibers in the nonwoven fabric to microfine fibers thereby producing a substrate for artificial leather, producing an artificial leather from the obtained substrate for artificial leather, bringing the obtained artificial leather into close contact with an elastomer sheet stretched in a machine direction by 5 to 40%, shrinking the artificial leather in the machine direction simultaneously with the elastomer sheet by relaxing elongation of the elastomer sheet to obtain an artificial leather in shrunk state, heat treating the artificial leather in shrunk state, and then peeling the heat treated artificial leather off from the elastomer sheet.

Abstract: Disclosed is a production method of a napped artificial leather including the steps of: providing a fiber sheet including a non-woven fabric of ultrafine fibers with a fineness of 1 dtex or less that has been impregnated with a first elastic polymer; napping one or both surfaces of the fiber sheet to form a napped surface thereon; applying, to the napped surface, a resin solution containing a second elastic polymer having solubility in a predetermined solvent; and applying the predetermined solvent to the surface to which the resin solution is applied. Also disclosed is a napped artificial leather including a fiber sheet obtained by impregnating a first elastic polymer into a non-woven fabric that is an entangled body of ultrafine fibers with a fineness of 1 dtex or less, wherein the fiber sheet includes, on one or both surfaces thereof, a napped surface obtained by the ultrafine fibers, and a second elastic polymer is fixed to basal portions of the napped ultrafine fibers.

Abstract: This copper alloy wire consists of a precipitation strengthening type copper alloy containing Co, P, and Sn, wherein an average grain size of precipitates observed through cross-sectional structure observation immediately after performing an intermediate aging heat treatment is equal to or less than 15 nm and a number of precipitates having grain sizes of equal to or less than 5 nm is 10% or higher of a total number of observed precipitates, and the copper alloy wire is subjected to cold working and a final aging heat treatment after the intermediate aging heat treatment.

Abstract: A copper alloy trolley wire includes: 0.12 mass % to 0.40 mass % of Co; 0.040 mass % to 0.16 mass % of P; 0.005 mass % to 0.70 mass % of Sn; and the balance including Cu and unavoidable impurities, wherein precipitates have an average grain size of equal to or greater than 10 nm, and the number of precipitates having a grain size of equal to or greater than 5 nm is 90% or greater of the total number of observed precipitates, and a heat resistance HR defined by HR=TS1/TS0×100 in which TS0 is an initial tensile strength and TS1 is a tensile strength after holding the copper alloy trolley wire at 400° C. for 2 hours, is equal to or greater than 90%.

Abstract: A copper alloy wire of the present invention consists of a precipitation strengthening type copper alloy containing Co, P, and Sn, wherein an average grain size of precipitates observed through cross-sectional structure observation immediately after performing an aging heat treatment is equal to or greater than 15 nm and a number of precipitates having grain sizes of equal to or greater than 5 nm is 80% or higher of a total number of observed precipitates, and the copper alloy wire is subjected to cold working after the aging heat treatment.

Abstract: A production method of an elastically stretchable artificial leather which includes a step of making microfiberizable fibers into a web; a step of entangling the obtained web to produce an entangled nonwoven fabric; a step of converting the microfiberizable fibers in the nonwoven fabric to microfine fibers, thereby producing a substrate for artificial leather; a step of producing an artificial leather by using the obtained substrate for artificial leather; and a step wherein the obtained artificial leather is brought into close contact with an elastomer sheet stretched in a machine direction by 5 to 40%; the artificial leather is allowed to shrink in the machine direction simultaneously with allowing the elastomer sheet to shrink in the machine direction by relaxing elongation of the elastomer sheet; the artificial leather is heat-treated in shrunk state; and then the artificial leather is peeled off from the elastomer sheet.

Abstract: An object of the invention is to provide a leather-like sheet having excellent water absorbability (sweat absorbability, defined the same hereinafter), providing a natural leather-like touch, and suitably used as a ball covering or a non-slip covering, without lowering surface wear resistance. An aspect of the invention is directed to a leather-like sheet including a base material having an entangled fiber sheet; and a porous elastic resin layer laminated on a surface of the base material. The porous elastic resin layer has a concave-convex surface. The concave-convex surface of the porous elastic resin layer includes a projection having a top surface and a side surface, and a recess having a bottom surface contiguous to the side surface. The top surface of the projection has openings with a diameter from 10 to 500 nm at a density of 1,000 openings/mm2 or more.

Abstract: Provided are: a sheet-like ball material including a fibrous base material, and an elastic polymer cover layer that is laminated on a surface of the fibrous base material, in which continuous pebbles and discontinuous valleys are formed on a surface of the cover layer, the valleys discontinuously formed are formed at average intervals of 0.5 to 3 mm, the valley has a depth of 50 to 500 ?m, a vertical projected area of each valley is 1 to 5 mm2, and a total area of the vertical projected area of each valley accounts for 3 to 30% relative to a surface area of the elastic polymer cover layer; a ball used for volleyball or beach volleyball including the sheet-like ball material, which is excellent in the controllability for all types of ball plays such as tossing and serving in the smoothness of the attenuation degree in the ball speed of the ball during flight of the ball, and in the design, e.g.

Abstract: A grain-finished leather-like sheet having a fibrous substrate layer, a polyurethane non-porous layer and a polyurethane surface layer which are successively laminated in this order. The polyurethane surface layer contains a binder polyurethane and polyurethane fine particles having a particle size of 1 to 50 ?m. The total thickness of the polyurethane non-porous layer and the polyurethane surface layer is 150 ?m or more. The polyurethane surface layer contains the polyurethane fine particles in an amount of 10 to 40 parts by mass per 100 parts by mass of the binder polyurethane. The polyurethane fine particles are not exposed to the surface. The grain-finished leather-like sheet characterized by the above features has a smooth and luster surface, a good hand, and excellent scratch resistance, abrasion resistance and buckling wrinkle resistance. The sheet hardly damages or soils an object which is in contact with its surface by friction.

Abstract: In a rotation shaft seal provided with a rubber lip portion, disposed between a housing and a rotation shaft and sliding on the rotation shaft, and a supporting member receiving the lip portion from a low-pressure side, the cross-sectional configuration of the lip portion in free state is a trapezoid diminishing to the end having the maximum thickness portion within an area received by the supporting member.