Abstract: A cooling film for use in passively cooling an antenna includes an antisoiling layer secured to a first major surface of a reflective microporous layer. The reflective microporous layer comprises a first fluoropolymer and is diffusely reflective of electromagnetic radiation over a majority of wavelengths in the range of 400 to 2500 nanometers. The film can also include an infrared-absorptive layer secured to a second major surface of the film opposite the first major surface, and the infrared-absorptive layer is optionally metallized. The film is shaped into a self-supporting three-dimensional structure, such as fins, and a thermally conductive material is inside the structure and secured to a portion of the antenna, either the front side of the antenna for the non-metallized film or the back side of the antenna for the metallized film.

Abstract: Barrier films including a (co)polymeric substrate, at least one dyad on the substrate, each dyad made of a (co)polymer layer and an oxide layer overlaying the (co)polymer layer, and an outer (co)polymer layer overlaying the dyads. Optionally, at least one outer oxide layer overlays the outer (co)polymer layer. The barrier films transmit visible light and transmits, at an incident light angle of at least one of 0°, 30°, 45°, 60°, or 75°, at most 70 percent of incident ultraviolet light at a wavelength range from at least 100 nanometers to 400 nanometers or in a wavelength range from at least 100 nm to 350 nm. The barrier films exhibit atomic oxygen degradation of less than 1×10?20 mg/atom. The barrier films may be applied to decorative objects or electronic devices, (e.g., light receiving or emitting devices, in a satellite or aircraft. Methods of making the barrier films also are disclosed.

Abstract: Multi-layer films, and processes to make the films, that enable the delivery of a substrate featuring a peelable thin layer of low haze, amorphous, isotropic film with the desired properties of high modulus, high usage temperature, UV blockage, and toughness. The films are made using a co-extrusion, co-orientation and annealing process to enable the delivery of a thin isotropic, UV blocking layer on top of a release layer and support substrate. These film constructions can be kept together during additional processing steps such as coating and converting. The release and dimensionally stable substrate layer can be easily removed once processing steps are completed.

Abstract: The present disclosure provides a microstructured article (830, 930) including a thermoplastic polymer shaped to have a curve. At least a portion of the curve includes a microstructured surface (1010B, 10, 1110A, 200, 300, 400, 500, 600, 810, 840, 910, 940) of utilitarian discontinuities and the microstructured surface (101B, 10, 1110A, 200, 300, 400, 500, 600, 810, 840, 910, 940) includes peak structures and adjacent valleys (810, 910). The peak structures and the curve are formed of a single piece of the thermoplastic polymer. A method of making the microstructured articles is also provided including a) obtaining a tool (820, 920) shaped to include at least one of a protrusion or a concavity; b) disposing a microstructured film (800A, 800C, 900) on at least a portion of the tool (820, 920) including the protrusion and/or the concavity; and c) thermoforming a single piece of thermoplastic polymer onto the tool (820, 920) to form a microstructured article (830, 930) shaped to include a curve.

Abstract: A hybrid solar window comprises: at least one glazing; a wave-length-selective solar mirror positioned to reflect IR toward an IR absorbing element. The IR absorbing elements comprises a conduit having a respective fluid inlet and fluid outlet, and an IR absorbing compound, wherein the IR absorbing compound is in thermal communication with the conduit. The wavelength-selective solar mirror has an average visible light transmittance of at least 50 percent and an average IR reflectance of at least 50 percent over the wavelength range of 850 to 1150 nanometers, inclusive. The IR absorbing element is configured to transfer thermal energy to a heat transfer fluid circulating through the conduit, wherein the IR absorbing element has an average visible light transmittance of at least 30 percent, and wherein each IR absorbing element has an average IR absorptance of at least 50 percent over the wavelength range 850 to 1150 nanometers, inclusive. Certain IR absorbing elements are also disclosed.

Abstract: Ultraviolet light shielding articles are provided. An ultraviolet light shielding article includes a flexible substrate having a major surface and a multilayer optical film disposed on the major surface of the substrate. The multilayer optical film is comprised of at least a plurality of alternating first and second inorganic optical layers collectively reflecting and absorbing at an incident light angle of at least one of 0°, 15°, 30°, 45°, 60°, or 75°, an average of at least 50, 60, 70, 80, 90, or 95 percent of incident ultraviolet light over at least a 30-nanometer wavelength reflection bandwidth in a wavelength range from 190 nanometers (nm) to 400 nm. Solar cell covers including an ultraviolet shielding articles are also provided.

Abstract: Devices are provided, including a housing defining at least one window, a broadband UVC light source, and a multilayer article positioned within the housing. The multilayer article includes an absorbent layer and an ultraviolet mirror containing at least a plurality of alternating first and second optical layers. The absorbent layer absorbs and/or scatters ultraviolet light having a wavelength between at least 230 nanometers (nm) and 400 nm. The ultraviolet mirror reflects ultraviolet light in a wavelength range from 190 nm to 240 nm. Methods of disinfecting a material are also provided, including obtaining a device and directing ultraviolet radiation through the window, and exposing the material to the ultraviolet radiation for a time sufficient to achieve a desired degree of disinfection of the material. Systems and computing devices including the device are also provided.

Abstract: Barrier films including a (co)polymeric substrate, at least one dyad on the substrate, each dyad made of a (co)polymer layer and an oxide layer overlaying the (co)polymer layer, and an outer (co)polymer layer overlaying the dyads. Optionally, at least one outer oxide layer overlays the outer (co)polymer layer. The barrier films transmit visible light and transmits, at an incident light angle of at least one of 0°, 30°, 45°, 60°, or 75°, at most 70 percent of incident ultraviolet light at a wavelength range from at least 100 nanometers to 400 nanometers or in a wavelength range from at least 100 nm to 350 nm. The barrier films exhibit atomic oxygen degradation of less than 1×10?20 mg/atom. The barrier films may be applied to decorative objects or electronic devices, (e.g., light receiving or emitting devices, in a satellite or aircraft. Methods of making the barrier films also are disclosed.

Abstract: Multilayer optical film comprising at least a plurality of alternating first and second optical layers. Embodiments of the multilayer optical film are useful, for example, in UV-C shield, UV-C light collimator, and UV-C light concentrator applications.

Abstract: A device including a housing that is substantially impermeable to ultraviolet radiation having a wavelength of from 280 nm to 400 nm, and at least one window defined in the housing, the window including a UV-C radiation band-pass mirror film having a multiplicity of alternating first and second optical layers collectively transmitting UV-C radiation at a wavelength from at least 100 nm to less than 280 nm and not transmitting UV-A and UV-B radiation at a wavelength of from 280 nm to 400 nm, and an ultraviolet radiation source positioned within the housing, the ultraviolet radiation source being capable of emitting ultraviolet radiation at one or more wavelength from 100 nm to 400 nm. The device optionally further includes an ultraviolet mirror film positioned within the housing so as to reflect ultraviolet radiation emitted by the ultraviolet radiation source. A method of disinfecting a material is also disclosed.

Abstract: The composition includes an antimicrobial monomer represented by formula CH2?C(R1)—C(O)—O-Q-N+(R)2CnH2n+1(X—), a non-fluorinated crosslinking monomer having at least two acrylate groups, methacrylate groups, or a combination thereof, a polar monomer having at least one of acrylic acid, methacrylic acid, or a carboxylate salt thereof, and a nonpolar monomer represented by formula CH2?C(R1)—C(O)—O—R2. The antimicrobial monomer, the non-fluorinated crosslinking monomer, the polar monomer, and the nonpolar monomer together account for greater than 95 percent by weight, based on the total weight of the composition. The article includes a film having a plurality of pendent groups represented by formula —C(O)—O-Q-N+(R)2CnH2n+1(X—) covalently bonded in a crosslinked non-fluorinated acrylic network. A method of making an article is also described.

Abstract: A light guide comprising a polymeric layer at least 25 percent transmissive over at least a 30 nm bandwidth in a wavelength range from 180 to 280 nm over a distance of at least 100 micrometers and visible light transparent reflecting layers (UV-C mirror) that are at least 50 percent reflective over at least 30 nm bandwidth in a wavelength range from 180 to 280 nm over an incident light angle of 0 to 90 degrees and that are at least 25 percent transmissive of visible light over at least 30 nm bandwidth in a wavelength range of 400 to 800 nm over an incident light angle of 0 to 90 degrees. The light guide is useful, for example, for antimicrobial surfaces.

Abstract: Anti-reflective article includes a layer defining an anti-reflective surface. The anti-reflective surface includes a series of alternating micro-peaks and micro-spaces extending along an axis. The surface also includes a series of nano-peaks extending along an axis. The nano-peaks are disposed at least on the micro-spaces and, optionally, the micro-peaks. The article may be disposed on a photovoltaic module or skylight to reduce reflections and resist the collection of dust and dirt.

Abstract: A composite cooling film (100) comprises an antisoiling layer (160) secured to a first major surface of a reflective microporous layer (110). The reflective microporous layer (110) comprises a first fluoropolymer and is diffusely reflective of electromagnetic radiation over a majority of wavelengths in the range of 400 to 2500 nanometers. The antisoiling layer (160) has an outwardly facing antisoiling surface (162) opposite the micro-voided polymer film. An article (1100) comprising the composite cooling film (1112) secured to a substrate (1110) is also disclosed.

Abstract: A low-emissivity film for an article of personal protective equipment (PPE) having a lens is provided. The low-emissivity film is configured to be attached to at least one of an inner surface and an outer surface of the lens. A low-emissivity coating for the article of PPE is also provided.

Abstract: The present disclosure provides a radiative cooling article including a white diffusely reflective microporous layer and a non-white color reflective mirror film having first and second optical layers. The white diffusely reflective microporous layer has a solar weighted reflectivity at normal incidence of electromagnetic radiation over a majority of wavelengths in a range of 350 nanometers (nm) to 2500 nm of 0.8 or greater, 0.85, 0.9, or 0.95 or greater. The non-white color reflective film is disposed adjacent to a major surface of the white diffusely reflective microporous layer and the non-white color reflective film reflects a wavelength bandwidth of at least 30 nm within a wavelength range of 350 nm to 700 nm. The non-white color reflective film can be tuned to reflect light of a specific color (e.g., blue light, green light, or red light). The radiative cooling article may be useful for applications including commercial graphics located outdoors (e.g., on vehicles or buildings).

Abstract: Multilayer articles are provided, including an absorbent layer and an ultraviolet mirror containing at least a plurality of alternating first and second optical layers. The absorbent layer absorbs ultraviolet light having a wavelength between at least 230 nanometers (nm) and 400 nm. The ultraviolet mirror reflects ultraviolet light in a wavelength range from 190 nm to 240 nm. Systems are also provided including a broadband UVC light source and a multilayer article. Devices are provided including a chamber, a broadband UVC light source located within the chamber, an absorbent layer in the chamber, and an ultraviolet mirror between the light source and absorbent layer. Methods of disinfecting a material are further provided, including obtaining a system or device, directing UVC light at the ultraviolet mirror, and exposing the material to ultraviolet light in a wavelength range from 190 nm to 240 nm, reflected by the ultraviolet mirror towards the material.

Abstract: Passive cooling articles may include a first element defining a high absorbance in an atmospheric infrared wavelength range and a high average reflectance in a solar wavelength range. The first element may define a first major surface (114, 214, 314, 414) positioned and shaped to reflect solar energy in the solar wavelength range to an energy absorber (108, 208, 308, 408, 508, 608) spaced a distance from the first major surface (114, 214, 314, 414). The energy absorber (108, 208, 308, 408, 508, 608) may be a heating panel or a photovoltaic cell. A second element may define a high thermal conductivity and thermally coupled to a second major surface (116, 216, 416) of the first element to transfer thermal energy from the second element to the first element to cool the second element.

Abstract: A hybrid solar window comprises: at least one glazing; a wave-length-selective solar mirror positioned to reflect IR toward an IR absorbing element. The IR absorbing elements comprises a conduit having a respective fluid inlet and fluid outlet, and an IR absorbing compound, wherein the IR absorbing compound is in thermal communication with the conduit. The wavelength-selective solar mirror has an average visible light transmittance of at least 50 percent and an average IR reflectance of at least 50 percent over the wavelength range of 850 to 1150 nanometers, inclusive. The IR absorbing element is configured to transfer thermal energy to a heat transfer fluid circulating through the conduit, wherein the IR absorbing element has an average visible light transmittance of at least 30 percent, and wherein each IR absorbing element has an average IR absorptance of at least 50 percent over the wavelength range 850 to 1150 nanometers, inclusive. Certain IR absorbing elements are also disclosed.

Abstract: A composite cooling film including a reflective nonporous inorganic-particle-filled organic polymeric layer, an ultra-violet-protective layer or layers, and an antisoiling layer.