Abstract: This invention relates to a curable coating composition comprising: I. at least one acetoacetate functional polyester further comprising the residues of a. a hydroxyl component comprising: i. a diol in an amount ranging from 70 to 100 mole %, based on the total moles of (i) and (ii); and ii. a polyol in an amount ranging from 0 to 30 mole %, based on the total moles of (i) and (ii); b. a carboxyl component comprising a polycarboxylic acid compound, a derivative of polycarboxylic acid compound, or a combination thereof; and c. an alkyl acetoacetate, a diketene, or a combination thereof in an amount ranging from about 5 to about 50 weight %, based on the total weight of (a), (b), and (c). II. a curing agent having two or more aldehyde functional groups, and III. a basic catalyst.

Abstract: This invention pertains to coating compositions based on a blend of polyester containing 2,2,4,4-tetramethyl-1,3-cyclobutanediol (TMCD) and malonic polyester. Coatings based on such polyester blends are capable of providing a good balance of the desirable coating properties, such as solvent resistance, retort resistance, microcracking resistance, and bending ability, for metal packaging applications.

Abstract: This invention relates to polyesteramide compositions that are curable with isocyanates, phenolic resins, amino resins, or a combination thereof. The polyesteramide compositions comprise a cycloaliphatic diol such as 2,2,4,4-tetramethyl-1,3-cyclobutanediol (TMCD). Coating compositions prepared from such polyesteramides are capable of providing a good balance of the desirable coating properties such as solvent resistance and wedge bend resistance for metal packaging applications.

Abstract: Disclosed are novel curable polyesters comprising the reaction product of 2,2,4,4-tetramethyl-1,3-cyclobutanediol (TMCD) and dimethylolpropionic acid. The curable polyesters have particular utility in waterborne coating compositions. Such waterborne coating compositions provide a good balance of desirable coating properties for metal packaging applications.

Abstract: Disclosed are novel curable acrylic modified polyesters comprising the reaction product of 2,2,4,4-tetramethyl-1,3-cyclobutanediol (TMCD) and dimethylolpropionic acid modified by an acrylic graft. The curable acrylic modified polyesters have particular utility in waterborne coating compositions. Such waterborne coating compositions provide a good balance of desirable coating properties for metal packaging applications.

Abstract: Disclosed are novel curable acrylic modified polyesters comprising the reaction product of 2,2,4,4-tetramethyl-1,3-cyclo butanediol (TMCD) modified by a polycarboxylic acid anhydride. The curable acrylic modified polyesters have particular utility for use in waterborne coating compositions containing a crosslinker. Such waterborne coating compositions provide a good balance of desirable coating properties for metal packaging applications.

Abstract: This invention relates to adhesive compositions comprising a polyester polyol that includes residues of at least one 2, 2, 4, 4-tetraalkylcyclobutane-1, 3-diol, including, for example, 2, 2, 4, 4-tetramethylcyclobutane-1, 3-diol (TMCD). Adhesive compositions as described herein exhibit enhanced properties as compared to conventional adhesive compositions, and may be suitable for a wide variety of end use applications, including, flexible packaging, woodworking, automotive uses, and electronics.

Abstract: This invention pertains to improved polyester polyol compositions comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol (TMCD). Coating compositions based on such TMCD polyester polyols are capable of providing a good balance of the desirable coating properties, such as solvent resistance, acid resistance, retort resistance, microcracking resistance, and bending ability, for metal packaging applications.

Abstract: Adhesive compositions comprising a polyester polyol that includes residues of at least one 2,2,4,4-tetraalkylcyclobutane-1,3-diol, including, for example, 2,2,4,4-tetramethylcyclobutane-1,3-diol (TMCD). Adhesive compositions may exhibit enhanced properties as compared to conventional adhesive compositions, and may be suitable for a wide variety of end use applications, including, flexible packaging, woodworking, automotive uses, and electronics.

Abstract: Polyesters having both ?,?-unsaturated groups and moieties containing activated methylene or methine groups, such as those of beta-ketoester and malonate, are curable in the presence of a base catalysts to form crosslinked networks. Formulations based on such polyesters are suitable for use in coatings and cure at temperatures less than 230° C. without the use of isocyanates.

Abstract: This invention pertains to improved polyester polyol compositions comprising 1,3-cyclohexanedimethanol (1,3-CHDM). Coating compositions based on such polyester polyols are capable of providing a good balance of the desirable coating properties, such as solvent resistance, acid resistance, retort resistance, microcracking resistance, and bending ability, for metal packaging applications.

Abstract: This invention pertains to improved polyester polyol compositions containing 2,2,4,4-tetramethyl-1,3-cyclobutanediol (TMCD). Coating compositions based on such TMCD polyester polyols are capable of providing a good balance of desirable coating properties such as solvent resistance, acid resistance, retort resistance, microcracking resistance, and bending ability. The TMCD coating compositions have particular utility for use in metal packaging applications.

Abstract: This invention pertains to coating compositions based on polyesters containing 2,2,4,4-tetrametbyM,3-cyclobutanediol (TMCD) and modifying polyester polyols. Coatings based on such polyester blends are capable of providing a good balance of the desirable coating properties, such as solvent resistance, acid resistance, retort resistance, crazing resistance, and bending ability, for metal packaging applications.

Abstract: This invention pertains to a curable composition comprising a first component having ?-ketoester and/or malonate functionalities and a second component having two or more aldehyde functionalities. The compositions can be cured at room temperature or low temperatures to yield crosslinked networks that are capable of providing desirable properties for coating and adhesive applications. The reactive functionalities of ?-ketoester, malonate, and aldehyde can be either on polymers as the main binders or on small molecules as the crosslinkers. The curable compositions desirably are either solventless or organic solvent based.

Abstract: Disclosed are curable adhesive compositions comprising hydroxyl functional polymers and silane functionalized resins. Such adhesive compositions are capable of providing unexpected properties for various uses and end products. The adhesive may be used for woodworking, automotive, textile, appliances, electronics, bookbinding, and packaging. Suitable substrates can be metal, polymer film, plastics, wood, glass, ceramic, paper, and concrete.

Abstract: Disclosed are silane functionalized rosins having multiple functionalities. Such silane functionalized rosins are curable and thus capable of providing unexpected properties for various uses and end products. Also disclosed are synthetic routes to prepare silane functionalized rosins, which are formulated with hydroxyl functional polymers to provide curable adhesive compositions. The adhesives may be used for woodworking, automotive, textile, appliances, electronics, bookbinding, and packaging. Suitable substrates can be metal, polymer film, plastics, wood, glass, ceramic, paper, and concrete.

Abstract: This invention relates to a curable composition comprising: I. a first component comprising a resin having at least one functional group selected from the group consisting of ?-ketoester and malonate functional groups, II. a second component comprising at least one curing agent having at least one aldehyde functional group, and III. a third component comprising at least one primary amine or at least one secondary amine, salts thereof, or combinations thereof.

Abstract: This invention relates to a curable adhesive composition comprising: I. Component (I) comprising at least one amorphous or semi-crystalline polyester or at least one polyether or combinations thereof having at least one or at least two functional groups selected from the group consisting of ?-ketoester and malonate functional groups, II. Component (II) comprising at least one or at least two aldehyde functional groups or isomers thereof, and III. Component (III) comprising at least one basic catalyst, salts thereof, or combinations thereof.

Abstract: This invention relates to an assembly component comprising at least one substrate coated with at least one curable composition comprising: I. a first component (I) comprising a resin having at least one functional group selected from the group consisting of ?-ketoester and malonate functional groups, II. a second component (II) comprising at least one curing agent having at least one aldehyde functional group, and III. a third component (III) comprising at least one compound having amine functionality, salts thereof, or combinations thereof.

Abstract: Polyesters having both ?,?-unsaturated groups and moieties containing activated methylene or methine groups, such as those of beta-ketoester and malonate, are curable in the presence of a base catalysts to form crosslinked networks. Formulations based on such polyesters are suitable for use in coatings and cure at temperatures less than 230° C. without the use of isocyanates.