Publication number: 20120283371
Abstract: A method for casting a styrenic fluoropolymer film on a substrate includes preparing a polymer solution by dissolving the fluoropolymer in a solvent or solvent blend whose Hansen solubility parameters (HSPs. MPa1/2) satisfy the following relations: |SPb?SPp|<5, |SPb?SPs|<4, |SPb(H)?SPp(H)|<7, and 2<|SPb(H)?SPs(H)|<10 wherein SPb, SPp, SPs, are the total Hansen solubility parameters of solvent/solvent blend, fluoropolymer, and substrate, respectively; SPb(H), SPp(H), and, SPs(H) are the hydrogen-bond Hansen solubility parameters of solvent/solvent blend, fluoropolymer, and substrate, respectively; wherein the fluoropolymer comprises a moiety of: wherein R1, R2, and R3 are each independently hydrogen atoms, alkyl groups, substituted alkyl groups, or halogens, wherein at least one of R1, R2, and R3 is a fluorine atom, and wherein R is each independently a substituent on the styrenic ring, n is an integer from 0 to 5 representing the number of the substituents on the styrenic ring.
Type:
Application
Filed:
May 1, 2012
Publication date:
November 8, 2012
Applicant:
AKRON POLYMER SYSTEMS, INC.
Inventors:
BIN WANG, THAUMING KUO, DOUGLAS STEPHENS McWILLIAMS, FRANK W. HARRIS, TED CALVIN GERMROTH, JIAOKAI JING, DONG ZHANG, XIAOLIANG ZHENG