Abstract: A composite cooling film (100) comprises an ultraviolet-reflective multilayer optical film (120) and a reflective microporous layer (110) secured thereto. The ultraviolet-reflective multilayer optical film (120) hat is at least 50 percent reflective of ultraviolet radiation over a majority of the wavelength range of at least 340 but less than 400 nanometers. The reflective microporous layer (110) has a continuous phase comprising a nonfluorinated organic polymer and is diffusely reflective of solar radiation over a majority the wavelength range of 400 to 2500 nanometers, inclusive. The composite cooling film (100) has an average absorbance over the wavelength range 8-13 microns of at least 0.85. An article (1200) comprising the composite cooling film (100) adhered to a substrate (1210) is also disclosed.

Abstract: A method includes reactively extruding a polymeric composition to form a film. The polymeric composition includes a polyisocyanate and at least one dimer fatty diol.

Abstract: A dental appliance includes a polymeric shell with an arrangement of one or more cavities configured to receive one or more teeth, and the polymeric shell includes an antimicrobial lipid, such as monolaurin, and optionally an enhancer.

Abstract: A composite film comprises first and second layers. The first layer comprises a first copolymer of monomers comprising tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride, wherein the first copolymer contains at least 35 mole percent of vinylidene fluoride monomer units. The second layer is disposed on the first layer, and comprises a second copolymer comprising 50 to 83 weight percent of ethylene monomer units and at least 17 weight percent of alkyl (meth)acrylate monomer units represented by the formula (I) wherein R1 is H or methyl, and each R2 is independently an alkyl group having from 1 to 4 carbon atoms. Methods of making the composite film and articles including it are also disclosed.

Abstract: Multilayer infrared (IR) reflecting films are provided. An optical repeating unit of the film include a plurality of optical polymeric layers arranged to reflect light by constructive and destructive interference. Optical layer A is a high refractive index polymeric layer, and optical layer B is a low refractive index isotropic polymeric layer containing fluoropolymers. The film has an average reflectance of about 50% to about 100% in a near infrared wavelength range of about 850 nm to about 1850 nm, and an average transmission of about 70% to about 90% in a visible light range.

Abstract: A multilayer fluoropolymer film comprising, in order: a first layer comprising a first polymer, the first polymer comprising at least 35 mol percent tetrafluoroethylene comonomer, at least 15 mole percent vinylidene fluoride comonomer, and at least 5 mol percent hexafluoropropylene comonomer, based on the total mol percent of the first polymer; a second layer comprising a second polymer, the second polymer comprising at least 50 mol percent vinylidene fluoride comonomer, based on the total mol percent of the second polymer; and a third layer comprising a third polymer, the third polymer comprising at least 50 mol percent methylmethacrylate comonomer, based on the total mol percent of the third polymer. The multilayer fluoroplymer films are useful for example, in multi-layer film applications (e.g., traffic sign protection, commercial graphic protection, paint protection, windows, windshields, building exteriors, and photo voltaics).

Abstract: A light guide comprising a polymeric layer at least 25 percent transmissive over at least a 30 nm bandwidth in a wavelength range from 180 to 280 nm over a distance of at least 100 micrometers and visible light transparent reflecting layers (UV-C mirror) that are at least 50 percent reflective over at least 30 nm bandwidth in a wavelength range from 180 to 280 nm over an incident light angle of 0 to 90 degrees and that are at least 25 percent transmissive of visible light over at least 30 nm bandwidth in a wavelength range of 400 to 800 nm over an incident light angle of 0 to 90 degrees. The light guide is useful, for example, for antimicrobial surfaces.

Abstract: Multilayer optical film comprising at least a plurality of alternating first and second optical layers. Embodiments of the multilayer optical film are useful, for example, in UV-C shield, UV-C light collimator, and UV-C light concentrator applications.

Abstract: Surface structured articles comprising a polymer matrix and a dispersed phase, the article having first and second opposed major surfaces, at least a portion of the first major surface is a microstructured, anisotropic surface comprises features having at least one dimension in a range from 1 micrometer to 500 micrometers, wherein the dispersed phase comprises an antimicrobial material, and wherein at least a portion of the dispersed phase is present on the microstructured, anisotropic surface. Surface structured articles are useful, for example, for marine applications (e.g., surfaces in contact with water (e.g., fresh water, ocean water)) such as boats, ships, piers, oil rigs, decks, and roofing materials.

Abstract: Article comprising a transparent substrate having an anti-reflective, structured surface and a coating comprising a porous network of silica nanoparticles thereon, wherein the silica nanoparticles are bonded to adjacent silica nanoparticles.

Abstract: A film is described comprising a first film layer having a Tg ranging from 30° C. to 60° C. The first film layer comprises a (meth)acrylic polymer and polyvinyl acetal polymer composition. The film further comprises a second layer proximate the first film layer. The second layer is different than the first film layer. The second may be a cured (meth)acrylic polymer film or coating; a backing such as thermoplastic polymer, woven or nonwoven fabrics, metal foils, paper, foams; or a coverfilm such as a fluoropolymer.

Abstract: Anti-reflective article includes a layer defining an anti-reflective surface. The anti-reflective surface includes a series of alternating micro-peaks and micro-spaces extending along an axis. The surface also includes a series of nano-peaks extending along an axis. The nano-peaks are disposed at least on the micro-spaces and, optionally, the micro-peaks. The article may be disposed on a photovoltaic module or skylight to reduce reflections and resist the collection of dust and dirt.

Abstract: Various embodiments disclosed relate to multilayer films including hidden fluorescent features. The present disclosure includes a multilayer optical film including an isotropic multilayer optical film having first and second opposed major surfaces. The isotropic multilayer optical film reflects at least 50% of a light that is at least one of ultraviolet light or visible light, having an incident angle less than a cutoff angle from normal to the first major surface of the isotropic multilayer optical film, wherein the cutoff angle is in a range from 10° to 70°. The isotropic multilayer optical film allows at least 50% of the light having an incident angle of more than the cutoff angle from normal to the first major surface of the isotropic multilayer optical film to pass through the isotropic multilayer optical film. The isotropic multilayer optical film includes a marking on the second major surface of the isotropic multilayer optical film, the marking including at least one fluorescent compound.

Abstract: A passive cooling article is disposed on a substrate to cool the substrate. The article includes an outer layer having a high absorbance in the atmospheric window region of the electromagnetic spectrum and having a high transmittance in the solar region of the spectrum. The article also includes a reflector having a high reflectivity in the solar region of the spectrum. At least one of the outer layer and the reflector includes a fluoropolymer. Micro-sized particles or surface structures may be disposed in or on the outer layer or the reflector to improve absorbance. A metallic layer may be disposed between the fluoropolymer and the substrate to be cooled.

Abstract: Solar energy device comprising at least one of a photovoltaic cell or a solar thermal collector having an absorption bandwidth in the infrared wavelength region of the solar spectrum; a visible light-transmitting reflector; and at least one of a graphic film or lighted display. The graphic film or a lighted display present is visible through the visible light-transmitting reflector. The solar energy devices can be used, for example, as a sign (e.g., an advertising sign or a traffic sign), on the side and/or roof, as well as in a window, of a building.

Abstract: Light transparent fluoropolymer composition having less than 2 percent haze, comprising at least one of alkali metal (e.g., lithium, sodium, and potassium) cation, alkali metal (e.g., lithium, sodium, and potassium) and a corresponding anion (e.g., CO3,OH, OOCCH3), alkaline earth metal cation (e.g., calcium, magnesium, strontium, and barium), or alkaline earth metal cation (e.g., calcium, magnesium, strontium, and barium) and a corresponding anion (e.g., CO3,OH, OOCCH3), wherein the light transparent fluoropolymer has at least 90% visible light transmission. Exemplary uses of light transparent fluoropolymer compositions described herein include as films (e.g., solar reflective films, solar transparent frontside photovoltaic films, commercial graphic overlay film, commercial graphic film, and tubing (e.g., transparent tubing for medical)).

Abstract: A multilayer optical film includes alternating layers of first and second optical layers; the first optical layer comprising a first polyester, wherein the first polyester comprises first dicarboxylate monomers and first diol monomers, and from about 0.25 to less than 10 mol % of the first dicarboxylate monomers have pendant ionic groups; the second optical layer comprising a second polyester; and wherein the first and second optical layers have refractive indices along at least one axis that differ by at least 0.04. The multilayer optical film may be a polarizer film, a reflective polarizer film, a diffuse blend reflective polarizer film, a diffuser film, a brightness enhancing film, a turning film, a mirror film, or a combination thereof. The multilayer optical film may also be a transaction card such as a financial transaction card, an identification card, a key card, or a ticket card. A method of making the multilayer film is also disclosed.

Abstract: Multi-layer films, and processes to make the films, that enable the delivery of a substrate featuring a peelable thin layer of low haze, amorphous, isotropic film with the desired properties of high modulus, high usage temperature, UV blockage, and toughness The films are made using a co-extrusion, co-orientation and annealing process to enable the delivery of a thin isotropic, UV blocking layer on top of a release layer and support substrate. These film constructions can be kept together during additional processing steps such as coating and converting. The release and dimensionally stable substrate layer can be easily removed once processing steps are completed.

Abstract: Article comprising a transparent substrate having an anti-reflective, structured surface and a coating comprising a porous network of silica nanoparticles thereon, wherein the silica nanoparticles are bonded to adjacent silica nanoparticles.

Abstract: Provided are surfacing films that have a surface layer having opposed first and second major surfaces, the first major surface comprising a fluoropolymer surface and the second major surface optionally comprising a nanostructured surface. A printed layer can be disposed on the second major surface and can be at least partially embedded in the nanostructured surface, if present. As a further option, the fluoropolymer surface can be microreplicated to provide a frictional surface and/or provide aerodynamic drag reduction on aircraft structures. Optionally, the delamination peel strength of the surface layer from the remaining layers can be greater than the tensile strength of the surface layer.