Patents by Inventor Thomas Haring

Thomas Haring has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20150232624
    Abstract: A method is disclosed for production of solutions of aminophosphonic acids and polymeric sulfonic acids in aprotic solvents. Membranes for membrane methodologies are produced from said solutions. Said membranes can also be doped with phosphoric acid.
    Type: Application
    Filed: May 4, 2015
    Publication date: August 20, 2015
    Inventor: Thomas Häring
  • Patent number: 9023557
    Abstract: A method is disclosed for production of solutions of aminophosphonic acids and polymeric sulphonic acids in aprotic solvents. Membranes for membrane methodologies are produced from said solutions. Said membranes can also be doped with phosphoric acid.
    Type: Grant
    Filed: January 23, 2007
    Date of Patent: May 5, 2015
    Assignee: Between Lizenz GmbH
    Inventor: Thomas Häring
  • Publication number: 20150064609
    Abstract: Ionomers and ionomer membranes, consisting of a non-fluorinated or partly fluorinated non-, partly or fully-aromatic main chain and a non- or partly-fluorinated side chain with ionic groups or their non-ionic precursors, have a positive impact on the proton conductivity of the ionomers. Various processes produce these polymeric proton conductors.
    Type: Application
    Filed: November 12, 2014
    Publication date: March 5, 2015
    Inventors: Thomas Häring, Rima Häring
  • Publication number: 20140213672
    Abstract: The invention relates to blends and blend membranes from low-molecular hydroxymethylene-oligo-phosphonic acids R—C(PO3H2)x(OH)y and polymers, the group R representing any organic group and the polymers containing the following functional groups: cation exchanger groups or their nonionic precursors of the type SO2X, X?HaI, OH, OMe, NR1R2, OR1 with Me=any metal cation or ammonium cation, R1, R2=H or any aryl- or alkyl group, POX2, COX and/or basic groups such as primary, secondary or tertiary amino groups, imidazole groups, pyridine groups, pyrazole groups etc. and/or OH groups. Low molecular hydroxymethylene-oligo-phosphonic acids R—C(PO3H2)x(OH)y are preferred in which x=2 and y=1. The invention also relates to low-molecular hydroxymethylene-oligo-phosphonic acids R—C(PO3H2)2(OH)1 and polymers, wherein the group R of the hydroxymethylene-oligophosphonic acid contains an aliphatic or aromatic basic group which ionically interacts with the acidic groups of the polymer or of the polymer mixture.
    Type: Application
    Filed: January 27, 2014
    Publication date: July 31, 2014
    Inventor: Thomas Häring
  • Publication number: 20140155502
    Abstract: A non crosslinked, covalently crosslinked and/or conically crosslinked polymer, having repeating units of the general formula (1) —K—R—??(1) In which K is a bond, oxygen, sulfur, the radical R is a divalent radical of an aromatic or heteroaromatic compound.
    Type: Application
    Filed: February 10, 2014
    Publication date: June 5, 2014
    Inventor: Thomas Häring
  • Patent number: 8742021
    Abstract: Ionomers and ionomer membranes, consisting of a non-fluorinated or partly fluorinated non-, partly or fully-aromatic main chain and a non- or partly-fluorinated side chain with ionic groups or their non-ionic precursors, have a positive impact on the proton conductivity of the ionomers. Various processes produce these polymeric proton conductors.
    Type: Grant
    Filed: December 19, 2011
    Date of Patent: June 3, 2014
    Assignee: Thomas Häring and Rima Häring
    Inventors: Thomas Haring, Jochen Kerres, Martin Hein
  • Patent number: 8710175
    Abstract: A non crosslinked, covalently crosslinked and/or ionically crosslinked polymer, having repeating units of the general formula (1) —K—R—??(1) In which K is a bond, oxygen, sulfur, the radical R is a divalent radical of an aromatic or heteroaromatic compound.
    Type: Grant
    Filed: March 14, 2011
    Date of Patent: April 29, 2014
    Inventor: Thomas Häring
  • Patent number: 8637174
    Abstract: Various blends and blend membranes from low-molecular hydroxymethylene-oligo-phosphonic acids R—C(PO3H2)x(OH)y and polymers, the group R representing any organic group, the polymers containing cation exchanger groups or their nonionic precursors of the type SO2X, X being a halogen, OH, OMe, NR1R2, OR1 with Me being any metal cation or ammonium cation, R1, R2 being H or any aryl- or alkyl group, PDX2, COX and/or basic groups such as primary, secondary or tertiary amino groups, imidazole groups, pyridine groups, pyrazole groups etc. and/or OH groups. Such membranes may also include polymers that are modified with the 1-hydroxymethylene-1,1-bisphosphonic acid group.
    Type: Grant
    Filed: February 5, 2007
    Date of Patent: January 28, 2014
    Inventors: Thomas Häring, Jochen Kerres, Frank Schönberger, Martin Hein
  • Patent number: 8629216
    Abstract: Ionomers and ionomer membranes, consisting of a non-fluorinated or partly fluorinated non-, partly or fully-aromatic main chain and a non- or partly-fluorinated side chain with ionic groups or their non-ionic precursors, have a positive impact on the proton conductivity of the ionomers. Various processes produce these polymeric proton conductors.
    Type: Grant
    Filed: December 19, 2011
    Date of Patent: January 14, 2014
    Assignee: Thomas Häring and Rima Häring
    Inventors: Thomas Haring, Jochen Kerres, Martin Hein
  • Publication number: 20120248031
    Abstract: The invention relates to a composite or a composite membrane consisting of an ionomer and of an inorganic optionally functionalized phyllosilicate. The isomer can be: (a) a cation exchange polymer; (b) an anion exchange polymer; (c) a polymer containing both anion exchanger groupings as well as cation exchanger groupings on the polymer chain; or (d) a blend consisting of (a) and (b), whereby the mixture ratio can range from 100% (a) to 100% (b). The blend can be ionically and even covalently cross-linked. The inorganic constituents can be selected from the group consisting of phyllosilicates or tectosilicates.
    Type: Application
    Filed: February 6, 2012
    Publication date: October 4, 2012
    Inventors: Jochen Kerres, Thomas Häring, Rima Häring
  • Publication number: 20120245237
    Abstract: Ionomers and ionomer membranes with the ionic group on a flexible side chain have a positive impact on the proton conductivity of the ionomers. Various processes produce these polymeric proton conductors.
    Type: Application
    Filed: December 19, 2011
    Publication date: September 27, 2012
    Inventors: Thomas Häring, Jochen Kerres, Martin Hein
  • Publication number: 20120088095
    Abstract: The Invention relates to a drawn polymer film, comprising (A) a polymer or polymer blend and at least (B) one additional component with an average particle diameter of between 0.1 and 15 ?m, which by means of (C) one or several secondary treatment steps is processed to form a membrane after being drawn. The average particle diameter of component (B) ranges between 0.1 and 15 ?m, preferably 0.5-8.0 ?m, with the range between 1.0 and 7.0 ?m being particularly preferred. The membranes are used for alkene-alkane separation, electrodialysis, the desalinisation of seawater, in fuel cell applications and other membrane applications.
    Type: Application
    Filed: December 16, 2011
    Publication date: April 12, 2012
    Inventors: Thomas Häring, Rima Häring
  • Patent number: 8110517
    Abstract: The invention relates to a composite or a composite membrane consisting of an ionomer and of an inorganic optionally functionalized phyllosilicate. The isomer can be: (a) a cation exchange polymer; (b) an anion exchange polymer; (c) a polymer containing both anion exchanger groupings as well as cation exchanger groupings on the polymer chain; or (d) a blend consisting of (a) and (b), whereby the mixture ratio can range from 100% (a) to 100% (b). The blend can be ionically and even covalently cross-linked. The inorganic constituents can be selected from the group consisting of phyllosilicates or tectosilicates.
    Type: Grant
    Filed: October 21, 2009
    Date of Patent: February 7, 2012
    Inventors: Jochen Kerres, Thomas Häring, Rima Häring
  • Publication number: 20120004330
    Abstract: A non crosslinked, covalently crosslinked and/or ionically crosslinked polymer, having repeating units of the general formula (1) —K—R—??(1) In which K is a bond, oxygen, sulfur, the radical R is a divalent radical of an aromatic or heteroaromatic compound.
    Type: Application
    Filed: March 14, 2011
    Publication date: January 5, 2012
    Inventor: Thomas Häring
  • Patent number: 8079480
    Abstract: The Invention relates to a drawn polymer film, comprising (A) a polymer or polymer blend and at least (B) one additional component with an average particle diameter of between 0.1 and 15 ?m, which by means of (C) one or several secondary treatment steps is processed to form a membrane after being drawn. The average particle diameter of component (B) ranges between 0.1 and 15 ?m, preferably 0.5-8.0 ?m, with the range between 1.0 and 7.0 ?m being particularly preferred. The membranes are used for alkene-alkane separation, electrodialysis, the desalinisation of seawater, in fuel cell applications and other membrane applications.
    Type: Grant
    Filed: May 13, 2002
    Date of Patent: December 20, 2011
    Inventors: Thomas Häring, Rima Häring
  • Patent number: 8030414
    Abstract: The invention relates to novel polymers or oligomers containing at least sulfinate groups (P—(SO2)nX, X=1-(n=1), 2-(n=2) or 3-(n=3) valent metal cation or H+ or ammonium ion NR4+ where R=alkyl, aryl, H), which are obtained by completely or partially reducing polymers or oligomers containing at least SO2Y-groups (Y?F, Cl, Br, I, OR, NR2 (R=alkyl and/or aryl and/or H), N-imidazolyl, N-pyrazolyl) by means of suitable reducing agents in a suspension or in a solution form. Polymer and polymer(blend)membranes which are obtained by further reacting the received sulfinated polymers, especially by alkylation of the sulfinate groups with mono- di- or oligo functional electrophiles. The invention further relates to methods for producing the sulfinated polymers and for further reacting the sulfinated polymers with electrophiles by S-alkylation.
    Type: Grant
    Filed: November 26, 2008
    Date of Patent: October 4, 2011
    Inventors: Thomas Haring, Jochen Kerres, Wei Zhang
  • Publication number: 20110104367
    Abstract: A method for producing membranes and membrane electrode units by laying thin film layers on a porous carrier substrate. The layers are applied using only one of several production methods, but have different functional properties. These membranes and membrane electrode units may be used to generate energy by electrochemical or photochemical processes, particularly applicable in fuel cells.
    Type: Application
    Filed: January 12, 2011
    Publication date: May 5, 2011
    Inventor: Thomas Häring
  • Publication number: 20100151352
    Abstract: The invention relates to the following types of composite membranes; composites or composite membranes obtained by adding a metal salt, e.g. from ZrOCl2, to a solvent, especially DMSO, for dissolving one or more polymers in an organic solvent or in aqueous systems, in addition to the subsequent precipitation in the matrix of the thus produced composite-membrane by post-treatment thereof in an acid or in a salt solution, especially phosphoric acid. The invention also relates to composites or composite membranes obtained by subsequent ion exchange of finished polymer membranes with a suitable salt cation, especially ZrO2+, wherein the polymer membrane is, optionally, swollen with an organic solvent or a mixture of organic solvent with water prior to the ion exchange and the subsequent precipitation of a low soluble salt, e.g. from Zr3(PO4)4, in the membrane by post-treatment thereof in an acid or in a salt solution, especially phosphoric acid.
    Type: Application
    Filed: December 11, 2009
    Publication date: June 17, 2010
    Inventors: Thomas Haring, Vladimir Linkov, Jochen Kerres, Andreas Ullrich, Chy-Ming Tang, Martin Hein, Wei Zhang
  • Publication number: 20100092833
    Abstract: The invention relates to a composite or a composite membrane consisting of an ionomer and of an inorganic optionally functionalized phyllosilicate. The isomer can be: (a) a cation exchange polymer; (b) an anion exchange polymer; (c) a polymer containing both anion exchanger groupings as well as cation exchanger groupings on the polymer chain; or (d) a blend consisting of (a) and (b), whereby the mixture ratio can range from 100% (a) to 100% (b). The blend can be ionically and even covalently cross-linked. The inorganic constituents can be selected from the group consisting of phyllosilicates or tectosilicates.
    Type: Application
    Filed: October 21, 2009
    Publication date: April 15, 2010
    Inventors: Jochen KERRES, Thomas HÄRING, Rima HÄRING
  • Publication number: 20100081783
    Abstract: A non crosslinked, covalently crosslinked and/or ionically crosslinked polymer, having repeating units of the general formula (1) —K—R—??(1) In which K is a bond, oxygen, sulphur, the radical R is a divalent radical of an aromatic or heteroaromatic compound.
    Type: Application
    Filed: November 10, 2009
    Publication date: April 1, 2010
    Inventor: Thomas Haring